Appendix A.1 Refractive Indices of Biaxial Minerals

Total Page:16

File Type:pdf, Size:1020Kb

Appendix A.1 Refractive Indices of Biaxial Minerals Appendix A.1 Refractive indices of biaxial minerals Silicates 14 1515416 1 7 18 amphiboles anthophyllite-gedrite tremolite-ferroactinolite the hornblende series glaucophane-riebeckite richterite katophorite -- oxyliornblende kaersutite eckermannite -- arfvedsonite -- Al2SiOs polymorphs andalusite - kyanite - sillimanite - chlorite chloritoid - clay minerals kaolin - illite f-- montmorillonite cordierite - r-- epidote group zoisite clinozoisite - epidote - feldspar group K feldspars - } alkali feldspars Na feldspars (albite) - } plagioclase feldspars Ca feldspars (anorthite) - I 1 4 1 5 1 54 1 6 17 1 8 19 humite group norbergite -- chondrodite humite --- clinohumite mica group phlogopite I-- biotite muscovite - I- lepidolite - - paragonite - glauconite - olivine group forsterite } Fo Fa fayalite 01" pumpellyite pyroxene group enstatite-orthoferrosilit e opx diopside-hedenbergite di" augite pigeonite - t-- aegirine aegirine - augite jadeite -- spodumene -- wollastonite -- serpentine I- silica group tridymite - sphene staurolite - talc ~ 1.4 1.5 1.54 1.6 1.7 1 8 1.9 topaz - zeolites - f-- Non-silicates carbonates aragonite sulphates barite - celestite - gypsum - anhydrite - ~ wolframite 2.15-2.44 --- Appendix A.2 Refractive indices of positive uniaxial minerals Silicates 14 1 5 16 17 18 19 20 beryl - feldspathoid family leucite melilite group gehlenite - silica group quartz - zircon Non-silicates cassiterite - rutile 2.6-2.9 ___ brucite - Appendix A.3 Refractive indices of negative uniaxial minerals Silicates 1.4 1.5 1.6 1.7 1.8 1.9 feldspathoid family nepheline - melilite group akermanite scapolite - silica group cristobalite tourmaline vesuvianite Non-silicates carbonates calcite dolomite siderite rhodochrosite corundum apatite Appendix A.4 Refractive indices of isotropic minerals Silicates 1.4 1.5 1.6 1.7 1.8 1.9 feldspathoid family (leucite) soda lite analcime garnet group Non-silicates sphalerite spinel group -+2.4 (transparent members) fluorite halite Appendix B 2V size and sign of biaxial minerals Positive (2V~) Negative (2Vo) Silicates o 20 40 60 80 90 80 60 40 20 o amphiboles anthophyllite-gedrite tremolite-ferroactinolite -t-- the hornblende series glaucophane glaucophane-riebeckite riebeckite richterite katophorite f- - oxyhornblende kaersutite - - eckermannite arfvedsonite Al 2SiOs polymorphs andalusite - kyanite . sillimanite - chlorite chloritoid - - clay minerals kaolin - f-- illite -- montmorillonite --- -- cordie rite epidote group zoisite clinozoisite epidote - - feldspar group K feldspar plagioclase feldspar 2Vy 2Va o 20 40 60 80 90 80 60 40 20 0 humite group norbergite - chondrodite I-f- humite -I- clinohumite mica group phlogopite - biotite -I-- muscovite lepidolite - I-- paragonite glauconite - olivine group Fe Fa pumpellyite pyroxene group En Fs ens tat i te--{) rth ofe rrosi Ii t e diopside-hedenbergite - augite pigeonite aegirine - aegirine-augite jadeite - spodumene - wollastonite - serpentine - antigorite silica group tridymite sphene -- 2V, 2V a o 20 40 60 80 90 80 60 40 20 0 staurolite 1- talc topaz - r- zeolites -- ~- 1-1- -- -- -- f- Non-silicates carbonates aragonite • sulphates barite • celestite • gypsum • anhydrite • wolframite I- Appendix C Properties of are minerals Mineral Formula ~R% Colour ~VHN Anisotropy Distinguished properties/resemblance See range (associations) page acanthite Ag2S 30-31 light grey 20-60 distinct twin lamellae low temp. polymorph (greenish) (Pb-Sb-As-Bi-Ag-Au) alabandite MnS 25 light grey 140-270 isotropic lamellar twinning; brown or green internal reflections (sulphides, Mn-carbonates) anatase Ti02 20 light grey 580-620 weak abundant colourful internal reflections; 164 low temp. polymorph resembles rutile (Fe-Ti-O, pyrite) argentite Ag2S 30 light grey 20-60 isotropic high temp. polymorph (greenish) (Ag-sulphides, Cu-Pb-S, Au) armalcolite (Fe,Mg)Ti2O, 13-14 grey ? moderate barrel shape (brownish) (Fe-Ti-O, moon) arsenopyrite FeAsS 52 white 1050-1130 distinct rhomb shape, twinning, zoning 140 (Sulphides, oxides, Au-Bi-Te-Sn, W) bismuth Bi 60-65 bright white 10-20 distinct tarnishes brown, multiple twinning (Co-Ni-As-S, Au-Bi, Te) bismuthinite Bi,S3 40-50 white (bluish) 70-220 very strong fibrous, straight extinction (Co-Ni-As-S, Au-Bi-Te, Mo, Sn, W) Mineral Formula -R% Colour -VHN Anisotropy Distinguished properties/resemblance See range (associations) page blaubleibender Cu.+xS resembles covellite but Ro blue in oil 144 covellite -- - - (Cu-Fe-S) bornite Cu,FeS4 22 light pinkish 100 very weak tarnishes to blue or purple. 141 brown Intergrowths with chalcopyrite (Cu-Fe-S) boulangerite PbsSb4 S 11 38-41 light grey 90-180 distinct stronger anisotropy than bournonite (greenish) (Pb-Sb-S,Cu-Fe-S) bournonite CuPbSbS, 35-37 light grey 130-210 weak common twinning (bluish) (Pb-Sb-S,Cu-Fe-S) braunite Mn,SiO.2 20-22 light grey 880-1190 weak resembles some manganese oxides; (brownish) may be magnetic (Mn-Fe-Si-O, mainly in metamorphic rocks) bravoite (Fe,Ni,Co)S2 31-54 light grey to 670-1540 isotropic colour zoning 149 Ni,eo-Fe white (pyrite and other sulphides) (brownish) carrollite C02CUS 4 43 white 350-570 isotropic resembles linnaeite (pinkish) (Co-Cu-Fe-S) cassiterite Sn02 11-13 grey 1030-1080 distinct common twinning; strong colourless to 158 brown internal reflections; cleavage (W, Bi, As, B, sulphides) chalcocite Cu2S 32 light grey 70-100 weak lancet shaped twinning 142 (bluish) ( colourful) (Cu-Fe-S) chalcopyrite CuFeSz 42-46 yellow 190-220 weak twinning,; more yellow and softer than 143 pyrite; as inclusions in sphalerite (Cu-Fe-Ni-S, sulphides) chromite FeCrzO. 12 grey 1200-1210 isotropic rounded octahedra; resembles 160 (brownish) (weak magnetite but non-magnetic anisotropy) (Fe-Ti-O) cinnabar HgS 28-29 light grey 50-100 moderate multiple twinning; abundant red 144 (bluish) internal reflections; rare (Hg-Sb--S, Fe-S) cobaltite CoAsS 53 white 1180-1230 weak often idiom orphic cubic; colour 144 orthorhombic (pinkish) zonation; cleavage traces (Cu-Fe-S, Co-Ni-As-S) cohenite Fe3C white weak resembles iron (Fe, Fe-O, Fe-Ni-S) meteorites copper Cu 81 metallic pink 120-140 isotropic scratches easily 177 (tarnishes) (Cu-O, Cu-Fe-S) covellite CuS 7-22 blue to 70-80 very strong plates and flakes; pleochroic 144 bluish light (fiery (Cu-Fe-S) grey orange) cryptomelane -KzMn,O,. 