US 20190281835A1 ( 19) United States (12 ) Patent Application Publication ( 10) Pub . No. : US 2019 /0281835 A1 SAELINGER et al. (43 ) Pub . Date : Sep . 19 , 2019 (54 ) METHOD AND PESTICIDAL MIXTURES Publication Classification FOR CONTROLLING PENTATOMIDAE (51 ) Int. Cl. PESTS AOIN 65 /00 ( 2006 .01 ) AOIN 47/ 20 ( 2006 . 01) ( 71 ) Applicant: BASF SE , Ludwigshafen (DE ) AOIN 43 /22 ( 2006 .01 ) ( 72 ) Inventors : Daniel SAELINGER , Ludwigshafen AOIN 43 /56 ( 2006 .01 ) (DE ) ; Joachim DICKHAUT, AOIN 43 / 90 (2006 .01 ) Heidelberg (DE ): Karsten KOERBER . (52 ) U . S . Cl. Eppelheim (DE ) ; Wolfgang VON CPC ...... A01N 65 / 00 (2013 . 01 ) ; AOIN 47 /20 DEYN , Neustadt (DE ) ; Raffael ( 2013 . 01 ) ; A01N 43/ 22 ( 2013. 01 ) ; Y024 KOLLER , Zuerich (CH ) ; Arun 50 /322 ( 2018 .01 ) ; A01N 43 /90 (2013 .01 ) ; NARINE , Mannheim (DE ) ; Jean - Yves YO2A 50 /354 ( 2018 . 01 ) ; YO2A 50 / 352 WACH , Zuerich ( CH ) ; Jochen DIETZ , (2018 .01 ); A01N 43 / 56 (2013 .01 ) Karlsruhe (DE ) ; Diana LONDONO , Apex , NC (US ) (57 ) ABSTRACT (21 ) Appl . No .: 16 /422 , 090 The invention relates to a method for controlling pests from (22 ) Filed : May 24 , 2019 the family of Pentatonidae , comprising the step of contact ing the pests , their food supply , habitat or breeding grounds Related U . S . Application Data with a pesticidal mixture comprising as active compound I at least one component of the ginkgo tree I , selected from the (63 ) Continuation of application No . 15 /519 , 278 , filed on group consisting of bilobalide, ginkgolide A , ginkgolide B , Apr. 14 , 2017 , now Pat. No. 10 ,334 ,859 , filed as ginkgolide C , ginkgolide J and ginkgolide M , and at least application No . PCT/ EP2015 /074067 on Oct . 16 , one pesticidally active compound II and / or at least one 2015. fungicidally active compound III , as defined in the descrip (60 ) Provisional application No. 62/ 064, 493 , filed on Oct . tion , in a synergistically effective amount. 16 , 2014 . The invention further relates to certain of these mixtures . US 2019 / 0281835 A1 Sep . 19 , 2019

METHOD AND PESTICIDAL MIXTURES [0011 ] There also exists the need for pest control agents FOR CONTROLLING PENTATOMIDAE that combine knock -down activity with prolonged control, PESTS that is , fast action with long lasting action . [0012 ] Another difficulty in relation to the use of pesti CROSS -REFERENCE TO RELATED cides is that the repeated and exclusive application of an APPLICATIONS individual pesticidal compound leads in many cases to a rapid selection of pests which have developed natural or [0001 ] This application is a continuation of U . S . applica adapted resistance against the active compound in question . tion Ser . No . 15 / 519 , 278 , filed Apr. 14 , 2017 , the entire contents of which are hereby incorporated herein by refer Therefore there is a need for pest control agents that help ence . U . S . application Ser. No. 15 /519 , 278 is a National prevent or overcome resistance . Stage application of International Application No . PCT/ [0013 ] It was therefore an object of the present invention EP2015 /074067 , filed Oct . 16 , 2015 , which claims the to provide pesticidal mixtures for the control of Pentatomi benefit of U . S . Provisional Application No .62 / 064 , 493, filed dae pests which solve at least one of the discussed problems Oct . 16 , 2014 , the entire contents of both of which are such as reducing the dosage rate , enhancing the spectrum of hereby incorporated herein by reference . activity or combining knock - down activity with prolonged [0002 ] The invention relates to a method for controlling control or as to resistance management. Pentatomidae pests , particularly in soybean crops, by apply [ 0014 ] It has been found that this object is in part or in ing a pesticidalmixture comprising insecticidal components whole achieved by applying the combination of active of the ginkgo tree . The invention further relates to pesticidal components of the ginkgo tree and further pesticides defined mixtures comprising insecticidal components of the ginkgo below . tree , their production and uses thereof. [0015 ] Further it has been found that mixtures of the [0003 ] Stink bugs (order of Hemiptera, family of Pentato specific active components of the ginkgo tree and further midae ) are animal pests and true bugs . They are probably insecticidal and /or fungicidal compounds show synergistic one of the most common pest problems in soybean (Stewart effect in the contest of various pests and fungi. et al. , Soybean Insects — Stink bugs , University of Tennessee [0016 ] Accordingly , in one aspect of the invention there is Institute of Agriculture, W200 09 - 0098 ) . provided a method for controlling pests from the family of [ 0004 ] Stink bugs feed on over 52 plants , including native Pentatonidae, comprising the step of contacting the pests , and ornamental trees, shrubs, vines, weeds , and many cul their food supply , habitat or breeding grounds with a pesti tivated crops such as corn and cotton , as well as numerous cidal mixture comprising as active compounds uncultivated plants, and their preferred hosts are nearly all [0017 ] 1 ) at least one compound I , which is a component wild plants . They build up on these hosts and move to of the ginkgo tree selected from the group consisting of soybeans late in the season as their preferred foods mature . bilobalide , ginkgolide A , ginkgolide B , ginkgolide C , [0005 ] Stink bugs may feed on many parts of the plant, ginkgolide J and ginkgolide M , however they typically target developing seed including the [0018 ] and pods , meaning that injury to soybean seed is the primary [0019 ] at least one pesticidally active compound II problem associated with stink bug infestations . selected from groups M and / or L consisting of [0006 ] Control of stinkbugs in soybean is often vital to [ 0020 ] II - M . 1 Acetylcholine esterase inhibitors : prevent significant economic damage . [0021 ] II - M . 1A carbamates : aldicarb , alanycarb , bendio [0007 ] Insecticides commonly used to control stinkbugs carb , benfuracarb, butocarboxim , butoxycarboxim , car include pyrethroids, neonicotinoids and organophosphates, baryl, carbofuran , carbosulfan , ethiofencarb , fenobucarb , though pyrethroid insecticides are usually the method of formetanate , furathiocarb , isoprocarb , methiocarb , choice for controlling stink bugs in soybean . However, there methomyl, metolcarb , oxamyl, pirimicarb , propoxur, thio are increasing problems with insecticide resistance , particu dicarb , thiofanox , trimethacarb , XMC , xylylcarb and tri larly in brown stink bug populations and particularly to azamate ; and pyrethroids . Euschistus heros can also be difficult to manage [0022 ] II - M . 1B organophosphates, for example acephate , using organophosphates or endosulfan ( Sosa -Gomez et al . , azamethiphos , azinphos - ethyl, azinphosmethyl, cadusa 2009 ). There is therefore a need for effective ecological fos, chlorethoxyfos , chlorfenvinphos, chlormephos , chlo methods of controlling stinkbugs in soybean . rpyrifos, chlorpyrifos- methyl , coumaphos, cyanophos, [0008 ] Particularly insecticides acting on the gamma demeton - S -methyl , diazinon , dichlorvos /DDVP , dicroto aminobutyric acid (GABA ) - gated chloride channel (dis phos, dimethoate , dimethylvinphos, disulfoton , EPN , closed in e .g . WO 2005 /085216 (EP1731512 ), WO2009 / ethion , ethoprophos, famphur, fenamiphos, fenitrothion , 002809 and WO2009 /080250 ) seem to be effective for fenthion , fosthiazate , heptenophos, imicyafos , isofen controlling stinkbugs , especially in soybean such as phos, isopropyl O - (methoxyaminothio -phosphoryl ) described in WO2012/ 104331. salicylate , isoxathion , malathion , mecarbam , methami [ 0009 ] One typical problem arising in the field of pest dophos, methidathion , mevinphos ,monocrotophos , naled , control lies in the need to reduce the dosage rates of the omethoate, oxydemeton -methyl , parathion , parathion active ingredient in order to reduce or avoid unfavorable methyl, phenthoate , phorate , phosalone , phosmet, phos environmental or toxicological effects whilst still allowing phamidon , phoxim , pirimiphos -methyl , profenofos, pro effective pest control. petamphos , prothiofos, pyraclofos, pyridaphenthion , [0010 ] Another problem encountered concerns the need to quinalphos, sulfotep , tebupirimfos, temephos , terbufos, have available pest control agents which are effective tetrachlorvinphos , thiometon , triazophos , trichlorfon and against a broad spectrum of pests . vamidothion ; US 2019 /0281835 A1 Sep . 19 , 2019

[0023 ] II - M .2 .GABA - gated chloride channel antagonists : [0048 ] II -M .13 Uncouplers of oxidative phosphorylation [ 0024 ] II - M .2A cyclodiene organochlorine compounds: via disruption of the proton gradient : chlorfenapyr, endosulfan or chlordane; and DNOC , and sulfluramid ; [0025 ] II - M . 2B fiproles: ethiprole , fipronil, flufiprole , ( 0049 ] II - M . 14 Nicotinic acetylcholine receptor channel pyrafluprole and pyriprole ; blockers: bensultap , cartap hydrochloride , thiocyclam , [0026 ] II - M . 3 Sodium channel modulators : and thiosultap sodium ; [0027 ] II- M .3A pyrethroids: acrinathrin , allethrin , d -cis [0050 ] II - M . 15 Inhibitors of the chitin biosynthesis type 1 : trans allethrin , d - trans allethrin , bifenthrin , bioallethrin , bistrifluron , chlorfluazuron , diflubenzuron , flucycloxuron , bioallethrin S - cylclopentenyl, bioresmethrin , cyclopro flufenoxuron , hexaflumuron , lufenuron , novaluron , novi thrin , cyfluthrin , beta - cyfluthrin , cyhalothrin , lambda - cy flumuron , teflubenzuron , and triflumuron ; halothrin , gamma - cyhalothrin , cypermethrin , alpha - cy [0051 ] II- M . 16 Inhibitors of the chitin biosynthesis type 1 : permethrin , beta - cypermethrin , theta - cypermethrin , zeta buprofezin ; cypermethrin , cyphenothrin , deltamethrin , empenthrin , esfenvalerate , etofenprox , fenpropathrin , fenvalerate , flu [ 0052 ] II- M . 17 Moulting disruptors : cyromazine ; cythrinate , flumethrin , tau -fluvalinate , halfenprox , hepta [ 0053 ] II- M . 18 Ecdyson receptor agonists : methoxyfenoz fluthrin , imiprothrin , meperfluthrin , metofluthrin , mom ide , tebufenozide, halofenozide , fufenozide or chromafe fluorothrin , permethrin , phenothrin , prallethrin , nozide; profluthrin , pyrethrin ( pyrethrum ) , resmethrin , silaflu [ 0054 ] II - M . 