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PDF Download SynformPeople, Trends and Views in Chemical Synthesis 2020/12 Continuous-Flow C(sp3)–H Functionaliza- tions of Volatile Alkanes Using Decatung- state Photocatalysis Highlighted article by G. Laudadio, Y. Deng, K. van der Wal, D. Ravelli, M. Nuño, M. Fagnoni, D. Guthrie, Y. Sun, T. Noël This document was downloaded for personal use only. Unauthorized distribution is strictly prohibited. Contact Your opinion about Synform is welcome, please correspond if you like: [email protected] Thieme A172 Synform Dear Readers, When I opened the window this morning I saw an In this issue amazingly bright and blue sky, it could not be any better. Then I suddenly remembered that a few hours Name Reaction Bio Johann Wilhelm Friedrich Adolf von Baeyer (1835–1917) earlier a new President and Vice-President of the and Victor Villiger (1868–1934): Peracid Oxidation of United States of America had been announced, and I Ketones .......................................................A173 realized that – for the first time this year – there was Literature Coverage light at the end of the tunnel. This editorial is not Continuous-Flow C(sp3)–H Functionalizations of Volatile about politics, but I believe that the world is a much Alkanes Using Decatungstate Photocatalysis ..........A179 better place now: better for science, better for the Literature Coverage Total Synthesis of (+)-Caldaphnidine J ..................A183 environment, better for us and – most of all – better for our children. This is going to be a very strange and Young Career Focus Young Career Focus: Professor Denis Chusov different Christmas for many, but it is a Christmas of (Nesmeyanov Institute, Russian Federation) ...........A186 hope, as there are signs that better times are ahead Coming soon .................................................A191 of us. But let’s have a look at the last SYNFORM issue of 2020 – a year that will not be missed. We start with a new, extraordinary Name Reaction Bio article by David Lewis on the Baeyer–Villiger reaction, followed Contact by Timothy Noël’s (The Netherlands) Science paper on If you have any questions or wish to send the C(sp 3)–H functionalizations of light hydrocarbons. feedback, please write to Matteo Zanda at: The third article is another Literature Coverage piece: [email protected] it covers the elegant total synthesis of the Daphni- phyllum alkaloid (+)-caldaphnidine by Jing Xu (P. R. of China). The article that closes the issue and the year for SYNFORM is a Young Career Focus interview with Denis Chusov (Russian Federation): look at the picture – besides reading the interesting article – because I think it beauti fully represents the sense of hope for the This document was downloaded for personal use only. Unauthorized distribution is strictly prohibited. future. Goodbye 2020… Enjoy your reading! © Georg Thieme Verlag Stuttgart • New York – Synform 2020/12, A172 • Published online: November 17, 2020 • DOI: 10.1055/s-0039-1691222 A173 Synform Name Reaction Bio Johann Wilhelm Friedrich Adolf von Baeyer (1835–1917) and Victor Villiger (1868–1934): Peracid Oxidation of Ketones The reaction between ketones and peracids, now known delberg, where Robert Bunsen (1811–1899) was one of the as the Baeyer–Villiger reaction, was first reported by Adolf most important chemists in Germany working in one of the von Baeyer (1835–1917) and his student and collabora- most modern laboratories. While with Bunsen, he published tor, Victor Villiger (1868–1934) in 1899.1 Of the two men, two papers, one on idiochemical induction,5 and a second on von Baeyer is by far the better known, having won the Nobel methyl chloride.6 Prize in Chemistry in 1905. In 1840, Bunsen had begun research on cacodyl com- pounds,7 and Baeyer continued that research in Bunsen’s labor atory. However, the relationship between student and mentor deteriorated, and an argument between the two men led to Baeyer leaving Bunsen’s research group and joining that of August Kekulé (1829–1896). The two men became life-long friends. von Baeyer (left) and Villiger (right). Image of von Baeyer courtesy of Science History Institute. The image of Villiger ©2019, Matthew A. Bergs; all rights reserved. Reproduced by permission of the artist. Johann Friedrich Wilhelm von Baeyer2 was born to Lieutenant-General Jakob Baeyer and Eugenie, née Hitzig, on Bunsen (left) and Kekulé (right). Image of Bunsen courtesy of October 31, 1835. From a young age, he demonstrated his in- Universitätsbibliothek Heidelberg. Public domain image of Kekulé terest in science by his exploration of chemistry. When just downloaded June 2020 from https://commons.wikimedia.org/ wiki/File:Frkekulé.jpg. 9 years old, he was conducting plant nutrition experiments, and just three years later3 he isolated a new double salt of cop- This document was downloaded for personal use only. Unauthorized distribution is strictly prohibited. per, whose formula was established