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Website F Boron Tribromide May Affect the Nervous System Right to Know Hazardous Substance Fact Sheet Common Name: BORON TRIBROMIDE Synonyms: Tribromoborane; Boron Bromide CAS Number: 10294-33-4 Chemical Name: Borane, Tribromo- RTK Substance Number: 0244 Date: July 1998 Revision: July 2007 DOT Number: UN 2692 Description and Use EMERGENCY RESPONDERS >>>> SEE BACK PAGE Boron Tribromide is a colorless, fuming liquid with a strong Hazard Summary odor. It is used to make Diborane, high purity Boron, and Hazard Rating NJDOH NFPA semiconductors. HEALTH - 3 FLAMMABILITY - 0 REACTIVITY - 2 W CORROSIVE WATER REACTIVE POISONOUS GASES ARE PRODUCED IN FIRE Reason for Citation f Boron Tribromide is on the Right to Know Hazardous Hazard Rating Key: 0=minimal; 1=slight; 2=moderate; 3=serious; Substance List because it is cited by ACGIH, DOT, NIOSH 4=severe and NFPA. f This chemical is on the Special Health Hazard Substance f Boron Tribromide can affect you when inhaled. List. f Contact can severely irritate and burn the skin and eyes. f Inhaling Boron Tribromide can irritate the nose and throat. f Inhaling Boron Tribromide can irritate the lungs. Higher exposures may cause a build-up of fluid in the lungs SEE GLOSSARY ON PAGE 5. (pulmonary edema), a medical emergency. f Boron Tribromide may affect the nervous system. FIRST AID f Boron Tribromide is REACTIVE and a DANGEROUS EXPLOSION HAZARD. Eye Contact f Immediately flush with large amounts of cool water. Continue for at least 30 minutes, occasionally lifting upper and lower lids. Remove contact lenses, if worn, while Workplace Exposure Limits rinsing. Immediate medical attention is necessary. NIOSH: The recommended airborne exposure limit (REL) is 1 ppm, which should not be exceeded at any time. Skin Contact f Quickly remove contaminated clothing. Immediately wash contaminated skin with large amounts of soap and water. ACGIH: The threshold limit value (TLV) is 1 ppm, which Seek medical attention immediately. should not be exceeded at any time. Inhalation f Remove the person from exposure. f Begin rescue breathing (using universal precautions) if breathing has stopped and CPR if heart action has stopped. f Transfer promptly to a medical facility. f Medical observation is recommended for 24 to 48 hours after breathing overexposure, as pulmonary edema may be delayed. EMERGENCY NUMBERS Poison Control: 1-800-222-1222 CHEMTREC: 1-800-424-9300 NJDEP Hotline: 1-877-927-6337 National Response Center: 1-800-424-8802 BORON TRIBROMIDE Page 2 of 6 Determining Your Exposure Reproductive Hazard f According to the information presently available to the New f Read the product manufacturer’s Material Safety Data Jersey Department of Health, Boron Tribromide has not Sheet (MSDS) and the label to determine product been tested for its ability to affect reproduction. ingredients and important safety and health information about the product mixture. Other Effects f Boron Tribromide can irritate the lungs. Repeated f For each individual hazardous ingredient, read the New exposure may cause bronchitis to develop with cough, Jersey Department of Health Hazardous Substance Fact phlegm, and/or shortness of breath. Sheet, available on the RTK website f Boron Tribromide may affect the nervous system. (www.nj.gov/health/eoh/rtkweb) or in your facility’s RTK Central File or Hazard Communication Standard file. f You have a right to this information under the New Jersey Worker and Community Right to Know Act, the Public Medical Employees Occupational Safety and Health (PEOSH) Act Medical Testing if you are a public worker in New Jersey, and under the Before beginning employment and at regular times after that, federal Occupational Safety and Health Act (OSHA) if you for those with frequent or potentially high exposures, the are a private worker. following are recommended: f The New Jersey Right to Know Act requires most f Lung function tests employers to label chemicals in the workplace and requires public employers to provide their employees with If symptoms develop or overexposure is suspected, the information concerning chemical hazards and controls. following are recommended: The federal OSHA Hazard Communication Standard (29 CFR 1910.1200) requires private employers to provide f Consider chest x-ray after acute overexposure similar information and training to their employees. f Exam of the nervous system This Fact Sheet is a summary of available information Any evaluation should include a careful history of past and regarding the health hazards that may result from exposure. present symptoms with an exam. Medical tests that look for Duration of exposure, concentration of the substance and other damage already done are not a substitute for controlling factors will affect your susceptibility to any of the potential exposure. effects described below. Request copies of your medical testing. You have a legal right to this information under the OSHA Access to Employee Health Hazard Information Exposure and Medical Records Standard (29 CFR 1910.1020). Acute Health Effects The following acute (short-term) health effects may occur Mixed