19 Octopamin receptor agonists : amitraz ; ofen , tefluthrin , tetramethylfluthrin , tetramethrin , tral [0055 ] II - M . 20 Mitochondrial complex III electron trans omethrin , and transfluthrin ; and port inhibitors : hydramethylnon , acequinocyl, and flu [0028 ] II - M . 3B sodium channel modulators: DDT, and acrypyrim ; methoxychlor ; [ 0056 ] II- M . 21 Mitochondrial complex I electron trans 00291 II- M .4 Nicotinic acetylcholine receptor agonists : port inhibitors : [ 00300 II- M .4A neonicotinoids: acetamiprid , clothianidin , [0057 ] II -M . 21A METI acaricides and insecticides : cycloxaprid , dinotefuran , imidacloprid , nitenpyram , thia fenazaquin , fenpyroximate , pyrimidifen , pyridaben , cloprid , and thiamethoxam ; tebufenpyrad , and tolfenpyrad ; and [0031 ] Il - M .4A . 2 ( 2E - ) - 1 - [ (6 - Chloropyridin - 3 - yl) [0058 ] II - M .21B rotenone ; methyl] -N '- nitro -2 -pentylidenehydrazinecarboximid [0059 ] II - M .22 Voltage -dependent sodium channel block amide ; ers : [0032 ] II - M . 4 . A . 3 1 - [ (6 -Chloropyridin - 3 - yl )methyl ] - 7 [0060 ] II - M .22A indoxacarb ; methyl- 8 -nitro -5 -propoxy - 1 , 2, 3 ,5 ,6 , 7 -hexahydroimidazo [0061 ] II - M .22B metaflumizone; [ 1 , 2 - a ]pyridine ; and [0062 ] II - M . 22B . 1 2 - [ 2 - ( 4 -Cyanophenyl ) - 1 - [ 3 - ( trifluo [0033 ] II - M .4B nicotine ; romethyl) phenyljethylidene ] - N - [ 4 - ( difluoromethoxy ) [0034 ] II - M .5 Nicotinic acetylcholine receptor allosteric phenyl] - hydrazinecarboxamide ; and activators from the class of spinosyns: spinosad , and spinetoram ; [ 0063 ] II- M . 22B . 2 N - ( 3 - Chloro - 2 -methylphenyl ) - 2 - [ (4 [ 0035 ] II - M . 6 Chloride channel activators from the class chlorophenyl) [ 4 - [methyl ( methylsulfonyl ) amino ]phenyl ] of avermectins and milbemycins: abamectin , emamectin methylene ] -hydrazinecarboxamide ; benzoate , ivermectin , lepimectin , and milbemectin ; [0064 ] II- M .23 Inhibitors of the of acetyl CoA carboxylase [0036 ] Il - M . 7 Juvenile hormone mimics: of the class of tetronic and tetramic acid derivatives : [0037 ] II - M .7A juvenile hormone analogues : hydroprene , spirodiclofen , spiromesifen , and spirotetramat; kinoprene , and methoprene ; and [0065 ] II - M . 24 Mitochondrial complex IV electron trans [ 0038 ] II- M .7B fenoxycarb , and pyriproxyfen ; port inhibitors : 00391 II- M . 8 miscellaneous non -specific inhibitors : [ 0066 ] II- M . 24A phosphorous compounds: aluminium [0040 ] II - M .8A alkyl halides : methyl bromide, and other phosphide, calcium phosphide, phosphine , and zinc phos alkyl halides ; and phide; and [ 0041 ] II- M .8B chloropicrin , sulfuryl fluoride, borax , and [0067 ] II - M .24B cyanide ; tartar emetic ; [0068 ] II- M .25 Mitochondrial complex II electron trans [0042 ] II - M . 9 Selective homopteran feeding blockers : port inhibitors from the class of beta - ketonitrile deriva pymetrozine , and flonicamid ; tives: cyenopyrafen , and cyflumetofen ; [0043 ] Il - M .10 Mite growth inhibitors : clofentezine , [0069 ] II - M . 28 Ryanodine receptor- modulators from the hexythiazox , diflovidazin , and etoxazole ; class of diamides : flubendiamide , chlorantraniliprole [0044 ] II - M .11 Microbial disruptors of insect midgut ( Rynaxypyr® ), cyantraniliprole (Cyazypyr® ), tetranilip membranes : Bacillus thuringiensis , Bacillus sphaericus , role ; and the phthalamide compounds and the insecticdal proteins they produce : Bacillus [ 0070 ] II - M .28 . 1 ( R ) - 3 - Chlor- N1- { 2 -methyl - 4 - [ 1 , 2 , 2 , 2 thuringiensis subsp . israelensis, Bacillus sphaericus , tetrafluor- 1 - (trifluormethyl ) ethyl] phenyl} -N2 - ( 1 -methyl Bacillus thuringiensis subsp . aizawai and Bacillus 2 -methylsulfonylethyl ) phthalamid ; thuringiensis subsp . tenebrionis , or the Bt crop proteins : [ 0071] II- M . 28 .2 (S )- 3 -Chlor - N1 - {2 -methyl - 4 - [1 , 2 , 2 ,2 Cry1Ab , Cry1Ac , Cry1Fa , Cry2Ab , mCry3A , Cry3Ab , tetrafluor- 1 -( trifluormethyl) ethyl] phenyl ) -N2 -( 1 -methyl Cry3Bb and Cry34 /35Ab1 ; 2 -methylsulfonylethyl )phthalamid ; [0045 ] II - M . 12 Inhibitors of mitochondrial ATP synthase: [0072 ] II - M . 28 . 3 3 -bromo - N - { 2 - bromo- 4 - chloro -6 - [ ( 1 [0046 ] Il - M .12A diafenthiuron , and organotin miticides : cyclopropylethyl )carbamoyl ] phenyl )- 1 -( 3 - chlorpyridin azocyclotin , cyhexatin , and fenbutatin oxide ; and 2 - yl ) - 1H -pyrazole - 5 - carboxamide (proposed ISO name: [ 0047 ] II - M . 12B propargite , and tetradifon ; cyclaniliprole) ; US 2019 / 0281835 A1 Sep . 19 , 2019

[0073 ] II - M .28 .4 methyl- 2 -[ 3 ,5 - dibromo -2 -( { [ 3 -bromo - 1 [0094 ] II -M .29 .6h (E / Z )- N - [1 - [( 2 -chloropyrimidin -5 -yl ) ( 3 - chlorpyridin - 2 - yl) - 1H - pyrazol - 5 - yl] carbonyl) - amino ) methyl] - 2 -pyridylidene ] - 2 , 2 , 2 - trifluoro - acetamide benzoyl] - 1 , 2 -dimethylhydrazinecarboxylate ; [0095 ] II -M .29 . 6i (E / Z )- N -[ 1- [ ( 6 -chloro -3 -pyridyl ) [0074 ] II - M .28 .5a N - [ 4 , 6 -dichloro - 2 - [ (diethyl - lambda - 4 methyl ) - 2 - pyridylidene ) - 2 , 2 , 3 , 3 , 3 - pentafluoropropana sulfanylidene ) carbamoyl] - phenyl ] - 2 -( 3 -chloro -2 mide . ); pyridyl) - 5 - ( trifluoromethyl )pyrazole - 3 - carboxamide ; [ 0096 ] II- M . 29 .6j N - [ 1 - [ (6 - chloro - 3 -pyridyl ) methyl ) - 2 [0075 ] IIM .28 . 5b N - [ 4 - chloro - 2 - [ (diethyl - lambda - 4 - sul pyridylidene ] -2 , 2 ,2 - trifluoro -thioacetamide ; and fanylidene ) carbamoyl ] - 6 -methyl - phenyl ] - 2 - ( 3 - chloro - 2 [0097 ] II - M .29 . 6k N - [ 1 - [ (6 -chloro - 3 - pyridyl) methyl ] - 2 pyridyl) - 5 - ( trifluoromethyl) pyrazole - 3 - carboxamide ; pyridylidene ] - 2 , 2 , 2 - trifluoro - N '- isopropyl - acetamidine ; [0076 ] II - M .28 . 5c N - [ 4 -chloro - 2 - [ ( di- 2 - propyl- lambda - 4 100981. II - M .29 . 8 : fluazaindolizine ; sulfanylidene) carbamoyl ] -6 -methyl -phenyl ] - 2 - ( 3 -chloro [0099 ] II - M .29 . 9 . a 4 - [ 5 - ( 3 , 5 -dichlorophenyl ) - 5 - (trifluo 2 -pyridyl ) - 5 - ( trifluoromethyl) pyrazole - 3 - carboxamide ; romethyl) -4H - isoxazol- 3 - yl) - 2 -methyl - N - ( 1 -oxothietan [0077 ] II - M . 28 . 5d N - [ 4 ,6 - dichloro - 2 - [ ( di- 2 -propyl 3 -yl ) benzamide ; and lambda - 4 -sulfanylidene )carbamoyl ] -phenyl ] -2 - ( 3 -chloro [0100 ] II - M . 29 . 9 .b fluxametamide; 2 -pyridyl ) - 5 -( trifluoromethyl) pyrazole - 3 - carboxamide; [0101 ] II - M .29 . 10 5 - [ 3 - [ 2 , 6 -dichloro - 4 -( 3 , 3 -dichloroally [0078 ] II - M . 28 .5h N - [ 4 , 6 - dibromo - 2 - [ (diethyl - lambda - 4 loxyphenoxylpropoxy ) - 1H - pyrazole ; sulfanylidene ) carbamoyl] -phenyl ] - 2 - ( 3 - chloro - 2 [0102 ] Il - M .29 . 11. b 3 - (benzoylmethylamino ) - N - [ 2 pyridyl) - 5 - trifluoromethyl) pyrazole - 3 - carboxamide ; bromo - 4 - [ 1 , 2 , 2 , 3 , 3 , 3 - hexafluoro - 1 - ( trifluoromethyl) pro [0079 ] II - M .28 .5i N - [ 2 - ( 5 - Amino - 1 , 3 , 4 -thiadiazol - 2 - yl) pyl] - 6 -( trifluoromethyl) phenyl ] - 2 - fluoro -benzamide ; 4 - chloro - 6 -methylphenyl ] - 3 -bromo - 1 - ( 3 - chloro - 2 -pyridi [0103 ] II - M .29 . 11 . c 3 - (benzoylmethylamino ) - 2 - fluoro - N nyl) - 1H - pyrazole - 5 - carboxamide ; [ 2 - iodo - 4 - [ 1 , 2 , 2 , 2 - tetrafluoro - 1 - ( trifluoromethyl ) ethyl] [0080 ] II - M . 28 . 5j 3 - Chloro - 1 - ( 3 - chloro - 2 -pyridinyl ) - N 6 - ( trifluoromethyl) phenyl ] -benzamide ; [ 2 , 4 -dichloro -6 - [ [ ( 1 - cyano - 1 -methylethyl ) amino ]carbo [0104 ] II- M . 29 . 11. d N - [ 3 - [ [ [ 2 - iodo - 4 - [ 1 , 2 , 2 , 2 - tetrafluoro nyl] phenyl ) - 1H - pyrazole - 5 - carboxamide ; 1 - ( trifluoromethyl) ethyl ] - 6 - ( trifluoromethyl) phenyl] [0081 ] II - M . 28 .5k 3 - Bromo - N - [ 2 , 4 - dichloro -6 - methyl amino ] carbonyl] phenyl] - N -methyl - benzamide ; carbamoyl) phenyl] - 1 - ( 3 , 5 -dichloro - 2 - pyridyl ) - 1H -pyra [0105 ] II - M .29 . 11. e N - [ 3 -[ [ [ 2 -bromo - 4 -[ 1, 2 ,2 , 2 -tetra zole - 5 -carboxamide ; fluoro - 1 - ( trifluoromethyl) ethyl] - 6 - ( trifluoromethyl) phe [ 0082 ] II- M . 28 .51 N -[ 4 -Chloro - 2 - [ [ ( 1 , 1 - dimethylethyl) nyl] amino ]carbonyl ] - 2 - fluorophenyl] - 4 - fluoro -N amino ]carbonyl ] - 6 -methylphenyl ] - 1 -( 3 -chloro -2 -pyridi methyl- benzamide ; nyl) - 3 -( fluoromethoxy ) - 1H -pyrazole -5 -carboxamide ; and [0106 ] II - M .29 . 11. f 4 - fluoro - N - [ 2 - fluoro - 3 - [ [ [ 2 - iodo - 4 11 - M . 28 . 6 : cyhalodiamide ; [ 1, 2 ,2 , 2 - tetrafluoro - 1- (trifluoromethyl ) ethyl ] -6 - ( trifluo [0083 ] II - M .29 . insecticidal active compounds of romethyl) phenyl ] amino ] carbonyl] phenyl ] - N -methyl - ben unknown or uncertain mode of action : afidopyropen , zamide ; afoxolaner, azadirachtin , amidoflumet , benzoximate , [0107 ] II - M .29 . 11. g 3 - fluoro - N - [ 2 - fluoro - 3 - [ [ [ 2 - iodo - 4 bifenazate, broflanilide , bromopropylate , chinomethionat, [ 1 , 2 , 2 , 2 - tetrafluoro - 1 - ( trifluoromethyl) ethyl] - 6 - ( trifluo cryolite , dicloromezotiaz , dicofol, flufenerim , flometo romethyl) phenyl ]amino ] carbonyl] phenyl ] -N -methyl -ben quin , fluensulfone , fluhexafon , fluopyram , flupyradifu Zamide ; rone , fluralaner, metoxadiazone , piperonyl butoxide , [0108 ] II - M . 29 .11 . h 2 - chloro - N - [ 3 - [[ [ 2 - iodo - 4 - [ 1 , 2 , 2 , 2 pyflubumide, pyridalyl, pyrifluquinazon , sulfoxaflor, tiox tetrafluoro - 1 - ( trifluoromethyl) ethyl] - 6 - ( trifluoromethyl) azafen , and triflumezopyrim ; phenyl] amino ] carbonyl ]phenyl ] - 3 -pyridinecarboxamide ; [0084 ] II - M . 29 .3 : 11 - (4 -chloro - 2 ,6 -dimethylphenyl )- 12 - [0109 ] II - M .29 . 11. i 4 -cyano - N - [2 -cyano -5 -[ [ 2, 6 - di hydroxy - 1, 4 - dioxa - 9- azadispiro [4 .2 .4 . 2 ]- tetradec - 11 -en bromo - 4 - [ 1 , 2 , 2 ,3 , 3 , 3 - hexafluoro - 1 - ( trifluoromethyl) pro 10 - one; pyl] phenyl ] carbamoyl ]phenyl ] - 2 -methyl - benzamide ; [0085 ] II - M .29 . 4 : 3 - ( 4 '- fluoro - 2 , 4 -dimethylbiphenyl - 3 [0110 ] II - M .29 .11 . j 4 -cyano - 3 - [ ( 4 - cyano - 2 -methyl - ben yl) - 4 - hydroxy - 8 -oxa - 1 - azaspiro [ 4 . 5 ]dec - 3 - en - 2 -one ; zoyl) amino ]- N -[ 2 ,6 -dichloro - 4 -[ 1, 2 ,2 , 3 ,3 ,3 -hexafluoro [0086 ] II - M .29 . 5 : 1 - [ 2 - fluoro - 4 - methyl- 5 - [ ( 2 , 2 , 2 - trifluo 1 -( trifluoromethyl) propyl ] phenyl ]- 2 - fluoro -benzamide ; roethyl) sulfinyl] phenyl ]- 3 -( trifluoromethyl) - 1H - 1 ,2 ,4 -tri [ 0111 ] Il - M . 29. 