minerals Article Genesis and Evolution of Ferromanganese Crusts from the Summit of Rio Grande Rise, Southwest Atlantic Ocean Mariana Benites 1,*, James R. Hein 2 , Kira Mizell 2 , Terrence Blackburn 3 and Luigi Jovane 1 1 Institute of Oceanography, University of São Paulo, Praça do Oceanográfico 191, 05508-120 São Paulo, SP, Brazil;
[email protected] 2 U.S. Geological Survey, PCMSC, 2885 Mission St., Santa Cruz, CA 95060, USA;
[email protected] (J.R.H.);
[email protected] (K.M.) 3 Department of Earth Sciences, University of California, Santa Cruz, 1156 High Street EMS A108, Santa Cruz, CA 95064, USA;
[email protected] * Correspondence:
[email protected]; Tel.: +55-11-3091-6609 Received: 23 February 2020; Accepted: 10 April 2020; Published: 14 April 2020 Abstract: The Rio Grande Rise (RGR) is a large elevation in the Atlantic Ocean and known to host potential mineral resources of ferromanganese crusts (Fe–Mn), but no investigation into their general characteristics have been made in detail. Here, we investigate the chemical and mineralogical composition, growth rates and ages of initiation, and phosphatization of relatively shallow-water (650–825 m) Fe–Mn crusts dredged from the summit of RGR by using computed tomography, X-ray diffraction, 87Sr/86Sr ratios, U–Th isotopes, and various analytical techniques to determine their chemical composition. Fe–Mn crusts from RGR have two distinct generations. The older one has an estimated age of initiation around 48–55 Ma and was extensively affected by post-depositional processes under suboxic conditions resulting in phosphatization during the Miocene (from 20 to 6.8 Ma).