LUBRICANT ADDITIVES 30 Winﬁ Eld Street, P.O

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LUBRICANT ADDITIVES 30 Winﬁ eld Street, P.O. Box 5150, Norwalk, CT 06856-5150 Telephone: (203) 853-1400 • Fax: (203) 853-1452 E-mail: [email protected] • Web Site: www.rtvanderbilt.com

CUVAN, MOLYVAN, NACAP, VANCHEM and VANLUBE are registered trademarks of R.T. Vanderbilt Company, Inc. Responsible Care is a registered trademark of the American Chemistry Council. NSF is a registered trademark of NSF International UCON is a registered trademark of Union Carbide Cprporation UL is a registered trademark of UL LLC. USDA BioPreferred™

DISCLAIMER

Before using, read, understand and comply with the information and precautions in the Material Safety Data Sheets, label and other product literature. The information presented herein, while not guaranteed, was prepared by technical personnel and, to the best of our knowledge and belief, is true and accurate as of the date hereof. No warranty, representation or guarantee, express or implied, is made regarding accuracy, performance, stability, reliability or use. This information is not intended to be all-inclusive, because the manner and conditions of use, handling, storage and other factors may involve other or additional safety or performance considerations. The user is responsible for determining the suitability of any material for a speciﬁ c purpose and for adopting such safety precautions as may be required. R.T. Vanderbilt Company, Inc. does not warrant the results to be obtained in using any material, and disclaims all liability with respect to the use, handling or further processing of any such material. No suggestion for use is intended as, and nothing herein shall be construed as, a recommendation to infringe any existing patent, trademark or copyright or to violate any federal, state or local law or regulation. rev05/11/2012

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ANTIOXIDANTS METAL DEACTIVATORS VANLUBE® AZ - Zinc diamyldithiocarbamate. *CUVAN® 303 - Corrosion inhibitor and metal deactivator. VANLUBE EZ - Zinc diamyldithiocarbamate and CUVAN 826 - Copper corrosion inhibitor. diamyl ammonium diamyldithiocarbamate. NACAP® - Aqueous sodium mercaptobenzothiazole. VANLUBE NA - Alkylated diphenylamine. VANCHEM NATD - Aqueous disodium dimercaptothiadiazole. *VANLUBE 81 - Purifi ed dioctyldiphenylamine. VANLUBE 601 - Heterocyclic sulfur-nitrogen compound. VANLUBE 818DM - Antioxidant/rust inhibitor. VANLUBE 601E - Heterocyclic sulfur-nitrogen compound. VANLUBE 887 - Ashless antioxidant synergist. VANLUBE 704S - Metal deactivator, rust inhibitor. VANLUBE 915M - Antioxidant blend. *VANLUBE 961 - Octylated and butylated diphenylamine. RUST INHIBITORS *VANLUBE 7723 - Methylene-bis-dibutyldithiocarbamate. *VANLUBE RI-A - Oil-soluble rust inhibitor. VANLUBE BHC - Phenolic antioxidant. VANLUBE RI-BA - Neutral barium sulfonate rust inhibitor. FRICTION REDUCERS/EP-ANTIWEAR AGENTS VANLUBE RI-G - Ashless rust inhibitor for greases. VANLUBE 8912E - Synthetic neutral calcium sulfonate. MOLYVAN® L - Molybdenum phosphorodithioate. MOLYVAN 2000 - Sulfurized molybdenum dtc. NNEWEW PPRODUCTSRODUCTS MOLYVAN 822 - Molybdenum dithiocarbamate. ** MOLYVAN 855 - Molybdenum friction reducer/no sulfur, TUNGSTEN COMPOUNDS - VANLUBE W324 no phosphorus. TPS™ 20 - Antiwear and extreme pressure additive for *VANLUBE 73 - Antimony dithiocarbamate. metalworking fl uids. VANLUBE 73 Super Plus - Antimony dithiocarbamate and TPS 32 - High active sulfur content for metalworking fl uids. zinc diamyldithiocarbamate. TPS 44 - Polysulfi de used in industrial and automotive gear *VANLUBE 829 - Thiadiazole dimer derivative. oils. VANLUBE 869 - Synergistic zinc dithiocarbamate/ sulfurized VANLUBE 289 - Borate Ester. olefi n mixture. VANLUBE 996E - Ashless DTC antioxidant. VANLUBE 871 - Ashless antioxidant/antiwear additive for VPS™ 15 - Vegetable based fatty acid ester for semi-synthetic engine oils. metalworking fl uids. VANLUBE 972M - Ashless extreme pressure additive for IINTRODUCINGNTRODUCING greases. VANLUBE 0902 - Multi functional sulfur and phosphorus *VANLUBE 7611M - Ashless additive containing sulfur and package for industrial oils and greases. phosphorus. bilt Com er p d a n n VANLUBE 8610 - Synergistic antimony dithiocarbamate/ *** a y V ,

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Before using any of these products, read and comply with the information contained in the MSDS, label and other product literature. CUVAN Metal Deactivator, MOLYVAN Fricton Reducer, NACAP Corrosion Inhibitor, VANCHEM Metal Deactivator, VANLUBE Antioxidant and VANLUBE Lubricant Additive are registered trademarks of R.T. Vanderbilt Company, Inc. NSF is a registered trademark of NSF International. UL is a registered trademark of UL LLC. TPS and VPS are trademarks of Arkema, Inc. USDA BioPreferred™ TABLE OF CONTENTS Quick–Scan Application Guide Page 1,2 Antioxidants VANLUBE® 915M Page 18 Aromatic Amines VANLUBE NA Page 8 VANLUBE RD Page 9 VANLUBE SL Page 10 VANLUBE SS Page 11 VANLUBE 81 Page 12 VANLUBE 887 Page 17 VANLUBE 887E Page 17 VANLUBE 961 Page 18 VANLUBE 9317 Page 21 Hindered Phenols VANLUBE BHC Page 8 Sulfur Compounds VANLUBE AZ Page 7 VANLUBE EZ Page 8 VANLUBE 869 Page 16 VANLUBE 996E Page 19 VANLUBE 7723 Page 19 VANLUBE 8610 Page 20 Organo-molybdenum MOLYVAN® A Page 4 MOLYVAN L Page 4 MOLYVAN 807 Page 4 MOLYVAN 822 Page 5 MOLYVAN 855 Page 5 MOLYVAN 856B Page 5 Antiwear & Extreme Pressure Additives MOLYVAN A Page 4 MOLYVAN L Page 4 MOLYVAN 807 Page 4 MOLYVAN 822 Page 5 VANLUBE EZ Page 8 VANLUBE SB Page 10 VANLUBE 73 Page 12 VANLUBE 73 Super Plus Page 12 VANLUBE 289 Page 13 VANLUBE 622 Page 14 VANLUBE 672 Page 14 VANLUBE 692 Page 14 VANLUBE 719 Page 15 VANLUBE 727 Page 15 VANLUBE 829 Page 16 VANLUBE 869 Page 16 VANLUBE 871 Page 17 VANLUBE 972M Page 18 VANLUBE 7611M Page 19 VANLUBE 8610 Page 20 VANLUBE 9123 Page 20 VANLUBE is a registered trademark of R.T. Vanderbilt Company, Inc. MOLYVAN Friction Reducer, VANLUBE Antioxidant and VANLUBE Lubricant Additive are registered trademarks of R.T. Vanderbilt Company, Inc. Metal Deactivators CUVAN® 303 Page 3 CUVAN 484 Page 3 CUVAN 826 Page 3 NACAP® Page 6 VANCHEM® DMTD Page 6 VANCHEM NATD Page 6 VANLUBE® 601 Page 13 Don’t VANLUBE 601E Page 13 VANLUBE 704S Page 15 Break Friction Reducers MOLYVAN® A Page 4 Under MOLYVAN L Page 4 MOLYVAN 807 Page 4 MOLYVAN 822 Page 5 Pressure MOLYVAN 855 Page 5 MOLYVAN 856B Page 5 VANLUBE 622 Page 14 Chemical Intermediates NACAP Page 6 VANCHEM DMTD Page 6 VANCHEM NATD Page 6 Rust Inhibitors VANLUBE RI-A Page 9 VANLUBE RI-BA Page 9 VANLUBE RI-G Page 10 VANLUBE 739 Page 16 VANLUBE 8912E Page 20 VANLUBE 9123 Page 20 Other VANLUBE TK-100 Page 11 Take Control With VVANLUBEANLUBE® 7733 SSuperuper PPluslus Lubricant Additive

VANLUBE is a registered trademark of R.T. Vanderbilt Company, Inc. VANLUBE is a registered trademark of R.T. Vanderbilt Company, Inc.