11. k N - [ 5 - [ [ 2 - chloro -6 -cyano - 4 - [ 1 , 2 , 2 , 3 , 3 , azole - 5 -amine , and actives on basis of Bacillus firmus 3 - hexafluoro - 1 -( trifluoromethyl) propyl ] -phenyl ] carbam (Votivo , 1 - 1582 ); and oyl] - 2 - cyano - phenyl] - 4 - cyano - 2 -methyl - benzamide; [0087 ] II - M . 29 .6a ( E / Z ) - N - [ 1 - [ ( 6 -chloro - 3 -pyridyl ) [0112 ] II - M . 29 . 11 .1 N -[ 5 -[ [ 2 -bromo -6 - chloro -4 - [ 2, 2, 2 -tri methyl) - 2 - pyridylidene ) - 2 , 2 , 2 -trifluoro - acetamide; fluoro - 1 -hydroxy - 1 -( trifluoromethyl) ethyl ] - phenyl ]car [0088 ] II - M .29 .6b (E /Z )- N -[ 1- [ (6 -chloro -5 - fluoro - 3 bamoyl] -2 -cyano - phenyl] - 4 -cyano -2 -methyl - benzamide ; pyridyl) methyl ) - 2 -pyridylidene ) - 2 , 2 , 2 - trifluoro - acet [0113 ] II- M .29 .11 . m N -[ 5 -[ [ 2 - bromo -6 -chloro - 4 -[ 1, 2 ,2 , 3 , amide ; 3 , 3 -hexafluoro - 1 - ( trifluoromethyl) propyl] phenyl ]car [ 0089 ] II - M .29 . 6c ( E / Z ) - 2 , 2 , 2 -trifluoro - N - [ 1 - [ ( 6 - fluoro bamoyl) - 2 - cyano - phenyl] - 4 -cyano - 2 -methyl - benzamide ; 3 - pyridyl) methyl ) - 2 -pyridylideneJacetamide ; [0114 ] II- M . 29. 11. n 4 - cyano - N - [ 2 - cyano - 5 - [ [ 2 ,6 - di [ 0090 ] Il - M .29 .6d ( E / Z ) - N - [ 1 - [ (6 -bromo - 3 -pyridyl ) chloro -4 - [1 , 2, 2 ,3 ,3 , 3 -hexafluoro - 1 -( trifluoromethyl) pro methyl] - 2 -pyridylidene )- 2 , 2 , 2 - trifluoro -acetamide ; pyl] phenyl] carbamoyl ]phenyl ] - 2 -methyl - benzamide ; [ 0091] II - M .29 .6e (E / Z )- N - [ 1- [ 1 -( 6 -chloro - 3 -pyridyl ) [0115 ] II -M .29 . 11 . o 4 -cyano - N - [2 -cyano - 5 -[ [ 2 ,6 - di ethyl] - 2 -pyridylidene ] - 2 , 2 , 2 - trifluoro - acetamide; chloro - 4 - [ 1 , 2 , 2 , 2 - tetrafluoro - 1 - ( trifluoromethyl) ethyl ] [0092 ] II - M .29 . 6f ( E / Z ) - N - [ 1 - [ (6 - chloro - 3 -pyridyl ) phenyl] carbamoyl] phenyl ] - 2 -methyl - benzamide ; methyl) - 2 - pyridylidene ) - 2 , 2 - difluoro -acetamide ; [0116 ] II - M .29 . 11. p N - [ 5 - [ [ 2 -bromo - 6 -chloro - 4 - [ 1 , 2 , 2 , 2 [0093 ] II - M .29 .6g ( E / Z ) - 2 - chloro - N - [ 1 - [ ( 6 - chloro - 3 tetrafluoro - 1 - ( trifluoromethyl) ethyl] phenyl] -carbamoyl ] pyridyl )methyl ] - 2 -pyridylidene ) - 2 , 2 - difluoro - acetamide ; 2 - cyano -phenyl ] - 4 - cyano - 2 -methyl - benzamide ; US 2019 / 0281835 A1 Sep . 19 , 2019

[0117 ] II- M .29 . 12. a 2 - ( 1 , 3 - Dioxan - 2 - yl) -6 - [ 2 - ( 3 -pyridi - [0146 ] Il - M .29 . 17e 2 - ( 3 - pyridinyl ) - N - [ (tetrahydro - 2 - fura nyl) - 5 -thiazolyl ] - pyridine ; nyl )methyl ] - 2H - indazole - 5 - carboxamide; [ 0118 ] II - M .29 . 12 .b 2- [6 - [ 2 - (5 - Fluoro - 3 -pyridinyl ) - 5 - thi [0147 ] II - M . 29 .17f methyl 2 - [[ 2 -( 3 -pyridinyl ) - 2H -inda azolyl] - 2 -pyridinyl ] -pyrimidine ; zol- 5 -yl ] carbonyl ] hydrazinecarboxylate ; [ 0119] II - M .29 . 12 . c 2 - [ 6 - [ 2 -( 3 -Pyridinyl ) - 5 - thiazolyl11) . -2 2 [0148 ] II- M .29 . 17g N -[ (2 ,2 - difluorocyclopropyl) methyl ] pyridinyl ] - pyrimidine ; 2 - ( 3 -pyridinyl ) - 2H - indazole - 5 - carboxamide; [ 0120 ] II - M . 29 .12 .d N -M ethylsulfonyl- 6 - [ 2 -( 3 -pyridyl ) [0149 ] II - M .29 .17h N -( 2 ,2 -difluoropropyl ) -2 - ( 3 -pyridi thiazol- 5 - yl] pyridine - 2 - carboxamide ; nyl) - 2H - indazole - 5 - carboxamide ; [ 0121 ] Il - M .29 . 12. e N - M ethylsulfonyl -6 - [ 2 - ( 3 -pyridyl ) [0150 ] II - M . 29 . 17i 2 - ( 3 - pyridinyl) - N - ( 2 -pyrimidinylm thiazol- 5 - yl] pyridine - 2 - carboxamide; ethyl) - 2H - indazole - 5 - carboxamide; and [0122 ] II- M .29 . 12 .f N -Ethyl -N - [4 -methyl - 2- ( 3 -pyridyl ) [0151 ] II - M . 29 . 17j N - [ ( 5 -methyl - 2 -pyrazinyl ) methyl ] - 2 thiazol- 5 -yl ] - 3 -methylthio - propanamide; ( 3 -pyridinyl ) - 2H - indazole - 5 - carboxamide ; [0123 ] Il -M .29 . 12 . g N -M ethyl -N - [4 -methyl - 2 - (3 - 0152 ] II - M .29 .18a N - [3 -chloro - 1 -( 3 -pyridyl ) pyrazol - 4 pyridyl) thiazol- 5 - yl] - 3 -methylthio -propanamide ; yl] - N - ethyl- 3 - ( 3 , 3 , 3 - trifluoropropylsulfanyl) propana [0124 ] II- M .29 .12 .h 1 ,2 -Dimethyl - N - [4 -methyl - 2 -( 3 mide ; pyridyl) thiazol- 5 -yl ] - 3 -methylthio - propanamide ; [0153 ] II - M . 29. 18b N - [ 3 -chloro - 1 - ( 3 - pyridyl) pyrazol - 4 [0125 ] II - M .29 . 12 . i N - Ethyl- 2 -methyl - N - [ 4 -methyl - 2 - ( 3 yl ] -N -ethyl -3 - (3 ,3 ,3 -trifluoropropylsulfinyl ) propana pyridyl ) thiazol- 5 - yl) - 3 -methylthio -propanamide ; mide; [ 0126 ] II- M . 29 . 12. j N - [ 4 -Chloro - 2 - ( 3 - pyridyl) thiazol- 5 [0154 ] II- M . 29 . 18c N - [ 3 - chloro - 1 - ( 3 -pyridyl ) pyrazol - 4 yl ]- N - ethyl- 2 -methyl - 3 -methylthio - propanamide ; yl] -3 - [( 2 ,2 -difluorocyclopropyl ) methylsulfanyl ] - N - ethyl [0127 ] Il - M .29 . 12 .k N - [4 - Chloro -2 - ( 3 -pyridyl ) thiazol- 5 propanamide ; and yl ]- N , 2 -dimethyl - 3 -methylthio -propanamide ; [0155 ] II -M .29 . 18d N - [3 -chloro - 1- (3 -pyridyl )pyrazol - 4 [0128 ] II - M .29 . 12 .1 N - [ 4 -Chloro - 2 - ( 3 -pyridyl ) thiazol- 5 yl] - 3 - [( 2 ,2 - difluorocyclopropyl) methylsulfinyl ] -N - ethyl yl] - N -methyl -3 -methylthio - propanamide ; propanamide; [0129 ] II - M .29 .12 . m N -[ 4 -Chloro -2 -( 3 -pyridyl )thiazol - 5 [0156 ] Il - M .29 .19 sarolaner; yl] - N - ethyl - 3 -methylthio - propanamide ; or the com [0157 ] Il - M .29 . 20 lotilaner; pounds [0158 ] Il - L Biopesticides : [0130 ] II - M . 29 . 14a 1 - [ (6 -Chloro - 3 -pyridinyl ) methyl ) - 1 , 2 , [0159 ] II - L . 1 Microbial pesticides with fungicidal, bacte 3 , 5 ,6 , 7 -hexahydro - 5 -methoxy - 7 -methyl - 8 - nitro - imidazo ricidal, viricidal and /or plant defense activator activity : [ 1 , 2 - a ]pyridine ; Ampelomyces quisqualis , Aspergillus flavus, Aureoba [0131 ] II - M .29 . 14b 1- [( 6 - Chloropyridin - 3 - yl) methyl ] - 7 sidium pullulans, Bacillus altitudinis, B . amyloliquefa methyl- 8 -nitro - 1 ,2 , 3 ,5 ,6 , 7 -hexahydroimidazo [ 1, 2 -a ]pyri ciens, B . megaterium , B . mojavensis , B . mycoides, B . din - 5 - ol; simplex , B . solisalsi , B . subtilis , B . subtilis var. amyloliq [0132 ] II - M . 29. 16a 1 - isopropyl- N , 5 -dimethyl - N uefaciens, Candida oleophila , C . saitoana , Clavibacter pyridazin - 4 -yl - pyrazole - 4 -carboxamide ; or michiganensis (bacteriophages ) , Coniothyrium minitans , [0133 ] II - M .29 . 16b 1 - ( 1, 2 - dimethyl propyl) - N - ethyl- 5 Cryphonectria parasitica , Cryptococcus albidus, Dilo methyl- N - pyridazin - 4 -yl - pyrazole - 4 - carboxamide ; phosphora alopecur Fusarium oxysporum , Clonostachys [ 0134 ] II- M . 29 . 16c 1 , 5 - dimethyl- N -pyridazin - 4 - yl- 1 - ( 2 , rosea f. catenulate ( also named Gliocladium catenula 2 , 2 - trifluoro - 1 -methyl - ethyl) pyrazole - 4 -carboxamide ; tum ) , Gliocladium roseum , Lysobacter antibioticus, L . [0135 ] II - M .29 . 16d 1 - [ 1 - ( 1 - cyanocyclopropyl) ethyl] - N enzymogenes , Metschnikowia fructicola , Microdochium ethyl- 5 -methyl - N - pyridazin - 4 -yl - pyrazole - 4 -carboxam dimerum , Microsphaeropsis ochracea , Muscodor albus, ide; Paenibacillus polymyxa , Pantoea vagans, Penicillium [ 0136 ] II - M . 29 .16€ N - ethyl- 1 - (2 - fluoro - 1 -methyl - pro bilaiae , Phlebiopsis gigantea , Pseudomonas sp. , pyl) - 5 -methyl - N - pyridazin - 4 - yl- pyrazole -4 - carboxam Pseudomonas chloraphis , Pseudozyma flocculosa , Pichia ide; anomala , Pythium oligandrum , Sphaerodes mycopara [ 0137 ] II- M . 29 . 16f 1 - ( 1 , 2 - dimethylpropyl) - N , 5 - dimethyl sitica , Streptomyces griseoviridis , S . lydicus, S . violaceus N -pyridazin - 4 - yl- pyrazole- 4 - carboxamide ; niger , Talaromyces flavus, T. asperellum , T. atroviride, T. [ 0138 ] II- M . 29 . 16g 1 - [ 1 - ( 1 - cyanocyclopropyl ) ethyl ] - N , 5 fertile , T . gamsii , T . harmatum , T. harzianum , T . polyspo dimethyl- N -pyridazin -4 -yl - pyrazole - 4 -carboxamide ; rum , T . stromaticum , T . virens, T . viride, Typhula phac [0139 ] II - M .29 . 16h N -methyl - 1 - (2 - fluoro - 1 -methyl - pro orrhiza , Ulocladium oudemansii, Verticillium dahlia , and pyl] -5 -methyl - N - pyridazin - 4 - yl- pyrazole -4 - carboxam zucchini yellow mosaic virus ( avirulent strain ) ; ide; [0160 ] II - L . 2 Biochemical pesticides with fungicidal , bac [ 0140 ] II - M . 29 .16i 1- ( 4, 4 -difluorocyclohexyl ) -N - ethyl- 5 tericidal, viricidal and /or plant defense activator activity : methyl- N -pyridazin - 4 - yl- pyrazole - 4 - carboxamide ; and harpin protein , and Reynoutria sachalinensis extract; [ 0141 ] II- M . 29 . 16j 1 - ( 4 , 4 - difluorocyclohexyl ) - N , 5 - dim [0161 ] II- L . 3 Microbial pesticides with insecticidal , aca ethyl- N -pyridazin - 4 - yl- pyrazole - 4 - carboxamide ; ricidal, molluscidal and / or nematicidal activity : Agrobac [ 0142 ] II- M . 29 . 17a N - ( 1 -methylethyl ) - 2 - ( 3 - pyridinyl) terium radiobacter , Bacillus cereus, B . firmus, B . thuringi 2H - indazole - 4 -carboxamide ; ensis, B . thuringiensis ssp . aizawai, B . t . ssp . israelensis , [ 0143] II - M .29 . 17b N -cyclopropyl - 2 - ( 3 -pyridinyl ) - 2H - in B . t. ssp . galleriae , B . t. ssp . tenebrionis , Beauveria dazole - 4 - carboxamide ; bassiana, B . brongniartii, Burkholderia spp ., Chromo [0144 ] II - M .29 .17c N -cyclohexyl - 2- (3 -pyridinyl ) - 2H - in bacterium subtsugae , Cydia pomonella granulovirus dazole - 4 - carboxamide ; (CpGV ), Cryptophlebia leucotreta granulovirus (Cr [ 0145 ] II - M . 29 .17d 2 - ( 3 -pyridinyl ) - N - (2 , 2 ,2 - trifluoro leGV ) , Flavobacterium spp . , Helicoverpa armigera ethyl) - 2H - indazole - 4 - carboxamide ; nucleopolyhedrovirus (HearNPV ), Helicoverpa zea US 2019 /0281835 A1 Sep . 19 , 2019