Exposures immediately or shortly after exposure to Boron Tribromide: f Because smoking can cause heart disease, as well as lung cancer, emphysema, and other respiratory problems, it may f Contact can severely irritate and burn the skin and eyes with worsen respiratory conditions caused by chemical exposure. possible eye damage. Even if you have smoked for a long time, stopping now will f Inhaling Boron Tribromide can irritate the nose and throat. reduce your risk of developing health problems. f Inhaling Boron Tribromide can irritate the lungs causing coughing and/or shortness of breath. Higher exposures may cause a build-up of fluid in the lungs (pulmonary edema), a medical emergency, with severe shortness of breath. Chronic Health Effects The following chronic (long-term) health effects can occur at some time after exposure to Boron Tribromide and can last for months or years: Cancer Hazard f According to the information presently available to the New Jersey Department of Health, Boron Tribromide has not been tested for its ability to cause cancer in animals. BORON TRIBROMIDE Page 3 of 6 Workplace Controls and Practices Eye Protection Very toxic chemicals, or those that are reproductive hazards or f Wear indirect-vent, impact and splash resistant goggles sensitizers, require expert advice on control measures if a less when working with liquids. toxic chemical cannot be substituted. Control measures f Wear a face shield along with goggles when working with include: (1) enclosing chemical processes for severely corrosive, highly irritating or toxic substances. irritating and corrosive chemicals, (2) using local exhaust f Contact lenses should not be worn when working with this ventilation for chemicals that may be harmful with a single substance. exposure, and (3) using general ventilation to control exposures to skin and eye irritants. For further information on Respiratory Protection workplace controls, consult the NIOSH document on Control Improper use of respirators is dangerous. Such equipment Banding at www.cdc.gov/niosh/topics/ctrlbanding/. should only be used if the employer has a written program that takes into account workplace conditions, requirements for The following work practices are also recommended: worker training, respirator fit testing, and medical exams as described in the OSHA Respiratory Protection Standard (29 f Label process containers. f Provide employees with hazard information and training. CFR 1910.134). f Monitor airborne chemical concentrations. f Use engineering controls if concentrations exceed f Where the potential exists for exposure over 1 ppm, use a recommended exposure levels. NIOSH approved full facepiece respirator with an acid gas f Provide eye wash fountains and emergency showers. cartridge which is specifically approved for Boron f Wash or shower if skin comes in contact with a hazardous Tribromide. Increased protection is obtained from full material. facepiece powered-air purifying respirators. f Always wash at the end of the workshift. f Leave the area immediately if (1) while wearing a filter or f Change into clean clothing if clothing becomes cartridge respirator you can smell, taste, or otherwise detect contaminated. Boron Tribromide, (2) while wearing particulate filters f Do not take contaminated clothing home. abnormal resistance to breathing is experienced, or (3) eye f Get special training to wash contaminated clothing. irritation occurs while wearing a full facepiece respirator. f Do not eat, smoke, or drink in areas where chemicals are Check to make sure the respirator-to-face seal is still good. being handled, processed or stored. If it is, replace the filter or cartridge. If the seal is no longer f Wash hands carefully before eating, smoking, drinking, good, you may need a new respirator. applying cosmetics or using the toilet. f Consider all potential sources of exposure in your workplace. You may need a combination of filters, prefilters or cartridges In addition, the following may be useful or required: to protect against different forms of a chemical (such as vapor and mist) or against a mixture of chemicals. f Before entering a confined space where Boron Tribromide f Where the potential exists for exposure over 10 ppm, use a may be present, check to make sure that an explosive NIOSH approved supplied-air respirator with a full facepiece concentration does not exist. operated in a pressure-demand or other positive-pressure mode. For increased protection use in combination with an auxiliary self-contained breathing apparatus operated in a pressure-demand or other positive-pressure mode. Personal Protective Equipment The OSHA Personal Protective Equipment Standard (29 CFR 1910.132) requires employers to determine the appropriate personal protective equipment for each hazard and to train Fire Hazards employees on how and when to use protective equipment. If employees are expected to fight fires, they must be trained and equipped as stated in the OSHA Fire Brigades Standard The following recommendations are only guidelines and may (29 CFR 1910.156). not apply to every situation.
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