Chemical composition of comet C/2007 N3 (Lulin): another "atypical" comet Proposed running head: Lulin: another “atypical” comet Erika L. Gibb1, Boncho P. Bonev2,3, Geronimo Villanueva2,3, Michael A. DiSanti3, Michael, J. Mumma3, Emily Sudholt1, Yana Radeva2,3 1 Department of Physics & Astronomy, University of Missouri - St Louis, St Louis, MO, 63121, USA 2 Department of Physics, The Catholic University of America, Washington, DC 20064, USA 3 Goddard Center for Astrobiology, Solar System Exploration Division, NASA Goddard Space Flight Center, code 690, Greenbelt, MD 20771, USA Submitted to Astrophysical Journal December 29, 2011 Editorial correspondence and proofs should be directed to ELG Erika Gibb 503 Benton Hall One University Blvd University of Missouri – St. Louis St. Louis, MO 63121 Phone: (314) 516-4145 Fax: (314) 516-6152 E-mail:
[email protected] Abstract We measured the volatile chemical composition of comet C/2007 N3 (Lulin) on three dates from 30 January to 1 February, 2009 using NIRSPEC, the high-resolution (λ/Δλ ≈ 25,000), long-slit echelle spectrograph at Keck 2. We sampled nine primary (parent) volatile species (H2O, C2H6, CH3OH, H2CO, CH4, HCN, C2H2, NH3, CO) and two product species (OH* and NH2). We also report upper limits for HDO and CH3D. C/2007 N3 (Lulin) displayed an unusual composition when compared to other comets. Based on comets measured to date, CH4 and C2H6 exhibited “normal” abundances relative to water, CO and HCN were only moderately depleted, C2H2 and H2CO were more severely depleted, and CH3OH was significantly enriched. Comet C/2007 N3 (Lulin) is another important and unusual addition to the growing population of comets with measured parent volatile compositions, illustrating that these studies have not yet reached the level where new observations simply add another sample to a population with well-established statistics.