nucleopolyhedrovirus (HzNPV ) , Helicoverpa zea single yl) phenoxy ]methyl ] phenyl ] -4 -methyl - tetrazol - 5 - one, capsid nucleopolyhedrovirus (HzSNPV ) , Heterorhabditis 1 - methyl- 4 - [ 3 - methyl- 2 - [ [ 2 -methyl - 4 - ( 1 -methyl pyrazol bacteriophora , Isaria fumosorosea , Lecanicillium long 3 - yl) phenoxy ]methyl ]phenyl ] tetrazol- 5 -one , 1 - methyl - 4 isporum , L . muscarium , Metarhizium anisopliae , Metar [ 3 -methyl - 2 -[ [ 1 -[ 3 -( trifluoromethyl) phenyl] - ethylide hizium anisopliae var. anisopliae, M . anisopliae var . neamino ] oxy -methyl ] phenyl ] tetrazol- 5 -one , (Z ,2E )- 5 -[ 1 acridum , Nomuraea rileyi , Paecilomyces fumosoroseus, ( 2 ,4 -dichlorophenyl )pyrazol - 3 -yl ) - oxy - 2 -methoxyimino P. lilacinus, Paenibacillus popilliae , Pasteuria spp ., P . N , 3 - dimethyl- pent - 3 - enamide , ( 2 , 2E ) - 5 - [ 1 - ( 4 nishizawae , P . penetrans, P . ramosa , P . thornea , P . usgae , chlorophenyl) pyrazol - 3 - yl] oxy - 2 -methoxyimino - N , 3 Pseudomonas fluorescens, Spodoptera littoralis nucleo dimethyl- pent - 3 - enamide , and ( 2 , 2E ) - 5 - [ 1 - ( 4 - chloro - 2 polyhedrovirus ( SpliNPV ), Steinernema carpocapsae, S. fluoro -phenyl ) pyrazol- 3 - yl] oxy - 2 -methoxyimino - N , 3 feltiae , S . kraussei Streptomyces galbus, and S . microfla dimethyl- pent - 3 - enamide ; vus; [0167 ] III - F .12 inhibitors of complex III at Qi site : cyazo [0162 ] II - L .4 Biochemical pesticides with insecticidal, famid , amisulbrom , [ ( 35 , 68 ,7R , 8R ) - 8 -benzyl - 3 - [ ( 3 - ac acaricidal, molluscidal, pheromone and / or nematicidal etoxy -4 -methoxy -pyridine - 2 -carbonyl ) amino ]- 6 -methyl activity : L - carvone , citral, ( E , Z ) - 7 , 9 - dodecadien - 1 - yl 4 , 9 - dioxo - 1 , 5 - dioxonan - 7 - yl] 2 -methylpropanoate , [ ( 3S , acetate , ethyl formate, ( E , Z ) - 2 ,4 - ethyl decadienoate (pear 65 ,7R ,8R )- 8 -benzyl - 3 - [[ 3 -( acetoxymethoxy ) -4 -methoxy ester) , (2 ,2 ,E )- 7 , 11, 13 -hexadecatrienal , heptyl butyrate , pyridine - 2 - carbonyl ] amino ] - 6 -methyl - 4 , 9 -dioxo - 1 , 5 isopropyl myristate , lavanulyl senecioate, cis - jasmone , dioxonan - 7 - yl] 2 -methylpropanoate , [ ( 35 ,68 ,7R ,8R ) - 8 2 -methyl 1 -butanol , methyl eugenol, methyl jasmonate , benzyl- 3 -[ ( 3 -isobutoxycarbonyloxy - 4 -methoxy - pyridine ( E ,Z )- 2 , 13 - octadecadien - 1- ol, (E ,Z )- 2 , 13 -octadecadien 2 - carbonyl) amino ] -6 -methyl - 4 ,9 -dioxo - 1 ,5 -dioxonan - 7 1 - ol acetate , ( E , Z ) - 3 , 13 - octadecadien - 1 -ol , R - 1 - octen - 3 yl] 2 -methylpropanoate , [( 35 ,68 ,7R ,8R )- 8 -benzyl - 3 -[ [ 3 ol, pentatermanone , ( E , Z , Z ) - 3 , 8 , 11 - tetradecatrienyl ( 1 , 3 -benzodioxol - 5 - ylmethoxy ) - 4 -methoxypyridine - 2 acetate , ( Z , E ) - 9 , 12 - tetradecadien - 1 - yl acetate , Z - 7 - tetra carbonyl] amino ] - 6 -methyl - 4 , 9 -dioxo - 1 , 5 - dioxonan - 7 - yl ] decen - 2 -one , Z - 9 - tetradecen -1 -yl acetate , Z - 11 - tetradece 2 -methylpropanoate ; ( 35 , 68 ,7R , 8R ) - 3 - [[ ( 3 - hydroxy - 4 nal, Z - 11 - tetradecen - 1 - ol, extract of Chenopodium methoxy -2 -pyridinyl ) carbonyl ]amino ]- 6 -methyl - 4 ,9 -di ambrosiodes , Neem oil , and Quillay extract ; oxo - 8 - ( phenylmethyl) - 1 , 5 -dioxonan - 7 - yl 2 -methylpro [0163 ] II- L . 5 Microbial pesticides with plant stress reduc panoate , and ( 35 ,68 ,7R ,8R ) - 8 -benzyl - 3 - [ 3 ing, plant growth regulator, plant growth promoting and / [ (isobutyryloxy )methoxy ]- 4 -methoxypicolinamido ]- 6 or yield enhancing activity : A . lipoferum , A . irakense , A . methyl- 4 , 9 -dioxo - 1, 5 -dioxonan -7 - yl isobutyrate ; halopraeferens, B . elkani B . liaoningense , B . lupini Delf [0168 ] III - F . 13 inhibitors of complex II : benodanil, ben tia acidovorans, Glomus intraradices , Mesorhizobium zovindiflupyr, bixafen , boscalid , carboxin , fenfuram , flu spp ., Rhizobium leguminosarum bv . phaseoli, R . 1 . bv. opyram , flutolani) , fluxapyroxad , furametpyr, isofetamid , trifolii , R . 1. bv. viciae, R . tropici , and Sinorhizobium isopyrazam , mepronil , oxycarboxin , penflufen , penthio meliloti ; pyrad , sedaxane , tecloftalam , thifluzamide , N - ( 4 '- trifluo [ 0164 ] and / or at least one fungicidally active compound romethylthiobiphenyl - 2 - yl) - 3 - difluoromethyl - 1 -methyl III selected from 1H -pyrazole - 4 -carboxamide , N - ( 2 - ( 1 , 3 , 3 - trimethyl [0165 ] III -F . I Respiration inhibitors butyl) -phenyl ) - 1, 3 -dimethyl -5 - fluoro - 1H -pyrazole -4 [0166 ] III - F . 11 Inhibitors of complex III at Qe site : azox carboxamide , 3 - ( difluoromethyl) - 1 -methyl - N - ( 1 , 1 , 3 ystrobin , coumethoxystrobin , coumoxystrobin , dimox trimethylindan - 4 -yl ) pyrazole - 4 - carboxamide , ystrobin , enestroburin , fenaminstrobin , fenoxystrobin / 3 -( trifluoromethyl) - 1- methyl - N - ( 1, 1 ,3 -trimethylindan - 4 flufenoxystrobin , fluoxastrobin , kresoxim -methyl , yl) pyrazole - 4 -carboxamide , 1 ,3 -dimethyl - N - ( 1 , 1, 3 -trim mandestrobin , metominostrobin , orysastrobin , picox ethylindan - 4 - yl) pyrazole - 4 -carboxamide , 3 - ( trifluorom ystrobin , pyraclostrobin , pyrametostrobin , pyraox ethyl) - 1, 5 - dimethyl -N -( 1 ,1 , 3 - trimethylindan -4 -yl ) ystrobin , trifloxystrobin , 2 - ( 2 - ( 3 - ( 2 ,6 - dichlorophenyl) - 1 pyrazole- 4 -carboxamide , 1 ,3 , 5 -trimethyl - N -( 1 , 1, 3 methyl- allylideneaminooxymethyl) -phenyl ) - 2 trimethyl indan - 4 - yl) pyrazole - 4 - carboxamide , N - ( 7 methoxyimino - N -methyl - acetamide , pyribencarb , fluoro - 1 , 1 , 3 - trimethyl- indan - 4 -yl ) - 1 , 3 -dimethyl triclopyricarb / chlorodincarb , famoxadone, and fenami pyrazole -4 - carboxamide, and N -[ 2 - (2 , 4 -dichlorophenyl ) done, methyl - N - [ 2 - [ ( 1 , 4 - dimethyl- 5 - phenyl- pyrazol - 3 2 -methoxy - 1 -methyl - ethyl] - 3 - (difluoromethyl ) - 1 yl) oxylmethyl] phenyl ] - N -methoxy - carbamate , 1 - [ 3 methyl- pyrazole - 4 -carboxamide ; chloro - 2 - [ [ 1 - ( 4 - chlorophenyl) - 1H -pyrazol - 3 - yl] 101691 III - F . 14 other respiration inhibitors : diflumetorim , oxymethyl ]phenyl ] - 4 -methyl - tetrazol - 5 -one , 1 -[ 3 -bromo ( 5 , 8 - difluoroquinazolin - 4 -yl ) - { 2 - [ 2 - fluoro - 4 - ( 4 - trifluo 2 - [[ 1- (4 -chlorophenyl ) pyrazol - 3 -yl ] oxymethyl] phenyl ] romethylpyridin - 2 -yloxy )- phenyl ]- ethyl } -amine ; 4 -methyl - tetrazol- 5 -one , 1 - [2 - [[ 1 -( 4 -chlorophenyl ) [0170 ] nitrophenyl derivates : binapacryl, dinobuton , pyrazol - 3 - yl] oxymethyl] - 3 -methyl - phenyl] - 4 -methyl dinocap , fluazinam , ferimzone ; organometal com tetrazol - 5 - one , 1 - [ 2 - [ [ 1 - ( 4 - chlorophenyl) pyrazol- 3 - yl] pounds : fentin -acetate , fentin chloride , and fentin oxymethyl] - 3 - fluoro - phenyl] - 4 -methyltetrazol - 5 - one, hydroxide ; ametoctradin ; and silthiofam ; 1 - [ 2 - [[ 1 -( 2 , 4 - dichlorophenyl) pyrazol - 3 - yl] oxymethyl] - 3 10171 ] III - F . II Sterol biosynthesis inhibitors : fluoro - phenyl] -4 -methyl - tetrazol - 5 - one, 1 - [ 2 - [ [ 4 - ( 4 - chlo [0172 ] III - F . 111 C14 demethylase inhibitors : rophenyl) thiazol- 2 -yl ] oxymethyl ] - 3 -methyl - phenyl ] - 4 101731 triazoles : azaconazole, bitertanol, bromucon methyl- tetrazol- 5 - one, 1 - [ 3 - chloro - 2 - [ [ 4 - ( p -tolyl ) thiazol azole , cyproconazole , difenoconazole , diniconazole , 2 - yl] oxymethyl] phenyl] - 4 -methyl -tetrazol - 5 - one , 1 - [ 3 diniconazole - M , epoxiconazole, fenbuconazole , cyclopropyl - 2 - [ [ 2 -methyl - 4 - ( 1 -methylpyrazol - 3 - yl) fluquinconazole , flusilazole , flutriafol, hexaconazole , phenoxy ]methyl ] phenyl] - 4 -methyl - tetrazol- 5 - one , 1 - [ 3 imibenconazole , ipconazole, metconazole , myclobuta (difluoromethoxy )- 2 -[ [ 2 -methyl - 4 -( 1 -methylpyrazol - 3 nil , oxpoconazole , paclobutrazole , penconazole , propi US 2019 /0281835 A1 Sep . 19 , 2019

conazole , prothioconazole , simeconazole , tebucon [0188 ] III -F . VI Signal transduction inhibitors : azole , tetraconazole , triadimefon , triadimenol, [0189 ] III -F . VII MAP /histidine kinase inhibitors: fluor triticonazole , uniconazole , 1 - [ rel- ( 2S ; 3R ) - 3 - ( 2 -chloro oimid , iprodione , procymidone , vinclozolin , fenpiclonil , phenyl) - 2 - ( 2 ,4 - difluorophenyl) oxiranylmethyl ) - 5 -thio and fludioxonil ; and cyanato - 1H -[ 1 ,2 , 4 ]triazolo , 2 -[ rel - ( 2S ;3R )- 3 - (2 - chlo [0190 ] III -F . VI2 G protein inhibitors: quinoxyfen ; rophenyl) - 2 -( 2 ,4 -difluorophenyl ) - oxiranylmethyl ) -2H f0191 ] III- F .VII Lipid and membrane synthesis inhibitors : 10192 ] III - F . VII1 Phospholipid biosynthesis inhibitors : [ 1 , 2 , 4 ]triazole - 3 - thiol, 2 -[ 2 -chloro -4 - ( 4 edifenphos, iprobenfos , pyrazophos , isoprothiolane ; chlorophenoxy )phenyl ] - 1 - ( 1 , 2 , 4 - triazol- 1 -yl ) pentan - 2 [0193 ] III - F . VII2 lipid peroxidation : dicloran , quintozene , ol, 1- [ 4 - (4 -chlorophenoxy ) - 2 -( trifluoromethyl) tecnazene, tolclofos -methyl , biphenyl, chloroneb , and phenyl] - 1 - cyclopropyl- 2 - ( 1 , 2 , 4 -triazol - 1 -yl ) ethanol, etridiazole ; 2 -[ 4 -( 4 -chlorophenoxy )- 2 -( trifluoromethyl ) phenyl ] - 1 [0194 ] III - F . VII3 phospholipid biosynthesis and cell wall ( 1 , 2 , 4 - triazol- 1 -yl ) butan - 2 -ol , 2 - [ 2 - chloro - 4 - ( 4 -chloro deposition : dimethomorph , flumorph , mandipropamid , phenoxy )phenyl ] - 1- ( 1, 2, 4 - triazol- 1 -yl ) butan -2 -ol , pyrimorph , benthiavalicarb , iprovalicarb , valifenalate , 2 -[ 4 - ( 4 -chlorophenoxy )- 2 - (trifluoromethyl ) phenyl ] - 3 and N - ( 1 - ( 1 - ( 4 - cyano - phenyl) ethanesulfonyl) -but - 2 - yl) methyl- 1 - (1 ,2 ,4 -triazol - 1 -yl ) butan - 2 -ol , 2 -[ 4 - (4 - chlo carbamic acid - ( 4 - fluorophenyl) ester; rophenoxy ) - 2 - ( trifluoromethyl ) phenyl] - 1 - ( 1 , 2 ,4 -tri [0195 ] III - F . VII4 compounds affecting cell membrane per azol- 1 -yl ) propan - 2 - ol, 2 - [ 2 - chloro - 4 - ( 4 meability and fatty acides : propamocarb ; and chlorophenoxy) phenyl ]- 3 -methyl - 1 -( 1 , 2 , 4 -triazol - 1 - yl) [0196 ] III - F . VII5 fatty acid amide hydrolase inhibitors: butan - 2 -ol , 2 - [ 4 - ( 4 -chlorophenoxy ) - 2 oxathiapiprolin , 2 - 3 - [ 2 - ( 1 - { [ 3 , 5 -bis ( difluoromethyl- 1H ( trifluoromethyl ) phenyl] - 1 - ( 1 , 2 , 4 - triazol- 1 - yl) pentan pyrazol- 1 - yl] acetyl } piperidin - 4 - yl) - 1 , 3 - thiazol - 4 - yl) - 4 , 5 2 - ol, 2 - [ 4 - ( 4 - fluorophenoxy ) - 2 - ( trifluoromethyl) dihydro - 1 , 2 -oxazol - 5 - yl} phenyl methanesulfonate , 2 - { 3 phenyl] - 1 - ( 1 , 2 , 4 - triazol- 1 - yl) propan - 2 - ol, 2 - [ 2 -chloro [ 2 -( 1 - {[ 3 ,5 -bis (difluoromethyl ) - 1H -pyrazol - 1 -yl ] 4 - ( 4 - chlorophenoxy ) phenyl] - 1 - ( 1 , 2 , 4 -triazol - 1 - yl ) acetyl} piperidin - 4 -yl ) , and 1 , 3 - thiazol- 4 - yl) - 4 , 5 - dihydro pent- 3 - yn - 2 -ol ; imidazoles : imazalil, pefurazoate , 1 , 2 - oxazol- 5 - yl ) - 3 - chlorophenyl methanesulfonate ; prochloraz, triflumizol; [0197 ] III -F .VIII Inhibitors with Multi Site Action : [0174 ] pyrimidines, pyridines and piperazines: fenari [0198 ] III -F . VIII1 inorganic active substances: Bordeaux mol, nuarimol, pyrifenox , triforine , and [ 3 -( 4 -chloro mixture , copper acetate , copper hydroxide , copper oxy 2 - fluoro -phenyl ) - 5 -( 2 ,4 -difluorophenyl ) isoxazol- 4 -yl ] chloride , basic copper sulfate , and sulfur ; ( 3 - pyridyl )methanol ; 0199 ) III - F .VIII2 thio - and dithiocarbamates : ferbam , [0175 ] III - F .112 Delta14 -reductase inhibitors : aldimorph , mancozeb , maneb , metam , metiram , propineb , thiram , dodemorph , dodemorph - acetate , fenpropimorph , tride zineb , and ziram ; morph , fenpropidin , piperalin , and spiroxamine ; [0200 III - F . VIII3 organochlorine compounds from the [0176 ] III - F . 