Paired Metamorphic Belts
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Facies and Mafic
Metamorphic Facies and Metamorphosed Mafic Rocks l V.M. Goldschmidt (1911, 1912a), contact Metamorphic Facies and metamorphosed pelitic, calcareous, and Metamorphosed Mafic Rocks psammitic hornfelses in the Oslo region l Relatively simple mineral assemblages Reading: Winter Chapter 25. (< 6 major minerals) in the inner zones of the aureoles around granitoid intrusives l Equilibrium mineral assemblage related to Xbulk Metamorphic Facies Metamorphic Facies l Pentii Eskola (1914, 1915) Orijärvi, S. l Certain mineral pairs (e.g. anorthite + hypersthene) Finland were consistently present in rocks of appropriate l Rocks with K-feldspar + cordierite at Oslo composition, whereas the compositionally contained the compositionally equivalent pair equivalent pair (diopside + andalusite) was not biotite + muscovite at Orijärvi l If two alternative assemblages are X-equivalent, l Eskola: difference must reflect differing we must be able to relate them by a reaction physical conditions l In this case the reaction is simple: l Finnish rocks (more hydrous and lower MgSiO3 + CaAl2Si2O8 = CaMgSi2O6 + Al2SiO5 volume assemblage) equilibrated at lower En An Di Als temperatures and higher pressures than the Norwegian ones Metamorphic Facies Metamorphic Facies Oslo: Ksp + Cord l Eskola (1915) developed the concept of Orijärvi: Bi + Mu metamorphic facies: Reaction: “In any rock or metamorphic formation which has 2 KMg3AlSi 3O10(OH)2 + 6 KAl2AlSi 3O10(OH)2 + 15 SiO2 arrived at a chemical equilibrium through Bt Ms Qtz metamorphism at constant temperature and = -
Finding of Prehnite-Pumpellyite Facies Metabasites from the Kurosegawa Belt in Yatsushiro Area, Kyushu, Japan
Journal ofPrehnite Mineralogical-pumpellyite and Petrological facies metabasites Sciences, in Yatsushiro Volume 107, area, page Kyushu 99─ 104, 2012 99 LETTER Finding of prehnite-pumpellyite facies metabasites from the Kurosegawa belt in Yatsushiro area, Kyushu, Japan * * ** Kenichiro KAMIMURA , Takao HIRAJIMA and Yoshiyuki FUJIMOTO *Department of Geology and Mineralogy, Graduate School of Science, Kyoto University, Kitashirakawa Oiwakecho, Kyoto 606-8502, Japan ** Nittetsu-Kogyo Co., Ltd, 2-3-2 Marunouchi, Chiyoda, Tokyo 100-8377, Japan. Common occurrence of prehnite and pumpellyite is newly identified from metabasites of Tobiishi sub-unit in the Kurosegawa belt, Yatsushiro area, Kyushu, where Ueta (1961) had mapped as a greenschist facies area. Prehnite and pumpellyite are closely associated with chlorite, calcite and quartz, and they mainly occur in white colored veins or in amygdules in metabasites of the relevant area, but actinolite and epidote are rare in them. Pumpellyite is characterized by iron-rich composition (7.2-20.0 wt% as total iron as FeO) and its range almost overlaps with those in prehnite-pumpellyite facies metabasites of Ishizuka (1991). These facts suggest that the metabasites of the Tobiishi sub-unit suffered the prehnite-pumpellyite facies metamorphism, instead of the greenschist facies. Keywords: Prehnite-pumpellyite facies, Lawsonite-blueschist facies, Kurosegawa belt INTRODUCTION 1961; Kato et al., 1984; Maruyama et al., 1984; Tsujimori and Itaya, 1999; Tomiyoshi and Takasu, 2009). Until now, The subduction zone has an essential role for the global there is neither clear geological nor petrological evidence circulation of solid, fluid and volatile materials between suggesting what type of metamorphic rocks occupied the the surface and inside of the Earth at present. -
The Origin of Formation of the Amphibolite- Granulite Transition
The Origin of Formation of the Amphibolite- Granulite Transition Facies by Gregory o. Carpenter Advisor: Dr. M. Barton May 28, 1987 Table of Contents Page ABSTRACT . 1 QUESTION OF THE TRANSITION FACIES ORIGIN • . 