This brochure contains brief descriptions of most of the products sold by R.T. Vanderbilt Company, Inc. to the lubricating oil and grease industry. The products not included in this brochure are either experimental, or those that are only available on a local basis.

We also welcome inquires with regard to custom-made lubricants or joint research projects.

For more detailed information, please contact your R.T. Vanderbilt Company Technical Sales Representative, or the Petroleum Department at our corporate ofﬁ ce in Norwalk, Connecticut.

R.T. Vanderbilt Company, Inc. will continuously improve all products and services to consistently meet customer expectations the ﬁ rst time and every time. CUVAN Metal Deactivator, NACAP Corrision Inhibitor, MOLYVAN Friction Reducer, VANCHEM Metal Deactivator, VANLUBE Lubricant Additive are registered trademarks of R.T. Vanderbilt Company, Inc. Quick-Scan Application/Function Guide Super Plus DMTD A

73 ® AZ ® 303 APPLICATION ® ®

® ® MOLYVAN L MOLYVAN 807 MOLYVAN 822 MOLYVAN 855 MOLYVAN 856B NACAP CUVAN VANCHEM VANCHEM NATD VANLUBE CUVAN 484 CUVAN 826 MOLYVAN VANLUBE 73 VANLUBE BHC VANLUBE EZ VANLUBE NA VANLUBE RD VANLUBE RI-A VANLUBE RI-BA VANLUBE RI-G VANLUBE SB VANLUBE SL VANLUBE SS VANLUBE TK-100* VANLUBE Coolant  Water-Based  Fluids Auto Transmission  Fluid Compressor Oil     

Engine Oil       Fuel  Gear Oil       Grease    Hydraulic Oil      Metalworking        Rust  Preventive Synthetic Lube   Turbine Oil      FUNCTION Ashless       High  Temperature Antioxidant 2222222 2 11111 11 2 2 Antiwear/ 2111112 21 2 21 Antiscuff Friction 111111 2 Reducer Biocide Corrosion 111 1112 222 Inhibitor Demulsiﬁ er 2 Chemical 111 Intermediate Extreme 2222 1 1 1 1 Pressure Metal 111 1112 Deactivator Rust Inhibitor 111 = Application/Function 1 = Primary Function 2 = Secondary Function * = Tackifier CUVAN Metal Deactivator, MOLYVAN Friction Reducer, NACAP Corrosion Inhibitor, VANCHEM Metal Deactivator, VANLUBE Anitoxidant and VANLUBE Lubricant Additive are registered trademarks of R.T. Vanderbilt Company, Inc.

1. APPLICATION 81 ® VANLUBE 289 VANLUBE 601 VANLUBE 601E VANLUBE 622 VANLUBE 672 VANLUBE 692 VANLUBE 704S VANLUBE 719 VANLUBE 727 VANLUBE 739 VANLUBE 829 VANLUBE 869 VANLUBE 871 VANLUBE 887 VANLUBE 887E VANLUBE 915M VANLUBE 961 VANLUBE 972M VANLUBE 996E VANLUBE 7611M VANLUBE 7723 VANLUBE 8610 VANLUBE 8912E VANLUBE 9123 VANLUBE 9317 VANLUBE Coolant Water-Based Fluids Auto Transmission      Fluid Compressor Oil     

Engine Oil       Fuel  Gear Oil       Grease   Hydraulic Oil        Metalworking     Rust  Preventive Synthetic Lube    Turbine Oil     FUNCTION Ashless      High  Temperature Antioxidant 12222222222111112121 Antiwear/ 11122122121221 Antiscuff Friction 11 2 2 Reducer Biocide Corrosion 11 1 22 2 2 Inhibitor Demulsiﬁ er 2 Chemical Intermediate Extreme 111 1 11 1 11 Pressure Metal 11 1 2 2 Deactivator Rust Inhibitor 11 11 = Application/Function 1 = Primary Function 2 = Secondary Function VANLUBE Anitoxidant and VANLUBE Lubricant Additive are registered trademarks of R.T. Vanderbilt Company, Inc.

2. CUVAN® 303 CUVAN 484 CUVAN 826 Metal Deactivator

Formula Proprietary Proprietary

Auto Transmission Fluid, Compressor Oil, Engine Compressor Oil, Engine Compressor Oil, Engine Oil, Oil, Fuel, Gear Oil, Oil, Fuel, Gear Oil, Grease, Gear Oil, Grease, Hydraulic Application Grease, Hydraulic Oil, Hydraulic Oil, Metalworking, Oil, Metalworking, Turbine Oil Metalworking, Turbine Oil Synthetic Lube, Turbine Oil Ashless, Antioxidant, Ashless, Antioxidant, Ashless, Corrosion Inhibitor, Antiwear/Antiscuff, Corrosion Corrosion Inhibitor, Metal Function Metal Deactivator Inhibitor, Metal Deactivator Deactivator N, N-bis(2-ethylhexyl)-ar- Chemical 2,5 dimercapto-1,3,4- 2,5 dimercapto-1,3,4- methyl-1H-benzotriazole-1- thiadiazole derivative thiadiazole derivative Composition methanamine Physical State Liquid Liquid Liquid Color Amber Amber Amber Density @ 15.6˚C 0.95 (7.9) @ 25˚C 1.07(9.0) 1.04(8.6) Mg/m3 (lb/gal) Viscosity @ 5.81 11 3.32 100˚C cSt Flash Point 125 76 192 (PMCC), ˚C Soluble in petroleum and Soluble in petroleum and Soluble in petroleum synthetic lubricant bases. synthetic lubricant bases. Solubility lubricating bases. Insoluble in water. Insoluble in water. Use Concentration, 0.05 - 0.20 0.10 - 0.50 0.10 - 0.50 % mass CUVAN 303 is an oil-soluble CUVAN 484 is an ashless CUVAN 826 is a ashless corrosion inhibitor and metal oil-soluble corrosion inhibitor oil-soluble corrosion deactivator for lubricants, and metal deactivator inhibitor and metal greases and metalworking for nonferrous metals, deactivator for nonferrous fl uids. As a corrosion inhibitor, particularly for copper. metals, particularly for it is effective in protecting Useful in industrial and copper. It is useful in copper, copper alloys, automotive oils and greases, industrial and automotive cadmium, cobalt, silver and metalworking fl uids, etc. oils and greases, zinc. As a metal deactivator, CUVAN 484 may also metalworking fl uids, etc. Typical Uses it is effective in precipitating enhance the antiwear CUVAN 826 has a unique ions of the same metals, and oxidation properties of composition enables it thus preventing galvanic lubricants. to suppress the corrosive corrosion of other metal action of hydrogen sulfi de. surfaces and inhibiting these ions from acting as oxidation catalysts.

NSF® Registered HX-1, 138995 CUVAN is a registered trademark of R.T. Vanderbilt Company, Inc. NSF is a registered trademark of NSF International. 3. MOLYVAN® A MOLYVAN L MOLYVAN 807 Friction Reducer