113 Inhibitors of 3 - keto reductase : fenhex class of phthalimides, sulfamides, and chloronitriles: amid ; anilazine, chlorothalonil , captafol, captan , folpet, dichlo [ 0177 ] III - F . II Nucleic acid synthesis inhibitors fluanid , dichlorophen , hexachlorobenzene , pentachlo [0178 ] III -F . III1 phenylamides or acyl amino acid fungi rphenole and its salts , phthalide, tolylfluanid , and N - ( 4 cides: benalaxyl, benalaxyl- M , kiralaxyl, metalaxyl, chloro -2 - nitro -phenyl ) -N - ethyl- 4 -methyl metalaxyl- M (mefenoxam ), ofurace , and oxadixyl; benzenesulfonamide ; and [0179 ] III - F. III2 others : hymexazole , octhilinone, oxolinic [0201 ] III - F .VIII4 guanidines and others: guanidine , acid , bupirimate , 5 - fluorocytosine , 5 - fluoro - 2 - ( p - tolyl dodine , dodine free base , guazatine , guazatineacetate , iminoctadine , iminoctadine - triacetate , iminoctadine - tris methoxy )pyrimidin - 4 - amine , and 5 - fluoro - 2 - ( 4 - fluoro (albesilate ) , dithianon , and 2 , 6 - dimethyl - 11 ,5H - [ 1 , 41 phenylmethoxy ) pyrimidin -4 - amine ; dithiino [ 2 , 3 - c : 5 , 6 - c ' ] dipyrrole - 1 , 3 , 5 , 7 ( 2H ,6H )tetraone ; [0180 ] III - F .IV Inhibitors of cell division and cytoskeleton 10202 ] III - F . IX Cell wall synthesis inhibitors : [0181 ] III - F . IV1 tubulin inhibitors from the class of [0203 ] III- F. IX1 inhibitors of glucan synthesis : validamy [0182 ] benzimidazoles, and thiophanates: benomyl, car cin , and polyoxin B ; bendazim , fuberidazole, thiabendazole , and thiophan [0204 ] III - F . 1X2 melanin synthesis inhibitors : pyroquilon , atemethyl; tricyclazole , carpropamid , dicyclomet, and fenoxanil ; [0183 ] triazolopyrimidines: 5 - chloro - 7 - ( 4 -methylpip [0205 ] III- F . X Plant defence inducers eridin - 1 - yl) - 6 - ( 2 , 4 ,6 -trifluorophenyl ) [ 1, 2 , 4 ] triazolo [ 1 , [0206 ] III -F .X1 acibenzolar - S -methyl , probenazole , iso 5 - a ]pyrimidine ; and tianil, tiadinil , prohexadione - calcium ; [0207 ] III -F .X2 phosphonates: fosetyl, fosetyl- aluminum , [0184 ] III - F .IV2 other cell division inhibitors : diethofen phosphorous acid and its salts ; potassium or sodium carb , ethaboxam , pencycuron , fluopicolide , zoxamide , bicarbonate ; and metrafenone , pyriofenone ; [0208 ] III -F .XI Unknown mode of action : [0185 ] III - F. V Inhibitors of amino acid and protein syn [0209 ] bronopol, chinomethionat , cyflufenamid , thesis : cymoxanil , dazomet, debacarb , diclomezine, difenzo [0186 ] III - F . V1 methionine synthesis inhibitors from the quat , difenzoquat- methylsulfate , diphenylamin , fen class of anilino - pyrimidines: cyprodinil, mepanipyrim , pyrazamine, flumetover, flusulfamide , flutianil , metha and pyrimethanil; and sulfocarb , nitrapyrin , nitrothal- isopropyl, [0187 ] III - F. V2 protein synthesis inhibitors: blasticidin - S , oxathiapiprolin , tolprocarb , oxin -copper , proquinazid , kasugamycin , kasugamycin hydrochloridehydrate , mil tebufloquin , tecloftalam , triazoxide , 2 -butoxy -6 - iodo diomycin , streptomycin , oxytetracyclin , polyoxine, and 3 - propylchromen - 4 -one , 2 - [ 3 , 5 -bis ( difluoromethyl) validamycin A ; 1H -pyrazol -1 -yl ] - 1- [ 4 -( 4 - {5 - [2 - (prop - 2 -yn - 1 -yloxy ) US 2019 / 0281835 A1 Sep . 19 , 2019

phenyl] - 4 , 5 - dihydro - 1 , 2 - oxazol- 3 - yl ) - 1 , 3 -thiazol - 2 - yl) bilobalide , ginkgolide A , ginkgolide B , ginkgolide C , piperidin - 1 - yl] ethanone, 2 - [ 3 , 5 -bis ( difluoromethyl) ginkgolide J and ginkgolide M , and 1H -pyrazol - 1 - yl] - 1 - [ 4 - ( 4 - 5 - [ 2 - fluoro - 6 - ( prop - 2 - yn - 1 [ 0215 ] 2 ) at least one pesticidally active compound II yloxy ) phenyl] - 4 , 5 - dihydro - 1 , 2 - oxazol- 3 -yl ) - 1 , 3 selected from groups M and / or L consisting of thiazol- 2 -yl ) piperidin - 1 -yl ] ethanone , 2 - [3 , 5- bis [ 0216 ] II- M . 1 Acetylcholine esterase inhibitors : ( difluoromethyl) - 1H - pyrazol- 1 - yl) - 1 - [ 4 - ( 4 - { 5 - [ 2 [0217 ] II - M . 1A carbamates : aldicarb , alanycarb , bendio chloro - 6 - (prop - 2 -yn - 1 -yloxy )phenyl ] - 4 , 5 - dihydro - 1 , 2 carb , benfuracarb , butocarboxim , butoxycarboxim , car oxazol- 3 - yl) - 1 , 3 - thiazol- 2 - yl ) piperidin - 1 - yl] ethanone, baryl, carbofuran , carbosulfan , ethiofencarb , fenobucarb , N -( cyclopropylmethoxyimino - (6 - difluoro -methoxy - 2 , formetanate , furathiocarb , isoprocarb , methiocarb , 3 - difluoro - phenyl) -methyl ) - 2 - phenyl acetamide, N - ( 4 methomyl, metolcarb , oxamyl, pirimicarb , propoxur, thio ( 4 -chloro - 3 - trifluoromethyl- phenoxy ) - 2 , 5 -dimethyl dicarb , thiofanox , trimethacarb , XMC , xylylcarb and tri phenyl) - N -ethyl - N - methyl formamidine , N '- ( 4 - ( 4 fluoro - 3 - trifluoromethyl- phenoxy ) - 2 , 5 - dimethyl azamate ; and phenyl) - N - ethyl- N -methyl formamidine , N '- ( 2 -methyl [0218 ] II - M .2 .GABA - gated chloride channel antagonists : 5 -trifluoromethyl - 4 - (3 - trimethylsilanyl- propoxy ) [0219 ] Il - M .2A cyclodiene organochlorine compounds: phenyl) - N -ethyl - N -methyl formamidine, N '- ( 5 endosulfan or chlordane ; and difluoromethyl- 2 -methyl - 4 - ( 3 -trimethylsilanyl [ 0220 ] II- M . 2B fiproles : ethiprole , fipronil , flufiprole , propoxy )- phenyl) - N - ethyl- N -methyl formamidine, pyrafluprole and pyriprole; methoxy - acetic acid 6 - tert -butyl - 8 - fluoro - 2 , 3 -dimeth [0221 ] II- M . 3 Sodium channel modulators: ylquinolin - 4 - yl ester, 3 - [ 5 - ( 4 -methylphenyl ) - 2 , 3 - dim [0222 ] Il - M .3B sodium channel modulators : DDT, and ethyl- isoxazolidin - 3 - yl ] -pyridine , 3 - [ 5 - ( 4 - chloro - phe methoxychlor ; nyl) - 2 , 3 - dimethyl- isoxazolidin - 3 - yl) -pyridine [0223 ] II - M . 4 Nicotinic acetylcholine receptor agonists : (pyrisoxazole ) , N -( 6 -methoxy -pyridin - 3 -yl ) cyclopro [0224 ] Il - M .4A neonicotinoids : acetamiprid , clothianidin , panecarboxylic acid amide , 5 - chloro - 1 - ( 4 ,6 - dime cycloxaprid , dinotefuran , imidacloprid, nitenpyram , thia thoxy - pyrimidin - 2 - yl) - 2 -methyl - 1H - benzoimidazole , cloprid , and thiamethoxam ; 2 -( 4 -chloro - phenyl ) - N -[ 4 -( 3 ,4 -dimethoxy -phenyl ) [0225 ] II - M .4A .2 (2E -) - 1- [( 6 - Chloropyridin - 3 -yl ) isoxazol- 5 - yl] - 2 -prop - 2 - ynyloxy - acetamide, ethyl ( Z ) methyl] - N ' -nitro - 2 -pentylidenehydrazinecarboximid 3 - amino - 2 - cyano - 3 -phenyl - prop - 2 - enoate , picarbutra amide ; zox , pentyl N - [6 - [[ ( Z ) - [( 1 -methyltetrazol - 5 -yl ) [0226 ] Il -M4 . A .3 1- [( 6 - Chloropyridin - 3 - yl )methyl ] - 7 phenyl- methyleneJamino ] oxymethyl )- 2 -pyridyl ] methyl- 8 -nitro -5 -propoxy -1 , 2, 3, 5 ,6 , 7 -hexahydroimidazo carbamate , 2 -[ 2 - [( 7 ,8 -difluoro - 2 -methyl - 3 -quinolyl ) [ 1 , 2 - a ]pyridine ; and oxy ] -6 -fluoro -phenyl ] propan - 2 - ol, 2 - [2 - fluoro -6 - [( 8 fluoro - 2 -methyl - 3 - quinolyl ) oxy ]phen - yl ] propan - 2 - ol, [0227 ] II - M .4B nicotine ; 3 -( 5 - fluoro - 3, 3, 4 , 4 - tetramethyl- 3, 4 -dihydroisoquino [0228 ] II- M .5 Nicotinic acetylcholine receptor allosteric lin - 1 -yl ) quinoline , 3 - (4 ,4 -difluoro -3 , 3 - dimethyl- 3 , 4 activators from the class of spinosyns: spinosad , and dihydroisoquinolin - 1 - yl) quinoline, 3 - ( 4 , 4 ,5 - trifluoro spinetoram ; 3 , 3 -dimethyl - 3 , 4 - dihydroisoquinolin - 1 -yl ) quinoline, [0229 ] II - M .6 Chloride channel activators from the class and 9 - fluoro - 2 , 2 - dimethyl- 5 - ( 3 - quinolyl) -3H - 1, 4 -ben of avermectins and milbemycins: abamectin , emamectin zoxazepine; benzoate, ivermectin , lepimectin , and mildemectin ; [0210 ] in a synergistically effective amount. [0230 ] II - M .7 Juvenile hormone mimics: [0211 ] Moreover, it has been found that simultaneous , that [0231 ] II -M .7A juvenile hormone analogues : hydroprene , is joint or separate , application of the active compound I and kinoprene , and methoprene ; and one or more compound ( s ) II and / or III , or successive appli [0232 ] II - M .7B fenoxycarb , and pyriproxyfen ; cation that is immediately one after another and thereby [0233 ] II - M . 8 miscellaneous non -specific inhibitors: creating the mixture “ in - situ ” on the desired location , as e . g . [0234 ] II - M .8A alkyl halides: methyl bromide, and other the plant ) of the active compound I and one or more active alkyl halides ; and compound ( s ) II and /or III allows enhanced control of pests [0235 ] II - M . 8B chloropicrin , sulfuryl fluoride, borax , and compared to the control rates that are possible with the tartar emetic ; individual compounds . [0236 ] II- M . 9 Selective homopteran feeding blockers : [0212 ] The invention also provides for the use of a mixture pymetrozine, and flonicamid ; according to the invention as disclosed above for controlling (0237 ] II - M . 10 Mite growth inhibitors : clofentezine , the pests from the family of Pentatomidae , preferably Acros hexythiazox, diflovidazin , and etoxazole ; ternum spp . , Euschistus spp ., Nezara spp and /or Piezodrus [0238 ] II - M . 11 Microbial disruptors of insect midgut spp ., in particular Acrosternum hilare, Euschistus heros , membranes : Bacillus thuringiensis , Bacillus sphaericus, Nezara viridula and / or Piezodrus guildini Further is pro and the insecticdal proteins they produce: Bacillus vided the use of a mixture of the invention as disclosed thuringiensis subsp . israelensis , Bacillus sphaericus, above for controlling Halyomorpha halys and / or Dichelops Bacillus thuringiensis subsp . aizawai and Bacillus spp ., such as Dichelops furcatus and Dichelops melacan thuringiensis subsp . tenebrionis , or the Bt crop proteins: thos. Cry1Ab , Cry1Ac, Cry1Fa , Cry2Ab , mCry3A , Cry3Ab , [0213 ] The mixtures of the invention are partly novel and Cry3Bb and Cry34 /35Ab1 ; partly known . Accordingly , the invention also provides for [0239 ] II - M . 12 Inhibitors of mitochondrial ATP synthase : pesticidal mixtures comprising as active compounds [0240 ] II - M . 12A diafenthiuron , and organotin miticides : [ 0214 ] 1 ) at least one compound I , which is a component azocyclotin , cyhexatin , and fenbutatin oxide ; and of the ginkgo tree selected from the group consisting of [ 0241 ] II- M . 12B propargite , and tetradifon ; US 2019 / 0281835 A1 Sep . 19 , 2019

