Feldspar and Nepheline Syenite 2016
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Benefits of Utilizing Nepheline Syenite in Porcelain Tile
1 BENEFITS OF UTILIZING NEPHELINE SYENITE IN PORCELAIN TILE AND SANITARYWARE Anais do 48º Congresso Brasileiro de Cerâmica Proceedings of the 48th Annual Meeting of the Brazilian Ceramic Society 28 de junho a 1º de julho de 2004 – Curitiba-PR SCOTT E. BARTON UNIMIN CORPORATION 500 WILSON PIKE CIRCLE, SUITE 127 BRENTWOOD, TENNESSEE 37027 USA EXECUTIVE SUMMARY Nepheline syenite is a commercially prepared, rare feldspathoid-rich rock product that contributes both potassium and sodium oxides to the ceramic formulation. It has been used in both North America and Europe for the production of porcelain tile and sanitaryware for many years. It is the unique mineralogy and high levels of alkalis of nepheline syenite that justify its use in ceramics. These characteristics promote lower firing temperatures that can enhance productivity and lower production costs. Depending on location, the use of nepheline syenite can lower raw material cost by allowing more silica to be used in the formulation. Additionally, the process control found in most nepheline syenite operations offers a controlled level of Fe2O3 that can help to improve fired color. The goal of this study is to illustrate the practical benefits of using nepheline syenite for the vitrification in a ceramic body formulation. Keywords: nepheline syenite, porcelain, tile, feldspar, sanitaryware INTRODUCTION As the porcelain tile and sanitaryware industries continue to globalize, manufacturers must continually improve the control and quality of their raw materials to effectively compete on the global scale. To do so, many manufacturers must look not only at domestic materials but also at external sources for these important requirements of quality and consistency. -
Multiple Processes of Geochemical Evolution for the Alkaline Rocks Of
213213 https://doi.org/10.11606/issn.2316-9095.v20-151049 Revista do Instituto de Geociências - USP Geol. USP, Sér. cient., São Paulo, v. 20, n. 4, p. 221-214, Dezembro 2020 Multiple processes of geochemical evolution for the alkaline rocks of Rio Bonito intrusive complex, Rio de Janeiro State, Brazil: 40Ar/39Ar and U-Pb ages and Lu-Hf isotopes on zircon and constraints on crustal signature Múltiplos processos de evolução geoquímica para as rochas alcalinas do complexo intrusivo de Rio Bonito, Estado do Rio de Janeiro, Brasil: idades 40Ar/39Ar e U-Pb e isótopos Lu-Hf em zircão – considerações sobre assinatura crustal Daniel Adelino da Silva1 , Akihisa Motoki1Ϯ, Anderson Costa dos Santos1 , Julio Mendes2 , Fred Jourdan3 , Mauro César Geraldes1 , Cristiano de Carvalho Lana4 2Universidade do Estado do Rio de Janeiro - UERJ, Departamento de Mineralogia e Petrologia Ígnea, Rua São Francisco Xavier, 524, CEP 20550-900, Rio de Janeiro, RJ, BR ([email protected]; [email protected]; [email protected]); Ϯin memoriam. 2Universidade Federal do Rio de Janeiro - UFRJ, Instituto de Geociências, Rio de Janeiro, RJ, BR ([email protected]) 1University of Technology - GPO, Western Australian Argon Isotope Facility, Department of Applied Geology & JdL Centre, Curtin, Perth, Australia ([email protected]) 4Universidade Federal de Ouro Preto - UFOP, Isotope Geochemistry Laboratory, Ouro Preto, MG, BR ([email protected]) Received on October 22, 2028; accepted on November 6, 2020 Abstract This article presents geochemical characteristics of the alkaline rocks of Rio Bonito intrusive complex, State of Rio de Janeiro, Brazil, which is constituted mainly by nepheline syenite. -
Rare Earth Element Mobility During Conversion of Nepheline Syenite Into Lateritic Bauxite at Passa Quatro, Minais Gerais, Brazil B
