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Infrared Spectroscopy of Minerals and Related Compounds, Springer Mineralogy, DOI 10.1007/978-3-319-25349-7 1050 References

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Infrared Spectroscopy of Minerals and Related Compounds, Springer Mineralogy, DOI 10.1007/978-3-319-25349-7 1050 References References Abdel-Gawad AM, Kerr PF (1961) Urano-organic min- Agrell SO, Gay M (1970) De la deerite dans les Alpes eral association. Am Miner 46:402–419 franco-italiennes. Bull Soc Fr Minéral Cristallogr Ackermann L, Cemič L, Langer K (1983) Hydrogarnet 93:263–264 (in French) substitution in pyrope: a possible location for “water” Agrell SO, Bown MG, McKie D (1965) Deerite, howieite in the mantle. Earth Planet Sci Lett 62:208–214 and zussmanite, three new minerals from the Francis- Adams DM, Fletcher PA (1988) Vibrational spectroscopy can of the Laytonville district, Mendocino Co., at high pressure: part 53. Alkali metavanadates and California. Am Miner 50:278 copper metagermanate. Spectrochim Acta A 44 Aines RD, Rossman GR (1984) The high temperature (2):233–240 behavior of water and carbon dioxide in cordierite and Aderemi BO, Hameed BH (2009) Alum as a heteroge- beryl. Am Miner 69:319–327 neous catalyst for the transesterification of palm oil. Akaogi M, Ross NL, McMillan P, Navrotsky A (1984) Appl Catal A 370:54–58 The Mg2SiO4 polymorphs (olivine, modified spinel Adler HH (1965) Examination of mass-radius effects, and spinel) – thermodynamic properties from oxide hydrogen bonding and vb splitting in infrared spectra melt solution calorimetry, phase relations, and models of Zr-Hf homologs. Am Miner 50:1553–1562 of lattice vibrations. Am Miner 69:499–512 Agakhanov AA, Pautov LA, Karpenko VYu, Beken- Akhmanova MV, Orlova LP (1966) Investigation of ova GK, Uvarova YuA (2011) Orlovite, KLi2Ti rare-earth carbonates by infra-red spectroscopy. Geo- Si4O11F, a new mineral of the mica group. New Data khimiya (Geochemistry) 5:571–578 (in Russian) Minerals 46:13–19 Akrap A, Tran M, Ubaldini A, Teyssier J, Giannini E, Agakhanov AA, Pautov LA, Karpenko VYu, Sokolova E, Van Der Marel D, Lerch P, Homes CC (2012) Optical Abdu YA, Hawthorne FC, Pekov IV, Siidra OI (2015) properties of Bi2Te2Se at ambient and high pressures. Yusupovite, Na2Zr(Si6O15)(H2O)3, a new mineral Phys Rev B 86(23):235207–9 species from the Darai-Pioz alkaline massif and its Aksenov SM, Rastsvetaeva RK, Chukanov NV, implications as a new microporous filter for large ions. Kolitsch U (2014) Structure of calcinaksite KNa[Ca Am Miner 100:1502–1508 (H2O)][Si4O10], the first hydrous member of the 8− Agakhanov AA, Pautov LA, Uvarova YuA, litidionite group of silicates with [Si8O20] tubes. Sokolova EV, Hawthorne F, Karpenko VYu (2005) Acta Crystallogr B 70:768–775 Senkevichite, CsKNaCa2TiO[Si7O18(OH)], a new Aleksovska S, Petruševski VM, Šoptrajanov B (1997) mineral. New Data Minerals 40:17–22 Infrared spectra of the monohydrates of manganese Agakhanov AA, Pautov LA, Uvarova YuA, (III) phosphate and manganese(III) arsenate: relation Sokolova EV, Hawthorne FC, Karpenko VYu to the compounds of the kieserite family. J Molec 2+ (2013) Laptevite-(Ce), NaFe (REE7Ca5Y3)(SiO4)4 Struct 408(409):413–416 (Si3B2PO18)(BO3)F11, a new mineral species in the Alemi A, Joo SW, Khademinia S, Dolatyari M, vicanite group from the Dara-i Pioz alkaline massif, Bakhtiari