27 light grey 530-1050 distinct fibrous, botryoidal; resembles psilomelane; straight extinction (Fe-Mn-O) cubanite CuFeZS3 40 light grey 150-260 strong lamellae within pyrrhotite, orthorhombic (yellowish chalcopyrite brown) (Cu-Fe-S) Mineral Formula -R% Colour -VHN Anisotropy Distinguished properties/resemblance See range (associations) page cubanite CuFe2S, 35 light grey isotropic intergrown with orthorhombic cubanite cubic (pinkish) (Cu-Fe-S) cuprite Cu2 0 25-30 light grey 180-220 strong deep red internal reflections (bluish) (Cu, Fe-OH, Cu-Fe-S, Ag) digenite Cu.S, 22 light grey 60-70 isotropic 142 (bluish) (Cu-Fe-S) djurleite Cu, .•• S ~ ~ ~ ~ resembles chalcocite electrum (Au,Ag) 83 light yellow 30-40 isotropic resembles gold 178 (Au-Te-Bi-Cu-Fe-As-Sb-Pb-S) enargite Cu,AsS4 25-29 light grey 130-580 strong cleavage II (110) (pinkish) colourful (Cu-Fe-Sb-As-S) galena PbS 43 white 70-80 isotropic triangular cleavage pits 145 (Pb-Ag-Sb-As-S, sulphides) gersdorffite (Ni,Co,Fe )AsS 47-54 white 520-910 isotropic zoning, cleavage II (100) gives (pinkish) triangular pits (Fe-Co-Ni-As-S) glaucodot (Co,Fe)AsS 45-50 white 840-1280 distinct idiomorphic, cleavage; as inclusions orthorhombic in cobaltite (Co-Ni-As-S) goethite HFe02 17 grey 770-820 distinct Colloform, botryoidal or elongate 170 orthorhombic crystals; red to brown internal reflections (in limonite, Fe-minerals, gossans) gold Au 74 bright yellow 50 isotropic very bright; as inclusions in 178 sulphides; in fractures; soft (A u-Te-Bi-Cu-Fe-As-Sb-Pb-S) goldfieldite Cu,(Te,Sb )S4 32 light grey isotropic zoned (brownish) (Fe-Zn-S, Au-Ag-Te, Bi) graphite C 6-16 dark grey 10 strong deformed flakes; bireflectance strong; 178 (brownish) to cleavage grey (graphitic schists, graphite 'veins') hematite Fe,O, 25-30 light grey 920-1060 strong tabular crystals, microcrystalline 161 masses; lamellar twinning; weak bireflectance (Fe-Ti-O) hydrocarbon <5 dark grey isotropic rounded grains, interstitial masses, frosted surface, low reflectance but no internal reflections (sedimentary rocks, barite, carbonate, sulphide veins, U) ilmenite FeTi03 18-21 light grey 520-700 moderate occasional twinning; lamellar 162 (slightly inclusions of hematite pinkish) (Fe-Ti-O) iron Fe 65 bright white 120-290 isotropic rounded grains (Fe-Ni-S, moon, meteorites) jacobsite (Mn,Fe,Mg)(Fe,Mn),04 19 grey (brownish 720-750 isotropic rounded grains; fine aggregates; -greenish) strongly magnetic; resembles braunite (Mn-minerals; Fe-OH; in metamorphic rocks) Mineral Formula -R% Colour -YHN Anisotropy Distinguishing properties/resemblance See range (associations) page jamesonite Pb4FeSb,S8 36-41 light grey 70-130 strong acicular with cleavage and twin (greenish) lamellae parallel to length (Fe-Pb-Sb-Ag-S) kamacite (Fe,Ni) 60 white isotropic (Fe-Ni-S, Fe-Ti-Cr-O, (bluish) meteorites) lepidocrocite FeO(OH) 10--19 grey 690-780 very strong red to brown internal refiectioI)s 170 (In limonite, Fe-minerals, gossans) limonite FeO.OH.nH,O 16-19 bluish grey 690-820 strong abundant brown to red internal 170 (see goethite and ( colourful) reflections lepidocrocite) (replaces iron minerals) linnaeite CoJS4 45-50 white 350-570 isotropic cleavage II (100) (pinkish) (Cu-Fe-Ni-S) livingstonite HgSb4 S8 35-40
Recommended publications
  • Xrd and Tem Studies on Nanophase Manganese