[0242 ] Il - M .13 Uncouplers of oxidative phosphorylation [0267 ] II - M . 28 . 4 methyl- 2 - [3 ,5 -dibromo - 2 -( { [ 3 -bromo -1 via disruption of the proton gradient: chlorfenapyr, ( 3 - chlorpyridin - 2 - yl) - 1H -pyrazol - 5 - yl] carbonyl) - amino ) DNOC , and sulfluramid ; benzoyl] - 1 , 2 - dimethyl hydrazinecarboxylate ; [0243 ] II- M .14 Nicotinic acetylcholine receptor channel [0268 ] II- M .28 .5a N -[ 4 ,6 -dichloro - 2 -[ ( diethyl - lambda -4 blockers: bensultap , cartap hydrochloride, thiocyclam , sulfanylidene )carbamoyl ] -phenyl ] -2 -( 3 - chloro - 2 and thiosultap sodium ; pyridyl) - 5 - ( trifluoromethyl )pyrazole - 3 - carboxamide ; [ 0244 ] II - M . 15 Inhibitors of the chitin biosynthesis type 0 : [0269 ] IIM .28 . 5b N - [ 4 - chloro - 2 - [ (diethyl - lambda - 4 - sul bistrifluron , chlorfluazuron , diflubenzuron , flucycloxuron , fanylidene) carbamoyl ] -6 -methyl - phenyl] - 2 - ( 3 - chloro - 2 flufenoxuron , hexaflumuron , lufenuron , novaluron , novi pyridyl) - 5 - ( trifluoromethyl) pyrazole - 3 -carboxamide ; flumuron , teflubenzuron , and triflumuron ; [ 0270 ] II- M . 28. 5c N - [ 4 - chloro - 2 - [ ( di - 2 - propyl -lambda - 4 [0245 ] Il -M . 16 Inhibitors of the chitin biosynthesis type 1: sulfanylidene ) carbamoyl] -6 -methyl - phenyl] - 2 - ( 3 -chloro buprofezin ; 2 - pyridyl) - 5 - ( trifluoromethyl) pyrazole - 3 - carboxamide ; [ 0271 ] II- M . 28. 5d N - [ 4 , 6 - dichloro - 2 - [ ( di- 2 -propyl [ 0246 ] II - M . 17 Moulting disruptors : cyromazine ; lambda - 4 -sulfanylidene )carbamoyl ] -phenyl ] -2 - ( 3 -chloro [0247 ] II - M .18 Ecdyson receptor agonists : methoxyfenoz 2 -pyridyl ) - 5 -( trifluoromethyl) pyrazole -3 -carboxamide ; ide, tebufenozide , halofenozide, fufenozide or chromafe [0272 ] II -M . 28 .5h N -[ 4 ,6 -dibromo - 2 -[ (diethyl - lambda - 4 nozide ; sulfanylidene ) carbamoyl ] -phenyl ] - 2 - ( 3 -chloro - 2 [ 0248 ] II - M . 19 Octopamin receptor agonists : amitraz ; pyridyl) - 5 - ( trifluoromethyl) pyrazole - 3 - carboxamide ; [ 0249] II - M . 20 Mitochondrial complex III electron trans [0273 ] II - M . 28 . 5i N - [ 2 - ( 5 - Amino - 1 , 3 , 4 - thiadiazol- 2 -yl ) port inhibitors : hydramethylnon , acequinocyl, and flu 4 - chloro - 6 - methylphenyl] - 3 - bromo- 1 - ( 3 - chloro - 2 - pyridi acrypyrim ; nyl) - 1H -pyrazole - 5 - carboxamide ; [0250 ] II -M .21 Mitochondrial complex I electron trans [0274 ] II - M .28 . 5j 3 - Chloro - 1 - ( 3 -chloro - 2 -pyridinyl ) - N port inhibitors : [ 2, 4 -dichloro -6 - [[ ( 1- cyano - 1 -methylethyl ) amino ]carbo [0251 ] II - M .21A METI acaricides and insecticides : nyl ]phenyl ] - 1H -pyrazole - 5 -carboxamide ; fenazaquin , fenpyroximate , pyrimidifen , pyridaben , [0275 ] II - M .28 .5k 3 -Bromo - N - [ 2 , 4 - dichloro - 6 - ( methyl tebufenpyrad , and tolfenpyrad ; and carbamoyl) phenyl] - 1 - ( 3 , 5 - dichloro - 2 -pyridyl ) - 1H -pyra [0252 ] Il - M .21B rotenone ; zole -5 -carboxamide ; [0253 ] II - M .22 Voltage -dependent sodium channel block [0276 ] II- M .28 .51 N - [ 4 -Chloro - 2 - [ [ ( 1 , 1 - dimethylethyl) ers : amino ] carbonyl] -6 -methylphenyl ] - 1 -( 3 - chloro - 2 -pyridi [0254 ] II - M .22A indoxacarb ; nyl) - 3 -( fluoromethoxy ) - 1H -pyrazole - 5 -carboxamide ; and [0255 ] II - M .22B metaflumizone ; [ 0277 ] II- M . 28. 6 : cyhalodiamide ; [0256 ] II - M .22B . 1 2 -[ 2 -( 4 -Cyanophenyl ) - 1 -( 3 -( trifluo [0278 ] II - M .29 . insecticidal active compounds of romethyl) phenyljethylidene ] - N - [ 4 - ( difluoromethoxy ) unknown or uncertain mode of action : afidopyropen , phenyl] - hydrazinecarboxamide ; and afoxolaner , azadirachtin , amidoflumet , benzoximate , [ 0257] II - M .22B . 2 N - ( 3 - Chloro - 2 -methylphenyl ) - 2 - [ ( 4 bifenazate , broflanilide, bromopropylate, chinomethionat, chlorophenyl) [ 4 - [methyl ( methylsulfonyl ) amino ]phenyl ] cryolite , dicloromezotiaz , dicofol, flufenerim , flometo methylene] -hydrazinecarboxamide ; quin , fluensulfone , fluhexafon , fluopyram , flupyradifu rone , fluralaner, metoxadiazone , piperonyl butoxide , [0258 ] II - M .23 Inhibitors of the of acetyl CoA carboxylase pyflubumide , pyridalyl, pyrifluquinazon , sulfoxaflor, tiox of the class of tetronic and tetramic acid derivatives : azafen , and triflumezopyrim ; spirodiclofen , spiromesifen , and spirotetramat; [ 0279 ] II- M . 29. 3 : 11 - ( 4 - chloro - 2 ,6 - dimethylphenyl) - 12 [0259 ] II - M .24 Mitochondrial complex IV electron trans hydroxy - 1, 4 -dioxa - 9 -azadispiro [ 4. 2 .4 . 2 ]- tetradec - 11 - en port inhibitors : 10 -one ; [ 0260 ] II - M . 24A phosphorous compounds : aluminium [0280 ] II - M .29 . 4 : 3 - ( 4 '- fluoro - 2 , 4 - dimethylbiphenyl- 3 phosphide, calcium phosphide, phosphine, and zinc phos yl) - 4 - hydroxy - 8 - oxa - 1 -azaspiro [ 4 . 5 ]dec - 3 - en - 2 - one; phide ; and [0281 ] Il - M .29 . 5 : 1 - [ 2 - fluoro - 4 -methyl - 5 - [ ( 2 , 2 , 2 - trifluo [0261 ] II - M .24B cyanide; roethyl) sulfinyl ] phenyl] - 3 - ( trifluoromethyl ) - 1H - 1 , 2 ,4 -tri [0262 ] II - M .25 Mitochondrial complex II electron trans azole - 5 -amine , and actives on basis of Bacillus firmus port inhibitors from the class of beta -ketonitrile deriva ( Votivo , 1 - 1582 ) ; and tives: cyenopyrafen , and cyflumetofen ; [0282 ] II - M .29 . 6a ( E / Z ) - N - [ 1 - [ (6 - chloro - 3 - pyridyl ) 102631 II - M . 28 Ryanodine receptor- modulators from the methyl ] - 2 - pyridylidene ) - 2 , 2 , 2 - trifluoro - acetamide; class of diamides : flubendiamide, chlorantraniliprole [0283 ] II- M .29 .6b ( E /Z )- N -[ 1 -[ ( -chloro -5 - fluoro - 3 (Rynaxypyr® ) , cyantraniliprole ( Cyazypyr® ) , tetranilip pyridyl )methyl ] - 2 -pyridylidene ) - 2 , 2 , 2 - trifluoro - acet role ; and the phthalamide compounds amide ; [0264 ] II -M .28 .1 (R )- 3 -Chlor - N1- {2 -methyl - 4 -[ 1, 2 ,2 ,2 - [0284 ] II -M .29 . 6c (E /Z ) -2 ,2 ,2 - trifluoro - N -[ 1 -[ (6 - fluoro tetrafluor - 1 - (trifluormethyl ) ethyl ] phenyl} -N2 - ( 1 -methyl 3 -pyridyl ) methyl ) - 2 -pyridylideneJacetamide ; 2 -methylsulfonylethyl ) phthalamid ; [0285 ] II - M .29 . 6d ( E / Z ) - N - [ 1 - [ ( 6 - bromo - 3 - pyridyl ) [0265 ] II- M .28 .2 (S )- 3 - Chlor- N1 - { 2 -methyl - 4 -[ 1 , 2 ,2 ,2 methyl) - 2 -pyridylidene )- 2 ,2 , 2 - trifluoro - acetamide; tetrafluor- 1 - ( trifluormethyl) ethyl] phenyl} -N2 - ( 1 -methyl [0286 ] II - M . 29 .6e ( E / Z ) - N - [ 1 - [ 1 - ( 6 - chloro - 3 - pyridyl) 2 -methylsulfonylethyl ) phthalamid ; ethyl] -2 -pyridylidene )- 2 , 2 ,2 - trifluoro -acetamide ; [0266 ] II - M .28 .3 3 -bromo -N - {2 - bromo- 4 -chloro -6 -[ ( 1 [0287 ] II -M .29 . 6f (E / Z )- N - [ 1- [ (6 -chloro -3 -pyridyl ) cyclopropylethyl) carbamoyl ] phenyl )- 1 -( 3 -chlorpyridin methyl) - 2 -pyridylidene ) - 2 , 2 - difluoro - acetamide ; 2 - yl ) - 1H -pyrazole - 5 - carboxamide (proposed ISO name: [0288 ] II - M .29 .6g ( E / Z ) - 2 - chloro - N - [ 1 - [ (6 - chloro - 3 cyclaniliprole ) ; pyridyl )methyl ) -2 -pyridylidene ] -2 ,2 -difluoro -acetamide ; US 2019 / 0281835 A1 Sep . 19 , 2019

[0289 ] II - M .29 . 6h ( E / Z ) -N -[ 1 -[ ( 2 -chloropyrimidin - 5 - yl) [0312 ] II - M . 29 .12 .a 2 -( 1 , 3 -Dioxan - 2 - yl) - 6 - [ 2 - (3 -pyridi methyl] - 2 -pyridylidene ] - 2 , 2 , 2 - trifluoro - acetamide nyl) - 5 - thiazolyl] -pyridine ; [ 0290 ] II - M .29 .6i ( E / Z )- N -[ 1 - [( 6 -chloro - 3 -pyridyl ) [0313 ] II- M .29 . 12 . b 2 - [6 - [ 2 - ( 5 - Fluoro - 3 -pyridinyl ) - 5 - thi methyl] - 2 -pyridylidene ] - 2 , 2 , 3 , 3 ,3 -pentafluoropropana azolyl] - 2 - pyridinyl] - pyrimidine ; mide . ); [0314 ] II - M .29 . 12 . c 2 - [6 - [ 2 - ( 3 -Pyridinyl ) - 5 -thiazolyl ] - 2 [ 0291] II - M . 29 .6j N - [1 - [( 6 -chloro - 3 -pyridyl )methyl ) - 2 pyridinyl] -pyrimidine ; pyridylidene ]- 2 ,2 , 2 -trifluoro -thioacetamide ; and [0315 ] Il - M .29 . 12 . d N - M ethylsulfonyl -6 - [ 2- (3 -pyridyl ) [ 0292] II - M .29 . 6k N - [ 1 - [ ( 6 - chloro - 3 -pyridyl )methyl ] - 2 thiazol- 5 -yl ] pyridine - 2 - carboxamide ; pyridylidene ) -2 ,2 ,2 - trifluoro -N '- isopropyl - acetamidine ; [ 0316 ] II- M . 29. 12. e N - M ethylsulfonyl -6 - [ 2 - ( 3 -pyridyl ) [0293 ] II - M .29 . 8 : fluazaindolizine ; thiazol- 5 -yl ] pyridine - 2 - carboxamide ; [ 0294 ] Il - M .29 . 9 . a 4 - [ 5 - ( 3 , 5 -dichlorophenyl ) - 5 - ( trifluo [0317 ] II- M . 29 .12 .f N - Ethyl- N - [4 -methyl - 2 - 3- pyridyl ) romethyl) - 4H - isoxazol - 3 -yl ] - 2 -methyl - N - ( 1 - oxothietan thiazol- 5 - yl) - 3 -methylthio -propanamide ; 3 - yl) benzamide ; and [0318 ] II - M . 29. 12 . g N - M ethyl- N - [ 4 -methyl - 2 - ( 3 [0295 ] II - M .29 . 9 . b fluxametamide ; pyridyl) thiazol- 5 -yl ] -3 -methylthio -propanamide ; [0296 ] II - M . 29 . 10 5 - [3 - [ 2 , 6 - dichloro - 4 - ( 3 , 3 -dichloroally - ( 0319 ] Il - M .29 . 12h . N , 2 -Dimethyl - N - [ 4 -methyl - 2 - ( 3 loxy ) phenoxy ]propoxy ] - 1H - pyrazole ; pyridyl) thiazol - 5 - yl) - 3 -methylthio -propanamide ; [0297 ] II - M . 29 . 11 . b 3 - (benzoylmethylamino ) - N - [ 2 - (0320 ] II - M .29 . 12 . i N - Ethyl - 2 -methyl - N - [ 4 -methyl - 2 - (3 bromo - 4 - [ 1 , 2 , 2 , 3 , 3 , 3 -hexafluoro - 1 - ( trifluoromethyl) pro pyridyl) thiazol - 5 - y1 ] - 3 -methylthio - propanamide ; pyl] - 6 -( trifluoromethyl ) phenyl ]- 2 - fluoro -benzamide ; [0321 ] II - M . 29 . 12 .j N -[ 4 -Chloro - 2 - ( 3 -pyridyl ) thiazol- 5 [0298 ] II - M .29 . 11 . c 3 - (benzoylmethylamino ) - 2 - fluoro - N yl] - N - ethyl - 2 -methyl - 3 -methylthio - propanamide ; [ 2 - iodo - 4 - [ 1 , 2 , 2 , 2 - tetrafluoro - 1 - ( trifluoromethyl ) ethyl] [ 0322 ] II- M . 29 . 12. k N - [ 4 - Chloro - 2 - ( 3 - pyridyl) thiazol - 5 6 - ( trifluoromethyl) phenyl] -benzamide ; yl ]- N , 2 -dimethyl - 3 -methylthio -propanamide ; [0299 ] II - M .29 . 11 . d N - [ 3 - [ [ [ 2 - iodo - 4 - [ 1 , 2 , 2 , 2 - tetrafluoro [0323 ] II - M . 29 . 12 .1 N - [ 4 -Chloro - 2 - ( 3 -pyridyl ) thiazol- 5 1 - (trifluoromethyl ) ethyl ] -6 - (trifluoromethyl ) phenyl] yl] - N -methyl - 3 -methylthio - propanamide; amino ] carbonyl] phenyl ] - N -methyl - benzamide ; [0324 ] II - M .29 . 12 . m N - [ 4 - Chloro - 2 - ( 3 -pyridyl ) thiazol- 5 [0300 ] Il - M .29 . 