2 DEFINING THE FACIES INVOLVED • • • • • • • • • • 3 Amphibolite Facies • • • • • • • • • • 3 Granulite Facies • • • • • • • • • • • 5 Amphibolite-Granulite Transition Facies 6 CONDITIONS OF FORMATION FOR THE FACIES INVOLVED • • • • • • • • • • • • • • • • • 8 Amphibolite Facies • • • • • • • • 9 Granulite Facies • • • • • • • • • •• 11 Amphibolite-Granulite Transition Facies •• 13 ACTIVITIES OF C02 AND H20 . • • • • • • 1 7 HYPOTHESES OF FORMATION • • • • • • • • •• 19 Deep Crust Model • • • • • • • • • 20 Orogeny Model • • • • • • • • • • • • • 20 The Earth • • • • • • • • • • • • 20 Plate Tectonics ••••••••••• 21 Orogenic Events ••••••••• 22 Continent-Continent Collision •••• 22 Continent-Ocean Collision • • • • 24 CONCLUSION • . • 24 BIBLIOGRAPHY • • . • • • • 26 List of Illustrations Figure 1. Precambrian shields, platform sediments and Phanerozoic fold mountain belts 2. Metamorphic facies placement 3. Temperature and pressure conditions for metamorphic facies 4. Temperature and pressure conditions for metamorphic facies 5. Transformation processes with depth 6. Temperature versus depth of a descending continental plate 7. Cross-section of the earth 8. Cross-section of the earth 9. Collision zones 10. Convection currents Table 1. Metamorphic facies ABSTRACT The origin of formation of the amphibolite granulite transition -
What We Know About Subduction Zones from the Metamorphic Rock Record
What we know about subduction zones from the metamorphic rock record Sarah Penniston-Dorland University of Maryland Subduction zones are complex We can learn a lot about processes occurring within active subduction zones by analysis of metamorphic rocks exhumed from ancient subduction zones Accreonary prism • Rocks are exhumed from a wide range of different parts of subduction zones. • Exhumed rocks from fossil subduction zones tell us about materials, conditions and processes within subduction zones • They provide complementary information to observations from active subduction systems Tatsumi, 2005 The subduction interface is more complex than we usually draw Mélange (Bebout, and Penniston-Dorland, 2015) Information from exhumed metamorphic rocks 1. Thermal structure The minerals in exhumed rocks of the subducted slab provide information about the thermal structure of subduction zones. 2. Fluids Metamorphism generates fluids. Fossil subduction zones preserve records of fluid-related processes. 3. Rheology and deformation Rocks from fossil subduction zones record deformation histories and provide information about the nature of the interface and the physical properties of rocks at the interface. 4. Geochemical cycling Metamorphism of the subducting slab plays a key role in the cycling of various elements through subduction zones. Thermal structure Equilibrium Thermodynamics provides the basis for estimating P-T conditions using mineral assemblages and compositions Systems act to minimize Gibbs Free Energy (chemical potential energy) Metamorphic facies and tectonic environment SubduconSubducon zone metamorphism zone metamorphism Regional metamorphism during collision Mid-ocean ridge metamorphism Contact metamorphism around plutons Determining P-T conditions from metamorphic rocks Assumption of chemical equilibrium Classic thermobarometry Based on equilibrium reactions for minerals in rocks, uses the compositions of those minerals and their thermodynamic properties e.g. -
Metamorphic Facies Metamorphic Grade Metamorphic Zones
Metamorphic Grade • Controlled by the temperature of Metamorphic Facies metamorphism • Low-grade rocks contain hydrated and Best, Chapter 10 carbonated phases • High-grade rocks are dehydrated and decarbonized Metamorphic Zones • Mappable metamorphic units of similar grade in a rock of distinct composition • Isograds are lines marking the first appearance of key minerals • Zones of Barrow – Biotite, garnet, staurolite, kyanite, sillimanite Metamorphic Reactions Metamorphic Facies • Formation of talc in a siliceous dolomite Dol + Qtz + H20 = Tlc + Cal + C02 • The set of mineral assemblages occurring in • Controlled by the ratio of H 0/ C0 2 2 rocks of diverse composition • Facies develop under restricted P,T conditions • Mineral assemblages may be plotted on ACF diagrams Main Facies Review of Facies • Zeolite • Prehnite- • Mineral assemblages in metamorphosed pumpellyite mafic rocks •Blueschist • Greenschist • Correlation of Barrow’s zones with facies • Amphibolite from different protoliths • Granulite • P, T diagram for various facies • Eclogite P,T Relations Review of Phase Diagrams Jadeite + Quartz = Albite • Solid-solid reactions • Governed by Clapeyron equation – dP/dT = 10 ∆H/T ∆V = ∆S/∆V – ∆H is the heat of reaction – ∆S is the change in entropy – ∆V is the change in volume • The slope of the stability is dP/dT Open System Models - H2O Open System Models - CO2 • Dehydration curves • Dehydration curves • Example of the general • Example of the general case case • Specific minerals • Specific minerals – Breakdown of chlorite, – Breakdown of calcite, muscovite, biotite, etc dolomite, etc Univariant Curves • Curves that define reactions with one degree of freedom • In P-T space this means that if T is changed, than P must also change to maintain equilibrium • Many important metamorphic reactions are defined by these curves P-T Examples Stability of Iron Oxides • PO2 vs. -