    Clays and Clay Minerals, Vol. 64, No. 5, 488–501, 2016. 1 1 2 2 3 XRD AND TEM STUDIES ON NANOPHASE MANGANESE OXIDES IN 3 4 FRESHWATER FERROMANGANESE NODULES FROM GREEN BAY, 4 5 5 6 LAKE MICHIGAN 6 7 7 8 8 S EUNGYEOL L EE AND H UIFANG X U* 9 9 NASA Astrobiology Institute, Department of Geoscience, University of Wisconsin Madison, Madison, 10 À 10 1215 West Dayton Street, A352 Weeks Hall, Wisconsin 53706 11 11 12 12 13 Abstract—Freshwater ferromanganese nodules (FFN) from Green Bay, Lake Michigan have been 13 14 investigated by X-ray powder diffraction (XRD), micro X-ray fluorescence (XRF), scanning electron 14 microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), and scanning 15 transmission electron microscopy (STEM). The samples can be divided into three types: Mn-rich 15 16 nodules, Fe-Mn nodules, and Fe-rich nodules. The manganese-bearing phases are todorokite, birnessite, 16 17 and buserite. The iron-bearing phases are feroxyhyte, goethite, 2-line ferrihydrite, and proto-goethite 17 18 (intermediate phase between feroxyhyte and goethite). The XRD patterns from a nodule cross section 18 19 suggest the transformation of birnessite to todorokite. The TEM-EDS spectra show that todorokite is 19 associated with Ba, Co, Ni, and Zn; birnessite is associated with Ca and Na; and buserite is associated with 20 2+ +2 3+ 20 Ca. The todorokite has an average chemical formula of Ba0.28(Zn0.14Co0.05 21 2+ 4+ 3+ 3+ 3+ 2+ 21 Ni0.02)(Mn4.99Mn0.82Fe0.12Co0.05Ni0.02)O12·nH2O.
    [Show full text]
  • The Behavior of Molybdenum., Tungsten, and Titanium
    The behavior of molybdenum, tungsten, and titanium in the porphyry copper environment Item Type text; Dissertation-Reproduction (electronic) Authors Kuck, Peter Hinckley Publisher The University of Arizona. Rights Copyright © is held by the author. Digital access to this material is made possible by the University Libraries, University of Arizona. Further transmission, reproduction or presentation (such as public display or performance) of protected items is prohibited except with permission of the author. Download date 08/10/2021 00:24:06 Link to Item http://hdl.handle.net/10150/565421 THE BEHAVIOR OF MOLYBDENUM., TUNGSTEN, AND TITANIUM IN THE PORPHYRY COPPER ENVIRONMENT Peter' 'Hinckley Kuck A Dissertation Submitted to the Faculty of the DEPARTMENT OF GEOSCIENCES. In Partial.Fulfillment of the Requirements. ' ■ For the Degree of DOCTOR OF PHILOSOPHY In the Graduate College ■ THE UNIVERSITY OF ARIZONA 1 9 7 8 THE UNIVERSITY OF ARIZONA GRADUATE COLLEGE I hereby recommend that this dissertation prepared under my Peter Hinckley Kuck direction by ___________ , , The Behavior of Molybdenum, Tungsten, and Titanium entitled ________________________________________________________ in the Porphyry Copper Environment be accepted as fulfilling the dissertation requirement for the Doctor of Philosophy degree of _______________________________________________________ Dissertation Director Date As members of the Final Examination Committee, we certify that we have read this dissertation and agree that it may be presented for final defense. \ R A j r i A hi / 7IT 2 / 1 r 7 - Final approval and acceptance of this dissertation is contingent on the candidate's adequate performance and defense thereof at the final oral examination. STATEMENT BY AUTHOR This dissertation has been submitted in partial fulfillment of requirements for an advanced degree at The University of Arizona and is deposited in the University Library to be made available to borrowers under rules of.