S R S R O P S Mo O S Formula N S Mo O S 2 2 2 Proprietary 2 x y O R R 2 2

Engine Oil, Gear Oil, Grease, Engine Oil, Gear Oil, Grease, Synthetic Lube Metalworking, Synthetic Application Grease, Synthetic Lube Lube High Temperature, Antioxidant, Antiwear/ Antioxidant, Antiwear/ Antioxidant, Antiwear/ Antiscuff, Friction Reducer, Antiscuff, Friction Reducer, Function Antiscuff, Friction Reducer, Extreme Pressure Extreme Pressure Extreme Pressure Chemical Molybdenum di-n-butyldi- Molybdenum di(2-ethylhexyl) Molybdenum dialkyldithio- Composition thio-carbamate phosphorodithioate carbamate in oil Physical State Powder Liquid Liquid Color Yellow Dark Green Dark Green Density @ 15.6˚C 1.59 @ 25˚C 1.08 (9.0) 0.97 (8.1) Mg/m3 (lb/gal) Viscosity @ — 8.6 13 100˚C cSt Flash Point — 142 135 (PMCC), ˚C Slightly soluble in aromatic Soluble in petroleum and Soluble in petroleum and Solubility hydrocarbons. Insoluble in synthetic lubricant bases. synthetic lubricant bases. water. Insoluble in water. Insoluble in water. Use Concentration, 0.5 - 3.0 0.25 - 1.0 0.25 - 0.5 % mass MOLYVAN A is used in long life MOLYVAN L is an oil-soluble MOLYVAN 807 offers a chassis greases for ball joints, organic molybdenum unique molybdenum-sulfur steering linkages and other additive containing sulfur and combination in an oil- lubricating greases requiring phosphorus. It functions as a soluble form which is easy good antioxidant and antiwear friction reducer, antioxidant, to blend into lubricants. It at high temperatures for long antiwear, and extreme pressure can be used to maintain the periods of time. It is an organic agent. It is used in engine oils, antifriction properties of an molybdenum extreme pressure metalworking compositions engine oil while reducing and antiwear additive for and in a variety of industrial the phosphorus content. To petroleum and synthetic and automotive lubricating obtain signiﬁ cant increases in lubricants. It has good high oils, greases and specialties. extreme pressure properties Typical Uses temperature stability. In MOLYVAN L is an outstanding and to impart improved lubricating greases it is superior antiwear agent. It is quite useful antiwear performance. to inorganic molybdenum in automotive and industrial MOLYVAN 807 can be additives for both antiwear gear oils and greases which used in combination with and antioxidant properties. operate under heavy load VANLUBE® 7723 Antioxidant, a MOLYVAN A is slightly basic and conditions. nonmetallic dithiocarbamate does not promote rusting. It has which functions as an a low speciﬁ c gravity which antioxidant and extreme makes it easy to disperse with pressure agent. simple equipment. It is used in non-petroleum base valve Not recommended for diesel Not recommended for diesel lubricants. engine oils. engine oils.

MOLYVAN and VANLUBE Antioxidant are registered trademarks of R.T. Vanderbilt Company, Inc. 4. MOLYVAN® 822 MOLYVAN 855 MOLYVAN 856B Friction Reducer Formula Proprietary Proprietary Proprietary Engine Oil, Gear Oil, Grease, Engine Oil, Grease, Engine Oil Application Synthetic Lube Metalworking Antioxidant, Antiwear/ Antioxidant, Antiwear/ Antioxidant, Antiwear/ Antiscuff, Friction Reducer, Function Antiscuff, Friction Reducer Antiscuff Extreme Pressure Chemical Molybdenum Organomolybdenum Organomolybdenum Composition dialkyldithiocarbamate in oil complex complex Physical State Liquid Liquid Liquid Color Brown Brown Dark Amber Density @ 15.6˚C 0.97 (8.1) 1.08 (8.9) 0.98 (8.2) Mg/m3 (lb/gal) Viscosity @ 13 55 15.0 100˚C cSt Flash Point 135 193 174 (PMCC), ˚C Soluble in petroleum and Soluble in petroleum and Soluble in petroleum and Solubility synthetic lubricant bases. synthetic lubricant bases. synthetic lubricating bases. Insoluble in water Insoluble in water Insoluble in water. Use Concentration, 0.25 - 0.5 0.1 - 0.5 0.1 - 0.5 % mass MOLYVAN 822 may be used MOLYVAN 855 is a liquid MOLYVAN 856B is to maintain or improve the organomolybdenum specifi cally designed antifriction properties of an friction modifi er specifi cally for crankcase oils to engine oil while reducing designed for crankcase oils. signifi cantly modify the the phosphorus content. MOLYVAN 855 provides coeffi cient of friction. engine oils with a substantial reduction in the coeffi cient of friction.

Typical Uses

Not recommended for Not recommended for diesel Not recommended for diesel engine oils. engine oils. diesel engine oils.

MOLYVAN is a registered trademark of R.T. Vanderbilt Company, Inc. USDA BioPreferred™ 5. NACAP® VANCHEM® VANCHEM Corrosion Inhibitor DMTD NATD Metal Deactivator N N N N N SNa Formula HS SH NaS SNa S S S

Coolant, Water-Based Fluids, Coolant, Water-Based Coolant, Water-Based Fluids Application Metalworking Fluids, Metalworking Antioxidant, Corrosion Ashless, Corrosion Inhibitor, Corrosion Inhibitor, Inhibitor, Chemical Chemical Intermediate, Chemical Intermediate, Function Intermediate, Metal Metal Deactivator Metal Deactivator Deactivator Sodium Disodium 2,5-dimercapto- Chemical 2,5-dimercapto-1,3,4- 2-mercaptobenzothiazole, thiadiazole, 30% aqueous thiadiazole Composition 50% aqueous solution solution Physical State Liquid Powder Liquid Color Light Amber Cream to Light Yellow Amber Density @ 15.6˚C 1.27 (10.6) 1.79 1.22 (10.2) Mg/m3 (lb/gal) Viscosity @ ——— 100˚C cSt Flash Point ——— (PMCC), ˚C Soluble in water, ethanol, acetone and diesters. Soluble in water, alcohols Slightly soluble in petroleum and glycols. Insoluble in Soluble in water. Solubility lubricant bases, hexane, petroleum hydrocarbons. petroleum ether, chloroform and toluene. Use Concentration, 0.1 - 0.6 Chemical Intermediate 0.1 - 0.25 % mass NACAP is a corrosion inhibitor VANCHEM DMTD’s common VANCHEM NATD is a for water, alcohol and glycol reactions are double corrosion inhibitor and systems. It is particularly decomposition reactions metal deactivator for effective in preventing with soluble metal salts, salt nonferrous metals in corrosion of copper and formation with alkaline metal aqueous systems. It is brass. Widely used in hydroxides, oxidation reactions particularly indicated for antifreeze, where it functions involving mercaptans, addition the protection of solder, reactions with organic as a copper corrosion aluminum, copper and compounds containing inhibitor and alkaline buffer. copper alloys. It is stable It is an excellent corrosion activated double bonds, Typical Uses reactions with epoxy groups, and active at lower inhibitor for aluminum in reactions with aldehydes and pH values than many systems where aluminum alcohols, salt formation with mercapto compounds. is used in the presence amines and ammonia and VANCHEM NATD as of copper and copper reactions with acyl chlorides. a stable reactive alloys. NACAP is one of the The two active sites on dimercaptide which standard copper corrosion VANCHEM DMTD can generally is readily alkylated, inhibitors for the antifreeze be reacted successively. oxidized to the disulﬁ de, or industry. Used as a chemical converted to metal salts. intermediate. NACAP and VANCHEM are registered trademarks of R.T. Vanderbilt Company, Inc. 6. VANLUBE® AZ VANLUBE BHC VANLUBE EZ Lubricant Additive Antioxidant _ S S C H Zn++ 5 11 O C H 5 11 N S or N SZn HO CH CH C Oi-CH C H Formula C H 2 2 8 17 H N+ 5 11 5 11 C H 2 5 11 C H n 5 11 2 n = 2 or 1 respectively

Auto Transmission Fluid, Auto Transmission Fluid, Compressor Oil, Engine Compressor Oil, Engine Oil, Gear Oil, Grease, Application Oil, Gear Oil, Grease, Gear Oil, Grease, Hydraulic Metalworking, Synthetic Metalworking, Rust Oil, Metalworking, Synthetic Lube Preventive, Synthetic Lube Lube, Turbine Oil Antioxidant, Antiwear/ Antioxidant, Antiwear/ Antiscuff, Corrosion Inhibitor, Ashless, Antioxidant Function Antiscuff, Extreme Pressure Metal Deactivator Zinc Chemical Zinc diamyldithiocarbamate Butylated diamyldithiocarbamate Composition in oil hydroxylhydrocinnamate and diamyl ammonium diamyldithiocarbamate Physical State Liquid Liquid Liquid Color Amber Yellowish Yellowish/Amber Density @ 15.6˚C 1.02 (8.2) 0.9665 1.1 Mg/m3 (lb/gal) Viscosity @ 9.8 — 40 - 70 100˚C cSt Flash Point 136 152 93 (PMCC), ˚C Soluble in petroleum and Soluble in petroleum and Soluble in petroleum and Solubility synthetic lubricant bases. synthetic lubricant bases. synthetic lubricant bases. Insoluble in water. Insoluble in water. Insoluble in water. Use Concentration, 0.25 - 1.5 0.1 - 2.0 0.1 - 2.0 % mass VANLUBE AZ is used in engine oils, in VANLUBE BHC is an effective VANLUBE EZ is a industrial oils, and in soap and clay- general purpose, nonstaining, multifunctional additive thickened greases. Used in both ashless antioxidant that provides gasoline and diesel crankcase oils to that imparts excellent excellent oxidative stability inhibit oxidation, bearing corrosion antiwear, extreme to wide range of automotive and wear. Used in combination pressure, corrosion and industrial lubricants. It has with detergents, it inhibits corrosion resistance and antioxidant and wear by inhibiting oxidation of excellent solubility in mineral the oil and also by the formation of and nonconventional base properties to industrial protective fi lms on metal surfaces. stocks, and contains no diluents. lubricants and greases. It is Used as a partial replacement for It is easy to handle and will not a concentrated version of zinc dithiophosphates. Because of its crystallize at low temperatures. Typical Uses effectiveness at high temperatures, VANLUBE AZ. it is a good additive for crankcase It has low volatility and helps oils in heavy duty service. In industrial control oxidation and high oils and automatic transmission fl uids temperature deposits especially it functions as a high temperature when combined with alkylated oxidation and corrosion inhibitor. diphenylamines, molybdenum Used in lubricating greases both as compounds, sulfur-containing an oxidation inhibitor and metal antioxidants and/or phosphites deactivator. An excellent copper corrosion inhibitor of fi lm-forming in many industrial oils and type. automotive lubricants.