11. e N -[ 3 -[ [ [ 2 -bromo - 4 -[ 1, 2 ,2 , 2 -tetra yl] - N - ethyl- 3 -methylthio - propanamide ; or the com fluoro - 1 - ( trifluoromethyl) ethyl ] - 6 - ( trifluoromethyl )phe pounds nyl] amino ]carbonyl ] - 2 -fluorophenyl ] - 4 - fluoro - N [0325 ] II - M . 29 . 14a 1 - [ (6 - Chloro - 3 -pyridinyl )methyl ) - 1 , 2 , methyl- benzamide ; 3 ,5 , 6 , 7 - hexahydro - 5 -methoxy - 7 -methyl - 8 -nitro - imidazo [0301 ] Il - M .29 .11 . f 4 - fluoro - N - [ 2 - fluoro - 3 - [ [ [ 2 - iodo - 4 [ 1 , 2 - a ]pyridine ; [1 , 2 ,2 , 2 -tetrafluoro - 1- (trifluoromethyl ) ethyl ] -6 -( trifluo [0326 ] II - M .29 . 14b 1- [( 6 - Chloropyridin - 3 - yl) methyl ] - 7 romethyl) phenyl ]amino ]carbonyl ]phenyl ] -N -methyl -ben methyl- 8 -nitro - 1 , 2 , 3 , 5 , 6 , 7 -hexahydroimidazo [ 1 , 2 - a ]pyri zamide; din - 5 -ol ; 50302 ] II- M .29 .11 . g 3 - fluoro - N - [ 2 - fluoro - 3 - [[ [ 2 - iodo - 4 - (0327 ] II - M .29 . 16a l- isopropyl- N ,5 - dimethyl- N [ 1 , 2 , 2 , 2 - tetrafluoro - 1 - (trifluoromethyl ) ethyl] -6 - (trifluo pyridazin - 4 -yl - pyrazole - 4 - carboxamide ; or romethyl) phenyl ] amino ]carbonyl ]phenyl ] -N -methyl -ben [0328 ] II - M . 29 .16b 1- ( 1, 2 -dimethyl propyl) - N - ethyl- 5 zamide ; methyl- N -pyridazin - 4 - yl- pyrazole - 4 - carboxamide ; [ 0303] II - M .29 . 11. h 2 - chloro - N - [ 3 - [ [ [ 2 - iodo - 4 - [ 1 , 2 , 2 , 2 [0329 ] II - M . 29 . 16€ 1 , 5 - dimethyl- N - pyridazin - 4 -yl - 1 - ( 2 , tetrafluoro - 1 - (trifluoromethyl ) ethyl ] -6 -( trifluoromethyl) 2 , 2 - trifluoro - 1 -methyl - ethyl) pyrazole - 4 -carboxamide ; phenyl] amino ] carbonyl] phenyl ] - 3 -pyridinecarboxamide ; [0330 ] II -M . 29 . 16d 1- [ 1 - (1 -cyanocyclopropyl ) ethyl] -N [0304 ] II - M .29 . 11. i 4 - cyano - N -[ 2 - cyano -5 -[ [2 , 6 - di ethyl- 5 -methyl - N - pyridazin - 4 - yl- pyrazole - 4 - carboxam bromo - 4 - [ 1 , 2 , 2 , 3 , 3 , 3 - hexafluoro - 1 - ( trifluoromethyl) pro ide ; pyl] phenyl ] carbamoyl ]phenyl ] - 2 -methyl -benzamide ; [0331 ] II - M . 29 . 16e N - ethyl- 1 - ( 2 - fluoro - 1 -methyl - pro [0305 ] II - M .29 . 11 .j 4 -cyano - 3 - [ ( 4 - cyano - 2 -methyl - ben pyl) - 5 -methyl - N -pyridazin - 4 - yl- pyrazole - 4 - carboxam zoyl) amino ]- N -[ 2 ,6 - dichloro -4 - [ 1 ,2 , 2, 3 ,3 ,3 -hexafluoro ide ; 1 - (trifluoromethyl ) propyl ] phenyl ] -2 - fluoro -benzamide ; [0332 ] II - M .29 . 16f 1 - ( 1 , 2 - dimethylpropyl) - N , 5 - dimethyl [ 0306 ] II - M .29 . 11. k N - [ 5 - [ [ 2 - chloro -6 - cyano - 4 - [ 1 , 2 , 2 , 3 , N -pyridazin - 4 - yl- pyrazole - 4 - carboxamide ; 3 , 3 - hexafluoro - 1 - ( trifluoromethyl) propyl ] - phenyl] car [0333 ] II - M .29 . 16g 1 -[ 1 -( 1 -cyanocyclopropyl ) ethyl ] - N ,5 bamoyl ] - 2 - cyano - phenyl] -4 - cyano - 2 - methyl -benzamide ; dimethyl- N -pyridazin - 4 -yl - pyrazole - 4 - carboxamide ; [ 0307] II - M .29 . 11. 1 N - [ 5 - [ [ 2 - bromo -6 - chloro - 4 - [ 2 , 2 , 2 -tri [0334 ] II - M .29 . 16h N -methyl - 1 - ( 2 - fluoro - 1 -methyl - pro fluoro - 1 -hydroxy - 1 - ( trifluoromethyl) ethyl ] -phenyl ] car pyl] -5 -methyl - N - pyridazin - 4 - yl- pyrazole - 4 - carboxam bamoyl] -2 - cyano -phenyl ]- 4 -cyano - 2 -methyl - benzamide ; ide ; [0308 ] II - M .29 . 11 . m N - [ 5 - [ [ 2 -bromo - 6 -chloro - 4 - [ 1 , 2 , 2 , 3 , [0335 ] II- M .29 . 16i 1 -( 4 ,4 - difluorocyclohexyl) - N -ethyl - 5 3 , 3 -hexafluoro - 1 - ( trifluoromethyl) propyl] phenyl ] car methyl- N - pyridazin - 4 -yl - pyrazole - 4 -carboxamide ; and bamoyl] - 2 - cyano - phenyl] - 4 - cyano - 2 - methyl- benzamide ; [ 0336 ] II- M . 29 . 16j 1 - ( 4 , 4 - difluorocyclohexyl) - N , 5 -dim [ 0309] II - M .29 . 11. n 4 - cyano - N - [ 2 - cyano - 5 - [ [ 2 ,6 - di ethyl- N -pyridazin - 4 -yl - pyrazole - 4 - carboxamide ; chloro -4 - [ 1 ,2 , 2, 3 ,3 , 3 -hexafluoro - 1 -( trifluoromethyl) pro [0337 ] II - M .29 .17a N -( 1- methylethyl )- 2 -( 3 -pyridinyl ) pyl] phenyl ] carbamoyl] phenyl ] -2 -methyl - benzamide zomide ;. 2H - indazole - 4 - carboxamide; [ 0310 ] II - M .29 .11 .0 4 -cyano -N -[ 2 -cyano -5 - [[ 2 ,6 -di [ 0338 ] II- M . 29. 17b N - cyclopropyl- 2 - ( 3 - pyridinyl )- 2H - in chloro - 4 - [ 1 , 2 , 2 , 2 - tetrafluoro - 1 - ( trifluoromethyl) ethyl] dazole - 4 - carboxamide ; phenyl] carbamoyl ] phenyl] - 2 -methyl - benzamide ; [0339 ] II -M . 29 .17c N -cyclohexyl - 2 -( 3 -pyridinyl ) -2H -in [0311 ] II - M .29 . 11 . p N - [ 5 - [ [ 2 -bromo -6 -chloro - 4 - [ 1 , 2 , 2 , 2 dazole - 4 -carboxamide ; tetrafluoro - 1 - ( trifluoromethyl ) ethyl] phenyl] -carbamoyl ] [0340 ] II - M . 29 .17d 2 - ( 3 -pyridinyl ) - N - (2 , 2 ,2 - trifluoro 2 - cyano -phenyl ] - 4 - cyano - 2 -methyl - benzamide ; ethyl) -2H - indazole - 4 - carboxamide ; US 2019 / 0281835 A1 Sep . 19 , 2019 10

[0341 ] II - M .29 .17e 2 -( 3 -pyridinyl ) - N -[ ( tetrahydro - 2- fura nucleopolyhedrovirus ( HzNPV ) , Helicoverpa zea single nyl) methyl ) - 2H - indazole - 5 -carboxamide ; capsid nucleopolyhedrovirus (HzSNPV ) , Heterorhabditis [ 0342 ] II - M . 29 .17f methyl 2 - [[ 2 -( 3 -pyridinyl ) - 2H -inda bacteriophora , Isaria fumosorosea , Lecanicillium long zol -5 - yl] carbonyl ] hydrazinecarboxylate ; isporum , L . muscarium , Metarhizium anisopliae , Metar [ 0343 ] II- M . 29 . 17g N - [ ( 2 , 2 - difluorocyclopropyl)methyl ] hizium anisopliae var. anisopliae, M . anisopliae var . 2 - ( 3 -pyridinyl ) - 2H - indazole - 5 -carboxamide ; acridum , Nomuraea rileyi , Paecilomyces fumosoroseus, [0344 ] Il - M .29 .17h N - ( 2 , 2 -difluoropropyl ) - 2 - ( 3 -pyridi P . lilacinus, Paenibacillus popilliae, Pasteuria spp ., P . nyl) -2H - indazole- 5 - carboxamide ; nishizawae , P . penetrans , P . ramosa , P . thornea , P . usgae , [ 0345 ] II- M . 29 . 17i 2 - ( 3 - pyridinyl) - N - ( 2 - pyrimidinylm Pseudomonas fluorescens, Spodoptera littoralis nucleo ethyl) - 2H -indazole - 5 - carboxamide ; and polyhedrovirus ( SpliNPV ) , Steinernema carpocapsae , S . [ 0346 ] II - M .29 . 17j N - [ ( 5 -methyl - 2 -pyrazinyl )methyl ] - 2 feltiae , S . kraussei Streptomyces galbus , and S . microfla ( 3 -pyridinyl ) -2H - indazole- 5 - carboxamide ; vus; [0347 ] II - M .29 . 18a N - [ 3 -chloro - 1 - ( 3 -pyridyl ) pyrazol- 4 [0357 ] II- L . 4 Biochemical pesticides with insecticidal, yl ] - N - ethyl- 3 - ( 3 , 3 , 3 - trifluoropropylsulfanyl )propana acaricidal, molluscidal, pheromone and / or nematicidal mide; activity : L - carvone , citral, ( E , Z ) - 7 , 9 -dodecadien - 1 -yl [ 0348 ] II - M .29 . 18b N - [ 3 -chloro - 1 - ( 3 - pyridyl) pyrazol - 4 acetate , ethyl formate , ( E , Z ) - 2 , 4 - ethyl decadienoate (pear yl] - N - ethyl - 3 -( 3, 3, 3 - trifluoropropylsulfinyl )propana ester) , ( Z , Z , E ) - 7 , 11, 13 - hexadecatrienal, heptyl butyrate , mide ; isopropyl myristate , lavanulyl senecioate , cis -jasmone , [ 0349] II - M .29 . 18€ N - [ 3 -chloro - 1 - ( 3 - pyridyl) pyrazol - 4 2 -methyl 1 - butanol, methyl eugenol, methyl jasmonate , yl] - 3 - [( 2 , 2 -difluorocyclopropyl )methylsulfanyl ]- N -ethyl ( E , Z ) - 2 , 13 - octadecadien - 1 - ol, ( E , Z ) - 2 , 13 -octadecadien propanamide ; and 1 -ol acetate , ( E , Z ) - 3 , 13 -octadecadien - 1 - ol, R - 1 - octen - 3 [0350 ] II -M .29 . 18d N - [3 - chloro - 1 -( 3- pyridyl ) pyrazol -4 ol, pentatermanone, ( E , Z , Z ) - 3 , 8 , 11 -tetradecatrienyl yl ]- 3 - [( 2 ,2 - difluorocyclopropyl) methylsulfinyl ] -N - ethyl acetate, ( Z ,E )- 9, 12 -tetradecadien - 1 - yl acetate , Z - 7 - tetra propanamide ; decen - 2 - one, Z - 9 - tetradecen - 1 - yl acetate , Z - 11 - tetradece [0351 ] II - M .29 . 19 sarolaner ; nal, Z - 11 - tetradecen - 1 -ol , extract of Chenopodium [0352 ] II - M .29 . 20 lotilaner ; ambrosiodes , Neem oil, and Quillay extract ; [0353 ] II - L Biopesticides: [0358 ] II - L .5 Microbial pesticides with plant stress reduc [0354 ] II -L . 1 Microbial pesticides with fungicidal, bacte ing , plant growth regulator, plant growth promoting and / ricidal, viricidal and / or plant defense activator activity : or yield enhancing activity : A . lipoferum , A . irakense, A . Ampelomyces quisqualis , Aspergillus flavus, Aureoba halopraeferens, B . elkani B . liaoningense , B . lupini, Delf sidium pullulans, Bacillus altitudinis , B . amyloliquefa tia acidovorans, Glomus intraradices, Mesorhizobium ciens, B . megaterium , B . mojavensis , B . mycoides, B . spp ., Rhizobium leguminosarum bv . phaseoli , R . 1. bv. simplex , B . solisalsi, B . subtilis , B . subtilis var. amyloliq trifolii , R . 1 . bv . viciae , R . tropici and Sinorhizobium uefaciens , Candida oleophila , C . saitoana , Clavibacter meliloti; michiganensis (bacteriophages ) , Coniothyrium minitans, [0359 ] and / or at least one fungicidally active compound Cryphonectria parasitica , Cryptococcus albidus, Dilo III selected from phosphora alopecuri, Fusarium oxysporum , Clonos [0360 ] III - F . I Respiration inhibitors tachys rosea f. catenulate ( also named Gliocladium [0361 ] III - F. 11 Inhibitors of complex III at Q . site : azox catenulatum ), Gliocladium roseum , Lysobacter antibioti ystrobin , coumethoxystrobin , coumoxystrobin , dimox cus, L . enzymogenes, Metschnikowia fructicola , Microd ystrobin , enestroburin , fenaminstrobin , fenoxystrobin / ochium dimerum , Microsphaeropsis ochracea , Muscodor flufenoxystrobin , fluoxastrobin , kresoxim -methyl , albus, Paenibacillus polymyxa , Pantoea vagans, Penicil mandestrobin , metominostrobin , orysastrobin , picox lium bilaiae, Phlebiopsis gigantea , Pseudomonas sp ., ystrobin , pyraclostrobin , pyrametostrobin , pyraox Pseudomonas chloraphis , Pseudozyma flocculosa , Pichia ystrobin , trifloxystrobin , 2 - ( 2 - ( 3 - ( 2 , 6 -dichlorophenyl ) - 1 anomala , Pythium oligandrum , Sphaerodes mycopara methyl- allylideneaminooxymethyl) - phenyl) - 2 sitica , Streptomyces griseoviridis , S . lydicus, S . violaceus methoxyimino - N -methyl - acetamide, pyribencarb , niger, Talaromyces flavus, T. asperellum , T. atroviride, T . triclopyricarb /chlorodincarb , famoxadone , and fenami fertile , T . gamsii, T . harmatum , T . harzianum , T . polyspo done, methyl - N - [ 2 - [ ( 1 , 4 - dimethyl- 5 - phenyl- pyrazol - 3 rum , T . stromaticum , T . virens, T . viride, Typhula phac yl) oxylmethyl ] phenyl] - N -methoxy - carbamate , 1 - [ 3 orrhiza , Ulocladium oudemansii, Verticillium dahlia , and chloro - 2 - [ [ 1 - ( 4 -chlorophenyl ) - 1H - pyrazol- 3 -yl ] zucchini yellow mosaic virus (avirulent strain ) ; oxymethyl] phenyl ] - 4 -methyl - tetrazol - 5 -one , 1 - [ 3 -bromo [0355 ] II - L . 