Metamorphic Rocks
Metamorphic Rocks Geology 200 Geology for Environmental Scientists Regionally metamorphosed rocks shot through with migmatite dikes. Black Canyon of the Gunnison, Colorado Metamorphic rocks from Greenland, 3.8 Ga (billion years old) Major Concepts • Metamorphic rocks can be formed from any rock type: igneous, sedimentary, or existing metamorphic rocks. • Involves recrystallization in the solid state, often with little change in overall chemical composition. • Driving forces are changes in temperature, pressure, and pore fluids. • New minerals and new textures are formed. Major Concepts • During metamorphism platy minerals grow in the direction of least stress producing foliation. • Rocks with only one, non-platy, mineral produce nonfoliated rocks such as quartzite or marble. • Two types of metamorphism: contact and regional. Metamorphism of a Granite to a Gneiss Asbestos, a metamorphic amphibole mineral. The fibrous crystals grow parallel to least stress. Two major types of metamorphism -- contact and regional Major Concepts • Foliated rocks - slate, phyllite, schist, gneiss, mylonite • Non-foliated rocks - quartzite, marble, hornfels, greenstone, granulite • Mineral zones are used to recognize metamorphic facies produced by systematic pressure and temperature changes. Origin of Metamorphic Rocks • Below 200oC rocks remain unchanged. • As temperature rises, crystal lattices are broken down and reformed with different combinations of atoms. New minerals are formed. • The mineral composition of a rock provides a key to the temperature of formation (Fig. 6.5) Fig. 6.5. Different minerals of the same composition, Al2SiO5, are stable at different temperatures and pressures. Where does the heat come from? • Hot magma ranges from 700-12000C. Causes contact metamorphism. • Deep burial - temperature increases 15-300C for every kilometer of depth in the crust. -
12. Prehnite-Pumpellyite Facies Metamorphism in Oceanic Arc Basement from Site 791 in the Sumisu Rift, Western Pacific1
Taylor, B., Fujioka, K., et al., 1992 Proceedings of the Ocean Drilling Program, Scientific Results, Vol. 126 12. PREHNITE-PUMPELLYITE FACIES METAMORPHISM IN OCEANIC ARC BASEMENT FROM SITE 791 IN THE SUMISU RIFT, WESTERN PACIFIC1 Makoto Yuasa,2 Teruo Watanabe,3 Toshiaki Kuwajima,3 Tadao Hirama,4 and Kantaro Fujioka5 ABSTRACT Prehnite-pumpellyite facies metamorphism is described in the oceanic-arc basement rocks of Ocean Drilling Program Leg 126, Site 791 in the Sumisu Rift, western Pacific. Chemical variations of pumpellyite, epidote, chlorite, and prehnite are examined and paragenetic relations discussed. The metamorphism took place during the pre-rifting stage of an intraoceanic arc. During the backarc rifting stage, the geothermal gradient of the area was not as high as that of a spreading mid-oceanic ridge. INTRODUCTION The drill hole penetrated about 1100 m below the seafloor (mbsf) into basaltic basement (Shipboard Scientific Party, 1990). Studies of the metamorphism of the oceanic crust have advanced since the International Phase of Ocean Drilling (IPOD) project. Forearc "Ohmachi" Seamount According to the summary by Maruyama and Liou (1988), diversity in ocean-floor metamorphism reflects a difference in tectonics. For The Nishinoshima Trough has a rift morphology and obliquely cuts example, the fast-spreading Pacific Ocean has higher geothermal across the Izu-Bonin Arc between the Sofugan and Nishinoshima islands gradients than the slow-spreading Atlantic; and prehnite-pumpellyite (Fig. 1). The distance between the nearest islands is widest at about facies metamorphic rocks have not been collected from the Pacific 290 km here at the Shichito-Iwojima Ridge. There are nine large Ocean floor, but they have been obtained from the Atlantic Ocean and seamounts, some of which have parasitic highs, between the Sofugan and Philippine Sea floors where the geothermal gradient is rather low Nishinoshima islands. -
Geology of Natural Zeolites and Zeolitic Rocks