VANLUBE Antioxidant and VANLUBE Lubricant Additive are registered trademarks of R.T. Vanderbilt Company, Inc. 7. VANLUBE® NA VANLUBE RD VANLUBE RI-A Antioxidant Lubricant Additive

CH 3 H R N R Proprietary 1 1 CH Formula 3 R R 2 2 N CH H 3

Auto Transmission Fluid, Compressor Oil, Engine Oil, Gear Oil, Grease, Hydrau- Application Gear Oil, Grease, Hydraulic Grease, Synthetic Lube lic Oil, Rust Preventive, Oil, Metalworking, Synthetic Turbine Oil Lube, Turbine Oil Ashless, Corrosion Inhibitor, Ashless, Antioxidant Ashless, Antioxidant Function Rust Inhibitor Chemical Alkylated diphenylamines Polymerized 1,2-dihydro- Dodecenylsuccinic acid Composition 2,2,4-trimethylquinoline reaction product Physical State Liquid Small Pastilles Liquid Color Brown Amber Amber Density @ 15.6˚C 0.94 (7.8) 1.06 0.96 (8.0) Mg/m3 (lb/gal) Viscosity @ 15 — 19 100˚C cSt Flash Point 213 (COC) — 165 (PMCC), ˚C Soluble in diesters, Soluble in petroleum and polyglycols and Ucon® Soluble in petroleum synthetic lubricant bases. Solubility fl uids. Insoluble in water and lubricant bases. Insoluble in water. petroleum oils. Use Concentration, 0.25 - 1.5 0.1 - 1.0 0.05 - 0.25 % mass VANLUBE NA is a versatile VANLUBE RD inhibits oxidation VANLUBE RI-A is an liquid amine antioxidant with in polyglycols, Ucon fl uids and oil-soluble rust inhibitor several advantages over other diester synthetic lubricants. recommended for steam antioxidants of this type. The Good high temperature turbine oils, circulating amine group in inhibitor for both petroleum oils and hydraulic oils. VANLUBE NA is hindered by and synthetic lubricants. oil-soluble alkyl groups which Widely used in Ucon and In industrial gear oils contribute to antioxidant polyglycol brake fl uids at with extreme pressure effi ciency by reducing some of concentrations of 0.1 to 0.25%. additives, levels of the undesirable properties of Prevents the depolymerization approximately 0.25% are other amines. VANLUBE NA is a of polyoxyethylene and recommended. Typical Uses general purpose antioxidant for similar polymers. Used as a VANLUBE RI-A is most turbine, hydraulic, circulating, high temperature oxidation effective in greases when compressor and other industrial inhibitor in both petroleum used with a sulfonate such oils. It is an effective non- and synthetic base lubricating as VANLUBE RI-BA in a discoloring grease antioxidant greases. Effective in both and is applicable to ashless static (ASTM grease bomb and 50/50 ratio. crankcase oils for automotive, dynamic (bearing life or spindle) aviation, diesel and gas engine oxidation tests. service. Synergistic effects are obtained with VANLUBE PCX, VANLUBE AZ and VANLUBE 73. NSF® Registered H2, 139738

VANLUBE Antioxidant and VANLUBE Lubricant Additive are registered trademarks of R.T. Vanderbilt Company, Inc. NSF is a registered trademark of NSF International. UCON is a registered trademark of Union Carbide Corporation 8. VANLUBE® RI-BA VANLUBE RI-G VANLUBE SB Lubricant Additive Formula Proprietary Proprietary Proprietary Gear Oil, Grease, Hydraulic Gear Oil, Grease, Hydraulic Engine Oil, Gear Oil, Oil, Metalworking, Rust Application Oil, Rust Preventive Grease, Metalworking Preventive, Turbine Oil Corrosion Inhibitor, Rust Ashless, Corrosion Inhibitor, Antiwear/Antiscuff, Function Inhibitor Rust Inhibitor Extreme Pressure Chemical Fatty acid derivative of Barium sulfonate Sulfur-based additive Composition 4,5-dihydro-1H-imidazole Physical State Liquid Liquid Liquid Color Dark Brown Amber Amber Density @ 15.6˚C 1.00 (8.3) 0.94 (7.8) 1.14 (9.5) Mg/m3 (lb/gal) Viscosity @ 90 117 10 100˚C cSt Flash Point 175 271 79 (PMCC), ˚C SoSoluble in petroleum Soluble in petroleum Soluble in petroleum and Solubility lubricant bases. Insoluble in lubricant bases. Insoluble in synthetic lubricant bases. water. water. Insoluble in water. Use Concentration, 0.05 - 0.15 0.25 - 0.50 1.0 - 2.0 % mass VANLUBE RI-BA is an oil- VANLUBE RI-G was VANLUBE SB is a sulfur- soluble barium sulfonate speciﬁ cally designed to based additive used in the with excellent rust-inhibiting provide excellent rust formulation of industrial and water-resistant inhibition for greases. It is gear oils, automotive properties. Useful in many compatible with other and industrial greases industrial and automotive VANLUBE extreme pressure, of various types, and lubricant applications. antioxidant and antiwear other formulations where VANLUBE RI-BA is additives. noncorrosive sulfur is compatible with additives desired. VANLUBE SB is such as antioxidants, an economical source extreme pressure and of sulfur in a form that antiwear agents, and other provides good load- corrosion inhibitors used carrying and antiwear in turbine, hydraulic, and properties combined with Typical Uses circulating oil formulas. low copper corrosion. Useful in hard and soft rust- preventive coatings.

VANLUBE is a registered trademark of R.T. Vanderbilt Company, Inc. 9. VANLUBE® SL VANLUBE SS VANLUBE TK-100 Antioxidant Lubricant Additives Formula H H Proprietary N C H N C H C 8H17 8 17 8 17

Auto Transmission Fluid, Compressor Oil, Engine Oil, Auto Transmission Fluid, Gear Oil, Grease, Gear Oil, Grease, Hydraulic Compressor Oil, Engine Oil, Metalworking, Rust Application Oil, Metalworking, Rust Grease, Synthetic Lube, Preventive Preventive, Synthetic Lube, Turbine Oil Turbine Oil Ashless, High Temperature, Ashless, Antioxidant Tackifi er Function Antioxidant Chemical Mixture of alkylated Solution of a copolymer of Octylated diphenylamines Composition diphenylamines ethylene and propylene Physical State Liquid Powder Liquid Color Reddish Brown Light Tan Amber Density @ 15.6˚C 1.01 (8.4) 1.02 0.89 Mg/m3 (lb/gal) Viscosity @ 16.28 – 4,500 100˚C cSt Flash Point 210 (COC) – 121 (PMCC), ˚C Soluble in petroleum and Soluble in petroleum and Soluble in petroleum and Solubility synthetic lubricant bases. synthetic lubricant bases. synthetic lubricant bases. Insoluble in water. Insoluble in water. Insoluble in water. Use Concentration, 0.25 - 1.5 0.5 - 2.0 0.5 - 5.0 % mass VANLUBE SL is a general- VANLUBE SS is a general- VANLUBE TK-100 is used purpose antioxidant for purpose antioxidant. It is to provide adherence in industrial lubricants including used as a high temperature way oils, chain lubricants compressor, hydraulic, antioxidant in petroleum and greases. It provides turbine, gas engine and and synthetic lubricants. excellent aerosol circulating oils. One of Effective as an antioxidant resistance in pneumatic the most versatile amine and corrosion inhibitor in system lubricants. antioxidants available for silane and siloxane synthetic use in petroleum products. lubricants - both in fl uids and Used in greases of all types. greases. Used in hydraulic Effective in both static and fl uids, various industrial oils, dynamic oxidation tests. automatic transmission Typical Uses Often used in combination fl uids and synthetic and with VANLUBE PCX in petroleum-based engine oils. turbine and hydraulic oils. An outstanding oxidation inhibitor in solvent-refi ned oils that are high viscosity improvers. A good ashless antioxidant for use in automotive, diesel and aviation crankcase oils.

