New Rheology Models, Non-Newtonian Formulations and Multiphase Flows
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Shear Thickening in Concentrated Suspensions: Phenomenology
Shear thickening in concentrated suspensions: phenomenology, mechanisms, and relations to jamming Eric Brown School of Natural Sciences, University of California, Merced, CA 95343 Heinrich M. Jaeger James Franck Institute, The University of Chicago, Chicago, IL 60637 (Dated: July 22, 2013) Shear thickening is a type of non-Newtonian behavior in which the stress required to shear a fluid increases faster than linearly with shear rate. Many concentrated suspensions of particles exhibit an especially dramatic version, known as Discontinuous Shear Thickening (DST), in which the stress suddenly jumps with increasing shear rate and produces solid-like behavior. The best known example of such counter-intuitive response to applied stresses occurs in mixtures of cornstarch in water. Over the last several years, this shear-induced solid-like behavior together with a variety of other unusual fluid phenomena has generated considerable interest in the physics of densely packed suspensions. In this review, we discuss the common physical properties of systems exhibiting shear thickening, and different mechanisms and models proposed to describe it. We then suggest how these mechanisms may be related and generalized, and propose a general phase diagram for shear thickening systems. We also discuss how recent work has related the physics of shear thickening to that of granular materials and jammed systems. Since DST is described by models that require only simple generic interactions between particles, we outline the broader context of other concentrated many-particle systems such as foams and emulsions, and explain why DST is restricted to the parameter regime of hard-particle suspensions. Finally, we discuss some of the outstanding problems and emerging opportunities. -
Lecture 1: Introduction
Lecture 1: Introduction E. J. Hinch Non-Newtonian fluids occur commonly in our world. These fluids, such as toothpaste, saliva, oils, mud and lava, exhibit a number of behaviors that are different from Newtonian fluids and have a number of additional material properties. In general, these differences arise because the fluid has a microstructure that influences the flow. In section 2, we will present a collection of some of the interesting phenomena arising from flow nonlinearities, the inhibition of stretching, elastic effects and normal stresses. In section 3 we will discuss a variety of devices for measuring material properties, a process known as rheometry. 1 Fluid Mechanical Preliminaries The equations of motion for an incompressible fluid of unit density are (for details and derivation see any text on fluid mechanics, e.g. [1]) @u + (u · r) u = r · S + F (1) @t r · u = 0 (2) where u is the velocity, S is the total stress tensor and F are the body forces. It is customary to divide the total stress into an isotropic part and a deviatoric part as in S = −pI + σ (3) where tr σ = 0. These equations are closed only if we can relate the deviatoric stress to the velocity field (the pressure field satisfies the incompressibility condition). It is common to look for local models where the stress depends only on the local gradients of the flow: σ = σ (E) where E is the rate of strain tensor 1 E = ru + ruT ; (4) 2 the symmetric part of the the velocity gradient tensor. The trace-free requirement on σ and the physical requirement of symmetry σ = σT means that there are only 5 independent components of the deviatoric stress: 3 shear stresses (the off-diagonal elements) and 2 normal stress differences (the diagonal elements constrained to sum to 0). -
Rheology in Pharmaceutical Formulations-A Perspective
evelo f D pin l o g a D Mastropietro et al., J Develop Drugs 2013, 2:2 n r r u u g o s J Journal of Developing Drugs DOI: 10.4172/2329-6631.1000108 ISSN: 2329-6631 Review Article Open Access Rheology in Pharmaceutical Formulations-A Perspective David J Mastropietro1, Rashel Nimroozi2 and Hossein Omidian1* 1Department of Pharmaceutical Sciences, College of Pharmacy, Nova Southeastern University, Fort Lauderdale, Florida, USA 2Westside Regional Medical Center, Pharmacy Department, Plantation, Florida, USA Abstract Medications produced as semi-solids type product such as creams, ointments and lotions are based on emulsion or suspension type systems consisting of two or more incompatible materials. In order to be manufactured, these dosage forms need specific flow properties so they can be placed into a container, remain stable over time, dispensed, handled and properly applied to the affected area by patients. Rheology is therefore crucially important as it will directly affect the way a drug is formulated and developed, the quality of the raw and finished product, the drug efficacy, the way a patient adheres to the prescribed drug, and the overall healthcare cost. It can be concluded that there are inherent and independent factors that affect the flow property of a medicated material during every stage of its manufacturing all the way to its use. Keywords: Pharmaceutical formulation; Rheology; Viscosity; dampened as the particles easily slide over one another to maintain a Suspensions; Rheology modifiers; Hydrophilic polymers steady viscosity, or Newtonian behavior. If stress is applied at a faster rate, the spherical particles slide faster over each other to maintain Introduction their history of viscosity. -