    [Show full text]
  • Abstract in PDF Format
    PGM Associations in Copper-Rich Sulphide Ore of the Oktyabr Deposit, Talnakh Deposit Group, Russia Olga A. Yakovleva1, Sergey M. Kozyrev1 and Oleg I. Oleshkevich2 1Institute Gipronickel JS, St. Petersburg, Russia 2Mining and Metallurgical Company “Noril’sk Nickel” JS, Noril’sk, Russia e-mail: [email protected] The PGM assemblages of the Cu-rich 6%; the Ni content ranges 0.8 to 1.3%, and the ratio sulphide ores occurring in the western exocontact Cu/S = 0.1-0.2. zone of the Talnakh intrusion and the Kharaelakh Pyrrhotite-chalcopyrite ore occurs at the massive orebody have been studied. Eleven ore top of ore horizons. The ore-mineral content ranges samples, weighing 20 to 200 kg, were processed 50 to 60%, and pyrrhotite amount is <15%. The ore using gravity and flotation-gravity techniques. As a grades 1.1 to 1.3% Ni, and the ratio Cu/S = 0.35- result, the gravity concentrates were obtained from 0.7. the ores and flotation products. In the gravity Chalcopyrite ore occurs at the top and on concentrates, more than 20,000 PGM grains were the flanks of the orebodies. The concentration of found and identified, using light microscopy and sulphides ranges 50 to 60%, and pyrrhotite amount EPMA. The textural and chemical characteristics of is <1%; the Ni content ranges 1.3 to 3.4%, and the PGM were documented, as well as the PGM ratio Cu/S = 0.8-0.9. distribution in different size fractions. Also, the The ore types are distinctly distinguished balance of Pt, Pd and Au distribution in ores and by the PGE content which directly depends on the process products and the PGM mass portions in chalcopyrite quantity, but not on the total sulphide various ore types were calculated.
    [Show full text]
  • Redalyc.Mineralogical Study of the La Hueca Cretaceous Iron-Manganese
    Revista Mexicana de Ciencias Geológicas ISSN: 1026-8774 [email protected] Universidad Nacional Autónoma de México México Corona Esquivel, Rodolfo; Ortega Gutiérrez, Fernando; Reyes Salas, Margarita; Lozano Santacruz, Rufino; Miranda Gasca, Miguel Angel Mineralogical study of the La Hueca Cretaceous Iron-Manganese deposit, Michoacán, south-western Mexico Revista Mexicana de Ciencias Geológicas, vol. 17, núm. 2, 2000, pp. 142-151 Universidad Nacional Autónoma de México Querétaro, México Available in: http://www.redalyc.org/articulo.oa?id=57217206 How to cite Complete issue Scientific Information System More information about this article Network of Scientific Journals from Latin America, the Caribbean, Spain and Portugal Journal's homepage in redalyc.org Non-profit academic project, developed under the open access initiative Revista Mexicana de Ciencias Geológicas, volumen 17, número 2, 143 2000, p. 143- 153 Universidad Nacional Autónoma de México, Instituto de Geología, México, D.F MINERALOGICAL STUDY OF THE LA HUECA CRETACEOUS IRON- MANGANESE DEPOSIT, MICHOACÁN, SOUTHWESTERN MEXICO Rodolfo Corona-Esquivel1, Fernando Ortega-Gutiérrez1, Margarita Reyes-Salas1, Rufino Lozano-Santacruz1, and Miguel Angel Miranda-Gasca2 ABSTRACT In this work we describe for the first time the mineralogy and very briefly the possible origin of a banded Fe-Mn deposit associated with a Cretaceous volcanosedimentary sequence of the southern Guerrero terrane, near the sulfide massive volcanogenic deposit of La Minita. The deposit is confined within a felsic tuff unit; about 10 meters thick where sampled for chemical analysis. Using XRF, EDS and XRD techniques, we found besides todorokite, cryptomelane, quartz, romanechite (psilomelane), birnessite, illite-muscovite, cristobalite, chlorite, barite, halloysite, woodruffite, nacrite or kaolinite, and possibly hollandite-ferrian, as well as an amorphous material and two unknown manganese phases.