VANLUBE Antioxidant and VANLUBE Lubricant Additive are registered trademarks of R.T. Vanderbilt Company, Inc. 10. VANLUBE® 73 VANLUBE 73 VANLUBE 81 Lubricant Additive Super Plus Antioxidant Formula S Proprietary R H C H N C H N S Sb 8 17 8 17 R 3

Auto Transmission Fluid, Compressor Oil, Engine Oil, Compressor Oil, Engine Oil, Gear Oil, Grease, Synthetic Gear Oil, Grease Application Grease, Synthetic Lube, Lube Turbine Oil Antioxidant, Antiwear/ Antioxidant, Antiwear/ Ashless, High Temperature, Antiscuff, Friction Reducer, Function Antiscuff, Extreme Pressure Antioxidant Extreme Pressure Antimony Chemical Proprietary blend of tris(dialkyldithiocarbamate) p,p’-dioctyldiphenylamine dialkyldithiocarbamates Composition in oil Physical State Clear to Hazy Liquid Liquid Powder Color Dark Amber Amber Off White Density @ 15.6˚C 1.03 (8.6) 1.0987 1.01 Mg/m3 (lb/gal) Viscosity @ 11 33.34 – 100˚C cSt Flash Point 171 > 118 – (PMCC), ˚C Soluble in petroleum and Soluble in petroleum and Soluble in petroleum and Solubility synthetic lubricant bases. synthetic lubricant bases. synthetic lubricant bases. Insoluble in water. Insoluble in water. Insoluble in water. Use 0.1 - 1.0 as antioxidant Concentration, 2.0 - 5.0 as extreme pressure 2.0 - 4.0 0.5 - 2.0 % mass agent. VANLUBE 73 is one of VANLUBE 73 Super Plus is VANLUBE 81 is similar chemically the most versatile of the a proprietary mixture of to VANLUBE SS but is a better high dialkyldithiocarbamates. temperature oxidation inhibitor dithiocarbamate additives. because of its high purity and high It has excellent antiwear, Based on equivalent p,p’-dioctyldiphenylamine content. antimony content, the extreme pressure and VANLUBE 81 can be used in a load-carrying capability of variety of petroleum and synthetic antioxidant properties. VANLUBE 73 Super Plus is lubricants where an ashless It is used as an antiwear superior to that of antimony oxidation inhibitor with good high temperature properties is needed. additive, a bearing corrosion dialkyldithiocarbamate Effective in silane, siloxane, silicone inhibitor in motor oils, gas (SDDC), and comparable to and diester fl uids at concentrations engine oil, compressor oils, that of combinations of SDDC of 0.5 to 2.0% and temperature Typical Uses etc. It is used in lubricating and sulfurized olefi n. As an of 400 to 500˚F. In lubricating antioxidant, VANLUBE 73 Super greases, VANLUBE 81 is effective in greases of all types as an both oxidation bomb tests and in antioxidant, antiwear and Plus outperforms both SDDC high speed spindle tests. Siloxane and SDDC/sulfurized olefi n and, extreme pressure additive. greases containing 2% VANLUBE unlike sulfurized olefi n, it does 81 have given outstanding results not lower the dropping point in bearing performance tests at of lithium complex grease. 350˚F. Has a good color stability. Widely used as a high temperature VANLUBE 73 Super Plus does antioxidant in jet engine oils. not have the pungent order of sulfurized olefi n. ® NSF Registered HX-2, 137553 NSF® Registered HX-1, 143815 VANLUBE Antioxidant and VANLUBE Lubricant Additive are registered trademarks of R.T. Vanderbilt Company, Inc. NSF is a registered trademark of NSF International. 11. VANLUBE® 289 VANLUBE 601 VANLUBE 601E Lubricant Additive Formula Proprietary Proprietary Proprietary

Auto Transmission Fluid, Fuel, Gear Oil, Fuel, Gear Oil, Grease, Compressor Oil, Engine Grease, Hydraulic Oil, Hydraulic Oil, Metalworking, Application Oil, Gear Oil, Grease, Metalworking, Synthetic Synthetic Lube, Turbine Oil Metalworking Lube, Turbine Oil Ashless, Antioxidant, Ashless, Antiwear/Antiscuff, Antioxidant, Corrosion Corrosion Inhibitor, Metal Function Friction Reducer Inhibitor Deactivator Chemical Heterocyclic sulfur-nitrogen Heterocyclic Borate ester Composition compound sulfur-nitrogen compound Physical State Liquid Liquid Liquid Color Yellowish Dark Amber Dark Amber Density @ 15.6˚C 0.99 0.98 (8.1) 0.98 (8.1) Mg/m3 (lb/gal) Viscosity @ 22.3 10.5 7 100˚C cSt Flash Point 191 122 157 (PMCC), ˚C Soluble in petroleum and Soluble in petroleum and Soluble in petroleum and Solubility synthetic lubricant bases. synthetic lubricant bases. synthetic lubricant bases. Insoluble in water. Insoluble in water. Insoluble in water. Use Concentration, 0.5 - 1.0 0.02 - 1.0 0.02 - 1.0 % mass VANLUBE 289 is an oil- VANLUBE 601 is a copper VANLUBE 601E is a copper soluble borate ester that passivator, corrosion and rust passivator, corrosion and is an effective antiwear inhibitor of the ﬁ lm-forming rust inhibitor of the ﬁ lm- additive, by itself or in type. It exhibits synergistic forming type. It exhibits synergistic combinations properties with various metal synergistic properties with other antiwear/ organic extreme pressure with various metal extreme pressure additives additives such as the organic extreme pressure such as dithiophosphates, dithiocarbamates. Used in additives such as the dithiocarbamates. Used in dithiocarbamates and alkyl petroleum fuels and solvents petroleum fuels and solvents thiadiazoles. It contains at concentration of 1 to 10 at concentrations to 1 to 10 no phosphorous, sulfur pounds per 1,000 barrels to pounds per 1,00 barrels to or metals. It is therefore prevent copper stain and prevent copper stain and useful in eliminating and/ corrosion. Used in petroleum corrosion. Used in petroleum Typical Uses or reducing levels of these base oils and greases and base oils and greases and elements in lubricants and in synthetic base greases in synthetic base greases greases while maintaining at concentrations of 0.02 at concentrations of 0.02 to cost-effective performance. to 0.5% to protect copper. 0.5% to protect copper. VANLUBE 601 has color VANLUBE 601E has shown stabilizing properties in color stabilizing properties oils and greases stored at in oils and greases stored at elevated temperatures. It elevated temperatures. It is is useful EP/synergist with a a useful extreme pressure/ variety of extreme pressure synergist with a variety and antiwear additives. of extreme pressure and antiwear additives.