Pure &Appl.Chern., Vol.52, pp.2II5—2l3O. Pergamon Press Ltd. 1980. Printed in Great Britain. PlenaryPaper — Geology and Mineralogy GEOLOGY OF NATURAL ZEOLITES AND ZEOLITIC ROCKS Azumalijima Geological Institute, Faculty of Science, University of Tokyo, 7-3-1 Hongo, Tokyo 113, Japan ABSTRACT Presentstatus, particularly development in the latest decade, of the geology of natural zeolites and zeolitic rocks has been overviewed. Emphases are focused on the classification of genetical occurrences and the synthesis deduced from the nature.. INTRODUCTION Nearly two centuries have passed since zeolite was discovered and named by Cronstedt in 1756. Collection and mineralogical description of pretty, coarse crystals were the primary studies of zeolites for a long time till early this century. It is a great monument that the concept of zeolite facies was established by Eskola in 1936 as the low— est grade of the metamorphic facies. The concept was greatly developed by Coombs in New Zealand, having further been visualized by lijima, Seki and Utada in Japan. Researches on zeolites in alkaline, saline lake deposits by Hay, Gude and Sheppard in USA made our eyes open to the zeolite formation at or near the Earth's surface. From deep—sea sediments zeolites were already reported by Murray and Renard in 1891. The Deep Sea Drilling Project (1968—1975) by the Glomar Challenger cruises shed light on the deep—sea zeolites. Our knowledge on natural zeolites and zeolitic rocks has rapidly expanded during the latest two decades. The growth of study on natural zeolites has been and will be stimulated by increasing needs of them as a potential natural resource, instead of synthetic zeolites, particularly in Africa, East and West Europe, Japan, USA and USSR. -
Multiple Veining in a Paleo–Accretionary Wedge: the Metamorphic Rock Record of Prograde Dehydration and Transient High Pore- GEOSPHERE, V
Research Paper THEMED ISSUE: Subduction Top to Bottom 2 GEOSPHERE Multiple veining in a paleo–accretionary wedge: The metamorphic rock record of prograde dehydration and transient high pore- GEOSPHERE, v. 16, no. 3 fluid pressures along the subduction interface (Western Series, https://doi.org/10.1130/GES02227.1 11 figures; 2 tables; 1 set of supplemental files central Chile) Jesús Muñoz-Montecinos1,2,*, Samuel Angiboust1,*, Aitor Cambeses3,*, and Antonio García-Casco2,4,* CORRESPONDENCE: 1 [email protected] Institut de Physique du Globe de Paris, Université de Paris, CNRS, F-75005 Paris, France 2Department of Mineralogy and Petrology, Faculty of Sciences, University of Granada, Campus Fuentenueva s/n, 18002 Granada, Spain 3Institut für Geologie, Mineralogie und Geophysik, Ruhr-Universität Bochum, Bochum 44801, Germany CITATION: Muñoz-Montecinos, J., Angiboust, S., 4Instituto Andaluz de Ciencias de la Tierra, CSIC–Universidad de Granada, Armilla, Granada 18100, Spain Cambeses, A., and García-Casco, A., 2020, Multiple veining in a paleo–accretionary wedge: The metamor- phic rock record of prograde dehydration and transient high pore-fluid pressures along the subduction inter- ABSTRACT that the formation of interlayered blueschist and fluid-rock interaction events (Zack and John, 2007). face (Western Series, central Chile): Geosphere, v. 16, greenschist layers in Pichilemu metavolcanics is a Textures recorded in veins yield information on no. 3, p. 765–786, https://doi.org/10.1130/GES02227.1. High pressure–low temperature metamorphic consequence of local bulk composition variations, crack aperture as well as crystal growth kinetics rocks from the late Paleozoic accretionary wedge and that greenschists are generally not formed due during each veining event (Cox and Etheridge, 1983; Science Editor: Shanaka de Silva exposed in central Chile (Pichilemu region) are to selective exhumation-related retrogression of Bons, 2001), while vein-filling mineral assemblages Guest Associate Editor: Gray E. -
Metamorphic Facies Metamorphic Facies
ERSC 3P21 Metamorphic Petrology II 24/08/2011 Metamorphic Facies • Facies – ____________________________ ____________________________________ ____________________________________ • There is a predictable and common correspondence between the __________ of each rock and its ______________________ • Mineral _____________ that define the metamorphic _______ indicate that a state of stable _________ has been ________ over a restricted T and P condition. ERSC 3P21 - Brock University Greg Finn Metamorphic Facies • Several different facies have been formally recognized and have been named according to distinct aspects of the facies – eg. greenschist = characterized by schists in which green chlorite, talc, serpentine, epidote and actinolite