Extremely Hazardous Substances
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Carbamate Pesticides Aldicarb Aldicarb Sulfoxide Aldicarb Sulfone
Connecticut General Statutes Sec 19a-29a requires the Commissioner of Public Health to annually publish a list setting forth all analytes and matrices for which certification for testing is required. Connecticut ELCP Drinking Water Analytes Revised 05/31/2018 Microbiology Total Coliforms Fecal Coliforms/ E. Coli Carbamate Pesticides Legionella Aldicarb Cryptosporidium Aldicarb Sulfoxide Giardia Aldicarb Sulfone Carbaryl Physicals Carbofuran Turbidity 3-Hydroxycarbofuran pH Methomyl Conductivity Oxamyl (Vydate) Minerals Chlorinated Herbicides Alkalinity, as CaCO3 2,4-D Bromide Dalapon Chloride Dicamba Chlorine, free residual Dinoseb Chlorine, total residual Endothall Fluoride Picloram Hardness, Calcium as Pentachlorophenol CaCO3 Hardness, Total as CaCO3 Silica Chlorinated Pesticides/PCB's Sulfate Aldrin Chlordane (Technical) Nutrients Dieldrin Endrin Ammonia Heptachlor Nitrate Heptachlor Epoxide Nitrite Lindane (gamma-BHC) o-Phosphate Metolachlor Total Phosphorus Methoxychlor PCB's (individual aroclors) Note 1 PCB's (as decachlorobiphenyl) Note 1 Demands Toxaphene TOC Nitrogen-Phosphorus Compounds Alachlor Metals Atrazine Aluminum Butachlor Antimony Diquat Arsenic Glyphosate Barium Metribuzin Beryllium Paraquat Boron Propachlor Cadmium Simazine Calcium Chromium Copper SVOC's Iron Benzo(a)pyrene Lead bis-(2-ethylhexyl)phthalate Magnesium bis-(ethylhexyl)adipate Manganese Hexachlorobenzene Mercury Hexachlorocyclopentadiene Molybdenum Nickel Potassium Miscellaneous Organics Selenium Dibromochloropropane (DBCP) Silver Ethylene Dibromide (EDB) -
Background Document on Cadmium ______
Hazardous Substances Series -------------------------------------------------------------------------------------------------------------------------------------------- Cadmium OSPAR Commission 2002 (2004 Update) OSPAR Commission, 2002: OSPAR Background Document on Cadmium _______________________________________________________________________________________________________ The Convention for the Protection of the Marine Environment of the North-East Atlantic (the “OSPAR Convention”) was opened for signature at the Ministerial Meeting of the former Oslo and Paris Commissions in Paris on 22 September 1992. The Convention entered into force on 25 March 1998. It has been ratified by Belgium, Denmark, Finland, France, Germany, Iceland, Ireland, Luxembourg, Netherlands, Norway, Portugal, Sweden, Switzerland and the United Kingdom and approved by the European Community and Spain. La Convention pour la protection du milieu marin de l'Atlantique du Nord-Est, dite Convention OSPAR, a été ouverte à la signature à la réunion ministérielle des anciennes Commissions d'Oslo et de Paris, à Paris le 22 septembre 1992. La Convention est entrée en vigueur le 25 mars 1998. La Convention a été ratifiée par l'Allemagne, la Belgique, le Danemark, la Finlande, la France, l’Irlande, l’Islande, le Luxembourg, la Norvège, les Pays-Bas, le Portugal, le Royaume-Uni de Grande Bretagne et d’Irlande du Nord, la Suède et la Suisse et approuvée par la Communauté européenne et l’Espagne. © OSPAR Commission, 2002. Permission may be granted by the publishers for the report to be wholly or partly reproduced in publications provided that the source of the extract is clearly indicated. © Commission OSPAR, 2002. La reproduction de tout ou partie de ce rapport dans une publication peut être autorisée par l’Editeur, sous réserve que l’origine de l’extrait soit clairement mentionnée. -
"U/^ ((*.U \ BIBLIOTHEEK STARINGGEBOUW Volatilization of Tri-Allate, Ethoprophos and Parathion Measured with Four Methods After Spraying on a Sandy Soil