    [Show full text]
  • Metamorphism of Sedimentary Manganese Deposits
    Acta Mineralogica-Petrographica, Szeged, XX/2, 325—336, 1972. METAMORPHISM OF SEDIMENTARY MANGANESE DEPOSITS SUPRIYA ROY ABSTRACT: Metamorphosed sedimentary deposits of manganese occur extensively in India, Brazil, U. S. A., Australia, New Zealand, U. S. S. R., West and South West Africa, Madagascar and Japan. Different mineral-assemblages have been recorded from these deposits which may be classi- fied into oxide, carbonate, silicate and silicate-carbonate formations. The oxide formations are represented by lower oxides (braunite, bixbyite, hollandite, hausmannite, jacobsite, vredenburgite •etc.), the carbonate formations by rhodochrosite, kutnahorite, manganoan calcite etc., the silicate formations by spessartite, rhodonite, manganiferous amphiboles and pyroxenes, manganophyllite, piedmontite etc. and the silicate-carbonate formations by rhodochrosite, rhodonite, tephroite, spessartite etc. Pétrographie and phase-equilibia data indicate that the original bulk composition in the sediments, the reactions during metamorphism (contact and regional and the variations and effect of 02, C02, etc. with rise of temperature, control the mineralogy of the metamorphosed manga- nese formations. The general trend of formation and transformation of mineral phases in oxide, carbonate, silicate and silicate-carbonate formations during regional and contact metamorphism has, thus, been established. Sedimentary manganese formations, later modified by regional or contact metamorphism, have been reported from different parts of the world. The most important among such deposits occur in India, Brazil, U.S.A., U.S.S.R., Ghana, South and South West Africa, Madagascar, Australia, New Zealand, Great Britain, Japan etc. An attempt will be made to summarize the pertinent data on these metamorphosed sedimentary formations so as to establish the role of original bulk composition of the sediments, transformation and reaction of phases at ele- vated temperature and varying oxygen and carbon dioxide fugacities in determin- ing the mineral assemblages in these deposits.
    [Show full text]
  • Mineralization at Le Pulec, Jersey, Channel Islands; No. 1 Lode
    134 SHORT COMMUNICATIONS REFERENCES McKay, W. J. (1975) Woodlawn copper-lead-zinc orebody. Ibid. 701-10. Davis, L. W. (1975) Captains Flat lead-zinc orebody. In Knight, C. L. (ed.). Economic Geology of Australia and Papua New Guinea I. Metals. Melbourne, Australasian [Revised manuscript received 2 June 1981] Institute of Mining and Metallurgy, 691-700. Malone, E. J., Olgers, F., Cucchi, F. G., Nicholas, T., and t~) Copyright the Mineralogical Society Dept. of Geology, University of Wollonoong, New South Wales, Australia F. IVOR ROBERTS [Present address: School of Applied Geology, University of New South Wales, PO Box 1, Kensinoton , NSW 2033, Australia] MINERALOGICAL MAGAZINE, MARCH 1982, VOL. 46, PP. 134-6 Mineralization at Le Pulec, Jersey, Channel Islands; No. 1 Lode THE No. 1 Lode is the westernmost and most Mineralization within the Brioverian sediments extensive of three lead-zinc veins cutting Brioverian sediments at Le Pulec. It was described by Williams Anatase is common within the sediments as 2-10 (1871) as being between 1.5 and 1.8 m in width and pm anhedral grains associated with silicates or 183 m in length, with a trend of 340 ~ and the as 10 x 2 #m laths, parallel to the basal cleavage galena was reported to have a high silver content. of the altered phyllosilicates, particularly musco- Since the investigation of the No. 3 Lode (Ixer and vite. Anatase is also found with hematite laths Stanley, 1980) it has been possible to examine (20x 2 /~m) included in early pyrite grains. A several specimens, collected from the recently re- coarse-grained (600 x 20 pm) generation of anatase discovered No.