Pharmaceutics I صيدالنيات 1
Pharmaceutics I صيدﻻنيات 1 Unit 6 1 Rheology of suspensions • Rheology, the study of flow, addresses the viscosity characteristics of powders, fluids, and semisolids. • Materials are divided into two general categories, Newtonian and non-Newtonian, depending on their flow characteristics. • The unit of viscosity is the poise, the shearing force required to produce a velocity of 1 cm per second between two parallel planes of liquid, each 1 cm2 in area and separated by a distance of 1 cm. • The most convenient unit to use is the centipoise, or cP (equivalent to 0.01 poise). Newton’s law of flow • Newton law of flow relates parallel layers of liquid, with the bottom layer fixed, when a force is placed on the top layer, the top plane moves at constant velocity, each lower layer moves with a velocity directly proportional to its distance from the stationary bottom layer. • The velocity gradient, or rate of shear (dv/dr), is the difference of velocity dv between two planes of liquid separated by the distance dr. • The force (F´/A) applied to the top layer that is required to result in flow (rate of shear, G) is called the shearing stress (F). NEWTONIAN’S LOW OF FLOW Let us consider a block of liquid consisting of parallel plates of molecules as shown in the figure. The bottom layer is considered to be fixed in place. If the top plane of liquid is moved at constant velocity, each lower layer will move with a velocity directly proportional to its distance from the stationary bottom layer Representation of shearing force acting on a block of material ☻Rate of Shear dv/dr = G Is the velocity difference dv between two planes of liquid separated by an infinite distance dr. -
Dilatancy in the Flow and Fracture of Stretched Colloidal Suspensions
Dilatancy in the flow and fracture of stretched colloidal suspensions M.I. Smith School of Engineering, University of Edinburgh, Kings Buildings, Mayfield Rd, Edinburgh, EH9 3JL, UK School of Physics and Astronomy, University of Nottingham, University Park, Nottingham, NG7 2RD e-mail: [email protected] R. Besseling SUPA, School of Physics and Astronomy, University of Edinburgh, Kings Buildings, Mayfield Rd, Edinburgh EH9 3JZ e-mail: [email protected] M.E. Cates SUPA, School of Physics and Astronomy, University of Edinburgh, Kings Buildings, Mayfield Rd, Edinburgh, EH9 3JZ, UK e-mail: m.e.cates@ ed.ac.uk V. Bertola* School of Engineering, University of Edinburgh, Kings Buildings, Mayfield Rd, Edinburgh, EH9 3JL, UK e-mail: [email protected] contacting author* 1 Dilatancy in the flow and fracture of stretched colloidal suspensions. Concentrated particulate suspensions, commonplace in the pharmaceutical, cosmetic and food industries, display intriguing rheology. In particular, the dramatic increase in viscosity with strain rate (shear thickening and jamming) which is often observed at high volume fractions, is of strong practical and fundamental importance. Yet manufacture of these products and their subsequent dispensing often involves flow geometries substantially different from that of simple shear flow experiments. Here we show that the elongation and breakage of a filament of a colloidal fluid under tensile loading is closely related to the jamming transition seen in its shear rheology. However, the modified flow geometry reveals important additional effects. Using a model system with nearly hard-core interactions, we provide evidence of surprisingly strong viscoelasticity in such a colloidal fluid under tension. -
Non-Newtonian Fluids Flow Characteristic of Non-Newtonian Fluid
Newtonian fluid dv dy 2 r 2 (P P ) (2 rL) (r ) Pr 2 1 P 2 = P x r (2 rL) 2 rL 2L 2 4 P R2 r PR v(r) 1 4 L R = 8LV0 Definition of a Newtonian Fluid F du yx yx A dy For Newtonian behaviour (1) is proportional to and a plot passes through the origin; and (2) by definition the constant of proportionality, Newtonian dv dy 2 r 2 (P P ) (2 rL) (r ) Pr 2 1 P 2 = P x r (2 rL) 2 rL 2L 2 4 P R2 r PR v(r) 1 4 L R = 8LV0 Newtonian 2 From (r ) Pr d u = P 2rL 2L d y 4 and PR 8LQ = 0 4 8LV P = R = 8v/D 5 6 Non-Newtonian Fluids Flow Characteristic of Non-Newtonian Fluid • Fluids in which shear stress is not directly proportional to deformation rate are non-Newtonian flow: toothpaste and Lucite paint (Casson Plastic) (Bingham Plastic) Viscosity changes with shear rate. Apparent viscosity (a or ) is always defined by the relationship between shear stress and shear rate. Model Fitting - Shear Stress vs. Shear Rate Summary