"u/^ ((*.u \ BIBLIOTHEEK STARINGGEBOUW Volatilization of tri-allate, ethoprophos and parathion measured with four methods after spraying on a sandy soil G. Bor F. van den Berg J.H. Smelt R.A. Smidt A.E. van de Peppel-Groen M. Leistra Report 104 DLO Winand Staring Centre, Wageningen (The Netherlands), 1995 1 h FEB. 1998 0000' ABSTRACT Bor, G., F. van den Berg, J.H. Smelt, R.A. Smidt, A.E. van de Peppel-Groen, M. Leistra, 1995. Volatilization of tri-allate, ethoprophos and parathion measured withfour methods after spraying on a sandy soil. Wageningen (The Netherlands), DLO Winand Staring Centre. Report 104. 62 pp.; 9 Figs; 6 Tables; 14 Refs; 3 Annex. At about eleven times after application of tri-allate, ethoprophos and parathion to a sandy soil, their rates of volatilization were determined with the aerodynamic method (AD),th e Bowen-ratio method (BR), the theoretical-profile method (TP) and the Box method (B). The volatilization was highest for tri-allate and lowest for parathion. On the first day after application, the volatilization rate decreased sharply,bu tthereafte r the decreasewa smor egradual .Th edifference s involatilizatio n rate asdetermine d withth eAD ,B R andT Pmethod s werecomparativel y small.Th erate sdetermine d with the Box method were mostly lower than those determined with the other methods. Keywords: aerodynamic method, air quality, air sampling, Bowen ratio method, Box method, field experiment, gas chromatography, pesticide, polystyrene, theoretical-profile method, XAD ISSN 0927-4537 ©1995 DLO Winand Staring Centre for Integrated Land, Soil and Water Research (SC-DLO) P.O. -
COMBINED LIST of Particularly Hazardous Substances
COMBINED LIST of Particularly Hazardous Substances revised 2/4/2021 IARC list 1 are Carcinogenic to humans list compiled by Hector Acuna, UCSB IARC list Group 2A Probably carcinogenic to humans IARC list Group 2B Possibly carcinogenic to humans If any of the chemicals listed below are used in your research then complete a Standard Operating Procedure (SOP) for the product as described in the Chemical Hygiene Plan. Prop 65 known to cause cancer or reproductive toxicity Material(s) not on the list does not preclude one from completing an SOP. Other extremely toxic chemicals KNOWN Carcinogens from National Toxicology Program (NTP) or other high hazards will require the development of an SOP. Red= added in 2020 or status change Reasonably Anticipated NTP EPA Haz list COMBINED LIST of Particularly Hazardous Substances CAS Source from where the material is listed. 6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10- hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide Acutely Toxic Methanimidamide, N,N-dimethyl-N'-[2-methyl-4-[[(methylamino)carbonyl]oxy]phenyl]- Acutely Toxic 1-(2-Chloroethyl)-3-(4-methylcyclohexyl)-1-nitrosourea (Methyl-CCNU) Prop 65 KNOWN Carcinogens NTP 1-(2-Chloroethyl)-3-cyclohexyl-1-nitrosourea (CCNU) IARC list Group 2A Reasonably Anticipated NTP 1-(2-Chloroethyl)-3-cyclohexyl-1-nitrosourea (CCNU) (Lomustine) Prop 65 1-(o-Chlorophenyl)thiourea Acutely Toxic 1,1,1,2-Tetrachloroethane IARC list Group 2B 1,1,2,2-Tetrachloroethane Prop 65 IARC list Group 2B 1,1-Dichloro-2,2-bis(p -chloropheny)ethylene (DDE) Prop 65 1,1-Dichloroethane -
Calarp) Program
California Accidental Release Prevention (CalARP) Program Administering Agency Guidance January 31, 2005 Preface This document provides general guidance to help Administering Agencies (AAs) implement and enforce the California Accidental Release Prevention (CalARP) Program. The intent is to identify the elements of the Program applicable to each regulated business, and assist AAs with oversight of the CalARP Program statutes and regulations. This document is not a substitute for the CalARP Program regulations; it does not impose legally binding requirements. About This Document This document follows the format of the California Code of Regulations, Title 19, Division 2, Chapter 4.5: California Accidental Release Prevention (CalARP) Program. The regulatory sections are presented in parentheses for ease of reference. Acknowledgements The California Emergency Management Agency (Cal EMA) would like to thank the following people for their valuable assistance in the preparation of this document: Howard Wines, Hazardous Materials Specialist, City of Bakersfield Fire Department Robert Distaso P.E., Fire Safety Engineer, Orange County Fire Authority Randall L. Sawyer, Supervisor, Accidental Release Prevention Programs, Contra Costa County Health Services Department Beronia Beniamine, Senior Hazardous Materials Specialist, Stanislaus County Environmental Resources Department Angie Proboszcz, Risk Management Program Coordinator, USEPA Region 9 Jon Christenson, Senior Environmental Health Specialist, Merced County Department of Public Health Teresa -