    [Show full text]
  • The Nature of Waste Associated with Closed Mines in England and Wales
    The nature of waste associated with closed mines in England and Wales Minerals & Waste Programme Open Report OR/10/14 BRITISH GEOLOGICAL SURVEY MINERALS & WASTE PROGRAMME OPEN REPORT OR/10/14 The National Grid and other Ordnance Survey data are used with the permission of the The nature of waste associated Controller of Her Majesty’s Stationery Office. OS Topography © Crown with closed mines in England and Copyright. All rights reserved. BGS 100017897/2010 Wales Keywords Abandoned mine waste facilities; Palumbo-Roe, B and Colman, T England and Wales; mineral deposits; environmental impact; Contributor/editor European Mine Waste Directive. Cameron, D G, Linley, K and Gunn, A G Front cover Graiggoch Mine (SN 7040 7410), Ceredigion, Wales. Bibliographical reference Palumbo-Roe, B and Colman, T with contributions from Cameron, D G, Linley, K and Gunn, A G. 2010. The nature of waste associated with closed mines in England and Wales. British Geological Survey Open Report, OR/10/14. 98pp. Copyright in materials derived from the British Geological Survey’s work is owned by the Natural Environment Research Council (NERC) and the Environment Agency that commissioned the work. You may not copy or adapt this publication without first obtaining permission. Contact the BGS Intellectual Property Rights Section, British Geological Survey, Keyworth, e-mail [email protected]. You may quote extracts of a reasonable length without prior permission, provided a full acknowledgement is given of the source of the extract. The views and statements expressed in this report are those of the authors alone and do not necessarily represent the views of the Environment Agency.
    [Show full text]
  • LOW TEMPERATURE HYDROTHERMAL COPPER, NICKEL, and COBALT ARSENIDE and SULFIDE ORE FORMATION Nicholas Allin
    Montana Tech Library Digital Commons @ Montana Tech Graduate Theses & Non-Theses Student Scholarship Spring 2019 EXPERIMENTAL INVESTIGATION OF THE THERMOCHEMICAL REDUCTION OF ARSENITE AND SULFATE: LOW TEMPERATURE HYDROTHERMAL COPPER, NICKEL, AND COBALT ARSENIDE AND SULFIDE ORE FORMATION Nicholas Allin Follow this and additional works at: https://digitalcommons.mtech.edu/grad_rsch Part of the Geotechnical Engineering Commons EXPERIMENTAL INVESTIGATION OF THE THERMOCHEMICAL REDUCTION OF ARSENITE AND SULFATE: LOW TEMPERATURE HYDROTHERMAL COPPER, NICKEL, AND COBALT ARSENIDE AND SULFIDE ORE FORMATION by Nicholas C. Allin A thesis submitted in partial fulfillment of the requirements for the degree of Masters in Geoscience: Geology Option Montana Technological University 2019 ii Abstract Experiments were conducted to determine the relative rates of reduction of aqueous sulfate and aqueous arsenite (As(OH)3,aq) using foils of copper, nickel, or cobalt as the reductant, at temperatures of 150ºC to 300ºC. At the highest temperature of 300°C, very limited sulfate reduction was observed with cobalt foil, but sulfate was reduced to sulfide by copper foil (precipitation of Cu2S (chalcocite)) and partly reduced by nickel foil (precipitation of NiS2 (vaesite) + NiSO4·xH2O). In the 300ºC arsenite reduction experiments, Cu3As (domeykite), Ni5As2, or CoAs (langisite) formed. In experiments where both sulfate and arsenite were present, some produced minerals were sulfarsenides, which contained both sulfide and arsenide, i.e. cobaltite (CoAsS). These experiments also produced large (~10 µm along longest axis) euhedral crystals of metal-sulfide that were either imbedded or grown upon a matrix of fine-grained metal-arsenides, or, in the case of cobalt, metal-sulfarsenide. Some experimental results did not show clear mineral formation, but instead demonstrated metal-arsenic alloying at the foil edges.