Applied Geochemistry, Vol. 9, pp. 701-711,1994 Pergamon Copyright 01994 Elsevier Science Ltd Printed in Great Britain. All rights reserved 0883-2927/94 $7.00+0.00 0883-2927(94)E0025-5 Rare earth element mobility during conversion of nepheline syenite into lateritic bauxite at Passa Quatro, Minais Gerais, Brazil B. BOULANGÉand F. COLÌN- ORSTOM, UM GECO, Laboratoire de Géosciences de l’Environnement, Université Aix Marseille III, 13397 Marseille CBdex 20, France (Received 10 July 1992; accepted in revised form 4 May 1994) Abstract-In a lateritic bauxite formed by weathering of nepheline syenite at Passa Quatro, Minas Gerais State, Brazil, bauxites on the hill-tops directly develop from the syenite bed-rock, while downslope, a kaolinitic layer occurs between bauxite and syenite. A petrological investigation was performed on undisturbed weathered rock samples collected from a representative upslope pit. The undisturbed weathered rocks were chemically analysed for major and trace elements including REE and Zr. Mass balance calculations were applied, and the behaviour of the REE in the Passa Quatro weathering system was established compared to REE reference chondrite and to REE reference parent rock. In the lateritic bauxite, the results suggest that the first stages of weathering induce a volumetric change of 50%, i.e. collapse, with respect to the parent rock, and remove REE with a slightly larger loss of the LREE, except Ce, compared to the HREE. In the upper layers, where bauxite is more mature, a net mass gain in REE is observed relative to the underlying layers. This gain takes place during the reduction of the upper layer during the downward progression of the weathering front. -
Petro-Geochemistry, Genesis and Economic Aspect of Syenitic and Mafic Rocks in Mindif Complex, Far North Cameroon, Central Africa
International Journal of Geosciences, 2019, 10, 1081-1114 https://www.scirp.org/journal/ijg ISSN Online: 2156-8367 ISSN Print: 2156-8359 Petro-Geochemistry, Genesis and Economic Aspect of Syenitic and Mafic Rocks in Mindif Complex, Far North Cameroon, Central Africa Nguo Sylvestre Kanouo1*, Lianxun Wang2, Arnaud Patrice Kouske3, Syprien Bovari Yomeun2, Emmanuel Archelaus Afanga Basua2 1Mineral Exploration and Ore Genesis Unit, Department of Mining Engineering and Mineral Processing, Faculty of Mines and Petroleum Industries, University of Maroua, Maroua, Cameroon 2School of Earth Sciences, China University of Geosciences, Wuhan, China 3Department of Civil Engineering, The University Institute of Technology, University of Douala, Douala, Cameroon How to cite this paper: Kanouo, N.S., Abstract Wang, L., Kouske, A.P., Yomeun, S.B. and Basua, E.A.A. (2019) Petro-Geochemistry, Syenitic and mafic rocks in Mindif Complex (Far North of Cameroon) were Genesis and Economic Aspect of Syenitic surveyed and characterized to classify them, understand their formation his- and Mafic Rocks in Mindif Complex, Far tory, and assess their economic interest. Syenitic bodies (hololeucocratic North Cameroon, Central Africa. Interna- tional Journal of Geosciences, 10, 1081-1114. microsyenites; mesocratic aplitic quartz-syenite; leucocratic porphyritic https://doi.org/10.4236/ijg.2019.1012062 quartz-biotite syenite, and leucocratic porphyritic biotite-syenite) are sili- ca-oversaturated to silica-saturated, alkaline, and metaluminous. Hololeu- Received: June 16, 2019 cocratic microsyenites are structural oriented rocks, cooled in shallow Accepted: December 6, 2019 Published: December 9, 2019 depth from low trace and REE dry residual alkaline melts. Mesocratic ap- litic quartz-syenite also crystallized in shallow depth from a much Ba-rich Copyright © 2019 by author(s) and less dry residual melt. -
Nepheline Syenite from Lyle Lake, Peter Lake Domain (NTS 64E-06) 1
Nepheline Syenite from Lyle Lake, Peter Lake Domain (NTS 64E-06) 1 David H. Quiff Quirt, D.H. (1992): Nepheline syenite from Lyle Lake, Peter Lake Domain (NTS 64E-06); in Summary of Investigations 1992, Sas katchewan Geological Survey, Sask. Energy Mines, Misc. Rep. 92-4. The Peter Lake Domain nepheline and nepheline-biotite The region has been geologically mapped by the Sas sodalite syenite occurrence located at Lyle Lake, Sas katchewan Geological Survey at 1:50 CXX> scale (Lewry, katchewan (NTS 64E-06; UTM 613000E 6366000N; Fig 1976; Lewry et al., 1980); the Lyle Lake area being ure 1) is the only known example of silica-under mapped as metadiorite and monzonite with syenite. saturated felsic magmatism in Saskatchewan. This MacDougall (1987) mapped the region immediately report presents new geological, petrological, and south of Lyle Lake at 1:20 000 scale. The nepheline mineralogical data about these rocks. syenite occurrence was discovered in 1982 during the course of off-property mineral exploration by the Sas katchewan Mining and Develop ment Corporation (now Cameco; Wittrup, 1983; Waterman et al., 1984). MacDougall (1987) briefly noted the presence of under saturated rocks in the Lyle Lake area. The nepheline syenite is found near the Lyle Lake pluton, a Hud sonian post-deformational granitic intrusion (MacDougall, 1987) ATHABASCA BASIN situated within the Archean Peter Lake Domain close to the bound 58' ary with the Hudsonian Wathaman / ,,,. ; Batholith. The Peter Lake Domain ' consists of massive to weakly foliated felsic plutonic rocks and a diorite-gabbroic plutonic suite which together have a complex Ar chean intrusion history (Lewry er al., 1980; Ray and Wanless, 1980; Annesley et al., 1992). -
FELDSPAR and NEPHELINE SYENITE by Michael J
FELDSPAR AND NEPHELINE SYENITE By Michael J. Potter Domestic survey data and tables were prepared by Hoa P. Phamdang, statistical assistant, and the world production table was prepared by Glenn J. Wallace, international data coordinator. Feldspars are the Earth’s most abundant mineral group, The value of total feldspar sold or used in table 4 is higher than estimated to constitute 60% of the earth’s crust (Kauffman and the feldspar production value shown in tables 1 and 2. The sold Van Dyk, 1994). They are aluminum silicate minerals that or used value represents the final marketed feldspar product. contain varying proportions of calcium, potassium, and sodium. The unit value of $65.27 per metric ton for the “pottery and Nepheline syenite is a light-colored, silica-deficient feldspathic miscellaneous” category in table 4 is less than the price range rock made up mostly of sodium and potassium feldspars and for ceramic-grade feldspar in table 5. However, the latter is nepheline; although not mined in the United States in 2002, it was stated by the publisher to be intended to serve only as a guide. imported from Canada for use in the glass and ceramic industries. World Review.—Canada.—Avalon Ventures Ltd. continued work on its high-lithium feldspar Separation Rapids project Feldspar in Kenora, Ontario. Project engineering and feasibility study work focused on process flowsheet design and transportation In glassmaking, alumina from feldspar improves product studies. To further evaluate a new dry process flowsheet, a 5-t hardness, durability, and resistance to chemical corrosion. In ore sample was collected for shipment to a test milling facility. -
The Red Syenite of the Pilanesberg Complex As a Nepheline Source for the South African Ceramics and Glass Industry
University of Pretoria etd Pantshi B 2006 The Red Syenite of the Pilanesberg Complex as a nepheline source for the South African ceramics and glass industry. By Bukiwe Pantshi Submitted in partial fulfilment of the requirements For the MSc in Earth Science Practice and Management In the Faculty of Natural and Agricultural Sciences. University of Pretoria March 2006 University of Pretoria etd Pantshi B 2006 CONTENTS Page ABSTRACT 5 1. INTRODUCTION 6 1.1. Statement of question 6 1.2. The hypothesis 7 1.3. Assumptions 7 1.4. Purpose of the study 7 1.5. Acknowledgements 8 2. REVIEW OF RELATED LITERATURE 9 2.1. Geology of the Pilanesberg Complex 9 2.1.1. Red Foyaite 11 2.1.2. White & Grey Foyaite 12 2.1.3. Tinguaite 13 2.1.4. Green Foyaite 13 2.1.5. Ledig Foyaite 14 2.1.6. Red Syenite 14 2.1.7. Volcanic rocks 15 2.2. Age of the plutonic rocks 15 2.3. Mineral potential of the Pilanesberg 16 2.3.1. Gold 16 2.3.2. Rare earth Elements 16 2.3.3. Dimension Stone 17 3. GENERAL DISCUSSION OF NEPHELINE AND ASSOCIATED DEPOSITS 18 3.1. Characteristics of nepheline 18 3.2. Classification of nepheline syenite ore deposits 19 3.3. Distribution of nepheline syenite deposits 19 3.3.1. Two deposits described for beneficiation 21 3.3.1.1. Table Mountain Deposit, Oregon 21 3.3.1.2. Bulls Run Syenite Complex, South Africa 22 3.4. Evaluation of raw material required in ceramics and glass 22 3.4.1. -
Crystallization and Metasomatism of Nepheline Syenite Xenoliths in Quartz-Bearing Intrusive Rocks in the Permian Oslo Rift, SE Norway