of Viscosity Models Newtonian n ( n 1) Pseudoplastic K n Dilatant K ( n 1) n Bingham y 1 1 1 1 Casson 2 2 2 2 0 c Herschel-Bulkley n y K or = shear stress, º = shear rate, a or = apparent viscosity m or K or K'= consistency index, n or n'= flow behavior index Herschel-Bulkley model (Herschel and Bulkley , 1926) n du m 0 dy Values of coefficients in Herschel-Bulkley fluid model Fluid m n Typical examples 0 Herschel-Bulkley >0 0<n< >0 Minced fish paste, raisin paste Newtonian >0 1 0 Water,fruit juice, honey, milk, vegetable oil Shear-thinning >0 0<n<1 0 Applesauce, banana puree, orange (pseudoplastic) juice concentrate Shear-thickening >0 1<n< 0 Some types of honey, 40 % raw corn starch solution Bingham Plastic >0 1 >0 Toothpaste, tomato paste Non-Newtonian Fluid Behaviour The flow curve (shear stress vs. -
Complex Fluids in Energy Dissipating Systems
applied sciences Review Complex Fluids in Energy Dissipating Systems Francisco J. Galindo-Rosales Centro de Estudos de Fenómenos de Transporte, Faculdade de Engenharia da Universidade do Porto, CP 4200-465 Porto, Portugal; [email protected] or [email protected]; Tel.: +351-925-107-116 Academic Editor: Fan-Gang Tseng Received: 19 May 2016; Accepted: 15 July 2016; Published: 25 July 2016 Abstract: The development of engineered systems for energy dissipation (or absorption) during impacts or vibrations is an increasing need in our society, mainly for human protection applications, but also for ensuring the right performance of different sort of devices, facilities or installations. In the last decade, new energy dissipating composites based on the use of certain complex fluids have flourished, due to their non-linear relationship between stress and strain rate depending on the flow/field configuration. This manuscript intends to review the different approaches reported in the literature, analyses the fundamental physics behind them and assess their pros and cons from the perspective of their practical applications. Keywords: complex fluids; electrorheological fluids; ferrofluids; magnetorheological fluids; electro-magneto-rheological fluids; shear thickening fluids; viscoelastic fluids; energy dissipating systems PACS: 82.70.-y; 83.10.-y; 83.60.-a; 83.80.-k 1. Introduction Preventing damage or discomfort resulting from any sort of external kinetic energy (impact or vibration) is an omnipresent problem in our society. On one hand, impacts and vibrations are responsible for several health problems. According to the European Injury Data Base (IDB), injuries due to accidents are killing one EU citizen every two minutes and disabling many more [1]. -
Non-Newtonian Fluid Math Dean Wheeler Brigham Young University May 2019
Non-Newtonian Fluid Math Dean Wheeler Brigham Young University May 2019 This document summarizes equations for computing pressure drop of a power-law fluid through a pipe. This is important to determine required pumping power for many fluids of practical importance, such as crude oil, melted plastics, and particle/liquid slurries. To simplify the analysis, I will assume the use of smooth and relatively long pipes (i.e. neglect pipe roughness and entrance effects). I further assume the reader has had exposure to principles taught in a college-level fluid mechanics course. Types of Fluids To begin, one must understand the difference between Newtonian and non-Newtonian fluids. There are many types of non-Newtonian fluids and this is a vast topic, which is studied under a branch of physics known as rheology. Rheology concerns itself with how materials (principally liquids, but also soft solids) flow under applied forces. Some non-Newtonian fluids exhibit time-dependent or viscoelastic behavior. This means their flow behavior depends on the history of what forces were applied to the fluid. Such fluids include thixotropic (shear-thinning over time) and rheopectic (shear-thickening over time) types. Viscoelastic fluids exhibit elastic or solid-like behavior when forces are first applied, and then transition to viscous flow under continuing force. These include egg whites, mucous, shampoo, and silly putty. We will not be analyzing any of these time-dependent fluids in this discussion. Time-independent or inelastic fluids flow with a constant rate when constant forces are applied to them. They are the focus of this discussion. -
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A Basic Introduction to Rheology