    [Show full text]
  • Washington State Minerals Checklist
    Division of Geology and Earth Resources MS 47007; Olympia, WA 98504-7007 Washington State 360-902-1450; 360-902-1785 fax E-mail: [email protected] Website: http://www.dnr.wa.gov/geology Minerals Checklist Note: Mineral names in parentheses are the preferred species names. Compiled by Raymond Lasmanis o Acanthite o Arsenopalladinite o Bustamite o Clinohumite o Enstatite o Harmotome o Actinolite o Arsenopyrite o Bytownite o Clinoptilolite o Epidesmine (Stilbite) o Hastingsite o Adularia o Arsenosulvanite (Plagioclase) o Clinozoisite o Epidote o Hausmannite (Orthoclase) o Arsenpolybasite o Cairngorm (Quartz) o Cobaltite o Epistilbite o Hedenbergite o Aegirine o Astrophyllite o Calamine o Cochromite o Epsomite o Hedleyite o Aenigmatite o Atacamite (Hemimorphite) o Coffinite o Erionite o Hematite o Aeschynite o Atokite o Calaverite o Columbite o Erythrite o Hemimorphite o Agardite-Y o Augite o Calciohilairite (Ferrocolumbite) o Euchroite o Hercynite o Agate (Quartz) o Aurostibite o Calcite, see also o Conichalcite o Euxenite o Hessite o Aguilarite o Austinite Manganocalcite o Connellite o Euxenite-Y o Heulandite o Aktashite o Onyx o Copiapite o o Autunite o Fairchildite Hexahydrite o Alabandite o Caledonite o Copper o o Awaruite o Famatinite Hibschite o Albite o Cancrinite o Copper-zinc o o Axinite group o Fayalite Hillebrandite o Algodonite o Carnelian (Quartz) o Coquandite o o Azurite o Feldspar group Hisingerite o Allanite o Cassiterite o Cordierite o o Barite o Ferberite Hongshiite o Allanite-Ce o Catapleiite o Corrensite o o Bastnäsite
    [Show full text]
  • Selective Flotation of Enargite from Copper Sulphides in Complex Ore Systems
    Selective flotation of enargite from copper sulphides in complex ore systems Maedeh Tayebi-Khorami M.Sc. (Mineral Processing Engineering) B.Sc. (Mining Engineering) A thesis submitted for the degree of Doctor of Philosophy at The University of Queensland in November 2016 Sustainable Minerals Institute Abstract Recent research has demonstrated promising results showing the possibility of separating arsenic- copper sulphides from other copper minerals by controlling the potential of the flotation pulp. Most of these studies were conducted on single mineral systems, and the selective removal of arsenic- copper minerals in real ore systems is not well understood. In real ore systems, the efficiency of the separation strongly depends on the mineralogical characteristics of the ore samples. This study seeks to understand the effect of ore mineralogy on the floatability of enargite in a complex ore system, under a controlled potential flotation environment. A composite of several high arsenic-containing drill core intersections for the high arsenic sample (HAS) and a composite of some low arsenic-containing drill core intersections for the low arsenic sample (LAS) were selected from the Tampakan copper-gold deposit in the Philippines, providing a range of arsenic levels. Arsenic in the HAS sample (enargite) was practically twice that for the LAS sample. The non-enargite copper minerals (NECu) were mostly chalcopyrite and bornite in both samples. Comprehensive size-by-size, chemical and mineralogical analyses were performed on both ore samples. It was observed that the two ore samples had similar mineralogical characteristics in terms of mineral content and liberation distribution, however there are some differences in the proportions of minerals.
    [Show full text]
  • Mineral Processing
    Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19
    [Show full text]
  • Key to Rocks & Minerals Collections
    STATE OF MICHIGAN MINERALS DEPARTMENT OF NATURAL RESOURCES GEOLOGICAL SURVEY DIVISION A mineral is a rock substance occurring in nature that has a definite chemical composition, crystal form, and KEY TO ROCKS & MINERALS COLLECTIONS other distinct physical properties. A few of the minerals, such as gold and silver, occur as "free" elements, but by most minerals are chemical combinations of two or Harry O. Sorensen several elements just as plants and animals are Reprinted 1968 chemical combinations. Nearly all of the 90 or more Lansing, Michigan known elements are found in the earth's crust, but only 8 are present in proportions greater than one percent. In order of abundance the 8 most important elements Contents are: INTRODUCTION............................................................... 1 Percent composition Element Symbol MINERALS........................................................................ 1 of the earth’s crust ROCKS ............................................................................. 1 Oxygen O 46.46 IGNEOUS ROCKS ........................................................ 2 Silicon Si 27.61 SEDIMENTARY ROCKS............................................... 2 Aluminum Al 8.07 METAMORPHIC ROCKS.............................................. 2 Iron Fe 5.06 IDENTIFICATION ............................................................. 2 Calcium Ca 3.64 COLOR AND STREAK.................................................. 2 Sodium Na 2.75 LUSTER......................................................................... 2 Potassium
    [Show full text]