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Grout Gas Generation Test Plan ECN No DISTRIBUTION SHEET To From Page 1 of 1 - W. J. Powell J. C. Person Date 9/8/93 Project Title/Work Order EDTNo. (pOo45^j[ Grout Gas Generation Test Plan ECN No. Text Text Only Attach./ EDT/ECN Name MSIN With All Appendix Only Attach. Only J. R. Jewett T6-09 X J. C. Person (4) T6-09 X W. J. Powell (3) R4-03 X Central Files L8-04 X 0.S.T.I. (2) L8-07 X A-6000-135 (01/93) WEF067 Page 1 of | ai p7 4QQC ENGINEERING DATA TRANSMITTAL I.EDT 600459 2. To: (Receiving Organization) 3. From: (Originating Organization) 4. Related EDT No.: Grout Technology Process Chemistry Laboratory N/A S. Proj./Prog./Dept./Div.: 6. Cog. Engr.: 7. Purchase Order No.: WM/Grout/PAL/FO J. C. Person _N/A_ 8. Originator Remarks: 9. Equip./Component No. N/A 10. Systea/Bldg./Facility: N/A 11. Receiver Remarks: 12. Major Assm. Dwg. No. 13. Permit/Permit Application No.: 14. Required Response Date: 15. DATA TRANSMITTED (F) (G) (H) (I) (A| (C) (D) Reason Origi• Receiv• (E) Title or Description of Data Impact Item Sheet Rev. for nator er (B) Document/Drawing No. Transmitted Level No. No. No. Trans• Dispo• Dispo• mittal sition sition 1. WHCSD-WM-TP-180 Grout Gas Generation 3Q Test Plan 16. KEY Impact Level (F) Reason for Transmittal (G) Disposition (H) & (I) 1, 2, 3, or 4 (see 1. Approval 4. Review 1. Approved 4. Reviewed no/comment MRP 5.431 3Q 2. Release 5. Post-Review 2. Approved w/comment 5. Reviewed w/comment 3. Information 6. Dist. (Receipt Acknow. Required) 3. Disapproved w/comment 6. Receipt acknowledged (G) (H) 17. SIGNATURE/DISTRIBUTION (G) (H) (See Impact Level for required signatures) Rea• Disp. (J) Name (K) Signature (U Date (M) MSIN W) Name IK) Signature (L) Date (M) MSIN Rea• Disp. son son Cog.Eng. J. C. Persi Cog. Mgr. J. R. Jewe 6 Mm4=^ - QA M. A. Richmai Safety Env. Prog. W. J. Powel KMfa<*gtym- 18. 19. 21. DOE APPROVAL (if required) Ltr. No. D Approved ,dpw 9-g-K LI Approved w/commen'ts Signature of EDT Date A inrorized Representative Date [] Disapproved u/conments originator foir Receiving Organization BD-7400-172-2 (07/91) GEF097 Mi BD-7400-172-1 (07/91) DISCLAIMER Portions of this document may be illegible in electronic image products. Images are produced from the best available original document. RELEASE AUTHORIZATION Document Number: WHC-SD-WM-TP-180, REV 0 Document Title: Grout Gas Generation Test Plan Release Date: 1/3/95 This document was reviewed following the procedures described in WHC-CM-3-4 and is: APPROVED FOR PUBLIC RELEASE WHC Information Release Administration Specialist: January 3, 1995 /Kara M. Broz TRADEMARK DISCLAIMER. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise, does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof or its contractors or subcontractors. This report has been reproduced from the best available copy. Available in paper copy and microfiche. Printed in the United States of America. Available to the U.S. Department of Energy and its contractors from: U.S. Department of Energy Office of Scientific and Technical Information (OSTI) P.O. Box 62 Oak Ridge, TN 37831 Telephone: (615) 576-8401 Available to the public from: U.S. Department of Commerce National Technical Information Service (NTIS) 5285 Port Royal Road Springfield, VA 22161 Telephone: (703) 487-4650 DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsi• bility for the accuracy, completeness, or usefulness of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Refer• ence herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise does not necessarily constitute or imply its endorsement, recom• mendation, or favoring by the United States Government or any agency thereof. The views and opinions of authors expressed herein do not necessarily state or reflect those of the P A-6001 -400.2 (09/94) WEF256 United States Gover„ment or any agency thereof. DISTRIBUTION OF THIS DOCUMENT IS UNUMJTfiD at SUPPORTING DOCUMENT 1. Total Pages Mo 2. Title 3. Number Rev No. Grout Gas Generation Test Plan HHC-SD-WM-TP-180 0 5. Key Words 6. Author Grout, Gas Generation Name: J. C. Person APPROVED FOR FTgnattJQe *'m& '/L/f* PUBLIC RELEASE Organization/Charge Code 12110/D44L2 7. Abstract Detailed procedures for measurements of the rate of gas generation by grout made from synthetic tanks waste or actual tank material. SE AND USE OF DOCUMENT - This document was preparediWuse RELEASE STAMP withir?