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Descargar Descargar Dirección Editorial: Rocío Bruquetas Galán Consejo de Redacción: María Aguiar, Emilio Cano Ruíz, Rafael Fort González, Emma García Alonso, Silvia García Fernández-Villa, Marisa Gómez González, Ana Laborde Marqueze, Margarita San Andrés Moya Edición y redacción de Suplemento: Cristina Ordóñez Goded, Leticia Ordóñez Goded, Vanessa Montesinos Muñoz, Margarita Pérez Grande, Mónica Ruiz Trilleros Secretaria de Edición: Mª Concepción de Frutos Sanz Webmaster GEIIC: Mª Concepción de Frutos Sanz Diseño página web: Pepe Nieto PEZRED Maquetación: Mª Concepción de Frutos Sanz y Emma García Alonso Traducción: María José Pimentel (Agoralíngua - Centro Oicial de Lengua Portuguesa) Foto portada: Imagen por microscopía óptica con iluminación UV de la sección transversal de un hilo entorchado metálico del siglo XV de la colección de la Hispanic Society of America. ©IVC+R,CulturArts Generalitat ISSN: 1989-8568 Esta publicación utiliza una licencia Creative Commons Se permite compartir, copiar, distribuir y comunicar públicamente la obra con el reconocimiento expreso de su autoría y procedencia. No se permite un uso comercial de la obra original ni la generación de obras derivadas. Esta revista utiliza Open Journal Systems, software libre de gestión y publicación de revistas desarrollando, soportado y libremente distribuido por el Public Knowledge Project bajo Licencia Pública General GNU. GRUPO ESPAÑOL de CONSERVACIÓN International Institute forConservation of historic and artistic works GE-conservación no se responsabiliza de la información contenida en los artículos ni se identiica necesariamente con ellas. © La propiedad intelectual de los artículos pertenece a los autores, y los derechos de edición y publicación de este número son de Ge-conservación. Rogamos que en la difusión libre de los contenidos queden patentes los créditos de los autores y la procedencia. El Grupo Español de Conservación es una asociación independiente ailiada a The International Institute for Conservation of Histtoric and Artistic Works, inscrita en el Registro Nacional de Asociaciones, Sección 1ª, Nº 160.299. Sede: I.P.C.E. C/Greco, 4 28040 Madrid. Asociación Declarada de Utilidad Pública por Orden del Ministerio del Interior 3404/2009 (BOE 18-12-2009). Ge- conservación Conservação|Conservation www.revista.ge-iic.com E-mail: [email protected] Biblioteca Complutense Catálogo CisneUCM Revista indexada en: Índice Artículos Páginas Evaluación in situ de recubrimientos protectores para patrimonio cultural metálico mediante espectroscopía de impedancia electroquímica Blanca Ramírez Barat y Emilio Cano Díaz 6 Propuesta de protocolo de valoración de la acidez ambiental en salas y vitrinas de la exposición temporal “El último viaje de la fragata Mercedes. La razón frente al expolio” (Museo Naval, Madrid) Javier Peña Poza, José María Gálvez Farfán, Mercedes González Rodrigo, Susana García Ramírez, María Ángeles Villegas Broncano, Manuel García Heras 14 Biología y Patrimonio Cultural: Estudio de la comunidad de plantas que colonizaban la fachada de la Iglesia de San Pablo (Valladolid) Manuel García Sáez 27 Información relevante que pasa a ser anecdótica: aerinita en las pinturas murales románicas de San Martín de Elines (Cantabria) Mª Rosa Tera Saavedra y Enrique Parra Crego 37 Reseñas de publicaciones Painting in the Laboratory. Scientiic examination for Art History and Conservation Marisa Gómez González 52 Vademécum del Conservador Emma García 54 Le Retable de la Passion de l’Eglise Saint-Marie de Güstrow - Etude historique et technologique. Der Passions-Altar der Pfarrkirche St. Marien zu Güstrow - Historische und technologische Studie. Maite Barrios 56 Current Technical Challenges in the Conservation of Paintings Silvia García Fernández-Villa 58 El yeso. Su elaboración y empleo en la pintura y dorado de retablos Rocío Bruquetas Galán 60 Museos y colecciones de la Universidad Complutense de Madrid Isabel García Fernández 62 3 Páginas Suplemento Jornadas de Conservación y Restauración de Artes Decorativas. (Grupo de Artes Decorativas del GEIIC) 13, 14 y 15 de Junio de 2012 Presentación Cristina y Leticia Ordóñez Goded 65 Industria, decoración y diseño. Historias del Museo Nacional de Artes Decorativas Paloma Muñoz Campos y Sofía Rodríguez Bernis 67 Conservación y mantenimiento de salas en una Casa-Museo del siglo XIX: el Museo Cerralbo Sofía de Alfonso Alonso- Muñoyerro 78 La porcelana del siglo XVIII. El nacimiento de un nuevo arte Elisa Ramiro Reglero 89 Controlar el tiempo: Apuntes sobre la conservación de relojes históricos del siglo XVIII Amelia Aranda Huete 98 Los abanicos de colección: sus patologías y su conservación Alet Restauración 107 Principales Actuaciones en la Conservación – Restauración de Vidrieras Fernando Cortés Pizano 122 Conservación