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MET 200 Lecture 6 Volume and Formation

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Clouds and Cloud Formation Observations by Last Year’s Class

3 4 Previous Lecture Cloud Importance of Formation Measuring Water in the Air The Hydrological Cycle

Outline • and the formation of clouds •

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Clouds Cloud Formation Clouds impact the environment in many ways – Radiation balance, , processing, - charge balance, etc… And they can be very beautiful.

All clouds require 3 things 1. Water 2. Cloud Condensation nuclei (CCN) 3. Cooling - heat transfer out of air parcel or work done by air molecules in parcel.

7 8 Sources of Surface Turbulent Fluxes • from the subtropical oceans Sensible Heat Flux Latent Heat Flux • Evapotranspiration from plants. • Evaporation from Lakes and Rivers ρ =density of the air • Sublimation from and ice. !! = ! − ! Cp =specific heat at constant r = mixing ratio ρ =density of the air z z

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daytime T nighttime T

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Sources of Atmospheric Water Impact of Surface Tension • Water vapor is Water vapor SST concentrated in the . • Evaporation from the sea surface depends on SST, , and RH. • The greatest source of water vapor is in the subtropics.

!!" = !!!!! !!" !! − !!"

FLE = latent heat flux Lv = specific heat of evaporation ρ = density of air CD = drag coefficient U10 = wind speed at 10 m Surface Tension caused by cohesion of similar T0 = at surface molecules, makes it hard for water molecules to enter

T10 = temperature at 10 m droplets, just as this pin is having trouble. Wind speed Evaporation

11 12 Impact of Surface Tension Impact of Surface Tension

Surface Tension pulls drops into spherical shape.

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Typical sizes Cloud Condensation Nuclei

• Pin head = 1 mm If the air temperature cools below the point (RH > 100%), water vapor will tend to condense and form cloud drops. • Drop formation occurs on particles known as cloud condensation nuclei (CCN). • The most effective CCN are water soluble. • Without CCN clouds would not form in the atmosphere, because a RH of several hundred percent is required for pure water drop formation. Why?

The smaller the droplet the harder it is for water the enter the drop so that it can grow.

15 16 Very Small Drops CCN that Dissolve in Water Tend to Evaporate!

Water molecule • Small drops have large curvature molecule • Large curvature gives a high saturation because of effect of surface tension. Water soluble CCN act to reduce • Very high RH required for the saturation vapor pressure over equilibrium over very small the droplet surface by taking up drops spaces on the surface, by reducing the curvature, and by reducing the – ~300% RH for “clean” air without CCN. cohesion with neighbor water molecules.

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CCN are Sources of Aerosols and CCN

Smoke from natural and man-made fires.

19 20 Sources of Aerosols and CCN CCN are Aerosols Industrial Pollution Iceland from China

African Dust

Aerosols from Volcanoes

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More Sources of CCN More about CCN CCN concentrations vary in time and space Sulfate Clouds even contribute to CCN – Typically 100-1000 per cubic production centimeter. – Higher in polluted environments – Clouds ingest sulfur dioxide (SO ) 2 – Higher CCN concentrations give – Chemical reactions in the cloud rise to greater cloud-drop SO2 H2SO4 drops convert dissolved SO2 to concentrations. – impacts of these more soluble forms of sulfate, such as Clean Clouds sulfuric acid reflective clouds? They have a sulfuric acid - H2SO4. Ship Tracks higher albedo and out much – When the cloud drops evaporate, more slowly. soluble sulfate particles are left behind. – SO2 is emitted by volcanoes and by phytoplankton in the ocean. SO2 Ship Tracks

23 24 CCN Summary Mechanisms for Cooling the Air • Natural CCN – Sea salt particles (NaCl) 1) Lifting – most clouds form when air is lifted. – Forest fire smoke, volcanic aerosols. a) Convergence – low press center – stratus – Dust and pollen blown into the air. b) Mountains – lifting by terrain • CCN from human activity c) Fronts – lifting over denser air. – from fossil fuel combustion form acids d) Warm air relative to surroundings and . i) Fires, volcanoes – cumulus – Smoke ii) Latent heat • Not all atmospheric particles are cloud condensation 2) Mixing – seeing your breath on cold day nuclei (CCN). 3) Contact – with cold surface – fog • Good CCN attract water (hydroscopic). 4) Radiation – ground fog • Clouds produce some CCN and leave them behind if

the cloud evaporates.

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Lifting Lifting

Most clouds form when air is lifted. a) Convergence of air into a low pressure center. b) Mountains – lifting by terrain c) Fronts – lifting over denser air. d) Warm air relative to surroundings i) Fires, volcanoes – cumulus ii) Latent heat

Convergence into a Low

27 28 Lifting Lifting

Lifting by terrain

Lifting by Fronts

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Lifting Mixing

Fog in cold air over warm water

Seeing your breath on a cloudy day

Warm Air Relative to Surroundings

31 32 Mixing fog Contact with a Cold Surface

• Your breath in because of mixing with cold air. • It does not fog in because of the small temperature difference.

Advection Fog

33 34 Radiation Fog Radiation

Ground Fog or Radiation Fog

35 36 Annual days of dense fog ( < 0.25 miles) Fog Summary

are clouds in contact with the ground • Several types of fogs commonly form – Radiation fog – Advection fog – Upslope fog – Evaporation (mixing) fog

37 38 Fogs and visibility

• Light scattering by fog drops (geometric scatterers) degrades visibility, leading to – fatalities – Airport accidents and closures Dew • Remedies – Fog monitoring and warning (optical sensors) – Fog dispersal (expensive and of limited utility)

• Surfaces cool strongly at night by radiative cooling – Strongest on clear, calm nights • The is the temperature at which the air is saturated with water vapor. • If a surface cools below the dew point, water condenses on the

surface and dew drops are formed.

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• If the temperature is below , the dew point is called the frost point • If the surface temperature falls below the frost point, water vapor is deposited directly as ice – deposition • The resulting crystals are known as frost, hoarfrost, or Small droplets that form at RH > 60% on hygroscopic nuclei white frost (salt, sulfuric and nitric acid) Also obscuring by smoke, dust, pollen, etc.

Becomes visible by scattering light.

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Wilson’s cloud chamber Questions? a sealed environment containing a supercooled, supersaturated water vapor. When an alpha particle or beta particle interacts with the , it ionizes it. The resulting ions act as condensation nuclei, around which a forms.

Brocken Spectre (Glory)

Charles Thomson Rees Wilson (1869-1959), a Scottish physicist, is credited with inventing the cloud chamber. Inspired by sightings of the spectre while working on the summit of Ben Nevis in 1894, he began to develop expansion chambers for studying cloud formation and optical phenomena in moist air. Very rapidly he discovered that ions could act as centers for water droplet formation in such chambers. He pursued the application of this discovery and perfected the first cloud chamber in 1911.

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