A, Moradi H, Saeidi S (2013) Hydrothermal Tajikistan. New Data Minerals 48:5–11 (in Russian) synthesis and characterization of straw bundle-like Agakhanov AA, Pautov LA, Uvarova YuA, lithium sodium disilicate (silinaite) micro-rods. Int Sokolova EV, Hawthorne FC, Karpenko VYu, Dus- Nano Lett 3(1):1–5 matov VD, Semenov YeI (2004) Arapovite, (U,Th) Alici E, Schmidt T, Lutz HD (1992) Zur Kenntnis des (Ca,Na)2(K1-x☐x)Si8O20·H2O – new mineral. New Calciumbromats und -iodats, Kristallstruktur, Data Minerals 39:14–18 röntgenographische, IR- und Raman-spektroskopische Agakhanov AA, Pautov LA, Uvarova YuA, und thermoanalytische Untersuchungen. Z anorg allg Sokolova EV, Hawthorne FC, Karpenko VYu, Chem 608:135–144 (in German) Gafurov FG (2007) Faizievite, K2Na(Ca6Na)Ti4Li6 Allen GC, Crofts JA, Griffiths AJ (1976) Infrared Si24O66F2 – a new mineral species. New Data spectroscopy of the uranium/oxygen system. J Nucl Minerals 42:5–10 Mater 62(2):273–281 © Springer International Publishing Switzerland 2016 1049 N.V. Chukanov and A.D. Chervonnyi, Infrared Spectroscopy of Minerals and Related Compounds, Springer Mineralogy, DOI 10.1007/978-3-319-25349-7 1050 References Allen GC, Paul M (1995) Chemical characterization of Antonkhina TF, Savchenko NN, Sergienko VI, Ignat'eva transition metal spinel-type oxides by infrared spec- LN, Markina IA (1992) Synthesis and physicochem- troscopy. Appl Spectrosc 49(4):451–458 ical investigation of mixed alkali-metal cation Al’Ama AG, Belokoneva EL, Dimitrova OV, hexafluorosilicates. Bull Russ Academy Sci, Division Kurazhkovskaya VS, Mochenova NN (2006) Bro- Chem Sci 41(2):193–200 mophosgenite: synthesis and structure solution. Zhur- Apollonov VN, Dolinina YuV, Yamnova NA, Pushchar- nal Neorganicheskoi Khimii (Russ J Inorg Chem) 51 ovsky DYu, Ivanova TN (1990) Kaminite from (8):1261–1265 (in Russian) Nepskoe K-salt deposit. Mineralogicheskiy Zhurnal Amayri S, Arnold T, Foerstendorf H, Geipel G, Bern- (Mineral J) 12(6):79–81 (in Russian) hard G (2004) Spectroscopic characterization of Apopei AI, Damian G, Buzgar N (2012) A preliminary synthetic becquerelite, Ca[(UO2)6O4(OH)6]·8H2O, Raman and FT-IR spectroscopic study of secondary and swartzite, CaMg[UO2(CO3)3]·12H2O. Can Miner hydrated sulfate minerals from the Hondol Open Pit 42:953–962 (Metaliferi Mts., Romania). Roman J Miner Depos 85 Amthauer G, Rossman GR (1998) The hydrous compo- (2):1–6 nent in andradite garnet. Am Miner 83:835–840 Apopei AI, Buzgar N, Buzatu A (2011) Raman and Anastassakis E, Perry CH (1976) Light scattering and ir infrared spectroscopy of kaersutite and certain com- measurements in XS2 pyrite-type compounds. J Chem mon amphiboles. Analele Stiintifice ale Universitatii Phys 64(9):3604–3609 “Al. I. Cuza” din Iasi Seria Geologie 57(2):35–58 Anderson A, Chieh C, Irish DE, Tong JPK (1980) An Appleton JD, Bland DJ, Nancarrow PH, Styles MT, X-ray crystallographic, Raman, and infrared spectral Mambwe SH, Zambezi P (1992) The occurrence of study of crystalline potassium uranyl carbonate, daqingshanite-(Ce) in the Nkombwa Hill carbonatite, K4UO2(CO3)3. Can J Chem 58(16):1651–1658 Zambia. Mineral Mag 56:419–422 Anderson AJ, Clark AH, Gray S (2001) The occurrence Aranda MAG, Bruque S (1990) Characterization of and origin of zabuyelite (Li2CO3)in manganese(III) orthophosphate hydrate. Inorg Chem spodumene-hosted fluid inclusions: Implications for 29:1334–1337 the internal