are predominant • Examine the mineralogical characteristics in metamorphosed mafic (basic) rocks subjected to prograde metamorphism ERSC 3P21 - Brock University Greg Finn Metamorphic Grade Calculated 14 Geothermal Water Gradient saturated 40 granite 12 solidus Diagenesis 10 30 Liquid 8 VERY LOW or+ab+q HIGH GRADE 20 GRADE Depth (km) 6 Pressure (kbar) LOW 4 GRADE MEDIUM 10 GRADE mu + q 2 or+Al2SiO5+H2O 100 200 300 400 500 600 700 800 900 1000 Temperature (C) ERSC 3P21 - Brock University Greg Finn 1 ERSC 3P21 Metamorphic Petrology II 24/08/2011 Metamorphic Facies Calculated 14 Geothermal Water Gradient saturated 40 Eclogite granite 12 solidus Diagenesis Glaucophane 30 10 Lawsonite 8 Granulite 20 Amphibolite Depth (km) 6 Prehnite Pressure (kbar) Greenschist Pumpellyite 4 10 Zeolite 2 Px Hornfels Hornfels Sanidinite -
The Genesis of Zeolites
Eur. J. Mineral. 1989,1,479-487 The genesis of zeolites GLAUCoGOTTARDIt* Istituto di Mineralogia e Petrologia, Università di Modena, via S. Eufemia 19,1-41100 Modena, Italy Abstract: The equilibrium diagrams of zeolites and the different possibilities of synthesizing zeolites starting from chemicals, minerals, and natural glasses are reviewed so to have a general picture of the conditions of crystallization of these minerals. Subsequently, a description and interpretation is given of the geological environments where zeolites crystallize in nature. Key-words: zeolite, diagenesis, very-low-grade metamorphism, hydrothermalism, volcanic glass. 1. Introduction and heulandite generally contain some M+ ca tions, which are almost absent in laumontite, yu This topic has been the subject of so many publi gawaralite and wairakite, so the alkali metal con cations (e.g. Hay, 1978, 1986; Iijima, 1978, 1980; centration in the system may influence the given Kastner & Stonecipher, 1978; Surdam & Shep- boundaries. Additional diagrams on these zeolites pard, 1978) over the last ten years, that one may can be found in the literature, but none is known wonder "Why another one?". As a matter of fact, to the author for zeolites other than those men all these previous studies give detailed informa tioned here. Field and laboratory evidence suggests tion on rock-forming zeolites, generally crystal that some other alkali zeolites may have a stabil lized from natural glasses during diagenesis, but ity field; this is certainly true for clinoptilolite, they omit any consideration of zeolites in veins the siliceous alkali-rich variant of heulandite, and and vugs of massive rocks. The author also aims is also probably true for natrolite and mordenite. -
Prehnite-Pumpellyite Facies Metamorphism
Andean Geology 37 (1): 54-77. January, 2010 Andean Geology formerly Revista Geológica de Chile www.scielo.cl/andgeol.htm Prehnite-pumpellyite facies metamorphism in the Cenozoic Abanico Formation, Andes of central Chile (33º50'S): chemical and scale controls on mineral assemblages, reaction progress and the equilibrium state Marcia Muñoz1, Luis Aguirre1, Mario Vergara1, Alain Demant2, Francisco Fuentes3, Andrés Fock4 1 Departamento de Geología, Universidad de Chile, Casilla 13518, Correo 21, Santiago, Chile. [email protected]; [email protected]; [email protected] 2 Laboratoire de Pétrologie Magmatique Université Aix-Marseille III, 13397 Marseille Cedex 20, France. [email protected] 3 Los Acacios, Parcela 142-3, Paine, Chile. [email protected] 4 SQM Salar S.A., Aníbal Pinto 3228, Antofagasta, Chile. [email protected] ABSTRACT. In the El Volcán and Rodeo de los Bueyes areas, Andean Principal Cordillera (east of Santiago; 33º50'S), an Upper Oligocene-Lower Miocene volcanic series belonging to the Abanico Formation (Late Eocene-Early Miocene) is exposed. The rock successions outcropping in both areas, ca. 3,300 m total thickness, have been affected by very low-grade, non-deformative metamorphism in the prehnite-pumpellyite facies. This is represented by the widespread development of secondary mineral assemblages composed of epidote, mixed-layer chlorite-smectite, albite, quartz, white mica, and titanite. These mineral assemblages also contain pumpellyite, prehnite or prehnite+actinolite in a few samples. Chemical characteristics, such as low compositional variability of mixed-layer chlorite-smectite and actino- lite independent from the metadomain where these phases are hosted, along with a high proportion of chlorite layers in the former, suggest that these phases closely represent the whole rock effective bulk composition.