Crystallization and metasomatism of nepheline syenite xenoliths in quartz-bearing intrusive rocks in the Permian Oslo rift, SE Norway TOM ANDERSEN & HENNING SØRENSEN Andersen, T. & Sørensen, H.: Crystallization and metasomatism of nepheline syenite xenoliths in quartz-bearing intrusive rocks in the Permian Oslo rift, SE Norway. Norsk Geologisk Tidsskrift, Vol. 73, pp. 250-266. Oslo 1993. ISSN 0029-196X. Small bodies of metasomatized nepheline syenite occur as xenoliths in syenitic and granitic intrusions in the Mykle area, ca. 30 km N of the Larvik pluton in the Vestfold Graben of the late Paleozoic Qslo rift of SE Norway. The nepheline syenite has a metaluminous major element composition, and its primary igneous mineralogy is: alkali feldspar + nepheline + clinopyroxene + titanite + magnetite + apatite ± amphibole. The mafic silicate minerals have lower (Na + K)/AI than comparable minerals in other fe lsic intrusions in the Oslo Rift. Gamet (grossular-andradite), analcime, sodalite, thomsonite and gonnardite occur as interstitial minerals in the )east altered parts of the nepheline syenite. The xenoliths were metasomatized as a result of interaction between nepheline syenite and younger silica-saturated to oversaturated magrnas and their associated fluids. Early, pervasive metasomatism led to breakdown of nepheline, replacement of pyroxene by biotite ± garnet and crystallization of quartz. Recrystallization took place at solidus-near temperatures (700-725°C), and was controlled by an increase in silica activity and oxygen fugacity. Titanite + magnetite were replaced by rutile + quartz + hematite + calcite at a late stage of the metasomatic history, at oxygen fugacities above the HM buffer, and T < 450°C. The xenoliths indicate the former presence of larger bodies of nepheline syenite in an area where no such rocks were known previously. -
Unusual Silicate Mineralization in Fumarolic Sublimates of the Tolbachik Volcano, Kamchatka, Russia – Part 2: Tectosilicates
Eur. J. Mineral., 32, 121–136, 2020 https://doi.org/10.5194/ejm-32-121-2020 © Author(s) 2020. This work is distributed under the Creative Commons Attribution 4.0 License. Unusual silicate mineralization in fumarolic sublimates of the Tolbachik volcano, Kamchatka, Russia – Part 2: Tectosilicates Nadezhda V. Shchipalkina1, Igor V. Pekov1, Natalia N. Koshlyakova1, Sergey N. Britvin2,3, Natalia V. Zubkova1, Dmitry A. Varlamov4, and Eugeny G. Sidorov5 1Faculty of Geology, Moscow State University, Vorobievy Gory, 119991 Moscow, Russia 2Department of Crystallography, St Petersburg State University, University Embankment 7/9, 199034 St. Petersburg, Russia 3Kola Science Center of Russian Academy of Sciences, Fersman Str. 14, 184200 Apatity, Russia 4Institute of Experimental Mineralogy, Russian Academy of Sciences, Akademika Osypyana ul., 4, 142432 Chernogolovka, Russia 5Institute of Volcanology and Seismology, Far Eastern Branch of Russian Academy of Sciences, Piip Boulevard 9, 683006 Petropavlovsk-Kamchatsky, Russia Correspondence: Nadezhda V. Shchipalkina ([email protected]) Received: 19 June 2019 – Accepted: 1 November 2019 – Published: 29 January 2020 Abstract. This second of two companion articles devoted to silicate mineralization in fumaroles of the Tol- bachik volcano (Kamchatka, Russia) reports data on chemistry, crystal chemistry and occurrence of tectosil- icates: sanidine, anorthoclase, ferrisanidine, albite, anorthite, barium feldspar, leucite, nepheline, kalsilite, so- dalite and hauyne. Chemical and genetic features of fumarolic silicates are also summarized and discussed. These minerals are typically enriched with “ore” elements (As, Cu, Zn, Sn, Mo, W). Significant admixture of 5C As (up to 36 wt % As2O5 in sanidine) substituting Si is the most characteristic. Hauyne contains up to 4.2 wt % MoO3 and up to 1.7 wt % WO3. -
NI 43-101 Songwe REE Deposit
NI 43-101 Technical Report and Mineral Resource Estimate for the Songwe Hill Rare Earth Element (REE) Project, Phalombe District, Republic of Malawi Prepared by The MSA Group (Pty) Ltd for: Mkango Resources Ltd Authors: Scott Swinden Consulting Geologist Ph.D., P.Geo. Michael Hall Consulting Geologist Resources Pr.Sci.Nat., MAusIMM Effective Date: September 30, 2012 Date of Signature: November 22, 2012 Table of Contents 1 Summary......................................................................................................................................... viii 1.1 Introduction.............................................................................................................................viii 1.2 Property, Location and