*"*l9£U.S. Department of Energy and its contractor^^Tt is to be used clh4jf to perform, direct, or integra^^'work under U.S. OepartmenrXjnergy contracts. This dogymeln is not approved for public release urT*4,Lreviewed. | OFFICIAL RELEASE (J*\ PATENT STATUS - This documen^Mf^ since it is transmitted in | BY VV!- !C ^Cx advance of patent clearar>ce^>*'inade>ai<ailable in confidence solely for use in performapetf^of work UnBwa^contracts with the DATE JAN 01,1995 U.S. Department of^Eriergy. This document is n&Ntobe published nor its contentsofefterwise disseminated or used for purptoaesother than specified*atSove before patent approval for such release*b*^jse has beea«s«£ured, upon request, from the Patent Counsel, U.S. Oeparbnexit : Energy Field Office, Richland, UA. .^TrW DISCLAIMER - This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency thereof, nor any of their employees, nor any of their contractors, subcontractors or their employees, makes any warranty, express or implied, or assumes any tegal liability or responsibility for the accuracy, completeness, or any third party's use or the results of such use of any information, apparatus, product, or process disclosed, or represents that its use would not infringe privately owned rights. Reference herein to any specific commercial product, process, or service by trade name, trademark, manufacturer, or otherwise, does not necessarily constitute or imply its endorsement, recommendation, or favoring by the United States Government or any agency thereof or its contractors or subcontractors. The views and opinions of authors expressed herein do not necessarily state or reflect those of the United States Government or any agency thereof. 9. Impact Level 3Q A-6400-073 (11/91) tEF> VEF124 WHC-SD-WM-TP-180, Rev. 0 CONTENTS 1.0 INTRODUCTION 1-1 2.0 OBJECTIVE 2-1 3.0 SCOPE 3-1 4.0 TEST BACKGROUND 4-1 5.0 DESCRIPTION OF TEST 5-1 5.1 TEST ITEM . 5-1 5.2 TEST CRITERIA 5-1 5.3 TEST ENVIRONMENT 5-2 5.4 CRITERIA FOR APPARATUS DESIGN 5-2 5.5 PRESTART CONDITIONS ' 5-3 5.6 TEST APPARATUS 5-3 5.7 SYNTHETIC GROUT FORMULATION . 5-6 5.8 DATA 5-6 5.8.1 Gas Generation Rate Data 5-6 5.8.2 Gas Composition Data 5-7 5.8.3 Determination of Amount of Gas Produced 5-8 5.8.4 Key Instrument Sensitivity and Calibration 5-8 6.0 EXPECTED RESULTS 6-1 7.0 TEST PROCEDURE 7-1 8.0 SAFETY 8-1 9.0 QUALITY ASSURANCE 9-1 10.0 LABORATORY QUALITY CONTROL.SAMPLES 10-1 10.1 REFERENCE SAMPLES (STANDARDS) 10-1 10.2 CALIBRATION BLANKS 10-1 11.0 PERFORMANCE AND SYSTEM AUDITS 11-1 12.0 CORRECTIVE ACTION 12-1 13.0 QUALITY ASSURANCE REPORT 13-1 14.0 DATA SHEETS 14-1 15.0 REFERENCES 15-1 APPENDIX A WASTE SOURCE TERM FOR MAKE-UP OF SYNTHETIC WASTE A-l APPENDIX B JOB SAFETY ANALYSIS B-l m WHC-SD-WM-TP-180, Rev. 0 LIST OF TERMS Argonne National Laboratory U.S. Department of Energy Gas Chromatograph Lower Flammability Limit Nondestructive Examination Operating Safety Requirements Process Chemistry Laboratories Pacific Northwest Laboratories lb/in2, absolute Westinghouse Hanford Company IV WHC-SD-WM-TP-180, Rev. 0 GROUT GAS GENERATION TEST PLAN 1.0 INTRODUCTION This document is to formalize the procedure provided in Section 7.0. The procedure is for gas generation experiments from grout produced by using either synthetic tank waste or actual tank material. This is the detailed procedure for the gas generation tests as referenced in Section 4.10 of WHC-SD-WM-TP-136, the Hanford Grout Disposal Program-Campaign 102 Feed Characterization and Test Plan (Hendrickson 1993). Section 2.0 discusses the objective of these experiments, which is to measure the rate of gas generation and to determine the gas composition. The experiments measure the pressure buildup in closed containers, from which gas samples are collected for gas analysis by either mass spectrometry or gas chromatography. The scope is provided in Section 3.0. Section 4.0 presents background for the test. Section 5.0 describes the test, with details on the test criteria, the criteria for apparatus design, the experimental apparatus and methods, the grout formulation, and the data to be generated. The expected results are discussed in Section 6.0. Section 7.0 presents one table with the detailed procedure and a second table with notes on the steps in the procedure. Sections 8.0 and 9.0 discuss safety and quality assurance issues.
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