VANLUBE is a registered trademark of R.T. Vanderbilt Company, Inc. 12. VANLUBE® 622 VANLUBE 672 VANLUBE 692 Lubricant Additive

R S O Proprietary Formula P S Sb Proprietary O R 3

Gear Oil, Grease, Gear Oil, Grease, Engine Oil, Gear Oil, Grease, Metalworking, Synthetic Metalworking, Synthetic Application Synthetic Lube Lube Lube Antioxidant, Antiwear/ Ashless, Antioxidant, Ashless, Antioxidant, Function Antiscuff, Friction Reducer, Antiwear/Antiscuff, Extreme Antiwear/Antiscuff, Extreme Pressure Pressure Extreme Pressure Antimony o,o- Chemical Aromatic amine dialkylphosphorodithioate Amine phosphate phosphate Composition in oil. Physical State Clear to slightly hazy liquid Viscous Liquid Viscous Liquid Color Amber Light Amber Dark Amber Density @ 15.6˚C 1.20 (10.0) 1.02 (8.5) 0.99 (8.2) Mg/m3 (lb/gal) Viscosity @ 5 250 53 100˚C cSt Flash Point 150 113 165 (PMCC), ˚C Soluble in petroleum and Soluble in water, petroleum Soluble in petroleum and Solubility synthetic lubricant bases. and synthetic lubricant synthetic lubricant bases. Insoluble in water. bases. Insoluble in water. Use Concentration, 0.5 - 3.0 1.0 - 3.0 1.0 - 3.0 % mass VANLUBE 622 is an antiwear VANLUBE 672 is an extreme VANLUBE 692 is used in and extreme pressure pressure and antiwear nonmetallic industrial additive for steel mill and additive for industrial gear oils to give high other industrial gear oils. lubricants, including load carrying properties. VANLUBE 622 has outstanding lubricating oils, greases and Extreme pressure and extreme pressure and synthetic fl uids. Used as antiwear additive for antiwear properties in a an extreme pressure and lubricants based on variety of base lubricants. antiwear additive in various petroleum oils and It will give unusually high metalworking lubricants synthetics. VANLUBE 692 Timken, Falex and 4-Ball such as drawing, stamping enhances the extreme extreme pressure values at and forming compounds. pressure properties Typical Uses economical concentrations Improves extreme pressure of 1 to 3%. It shows promise performance of conventional of sulfurized olefi ns, as an extreme pressure extreme pressure materials chlorinated paraffi ns, and antiwear additive such as sulfurized olefi ns, fatty dithiocarbamates and in automotive gear oils. oils, chlorinated paraffi ns, phosphorodithioates. Radioactive Ring Wear metal dithiocarbamates and Tests in crankcase oils show phosphorodithioates. Effective VANLUBE 622 to be superior in low concentrations as an to zinc dithiophosphates at antiwear additive in synthetic equivalent treat costs. Friction lubricants. reducer in engine oils and gear oils.

VANLUBE is a registered trademark of R.T. Vanderbilt Company, Inc. 13. VANLUBE® 704S VANLUBE 719 VANLUBE 727 Lubricant Additive Formula Proprietary Proprietary Proprietary Auto Transmission Fluid, Engine Oil, Gear Oil, Grease, Engine Oil, Grease, Gear Oil, Metalworking, Hydraulic Oil, Metalworking, Hydraulic Oil, Application Synthetic Lube Synthetic Lube, Turbine Oil Metalworking, Synthetic Lube Corrosion Inhibitor, Antioxidant, Antiwear/ Ashless, Antioxidant, Demulsifi er, Metal Function Antiscuff, Extreme pressure Antiwear/Antiscuff Deactivator, Rust Inhibitor Chemical Organosulfur-phosphorus Barium sulfonate blend Amine phosphate package Composition compound Physical State Viscous Liquid Liquid Liquid Color Dark Amber Dark Amber Light Amber Density @ 15.6˚C 1.03 (8.5) 0.99 (8.2) 1.01 (8.4) Mg/m3 (lb/gal) Viscosity @ 72 48 2.6 100˚C cSt mm 2/s Flash Point 188 85 100 (PMCC), ˚C Soluble in petroleum and Soluble in petroleum and Soluble in petroleum and Solubility synthetic lubricant bases. synthetic lubricant bases. synthetic lubricant bases. Insoluble in water. Insoluble in water. Insoluble in water. Use Concentration, 0.05 - 0.25 1.0 - 4.0 1.0 - 2.0 % mass VANLUBE 704S is used VANLUBE 719 was developed VANLUBE 727 is a versatile in petroleum and primarily for steel mill and additive for various types of synthetic lubricants as a similar industrial gear oils. It automotive and industrial multifunctional rust and gives good extreme pressure lubricating oils. VANLUBE 727 corrosion inhibitor. and antiwear properties, functions as an antiwear VANLUBE 704S is a synergistic good high temperature agent and antioxidant. Its blend of polar additives stability, and good nonmetallic nature makes capable of forming fi lms demulsibility. VANLUBE 719 it of interest for ashless or low ash applications. Some or complexes on metal at a concentration range suggested applications surfaces, particularly of 2 to 3% will meet the are: automotive engine copper and copper alloys requirements of most steel oils, railroad diesel oils, that might be exposed to mill gear oil specifi cations. It compressor oils, gas engine free sulfur of active sulfur is also used in 2-cycle engine oils, antiwear hydraulic and Typical Uses compounds. It is used oils. turbine oils, and various in a variety of lubricants types of industrial oils. Bench based on petroleum oils tests indicate that the or synthetics. Economical performance of concentrations enhance VANLUBE 727 is competitive antioxidants by passivating with that of commonly used catalytic metal surfaces in zinc dithiophosphates. One the lubricant system. percent in SAE 90 gear oil gives a 12-stage pass in the FZG test.

VANLUBE is a registered trademark of R.T. Vanderbilt Company, Inc. 14. VANLUBE® 734 VANLUBE 829 VANLUBE 869 Lubricant Additive N N N N

Formula Proprietary HS S S SH Proprietary S S

Auto Transmission Fluid, Compressor Oil, Engine Oil, Grease, Synthetic Lube Gear Oil, Grease Application Gear Oil, Grease, Hydraulic Oil, Turbine Oil Ashless, High Temperature, Antioxidant, Antiwear/ Ashless, Corrosion Inhibitor, Antioxidant, Antiwear/ Antiscuff, Friction Reducer, Function Rust Inhibitor Antiscuff, Extreme Pressure Corrosion Inhibitor, Extreme Pressure, Metal Deactivator Chemical 5,5-dithiobis(1,3,4- Zinc dithiocarbamate/ Ashless rust inhibitor in oil Composition thiadiazole-2(3H)-thione) sulfurized oleﬁ n blend Physical State Liquid Powder Liquid Color Light Amber Yellow Amber Density @ 15.6˚C 0.92 (7.7) 2.09 1.14 (9.5) Mg/m3 (lb/gal) Viscosity @ 5–28 100˚C cSt Flash Point 130 – 100 (PMCC), ˚C Soluble in petroleum and Soluble in petroleum and Solubility synthetic lubricant bases. Dispersible in grease. synthetic lubricant bases. Insoluble in water. Insoluble in water. Use Concentration, 0.05 - 0.5 1.0 - 3.0 1.25 - 2.0 % mass VANLUBE 739 was designed VANLUBE 829 possesses VANLUBE 869 is an to improve rust protection in excellent extreme pressure effective extreme lube oils and greases. properties when dispersed pressure/antioxidant in various greases. It also suitable for lubricating oils functions as an antiwear and greases. VANLUBE 869 agent and an antioxidant. is compatible with other VANLUBE 829 should be used VANLUBE rust inhibitors/ in greases in applications antioxidants and metal where extreme pressures deactivators. prevail, such as steel mills and heavy equipment Typical Uses lubrication.

NSF® Registered HX-2, 138302

VANLUBE is a registered trademark of R.T. Vanderbilt Company, Inc. NSF is a registered trademark of NSF International. 15. VANLUBE® 871 VANLUBE 887 VANLUBE 887E Lubricant Additive Antioxidant Formula Proprietary Proprietary Proprietary Auto Transmission Fluid, Auto Transmission Fluid, Compressor Oil, Engine Compressor Oil, Engine Oil, Engine Oil, Grease Oil, Gear Oil, Grease, Application Gear Oil, Grease, Hydraulic Hydraulic Oil, Synthetic Oil, Turbine Oil Lube, Turbine Oil Ashless, Antioxidant, Ashless, High Temperature, Ashless, High Temperature, Function Antiwear/Antscuff Antioxidant Antioxidant 2,5-dimercapto- Chemical Tolutriazole compound in 1,3,4-thiadiazole alkyl Tolutriazole compound in oil ester Composition polycarboxylate Physical State Liquid Liquid Liquid Color Amber Amber Light Amber Density @ 15.6˚C 1.10 (9.3) 1.00 (8.36) 1.01 (8.4) Mg/m3 (lb/gal) Viscosity @ 19.6 17 20 100˚C cSt Flash Point 178 146 180 (PMCC), ˚C Soluble in petroleum and Soluble in petroleum and Soluble in petroleum and Solubility synthetic lubricant bases. synthetic lubricant bases. synthetic lubricant bases. Insoluble in water. Insoluble in water. Insoluble in water. Use Concentration, 0.5 - 2.0 0.5 - 1.0 0.5 - 2.0 % mass VANLUBE 871 is a liquid VANLUBE 887 is a liquid VANLUBE 887E is a liquid ashless antioxidant/antiwear ashless antioxidant. It is most ashless antioxidant. It agent. Possible uses include effective as an antioxidant is most effective as an both gasoline and diesel synergist with mixtures of antioxidant synergist engine oil formulations to hindered phenols and /or with mixtures of hindered improve existing additive ashless dithiocarbamates phenols and /or ashless packages. such as VANLUBE 7723. dithiocarbamates such as VANLUBE 887 possesses VANLUBE 7723. excellent high temperature VANLUBE 887E stability. Combined with possesses excellent high VANLUBE 7723 and a suitable temperature stability. base stock, it will pass the Cincinnati Milacron Thermal Typical Uses Stability Test, Procedure A.