Florida State Emergency Response Commission
Florida State Emergency Response Commission Sub-Committee on Training (SOT) HAZARDOUS MATERIALS MEDICAL TREATMENT PROTOCOLS Version 3.3 TOXIDROMES Toxidromes are clinical syndromes that the patient presents with. These patterns of signs and symptoms are essential for the successful recognition of chemical exposure. The toxidromes identified in this protocol are chemical exposure based while others such as the opioids are found within general medical protocol. These chemical toxidromes are identified clinically into five syndromes: Irritant Gas Toxidrome Asphyxiant Toxidrome Corrosive Toxidrome Hydrocarbon and Halogenated Hydrocarbons Toxidrome Cholinergic Toxidrome Each can present as a clinical manifestation of the chemical/poisoning involved with some cross-over between toxidromes. This list combines the toxic syndromes found within NFPA 473 (A.5.4.1(2) and traditional syndromes. Toxidrome Correlation to NFPA Standard 473 and Traditional Syndromes Toxidrome NFPA 473 A.5.4.1(2) Hazardous Materials Protocol Correlation Irritant Gas (j) Irritants Bronchospasm OC Pepper spray & lacrimants Asphyxiant (c) Chemical asphyxiants Carbon Monoxide (d) Simple asphyxiants Aniline dyes, Nitriles, Nitrares (h) Blood Agents Cyanide & Hydrogen Sulfide (n) Nitrogen Compounds Closed Space Fires Simple Asphyxants Corrosive (a) Corrosives Hydrofluroic Acid (g) Vesicants Chemical burns to the eye Choramine and Chlorine Hydrocarbon (e) Organic solvents Phenol and (q) Phenolic Compounds Halogenated Hydrocarbons Halogenated Hydrocarbons Cholinergic (b) Pesticides -
EPA Method 538: Determination of Selected Organic Contaminants in Drinking Water with Direct Aqueous Injection LC/MS/MS
EPA Method 538: Determination of Selected Organic Contaminants in Drinking Water with Direct Aqueous Injection LC/MS/MS E. Michael Thurman and Imma Ferrer Center for Environmental Mass Spectrometry University of Colorado Boulder, CO, USA Confidentiality Label 1 March 20, 2012 Abstract EPA Method 538 is a new method from EPA for organophosphate pesticides in drinking water. It uses direct aqueous injection; thus, no sample preparation is needed. We use both UHPLC (Agilent 1290) and MS/MS (Agilent 6460) analysis for rapid analysis and sensitive detection with ng/L limits of detection. A second MRM is added for more reliable identification. Confidentiality Label 2 March 20, 2012 Hypothesis Direct injection of organophosphate pesticides (EPA Method 538) will work by UHPLC (Agilent Model 1290) and LC/MS/MS with Jetstream (Agilent Model 6460) with trace level detection at ng/L concentrations. Confidentiality Label 3 March 20, 2012 1. Introduction-Summary 1.1 EPA Method 538 (published in November 2009 by Shoemaker) deals with Organophosphate pesticides in drinking water (1) and one other contaminant, quinoline. 1.2 The method consists of 10 compounds: acephate, aldicarb, aldicarb sulfoxide, dicrotophos, diisopropylmethylphosphonate (DIMP), fenamiphos sulfone, fenamiphos sulfoxide, methamidophos, oxydemeton methyl, quinoline, and thiofanox with 5 labeled internal standards. 1.3 Direct aqueous injection is used with a large volume sample of 100 microliters; thus, no sample preparation is needed. 1.4 Because solid phase extraction (i.e. concentration of the sample is not carried out) suppression is mimimized in the analysis. 1.5 Part-per-Trillion Detection Limits. Confidentiality Label 4 March 20, 2012 Introduction 1.1: EPA Method 538: Determination of Selected Organic Contaminants in Drinking Water by Direct Aqueous Injection by Jody Shoemaker, EPA Cincinnati, OH [email protected] 513-569-7298 Confidentiality Label 5 March 20, 2012 Introduction: 1.2. -