Ownership.........................................................................................viii 1.3 Geology and Mineralization....................................................................................................viii 1.4 Status of Exploration ................................................................................................................ix 1.5 Mineral Resources.................................................................................................................... x 1.6 Conclusions and Recommendations........................................................................................xi 2 Introduction..................................................................................................................................... 12 2.1 Scope of Work -
Alkaline Magmas in Zones of Continental Convergence
1 Alkaline magmas in zones of continental convergence: 2 The Tezhsar volcano-intrusive ring complex, Armenia 3 4 Krzysztof Sokół1,2, Ralf Halama1*, Khachatur Meliksetian3, Ivan 5 P. Savov4, Gevorg Navasardyan3, Masafumi Sudo5 6 7 1 School of Geography, Geology and the Environment, Keele University, Keele, ST5 5BG, 8 United Kingdom 9 2 (Present address) School of Earth and Environmental Sciences, University of St Andrews, 10 St Andrews, KY16 9AL, United Kingdom 11 3 Institute of Geological Sciences, Armenian National Academy of Sciences, 24a Marshal 12 Baghramian Avenue, 0019, Yerevan, Republic of Armenia 13 4 School of Earth and Environment, University of Leeds, Leeds, LS2 9JT, United Kingdom 14 5 Institute of Earth and Environmental Science, University of Potsdam, Karl-Liebknecht- 15 Str. 24-25, 14476 Potsdam, Germany 16 17 * Corresponding author contact information: 18 Ralf Halama 19 School of Geography, Geology and the Environment 20 Keele University 21 Keele, ST5 5BG, United Kingdom 22 E-mail: [email protected] 23 Phone: +44 (0) 1782 7 34960 1 24 Abstract 25 Alkaline igneous rocks are relatively rare in settings of tectonic convergence and little 26 is known about their petrogenesis in these settings. This study aims to contribute to a 27 better understanding of the formation of alkaline igneous rocks by an investigation of the 28 Tezhsar volcano-intrusive alkaline ring complex (TAC) in the Armenian Lesser Caucasus, 29 which is located between the converging Eurasian and Arabian plates. We present new 30 petrological, geochemical and Sr-Nd isotope data for the TAC to constrain magma genesis 31 and magma source characteristics. -
Production, Reserves, and Processing of Feldspar and Feldspathoid Rocks in the Czech Republic from 2005 to 2019—An Overview
minerals Article Production, Reserves, and Processing of Feldspar and Feldspathoid Rocks in the Czech Republic from 2005 to 2019—An Overview Jan Zahradník 1,2 , Jakub Jirásek 3,*, Jaromír Starý 4 and Martin Sivek 2 1 LB MINERALS, s.r.o., Tovární 431, 330 12 Horní Bˇríza, Czech Republic; [email protected] 2 Department of Geological Engineering, Faculty of Mining and Geology, Vysoká Škola Báˇnská-Technical University of Ostrava, 17. listopadu 15/2172, 708 00 Ostrava-Poruba, Czech Republic; [email protected] 3 Department of Geology, Faculty of Science, Palacký University Olomouc, 17. listopadu 1192/12, 771 46 Olomouc, Czech Republic 4 Czech Geological Survey, Klárov 3, 118 21 Praha, Czech Republic; [email protected] * Correspondence: [email protected] Received: 5 July 2020; Accepted: 10 August 2020; Published: 17 August 2020 Abstract: This paper aims to characterize and interpret the trends in reserves, resources, and mine production of feldspar and feldspathoid rocks during 2005–2019 in the Czech Republic. With over 101 Mt of total resources and 22 Mt of reserves, feldspar belongs to the crucial industrial minerals of the Czech Republic. With annual outputs of approximately 400–450 kt of feldspars and 20–35 kt of feldspathoid rocks (nepheline syenite), the Czech Republic ranks among the top European and world feldspar producers. Most of the production comes from leucocratic granitoid rocks (key active deposit: Krásno-Vysoký Kámen), followed by sedimentary rocks (key active deposit: Halámky), and granitic pegmatites (key active deposit: Luženiˇcky).Nepheline syenite is mined at a single deposit. All deposits are extracted from open pits (quarries).