VANLUBE Antioxidant and VANLUBE Lubricant Additive are registered trademarks of R.T. Vanderbilt Company, Inc. 16. VANLUBE® 915M VANLUBE 961 VANLUBE 972M Antioxidant Lubricant Additive Formula Proprietary Proprietary Proprietary Auto Transmission Fluid, Compressor Oil, Engine Oil, Compressor Oil, Engine Oil, Gear Oil, Grease, Hydraulic Grease, Synthetic Lube Application Gear Oil, Grease, Turbine Oil Oil, Synthetic Lube, Turbine Oil Ashless, High Temperature, Ashless, Antiwear/Antis- Antioxidant, Metal Ashless, Antioxidant Function cuff, Extreme Pressure Deactivator Chemical Mixed octylated and Thiadiazole derivative in Antioxidant blend Composition butylated diphenylamines polyalkylene glycols Physical State Liquid Liquid Liquid Color Amber Light Amber Amber Density @ 15.6˚C 1.01 0.98 (8.2) 1.24 (10.2) Mg/m3 (lb/gal) Viscosity @ 10.5 9.9 6.0 100˚C cSt Flash Point 160 190 110 (PMCC), ˚C Soluble in petroleum and Soluble in petroleum and Soluble PAG ﬂ uids. Insol- Solubility synthetic lubricant bases. synthetic lubricant bases. uble petroleum lubricant Insoluble in water. Insoluble in water. bases and water. Use Concentration, 0.5-1.0 0.5 - 1.0 0.5 - 3.0 % mass VANLUBE 915M is a liquid VANLUBE 961 is a liquid VANLUBE 972M, a ashless antioxidant ashless antioxidant for use in thiadiazole derivative in recommended for use in oils and greases of various polyalkylene glycol, is an high quality mineral and types. It may be used in ashless extreme pressure synthetic base stocks. It industrial lubricants, including additive recommended can be used in a broad compressor, hydraulic, for use in grease and range of industrial and turbine, gas engine and some polyalkylene glycols automotive applications, circulating oils. VANLUBE 961 (PAG) and some synthetic and is particularly effective may be used as an ashless esters. The advantages in turbine and compressor antioxidant in all types of this product offers are that oils. crankcase oils. it contains no metals, is easily handled, is readily biodegradable, is a cost Typical Uses effective alternative to other metal-containing EP additives and does not have the strong sulfur odor that is typical of the other sulfur EP additives.

NSF® Registered HX-1, HX-2, 135573 VANLUBE Antioxidant and VANLUBE Lubricant Additive are registered trademarks of R.T. Vanderbilt Company, Inc. NSF is a registered trademark of NSF International. 17. VANLUBE® 996E VANLUBE 7611M VANLUBE 7723 Antioxidant Lubricant Additive S S C H 4 9 C 4H9 Formula Proprietary Proprietary N S S N C H C H 4 9 4 9 Auto Transmission Fluid, Auto Transmission Fluid, Compressor Oil, Engine Oil, Compressor Oil, Gear Oil, Engine Oil, Grease, Hydraulic Gear Oil, Grease, Hydraulic Grease, Hydraulic Oil, Application Oil, Metalworking, Synthetic Oil, Metalworking, Synthetic Synthetic Lube, Turbine Oil Lube Lube, Turbine Oil Ashless, High Temperature, Ashless, High Temperature, Ashless, Antioxidant, Antioxidant, Antiwear/ Antioxidant, Corrosion Function Antiwear/Antiscuff Antiscuff, Friction Reducer, Inhibitor Extreme Pressure Methylene bis Chemical Methylene (dibutyldithiocarbamate) Ashless phosphorodithioate bis(dibutyldithiocarbamate) Composition and tolutriazole derivative Physical State Liquid Liquid Liquid Color Amber Light Amber Amber Density @ 15.6˚C 1.06 (8.8) 1.08 (9.0) 1.06 (8.8) Mg/m3 (lb/gal) Viscosity @ 16.4 2.54 15 100˚C cSt Flash Point 191 142 177 (PMCC), ˚C Soluble in petroleum and Soluble in petroleum and Soluble in petroleum and Solubility synthetic lubricant bases. synthetic lubricant bases. synthetic lubricant bases. Insoluble in water. Insoluble in water. Insoluble in water. Use 0.1 - 1.0 as antioxidant; 0.1 - 1.0 as antioxidant; 1-4 1.0 - 2.0 2.0 - 4.0 as extreme Concentration, as extreme pressure agent % mass pressure agent. VANLUBE 996E is a liquid VANLUBE 7611M is an organic VANLUBE 7723 is a general ashless antioxidant that ﬁ nds liquid additive containing sulfur purpose, ashless antioxidant application in petroleum and phosphorus. 4-Ball Wear which should ﬁ nd application in petroleum lubricants of lubricants of all types. It tests show that VANLUBE 7611M, at a 20 kg load, performs all types. It is effective at possesses excellent high equivalently to typical zinc economical concentrations, temperature stability and is dialkyldithiophosphates. At a readily soluble, and easy to noncorrosive despite having 40 kg load it is superior to these blend. VANLUBE 7723 has been high sulfur content. products. VANLUBE 7611M tested in a variety of base VANLUBE 996E also will improve the antiwear stocks commonly used exhibits extreme pressure properties of sulfurized extreme in compounding turbine, pressure additives. It is a useful Typical Uses performance alone and hydraulic and circulating oils. In in combination with other component for extreme addition to being an effective additives. pressure/antiwear lubricant antioxidant, formulations and additive VANLUBE 7723 also exhibits packages. VANLUBE 7611M good extreme pressure does not contain metallic performance alone and elements. Thus, it is applicable in combination with other to ashless and low ash additives. Useful as a formulations. component of additive packages.

NSF® Registered HX-2, 136048 NSF® Registered HX-1, HX-2, 136049 VANLUBE Antioxidant and VANLUBE Lubricant Additive are registered trademarks of R.T. Vanderbilt Company, Inc. NSF is a registered trademark of NSF International. 18. VANLUBE® 8610 VANLUBE 8912E VANLUBE 9123 Lubricant Additive Formula Proprietary Proprietary Proprietary Gear Oil, Grease, Hydraulic Gear Oil, Grease, Rust Gear Oil, Grease Oil, Metalworking, Rust Application Preventive Preventive, Turbine Oil Antioxidant, Antiwear/ Corrosion Inhibitor, Rust Ashless, Antiwear/ Function Antiscuff, Extreme Pressure Inhibitor Antiscuff, Rust Inhibitor Chemical Antimony dithiocarbamate/ Calcium sulfonate Amine phosphate Composition sulfurized oleﬁ n blend Physical State Liquid Liquid Liquid Color Amber Dark Brown Amber Density @ 15.6˚C 1.16 (9.42) 0.97 0.94 (7.8) Mg/m3 (lb/gal) Viscosity @ 28.5 19 24 100˚C cSt Flash Point 100 150 (COC) 96 (PMCC), ˚C Soluble in petroleum and Soluble in petroleum and Soluble in petroleum and Solubility synthetic lubricant bases. synthetic lubricant bases. synthetic lubricant bases. Insoluble in water. Insoluble in water. Insoluble in water. Use Concentration, 1.25 - 2.0 0.05 - 0.10 0.10 - 1.0 % mass VANLUBE 8610 is an extreme VANLUBE 8912E is an VANLUBE 9123 is an pressure/antioxidant useful oil-soluble calcium sulfonate excellent antiwear for various lubricating oils with excellent rust-inhibiting additive and rust and greases. Impressive and water-resistant inhibitor in a wide range Timken loads of 90 to properties. of industrial oils and 100 lbs. are achieved lubricating greases. with 2% treatment levels. VANLUBE 8610 is compatible with other VANLUBE rust inhibitors/antioxidants and metal deactivators.