as CuCO3•Na2CO3•3H2O by Despite his break with Bunsen, Baeyer continued his re- 4 Struve in 1851. search on organic arsenic compounds of the cacodyl (Me2As) At age 17, Baeyer entered the University of Berlin, where series.8 In 1858, he submitted his work on cacodylic acid, he began his study of physics and mathematics. In his two Me2As(O)OH, done in Kekulé’s laboratory, to Berlin University, years there, however, neither physics nor mathematics excited where he was awarded his Ph.D. in 1858. This dissertation9 him as much as chemistry. Both physics and chemistry were was written in Latin. During this time, Kekulé had become taught as complete sciences, looking backwards. Chemistry, Professor at Ghent, and as soon as he held the Ph.D., Baeyer on the other hand, was taught as a new, vibrant science, and it followed him there. was this that changed Baeyer’s mind. In 1860, Baeyer presented his habilitation lecture (again, In 1855, Baeyer left the University for a year of military in Latin), then returned to Berlin as a Privatdozent in the service, and after he had satisfied his obligation he returned Berlin Gewerbeinstitut (The Royal Trade Institute, later the to his studies, this time in chemistry at the University of Hei- König liche Technische Hochschule Charlottenburg). There he © Georg Thieme Verlag Stuttgart • New York – Synform 2020/12, A173–A178 • Published online: November 17, 2020 • DOI: 10.1055/s-0039-1691219 A174 Synform Name Reaction Bio began his work with coloring matters, including indigo and alizarin, the red dye from madder root. In 1871, the Alsace– Lorraine region was ceded to France as a result of Prussia’s victory in the Franco–Prussian War of 1870–1871. This event was accompanied by the University of Strasbourg becoming the Kaiser-Wilhem-Universität, and an influx of new, young German-speaking staff members. One of these was 36-year- old Adolf von Baeyer, who became Professor in 1871. Four years later, Baeyer became the successor to Justus von Liebig at the University of Munich, where he spent the rest of his career. Baeyer’s research made a huge impact on the field of orga- nic chemistry. His major contributions to organic chemistry include the Baeyer strain theory (Figure 1),10 and a series of papers on indoles, indoxyl, and isatin,11 culminating in the synthesis of indigo (1; Scheme 1).12 Scheme 2 Figure 1 Baeyer’s strain theory (image taken from Ber. Dtsch. Chem. Ges. 1885, 18, 2269–2281) Scheme 1 In his degradation studies of uric acid (3), he obtained This document was downloaded for personal use only. Unauthorized distribution is strictly prohibited. the dimeric pyrimidinetrione, hydriluric acid (4), as well as monomeric pyrimidinetrione derivatives 5 (violuric acid), 6 (alloxan), and 7 (barbituric acid (Scheme 2), along with Scheme 3 several other pyrimidine derivatives.13 In 1871, he reported the discovery and synthesis of the phthalein dyes (Scheme 3);14 in 1900, he published a paper that proposed a system of proposed that the stability of carbocyclic compounds was de- nomenclature for polycyclic and spirocyclic compounds.15 pendent on the angles’ deviation from the commonly accepted Later he brought his chemical knowledge to the Univer- 109° standard. In 1905, he received the Nobel Prize in Chem- sity of Munich, where the true synthesis of indigo developed istry, further distinguishing himself in his field. alongside some of his other projects, such as his work with The other member of the team was Swiss chemist Victor acetylene and polyacetylene which later developed into the Villiger (1868–1934), the son of a lawyer and later City Ad- Baeyer strains theory of carbon rings. More specifically, he ministrator of Lenzburg, and grandson of the Swiss Aarau po- © Georg Thieme Verlag Stuttgart • New York – Synform 2020/12, A173–A178 • Published online: November 17, 2020 • DOI: 10.1055/s-0039-1691219 A175 Synform Name Reaction Bio litician and reformer, Augustin Kweller (1805–1883). He was Baeyer was very much impressed by the young Villiger, born in the small village of Cham am Zuger See and educated and therefore retained him as an assistant for another eleven at the Aarau Canton School. In 1888, he entered the University years after his graduation. Initially, Villiger worked with of Geneva, where he studied chemistry for a year and a half Baeyer on the ‘hot topic’ at the time – the structure of terpen- under Carl Graebe (1841–1927) before completing his com- oid compounds.18 During this work, the β-lactam 14 and pulsory year of military service. stereoisomeric lactones 16 and 17 from camphoronic acid (15) were prepared.19 Literature searches using any search engine and the names Baeyer or Villiger, separately, return more hits on the Baeyer– Villiger reaction than on anything else. This important reac- tion was first described in the last two years of the nineteenth century,1 and has remained an important synthetic organic Carl Graebe ca.
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