evolution of rare-element granitic peg- Arkhipova EV, Zuev MG, Perelyaeva LA (2006) Phase matites. Can Miner 39:1513–1527 relations and spectral properties of new phases in Ando T, Kanayama A, Kobayashi S, Miyawaki R, Sc2O3-V2O5-Nb2O5-Ta2O5 system. J Alloys Compd Kishi S, Tanabe M, Kusachi I (2015) Roweite from 414:48–54 the Fuka mine, Okayama Prefecture, Japan. J Mineral Armbruster T (1985) Ar, N2 and CO2 in the structural Petrol Sci 110:29–34 cavities of cordierite, an optical and X-ray Andreev IF, Sokolov AN, Shebyakov AM, Tarlakov YP, single-crystal study. Phys Chem Minerals 12:233–245 Toropov NA (1971) An IR-spectroscopic study of Armbruster T, Bloss FD (1982) Orientation and effects of solid solutions in the systems, Ce2Si2O7-Y2Si2O7 and channel H2O and CO2 in cordierite. Am Miner La2Si2O7-Y2Si2O7. Zhurnal Prikladnoi Spektroskopii 67:284–291 (J Appl Spectrosc) 14(2):340–343 (in Russian) Armbruster T, Oberhänsli R, Bermanec V (1992) Crystal 2 Andrieux J, Goutaudier C, Laversenne L, Jeanneau E, structure of SrMn [Si2O7](OH)2·H2O, a new mineral Miele P (2010) Synthesis, characterization, and crystal of the lawsonite type. Eur J Mineral 4:17–22 structure of a new trisodium triborate, Armbruster T, Schreyer W, Hoefs J (1982) Very high Na3[B3O4(OH)4]. Inorg Chem 49:4830–4835 CO2 cordierite from Norwegian Lapland: mineralogy, Andrut M, Brandstatter F, Beran A (2003) Trace hydro- petrology, and carbon isotopes. Contrib Mineral Petrol gen zoning in diopside. Miner Petrol 78:231–241 81:262–267 Andrut M, Wildner M, Beran A (2002) The crystal Armstrong CR, Nash KL, Griffiths PR, Clark SB (2011) chemistry of birefringent natural uvarovites. Part IV. Synthesis and characterization of françoisite-(Nd): Nd OH defect incorporation mechanisms in non-cubic [(UO2)3O(OH)(PO4)2]·6H2O. Am Miner 96:417–422 garnets derived from polarized IR spectroscopy. Eur J Arndt J, Hummel W, Gonzalez-Cabeza I (1982) Diaplec- Mineral 14:1019–1026 tic labradorite glass from the Manicouagan impact Ankinovitch EA, Bekenova GK, Podlipaeva NI (1989) crater. I. Physical properties, crystallization, structural 3+ 4+ 5+ Kazakhstanite, Fe 5V 3V 12O39(OH)9·8.55H2Oa and genetic implications. Phys Chem Minerals new hydrous ferrovanadian mineral from 8:230–239 carbonaceous-siliceous formation the NW Karatau Atencio D, Andrade MB, Christy AG, Gieré R, Kar- (South Kazakhstan). Zapiski RMO (Proc Russ Min- tashov PM (2010) The pyrochlore supergroup of eral Soc) 118(5): 95–100 (in Russian) minerals: nomenclature. Can Miner 48:673–698 Ansell VE, Chao GY (1987) Thornasite, a new hydrous Atencio D, Carvalho FMS, Matioli PA (2004) Coutin- sodium thorium silicate from Mont St-Hilaire, Que- hoite, a new thorium uranyl silicate hydrate, from bec. Can Miner 25:181–183 Urucum mine, Galiléia, Minas Gerais, Brazil. Am Antenucci D, Miehe G, Tarte P, Schmahl WW, Fransolet Miner 89:721–724 A-M (1993) Combined X-ray Rietveld, infrared and Atencio D, Roberts AC, Cooper MA, Menezes Raman study of a new synthetic variety of alluaudite, Filho LAD, Coutinho JMV, Stirling JAR, NaCdIn2(PO4)3. Eur J Mineral 5:207–213 Venance KE, Ball NA, Moffatt E, Chaves MLSC, References 1051 Brandão PRG, Romano AW (2012) Carlosbarbosaite, Baran EJ, Mormann T, Jeitschko W (1999b) Infrared and ideally (UO2)2Nb2O6(OH)2·2H2O, a new hydrated Raman spectra of (Hg2)3(AsO4)2 and Hg3(AsO4)2.
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