EPA Method 538: Determination of Selected Organic Contaminants in Drinking Water by Aqueous Direct Injection and LC/MS/MS Summar
EPA Method 538: Determination of Selected Organic Contaminants in Drinking Water by Aqueous Direct Injection and LC/MS/MS UCT Part Numbers: SLAQ100ID21-3UM - Selectra® Aqueous C18, 100 x 2.1mm, 3µm SLAQGDC20-3UM - Selectra® Aqueous C18, Guard column, 10 x 2.0mm, 3µm SLGRDHLDR - Guard Cartridge Holder June 2015 Summary: This application outlines a direct aqueous injection-liquid chromatography/tandem mass spectrometry (DAI-LC/MS/MS) method for the determination of 11 selected organic contaminants in drinking water, including methamidophos, acephate, aldicarb sulfoxide, oxydemeton methyl, dicrotophos, aldicarb, diisopropyl methylphosphonate (DIMP), fenamiphos sulfone, fenamiphos sulfoxide, thiofanox, and quinoline [1]. Dicrotophos, oxydemeton methyl, methamidophos, and acephate are UCMR4 compounds. An Aqueous C18 HPLC column was utilized for analyte retention and separation. Calibration curves were constructed using calibration standards prepared in reagent water with preservative reagents for analyte quantitation. The responses were linear over the entire analytical ranges (R2 ≥ 0.9970). Excellent accuracy (90 - 111%) and precision (RSD% < 20%, n=7) were achieved for fortified reagent water and tap water samples. Procedure: 1. Preserve drinking water sample with 64 mg/L of sodium omadine (antimicrobial) and 1.5 g/L of ammonium acetate (binding free chlorine). 2. Mix 0.99 mL of the preserved water sample with 10 μL of 0.4-12.5 ng/μL internal standard mixture, and vortex for 30 sec. 3. Inject 50 μL onto LC/MS/MS equipped with an aqueous -
Phytotoxicity of Some Organophosphate Insecticides to Oughly with Air Dry, Sieved Soil, to Pro Duce Rates of 37.5, 75 and ISO Mg Aj
Plant Protection Quarterly VoI.7(1} 1992 23 -------------------------------- ties of each pesticide were shaken thor Phytotoxicity of some organophosphate insecticides to oughly with air dry, sieved soil, to pro duce rates of 37.5, 75 and ISO mg aj. L-' onions and carrots during germination and emergence soil. Each pot constituted one plot. If it is assumed that in a field situation, P.J. Sinclair, New South Wales Agriculture, Horticultural Research and band-in-furrow treatment would treat a Advisory Station, Griffith, New South Wales 2680, Australia. strip 50 mm wide by 20 mm deep, the rates tested would correspond to 37.5, 75 R.J. Neeson and P.A. Williams, New South Wales Agriculture, Agricultural and 150 mg a.i. m" row, or 0.5,1.0 and 2.0 institute, Yanco, New South Wales 2703, Australia. kg a.i. ha" at a row spacing of 75 cm. The low and medium rates are then compara Summary ble to ra tes used in the field by Getzin The phytotoxicity of some commonly phytotoxicity from carbofuran applied to (1973), Thompson et al. (1981) and used insecticides to onions (Allium cepa) onions as a seed dressing. Chlorpyrifos is Goodyer et al. (1989) . and carrots (Daucus carota) during es generally non-phytotoxic at recom Daily counts of emerged seedlings were tablishment was assessed in pot trials. mended rates and methods of application, made at 7 to 18 days and at 21 days after Terbufos, ethoprophos, phoxirn and but some crops are especially sensitive to first watering. These data were used to de carbofuran (all 10% a.L granular fonnu it during the seedling stage or if the termine the total number of seedlings lations) and chlorpyrifos (25% a.i. -
Polyvinyl Chloride - Wikipedia Polyvinyl Chloride
1/24/2020 Polyvinyl chloride - Wikipedia Polyvinyl chloride Polyvinyl chloride (/ˌpɒlivaɪnəl ˈklɔːraɪd/;[5] colloquial: Polyvinyl chloride polyvinyl, vinyl;[6] abbreviated: PVC) is the world's third-most widely produced synthetic plastic polymer, after polyethylene and polypropylene.[7] About 40 million tonnes are produced per year. PVC comes in two basic forms: rigid (sometimes abbreviated as RPVC) and flexible. The rigid form of PVC is used in construction for pipe and in profile applications such as doors and windows. It is also used in making bottles, non-food packaging, food-covering sheets,[8] and cards (such as bank or membership cards). It can be made softer and more flexible by the addition of plasticizers, the most widely used being phthalates. In this form, it is also used in plumbing, electrical cable insulation, imitation leather, flooring, signage, phonograph records,[9] inflatable products, and many applications where it replaces rubber.