Typical Uses

NSF ® Registered HX-1, HX-2, 135575

VANLUBE Lubricant Additive is a registered trademark of R.T. Vanderbilt Company, Inc. NSF is a registered trademark of NSF International. 19. VANLUBE® 9317 Antioxidant Formula Proprietary Application Synthetic Lube High Temperature, Function Antioxidant Chemical Organic amine compounds Composition in a synthetic ester Physical State Liquid Color Dark Brown Density @ 15.6˚C 0.98 (8.1) Mg/m3 (lb/gal) Viscosity @ 128 100˚C cSt Flash Point 254 (PMCC), ˚C Soluble in petroleum and Solubility synthetic lubricant bases. Insoluble in water. Use Concentration, 0.5 - 4.0 % mass VANLUBE 9317 is an amine antioxidant designed to give excellent high temperature performance in synthetic polyolester based lubricants. At high temperatures, it signiﬁ cantly reduces the sludge and varnish typically seen with more conventional amine antioxidants.

Typical Uses

VANLUBE is a registered trademark of R.T. Vanderbilt Company, Inc. 20. VANLUBE® BHC PHENOLIC ANTIOXIDANT

Typical Properties Composition: Butylated hydroxy-hydrocinnamate Physical State: Yellowish liquid Specific Gravity, 25°C 0.96 Viscosity at 40°C, mm²/s 140 Ash content, % < 0.1

VANLUBE BHC is an effective general-purpose, nonstaining, ashless antioxidant that provides excellent oxidative stability to a wide range of automotive and industrial lubricants. It has excellent solubility in mineral oil and non-conventional base stocks, and contains no diluents. It is easy to handle and will not crystallize at low temperatures like some commercial phenolic antioxidants.

VANLUBE BHC has low volatility and helps control oxidation and high temperature deposits/sludge. It is effective at concentrations of 0.1% to 2.0% and works well when combined with alkylated diphenylamines, molybdenum compounds, sulfur-containing antioxidants, or phosphites in many industrial oils and automotive lubricants, especially modern engine oils meeting the ILSAC GF-4 specification.

Figure 1 Figure 2

ASTM D 7097 TEOST MHT- 4 Results ASTM D 2272 RPVOT Results ® 60 All oils contain 0.1% VANLUBE RI-A, 0.1% VANLUBE 887E 1200

50 1000

40 800

600 30

Standard deviation + 5 mg 400 20

Deposits, mg Deposits, 200

10 min. time, Induction 0

0 Oil A Oil B Oil C VANLUBE® BHC Methylene-bis-DTBP VANLUBE® 961 Oil A Oil B Base +2% VANLUBE® BHC +2% VANLUBE SL +1% each Oil A = Group I + 0.2% VANLUBE 7723 Oil B = Group II + 0.2% VANLUBE 7723 Oil C = Group II + 0.2% VANLUBE 961

VANLUBE SL and VANLUBE 961 are alkylated diphenyamines; VANLUBE 7723 is methylene-bis-dibutyl-dithiocarbamate

Fig. 1 VANLUBE BHC controls deposits in TEOST MHT- 4 as well as diphenylamine antioxidants. Fig. 2 VANLUBE BHC boosts RPVOT induction time better than methylene-bis-2’6’-di-tert-butyl phenol.

VANLUBE Antioxidant is a registered trademark of the R.T. Vanderbilt Company, Inc. 08/07 VANLUBE® 289 Lubricant Additive

Ask about our new boron antiwear additive, VANLUBE 289 and its synergistic performance with ZDDP. Please e-mail us at: [email protected]

Figure 4. Test Parameters: 80°C; 50 N break-in load; 200 N test load; 50 HZ; 1.00 mm stroke; test duration of 120 minutes.

Figure 5. Test Parameters: 25°C; 50 N break-in load; 1000 N test load; 50 HZ; 1.00 mm stroke. Experiments ran until failure as indicated by a large and sudden increase in the friction coefficients

VANLUBE is a registered trademark of R.T. Vanderbilt Company, Inc. VANLUBE® 996E Antioxidant

Looking for effective antioxidants with proven synergism in Group I-III base oils? Please e-mail us at: [email protected]

VANLUBE® 996E, 0.5 mass %

Figure 1. Rust inhibitor (VANLUBE RI-A Lubricant Additive, 0.05 mass %) was added to all test oils. ADPA is acronym for alkylated diphenylamine. The ADPA that was used for this study consisted of a mixture of butylated/octylated DPA components.

VANLUBE® 996E, 0.5 mass %

Figure 2. Rust inhibitor (VANLUBE RI-A Lubricant Additive, 0.05 mass %) was added to all test oils. ADPA is acronym for alkylated diphenylamine. The ADPA that was used for this study consisted of a mixture of butylated/octylated DPA components.

VANLUBE is a registered trademark of R.T. Vanderbilt Company, Inc. VANLUBE® 0401 Lubricant Additive

Are you working on GF-5 formulations for PCMO that require low phosphorus and low sulfur but improved antiwear, antioxidant and friction retention properties? Please e-mail us at: [email protected]

VANLUBE is a registered trademark of R.T. Vanderbilt Company, Inc.

VANLUBE® 73 Super Plus Lubricant Additive

Extreme Pressure Antiwear Antioxidant

Typical Properties

Composition: Metal dialkyldithiocarbamate mixture Physical State: Liquid Color, ASTM D 1500: 7.0 maximum Density at 25qC, Mg/m3: 1.05 Viscosity at 40qC, mm2/s: 1.190 Viscosity at 100qC, mm2/s: 33.34 Flash Point, PMCC, qC: 245 minimum Antimony Content, %: 5.8 Zinc Content, %: 4.5 Sulfur Content, %: 18.5 Nitrogen Content, %: 4.5

VANLUBE 73 Super Plus is a proprietary mixture of dialkyldithiocarbamates. Based on equivalent antimony content, as shown in the table below, the load-carrying capability of VANLUBE 73 Super Plus is superior to that of antimony dialkyldithiocarbamate (SDDC), and comparable to that of combinations of SDDC and sulfurized olefin. As an antioxidant, VANLUBE 73 Super Plus outperforms both SDDC and SDDC/sulfurized olefin and, unlike sulfurized olefin, it does not lower the dropping point of lithium complex grease. VANLUBE 73 Super Plus does not have the pungent odor of sulfurized olefin.

Component Treat Rate, Mass Percent VANLUBE® 73 Super Plus Lubricant Additive 3.0 Compound A (SDDC) 2.5 Compound B (SDDC) 2.5 Compound C (SDDC/sulfurized olefin 1:1 blend) 2.3 Lithium Complex Grease, NLGI 2 97.0 97.5 97.5 97.7 100 Antimony content in grease, % 0.17 0.17 0.17 0.17 0

Timken OK Load (ASTM D 2509), lb 70 25 Fail 60 <20 20 4-Ball Wear (ASTM D 2266), 1200 rpm, 75 qC, 40 kgf, 1h, mm 0.57 0.54 0.56 0.60 0.69 4-Ball EP (ASTM D 2596), Weld Point, kgf 400 400 400 400 250 Dropping Point (ASTM D 2265), qC 283 277 267 252 273 273 247 PDSC Oxidation Induction Time (ASTM D 5483), minutes at 180 qC 76.6 61.7 54.1 45.4 0.8

VANLUBE is a registered trademark of R.T. Vanderbilt Company, Inc. BBREAKREAK A Product that will meet your most challenging OOUT!UT! needs!

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For additional information or to request a sample, please visit us at www.rtvanderbilt.com

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IS O 1 9 46 00 02 1:2008 100 Lubricant Additive FFDADA CClearedleared

Lubricant manufacturers now have available the ashless dithiocarbamate of choice to formulate lubricants and greases for incidental food contact. For more information visit www.rtvanderbilt.com/7723

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IS O 1 9 46 00 02 1:2008 100 VANLUBE is a registered trademark of R.T. Vanderbilt Company, Inc. UL is a registered trademark of UL LLC. 30 Winﬁ eld Street, P.O. Box 5150, Norwalk, CT 06856 (203) 853-1400 ♦ Fax: (203) 853-1452 www.rtvanderbilt.com ♦ [email protected]

rev05/11/2012