WHITEPAPER A Basic Introduction to Rheology RHEOLOGY AND Introduction VISCOSITY Rheometry refers to the experimental technique used to determine the rheological properties of materials; rheology being defined as the study of the flow and deformation of matter which describes the interrelation between force, deformation and time. The term rheology originates from the Greek words ‘rheo’ translating as ‘flow’ and ‘logia’ meaning ‘the study of’, although as from the definition above, rheology is as much about the deformation of solid-like materials as it is about the flow of liquid-like materials and in particular deals with the behavior of complex viscoelastic materials that show properties of both solids and liquids in response to force, deformation and time. There are a number of rheometric tests that can be performed on a rheometer to determine flow properties and viscoelastic properties of a material and it is often useful to deal with them separately. Hence for the first part of this introduction the focus will be on flow and viscosity and the tests that can be used to measure and describe the flow behavior of both simple and complex fluids. In the second part deformation and viscoelasticity will be discussed. Viscosity There are two basic types of flow, these being shear flow and extensional flow. In shear flow fluid components shear past one another while in extensional flow fluid component flowing away or towards from one other. The most common flow behavior and one that is most easily measured on a rotational rheometer or viscometer is shear flow and this viscosity introduction will focus on this behavior and how to measure it. -
A Constitutive Framework for the Non-Newtonian Pressure Tensor of a Simple fluid Under Planar flows
A constitutive framework for the non-Newtonian pressure tensor of a simple fluid under planar flows Remco Hartkamp∗ and Stefan Ludingy Multi Scale Mechanics, Faculty of Engineering Technology, MESA+ Institute for Nanotechnology, University of Twente, P.O. Box 217, 7500 AE Enschede, The Netherlands B. D. Toddz Mathematics Discipline, Faculty of Engineering and Industrial Sciences and Centre for Molecular Simulation, Swinburne University of Technology, Hawthorn, Victoria 3122, Australia (Dated: May 24, 2013) Non-equilibrium molecular dynamics simulations of an atomic fluid under shear flow, pla- nar elongational flow and a combination of shear and elongational flow are unified consis- tently with a tensorial model over a wide range of strain rates. A model is presented that predicts the pressure tensor for a non-Newtonian bulk fluid under a homogeneous planar flow field. The model provides a quantitative description of the strain-thinning viscosity, pressure dilatancy, deviatoric viscoelastic lagging and out-of-flow-plane pressure anisotropy. The non-equilibrium pressure tensor is completely described through these four quantities and can be calculated as a function of the equilibrium material constants and the velocity gradient. This constitutive framework in terms of invariants of the pressure tensor departs from the conventional description that deals with an orientation-dependent description of shear stresses and normal stresses. The present model makes it possible to predict the full pressure tensor for a simple fluid under various types of flow without having to produce these flow types explicitly in a simulation or experiment. I. INTRODUCTION There is significant scientific and industrial interest in describing the relation between the pres- sure tensor for non-Newtonian fluids out of thermodynamic equilibrium and other quantities, such as the strain rate and the fluid density and temperature. -
Liquid Body Armor
Liquid Body Armor Organization: Children's Museum of Houston Contact person: Aaron Guerrero Contact information: [email protected] or 713‐535‐7226 General Description Type of program: Cart Demo Visitors will learn how nanotechnology is being used to create new types of protective fabrics. The classic experiment “Oobleck” is used to demonstrate how scientists are using similar techniques to recreate this phenomenon in flexible fabrics. Program Objectives Big idea: Nanotechnology can be used to create new protective fabrics with unique properties. Learning goals: As a result of participating in this program, visitors will be able to: 1. Explore and learn about the molecular behavior which gives Oobleck its unique properties. 2. Learn how nanotechnologists and material researchers are applying these properties to protective fabrics. NISE Network content map main ideas: [ ] 1. Nanometer‐sized things are very small, and often behave differently than larger things do. [ X ] 2. Scientists and engineers have formed the interdisciplinary field of nanotechnology by investigating properties and manipulating matter at the nanoscale. [ X ] 3. Nanoscience, nanotechnology, and nanoengineering lead to new knowledge and innovations that weren’t possible before. [ ] 4. Nanotechnologies have costs, risks, and benefits that affect our lives in ways we cannot always predict. 1 National Science Education Standards: 2. Physical Science [X] K‐4: Properties of objects and materials [ ] K‐4: Position and motion of objects [ ] K‐4: Light, heat, electricity, and magnetism [X] 5‐8: Properties and changes of properties in matter [X] 5‐8: Motions and forces [X] 5‐8: Transfer of energy [X] 9‐12: Structure of atoms [X] 9‐12: Structure and properties of matter [ ] 9‐12: Chemical reactions [X] 9‐12: Motions and force [ ] 9‐12: Conservation of energy and increase in disorder [X] 9‐12: Interactions of energy and matter 5.