[10] With cotton or linen, it is used to make canvas. Pure polyvinyl chloride is a white, brittle solid. It is insoluble in alcohol but slightly soluble in tetrahydrofuran. Contents Discovery Production Microstructure Names Producers IUPAC name Additives poly(1-chloroethylene)[1] Phthalate plasticizers Di-2ethylhexylphthalate Other names Metal stabilizers Polychloroethylene Heat stabilizers Identifiers Properties CAS Number 9002-86-2 (http://ww Mechanical w.commonchemistry. Thermal and fire org/ChemicalDetail.a Electrical spx?ref=9002-86-2) Chemical Abbreviations PVC Applications ChEBI CHEBI:53243 -
Veterinary Toxicology
GINTARAS DAUNORAS VETERINARY TOXICOLOGY Lecture notes and classes works Study kit for LUHS Veterinary Faculty Foreign Students LSMU LEIDYBOS NAMAI, KAUNAS 2012 Lietuvos sveikatos moksl ų universitetas Veterinarijos akademija Neužkre čiam ųjų lig ų katedra Gintaras Daunoras VETERINARIN Ė TOKSIKOLOGIJA Paskait ų konspektai ir praktikos darb ų aprašai Mokomoji knyga LSMU Veterinarijos fakulteto užsienio studentams LSMU LEIDYBOS NAMAI, KAUNAS 2012 UDK Dau Apsvarstyta: LSMU VA Veterinarijos fakulteto Neužkre čiam ųjų lig ų katedros pos ėdyje, 2012 m. rugs ėjo 20 d., protokolo Nr. 01 LSMU VA Veterinarijos fakulteto tarybos pos ėdyje, 2012 m. rugs ėjo 28 d., protokolo Nr. 08 Recenzavo: doc. dr. Alius Pockevi čius LSMU VA Užkre čiam ųjų lig ų katedra dr. Aidas Grigonis LSMU VA Neužkre čiam ųjų lig ų katedra CONTENTS Introduction ……………………………………………………………………………………… 7 SECTION I. Lecture notes ………………………………………………………………………. 8 1. GENERAL VETERINARY TOXICOLOGY ……….……………………………………….. 8 1.1. Veterinary toxicology aims and tasks ……………………………………………………... 8 1.2. EC and Lithuanian legal documents for hazardous substances and pollution ……………. 11 1.3. Classification of poisons ……………………………………………………………………. 12 1.4. Chemicals classification and labelling ……………………………………………………… 14 2. Toxicokinetics ………………………………………………………………………...………. 15 2.2. Migration of substances through biological membranes …………………………………… 15 2.3. ADME notion ………………………………………………………………………………. 15 2.4. Possibilities of poisons entering into an animal body and methods of absorption ……… 16 2.5. Poison distribution -
2002 NRP Section 6, Tables 6.1 Through
Table 6.1 Scoring Table for Pesticides 2002 FSIS NRP, Domestic Monitoring Plan } +1 0.05] COMPOUND/COMPOUND CLASS * ) (EPA) (EPA) (EPA) (EPA) (EPA) (FSIS) (FSIS) PSI (P) TOX.(T) L-1 HIST. VIOL. BIOCON. (B) {[( (2*R+P+B)/4]*T} REG. CON. (R) * ENDO. DISRUP. LACK INFO. (L) LACK INFO. {[ Benzimidazole Pesticides in FSIS Benzimidazole MRM (5- 131434312.1 hydroxythiabendazole, benomyl (as carbendazim), thiabendazole) Carbamates in FSIS Carbamate MRM (aldicarb, aldicarb sulfoxide, NA44234416.1 aldicarb sulfone, carbaryl, carbofuran, carbofuran 3-hydroxy) Carbamates NOT in FSIS Carbamate MRM (carbaryl 5,6-dihydroxy, chlorpropham, propham, thiobencarb, 4-chlorobenzylmethylsulfone,4- NT 4 1 3 NV 4 4 13.8 chlorobenzylmethylsulfone sulfoxide) CHC's and COP's in FSIS CHC/COP MRM (HCB, alpha-BHC, lindane, heptachlor, dieldrin, aldrin, endrin, ronnel, linuron, oxychlordane, chlorpyrifos, nonachlor, heptachlor epoxide A, heptachlor epoxide B, endosulfan I, endosulfan I sulfate, endosulfan II, trans- chlordane, cis-chlordane, chlorfenvinphos, p,p'-DDE, p, p'-TDE, o,p'- 3444NV4116.0 DDT, p,p'-DDT, carbophenothion, captan, tetrachlorvinphos [stirofos], kepone, mirex, methoxychlor, phosalone, coumaphos-O, coumaphos-S, toxaphene, famphur, PCB 1242, PCB 1248, PCB 1254, PCB 1260, dicofol*, PBBs*, polybrominated diphenyl ethers*, deltamethrin*) (*identification only) COP's and OP's NOT in FSIS CHC/COP MRM (azinphos-methyl, azinphos-methyl oxon, chlorpyrifos, coumaphos, coumaphos oxon, diazinon, diazinon oxon, diazinon met G-27550, dichlorvos, dimethoate, dimethoate