y Restauración de Mobiliario. Cuestiones de Funcionamiento y Labores de Mantenimiento Cristina Ordóñez Goded 134 Marcos y muebles dorados. Conocer para conservar Leticia Ordóñez Goded 144 La joya histórica como objeto de arte. Problemas de conservación Amelia Aranda Huete 154 Tejidos domésticos. La complejidad de su conservación, restauración y exposición María López Rey 161 Un modelo de conservación histórica y de intervención conservadora: Las Bodas de Mercurio. Colección de Tapices del Duque de Lerma Concha Herrero Carretero 172 El principio de reversibilidad en restauración textil Isabel Fernández López 185 La recuperación de tejidos y bordados de los siglos XV-XVI a través de la colección de la Hispanic Society of America. Su investigación, conservación, restauración y exposición Gertrudis Jaén Sánchez y Carmen Pérez García 196 La restauración de la colección de miniaturas del Museo Nacional del Prado Elena Arias Riera 211 4 Artículos Ge-conservación Conservação | Conservation Evaluación in situ de recubrimientos protectores para patrimonio cultural metálico mediante espectroscopía de impedancia electroquímica Blanca Ramírez Barat y Emilio Cano Díaz Resumen: Los métodos electroquímicos como la espectroscopía de impedancia electroquímica (EIS) son herramientas ampliamente utilizadas para estudios de corrosión y evaluación de recubrimientos. En el campo de la conservación del patrimonio cultural metálico, sin embargo, su uso se encuentra menos extendido por la dificultad para la realización de medidas in situ sobre esculturas y monumentos. En este trabajo se presentan las posibilidades de aplicación de esta técnica al estudio de recubrimientos protectores para el bronce con una novedosa celda portátil con un electrólito gelificado con agar. Palabras clave: agar, electrólitos sólidos, espectroscopía de impedancia electroquímica, patrimonio cultural metálico, recubrimientos In situ assessment of protective coatings for metallic cultural heritage using electrochemical impedance spectroscopy Abstract: Electrochemical methods such as electrochemical impedance spectroscopy (EIS) are widely used for corrosion studies and coatings evaluation. Nevertheless, their use in the field of metallic cultural heritage conservation is less widespread because of the difficulty to perform in situ measurements on sculptures and monuments. In this paper the possibilities of applying this technique to the study of protective coatings for bronze with an innovative portable cell with an electrolyte gelled with agar are presented. Key words: agar, coatings, electrochemical impedance spectroscopy, metal cultural heritage, solid electrolytes Avaliação in situ de coberturas de protecção do património cultural metálico através da espectroscopia de impedância electroquímica Resumo: Os métodos electroquímicos como a espectroscopia de impedância electroquímica (EIS) são ferramentas largamente utilizadas para estudos de corrosão e de avaliação de coberturas. Contudo, na área da conservação do património cultural metálico, a sua utilização não é tão alargada devido à dificuldade para a realização das medidas in situ nas esculturas e monumentos. No presente trabalho apresentam-se as possibilidades de aplicação desta técnica ao estudo das coberturas protectoras para o bronze através de uma célula portátil inovadora que possui um electrólito gelificado com ágar-ágar. Palavras-chave: ágar-ágar, electrólitos sólidos, espectroscopia de impedância electroquímica, património cultural metálico, coberturas Introducción inhibidores que ofrecen protecciones más o menos eicaces y duraderas según el producto, el sustrato y las condiciones Todos los objetos metálicos en contacto con el medio ambientales. Conocer la eicacia de un recubrimiento ambiente sufren un proceso más o menos lento de deterioro aplicado sobre un objeto, así como su evolución o por corrosión. La corrosión es un proceso inevitable; sin degradación con el tiempo, resulta fundamental a la hora embargo, lo que determina en la práctica sus efectos, es de diseñar estrategias para la conservación del patrimonio la velocidad a la que se produce. Para reducir o retardar cultural metálico y para ello es necesario disponer de la corrosión es frecuente el empleo de recubrimientos e técnicas de diagnóstico adecuadas. Ge-conservación nº 8/ 2015. ISSN: 1989-8568 La espectroscopía de impedancia electroquímica (EIS) es da el valor de la resistencia de un sistema como la relación una técnica ampliamente utilizada en la evaluación de de proporcionalidad entre la intensidad de corriente (I) que pinturas y recubrimientos industriales y que en los últimos circula por un conductor y la diferencia de potencial (E) años ha comenzado a utilizarse también en el campo del entre sus extremos, R = E/I, la impedancia Z viene
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