2 Biochemical pesticides with fungicidal , bac 2 -[ [ 1 - (4 -chlorophenyl ) pyrazol - 3 -yl ] oxymethyl ] phenyl ] tericidal, viricidal and / or plant defense activator activity : 4 -methyl - tetrazol- 5 -one , 1 - [ 2 - [ [ 1 - ( 4 - chlorophenyl) harpin protein , and Reynoutria sachalinensis extract; pyrazol - 3 - yl] oxymethyl ] - 3 -methyl - phenyl] - 4 -methyl [ 0356 ] II - L . 3 Microbial pesticides with insecticidal, aca tetrazol- 5 -one , 1 - [ 2 - [ [ 1 - ( 4 - chlorophenyl )pyrazol - 3 -yl ] ricidal, molluscidal and / or nematicidal activity : Agrobac oxymethyl] - 3 - fluoro -phenyl ] - 4 -methyltetrazol - 5 -one , terium radiobacter, Bacillus cereus , B . firmus , B . thuringi 1 - [ 2 - [ [ 1 - ( 2 , 4 -dichlorophenyl ) pyrazol - 3 - yl] oxymethy11 - 3 ensis, B . thuringiensis ssp . aizawai, B . t . ssp . israelensis , fluoro -phenyl ] -4 -methyl -tetrazol - 5 -one , 1 - [ 2 - [ [ 4 - ( 4 - chlo B . t . ssp . galleriae , B . t . ssp . tenebrionis , Beauveria rophenyl) thiazol- 2 -yl ] oxymethyl ] - 3 -methyl - phenyl ] - 4 bassiana , B . brongniartii, Burkholderia spp ., Chromo methyl- tetrazol- 5 - one , 1 - [ 3 - chloro - 2 - [ [ 4 - ( p - tolyl) thiazol bacterium subtsugae, Cydia pomonella granulovirus 2 - yl ] oxymethyl] phenyl] - 4 -methyl - tetrazol- 5 -one , 1 - [ 3 (CPGV ), Cryptophlebia leucotreta granulovirus (Cr cyclopropyl- 2 - [[ 2 -methyl - 4 - ( 1 -methylpyrazol - 3 -yl ) leGV ) , Flavobacterium spp . , Helicoverpa armigera phenoxy ]methyl ] phenyl] - 4 -methyl -tetrazol - 5 - one, 1 - [ 3 nucleopolyhedrovirus ( HearNPV ), Helicoverpa zea (difluoromethoxy )- 2 -[ [ 2 -methyl - 4 -( 1 -methylpyrazol - 3 US 2019 / 0281835 A1 Sep . 19 , 2019

yl) phenoxy ]methyl ] phenyl ] - 4 -methyl - tetrazol - 5 -one , conazole , prothioconazole , simeconazole , tebucon 1 - methyl- 4 - [ 3 - methyl- 2 - [ [ 2 -methyl - 4 - ( 1 -methyl pyrazol azole , tetraconazole , triadimefon , triadimenol, 3 - yl ) phenoxy ]methyl ] phenyl] tetrazol - 5 - one, 1 -methyl - 4 triticonazole , uniconazole , 1 - [ rel- (2S ; 3R ) - 3 - ( 2 - chloro [ 3 -methyl - 2 -[ [ 1 -[ 3 -( trifluoromethyl) phenyl] - ethylide phenyl) - 2 - ( 2 ,4 - difluorophenyl ) oxiranylmethyl ) - 5 -thio neamino ]oxy -methyl ] phenyl ] tetrazol- 5 -one , ( Z , 2E )- 5 -[ 1 cyanato - 1H - [ 1 , 2 , 4 ] triazolo , 2 - [ rel- (2S ; 3R ) - 3 - ( 2 -chlo ( 2 , 4 -dichlorophenyl )pyrazol - 3 -yl ) -oxy - 2 - methoxyimino rophenyl) - 2 - ( 2 ,4 - difluorophenyl) -oxiranylmethyl ] - 2H N , 3 - dimethyl- pent - 3 - enamide , ( 2 ,2E ) -5 - [ 1 - (4 [ 1 , 2 , 4 ] triazole - 3 - thiol, 2 - [ 2 - chloro - 4 - ( 4 chlorophenyl) pyrazol - 3 - yl] oxy - 2 -methoxyimino - N , 3 chlorophenoxy ) phenyl] - 1 - ( 1 , 2 , 4 - triazol- 1 - yl) pentan - 2 dimethyl- pent - 3 - enamide , and ( 2 , 2E ) - 5 - [ 1 - ( 4 - chloro - 2 ol , 1 -[ 4 - ( 4 - chlorophenoxy ) - 2 - (trifluoromethyl ) fluoro -phenyl ) pyrazol - 3 - yl] oxy - 2 -methoxyimino -N ,3 phenyl] - 1 - cyclopropyl- 2 -( 1 , 2 , 4 - triazol- 1 -yl ) ethanol, dimethyl -pent - 3 - enamide ; 2 - [ 4 - (4 - chlorophenoxy ) - 2 - ( trifluoromethyl) phenyl] - 1 [0362 ] III- F. 12 inhibitors of complex III at Qi site : cyazo ( 1 , 2 , 4 - triazol- 1 - yl) butan - 2 - ol, 2 - [ 2 - chloro - 4 - ( 4 - chloro famid , amisulbrom , [( 35 ,68 ,7R ,8R )- 8 -benzyl - 3 -[ (3 -ac phenoxy )phenyl ] - 1 -( 1, 2, 4- triazol- 1 - yl )butan - 2 -ol , etoxy - 4 -methoxy -pyridine - 2 -carbonyl ) amino ]- 6 -methyl 2 -[ 4 -( 4 -chlorophenoxy )- 2 -( trifluoromethyl ) phenyl ] - 3 4 , 9 -dioxo - 1 , 5 - dioxonan - 7 - yl] 2 -methylpropanoate , [ (3S , methyl - 1 - ( 1 , 2 , 4 - triazol- 1 - yl) butan - 2 - ol , 2 - [ 4 - ( 4 -chlo 68 ,7R ,8R )- 8 -benzyl - 3 - [[ 3 -( acetoxymethoxy ) -4 -methoxy rophenoxy ) - 2 - ( trifluoromethyl) phenyl] - 1 - ( 1 , 2 , 4 -tri pyridine - 2 - carbonyl ] amino ] - 6 -methyl - 4 , 9 - dioxo - 1 , 5 azol- 1 -yl ) propan - 2 -ol , 2 - [2 - chloro -4 -( 4 dioxonan - 7 -yl ] 2 - methylpropanoate , [ (35 ,65 ,7R , 8R ) - 8 chlorophenoxy )phenyl ]- 3 -methyl - 1- (1 , 2, 4 -triazol - 1 -yl ) benzyl- 3 - [( 3 -isobutoxycarbonyloxy - 4 -methoxy - pyridine butan - 2 -ol , 2 - [ 4 - ( 4 - chlorophenoxy ) - 2 2 -carbonyl ) amino ]- 6 -methyl - 4 , 9 - dioxo - 1 ,5 - dioxonan - 7 ( trifluoromethyl) phenyl ] - 1 - ( 1 , 2 , 4 - triazol - 1 - yl) pentan yl ] 2 -methylpropanoate , [ (35 ,68 ,7R , 8R )- 8 -benzyl - 3 - [[ 3 2 -ol , 2 - [ 4 - ( 4 - fluorophenoxy ) - 2 - ( trifluoromethyl) ( 1 , 3 -benzodioxol - 5 -ylmethoxy ) - 4 -methoxypyridine - 2 phenyl] - 1 - ( 1 , 2 , 4 -triazol - 1 - yl) propan - 2 - ol, 2 - [ 2 - chloro carbonyl] amino ) - 6 -methyl - 4 , 9 - dioxo - 1 , 5 -dioxonan - 7 -yl ] 4 - (4 - chlorophenoxy )phenyl ] - 1- (1 ,2 ,4 -triazol - 1 -yl ) 2 -methylpropanoate ; (38 ,6S , 7R , 8R ) - 3 - [ [ ( 3 -hydroxy - 4 pent- 3 - yn - 2 -ol ; imidazoles : imazalil, pefurazoate , methoxy - 2 -pyridinyl ) carbonyl] amino ]- 6 -methyl -4 , 9 -di prochloraz , triflumizol; oxo -8 -( phenylmethyl ) - 1, 5 - dioxonan - 7 -yl 2 -methylpro [0369 ] pyrimidines, pyridines and piperazines : fenari panoate , and ( 35 ,68 ,7R ,8R ) - 8 -benzyl - 3 - ( 3 mol, nuarimol, pyrifenox , triforine , and [3 -( 4 -chloro [ ( isobutyryloxy )methoxy ] - 4 -methoxypicolinamido ] - 6 2 - fluoro -phenyl ) - 5 -( 2 ,4 -difluorophenyl ) isoxazol- 4 -yl ] methyl- 4 , 9 -dioxo - 1 , 5 -dioxonan -7 -yl isobutyrate ; ( 3 - pyridyl) methanol ; [0363 ] III - F . 13 inhibitors of complex II : benodanil, ben [0370 ] III -F . 112 Delta14 -reductase inhibitors : aldimorph , zovindiflupyr, bixafen , boscalid , carboxin , fenfuram , flu dodemorph , dodemorph -acetate , fenpropimorph , tride opyram , flutolanil, fluxapyroxad , furametpyr, isofetamid , morph , fenpropidin , piperalin , and spiroxamine ; isopyrazam , mepronil, oxycarboxin , penflufen , penthio pyrad , sedaxane , tecloftalam , thifluzamide, N - ( 4 '- trifluo [0371 ] III - F . 113 Inhibitors of 3 -keto reductase : fenhex romethylthiobiphenyl- 2 -yl ) - 3 - difluoromethyl- 1 -methyl amid ; 1H -pyrazole - 4 -carboxamide , N - ( 2 - ( 1 , 3 , 3 - trimethyl [0372 ] III - F. III Nucleic acid synthesis inhibitors butyl) -phenyl ) - 1, 3 -dimethyl -5 - fluoro - 1H -pyrazole -4 [ 0373 ] IIIF . III1 phenylamides or acyl amino acid fungi carboxamide , 3 -( difluoromethyl ) - 1 -methyl -N -( 1 ,1 , 3 cides: benalaxyl, benalaxyl- M , kiralaxyl, metalaxyl, trimethylindan - 4 - yl) pyrazole - 4 - carboxamide , metalaxyl- M (mefenoxam ), ofurace , and oxadixyl ; 3 -( trifluoromethyl ) - 1- methyl - N - (1 , 1, 3 -trimethylindan - 4 [0374 ] III - F. III2 others : hymexazole , octhilinone , oxolinic yl) pyrazole - 4 -carboxamide , 1 ,3 - dimethyl - N - ( 1 , 1, 3 - trim acid , bupirimate , 5 - fluorocytosine, 5 - fluoro - 2 - ( p -tolyl ethylindan - 4 - yl ) pyrazole - 4 - carboxamide , 3 - (trifluorom methoxy )pyrimidin - 4 - amine, and 5 - fluoro - 2 - ( 4 - fluoro ethyl) - 1, 5 -dimethyl - N - ( 1, 1 ,3 - trimethylindan -4 -yl ) phenylmethoxy )pyrimidin - 4 - amine ; pyrazole - 4 - carboxamide, 1 , 3 , 5 - trimethyl- N - ( 1 , 1 , 3 [0375 ] III - F. IV Inhibitors of cell division and cytoskeleton trimethyl indan - 4 - yl) pyrazole - 4 -carboxamide , N - ( 7 fluoro - 1 , 1 , 3 - trimethyl- indan - 4 -yl ) - 1 , 3 -dimethyl [0376 ] III - F. IV1 tubulin inhibitors from the class of pyrazole -4 -carboxamide , and N -[ 2 - (2 , 4 -dichlorophenyl ) [ 0377 ] benzimidazoles , and thiophanates : benomyl, car 2 - methoxy - 1 -methyl - ethyl ] - 3 - (difluoromethyl ) - 1 bendazim , fuberidazole , thiabendazole , and thiophan methyl -pyrazole - 4 -carboxamide ; atemethyl; [0364 ] III -F . 14 other respiration inhibitors : diflumetorim , [0378 ] triazolopyrimidines: 5 -chloro - 7 -( 4 -methylpip ( 5 , 8 -difluoroquinazolin - 4 -yl ) - { 2 - [ 2 - fluoro - 4 - ( 4 - trifluo eridin - 1 -yl ) - 6 - ( 2 , 4 ,6 - trifluorophenyl) [ 1, 2 , 4 ] triazolo [ 1 , romethylpyridin - 2 -yloxy ) - phenyl] -ethyl ) - amine ; 5 - a ]pyrimidine ; and [0365 ] nitrophenyl derivates: binapacryl, dinobuton , [0379 ] III -F . IV2 other cell division inhibitors : diethofen dinocap , fluazinam , ferimzone ; organometal com carb , ethaboxam , pencycuron , fluopicolide, zoxamide, pounds : fentin -acetate , fentin chloride, and fentin metrafenone, pyriofenone ; hydroxide ; ametoctradin ; and silthiofam ; [0380 ] III - F. V Inhibitors of amino acid and protein syn [0366 ] III -F . II Sterol biosynthesis inhibitors : thesis : [ 0367 ] III - F . 111 C14 demethylase inhibitors : [ 0381 ] III - F .V1 methionine synthesis inhibitors from the 10368 ] triazoles : azaconazole , bitertanol, bromucon class of anilino- pyrimidines : cyprodinil, mepanipyrim , azole , cyproconazole , difenoconazole , diniconazole , and pyrimethanil ; and diniconazole - M , epoxiconazole , fenbuconazole , [0382 ] III - F. V2 protein synthesis inhibitors: blasticidin - S , fluquinconazole , flusilazole , flutriafol, hexaconazole , kasugamycin , kasugamycin hydrochloridehydrate , mil imibenconazole , ipconazole , metconazole, myclobuta diomycin , streptomycin , oxytetracyclin , polyoxine , and nil, oxpoconazole , paclobutrazole , penconazole , propi validamycin A ; US 2019 / 0281835 A1 Sep . 19 , 2019 12

[0383 ] III - F .VI Signal transduction inhibitors: 1H -pyrazol - 1 -yl ] - 1 - [ 4 - ( 4 - 5 - [ 2 - (prop - 2 -yn - 1 - yloxy ) [0384 ] III - F . VI1 MAP / histidine kinase inhibitors: fluor phenyl ] - 4 , 5 -dihydro - 1 , 2 - oxazol - 3 - yl) - 1 , 3 - thiazol- 2 - yl) oimid , iprodione , procymidone , vinclozolin , fenpiclonil, piperidin - 1 - yljethanone, 2 - [ 3 , 5 - bis (difluoromethyl ) and fludioxonil ; and 1H -pyrazol - 1 - yl) - 1 - [ 4 - ( 4 - { 5 - [ 2 - fluoro - 6 - ( prop - 2 - yn - 1 [ 03851 III - F .VI2 G protein inhibitors: quinoxyfen ; yloxy )phenyl ] -4 , 5 -dihydro - 1, 2 -oxazol - 3 -yl ) - 1, 3 [0386 ] III - F . VII Lipid and membrane synthesis inhibitors : thiazol- 2 - yl )piperidin - 1 - yl] ethanone , 2 - [ 3 , 5 -bis [0387 ] F. VII1 Phospholipid biosynthesis inhibitors : (difluoromethyl ) - 1H - pyrazol- 1 - yl] - 1 - [ 4 - ( 4 - 5 - [ 2 edifenphos , iprobenfos, pyrazophos, isoprothiolane ; chloro - 6 - (prop - 2 - yn - 1 - yloxy ) phenyl] -4 , 5 - dihydro - 1 , 2 [0388 ] III -F . VII2 lipid peroxidation : dicloran , quintozene , oxazol- 3 -yl ) - 1, 3 - thiazol- 2 -yl ) piperidin - 1- yl] ethanone, tecnazene , tolclofos -methyl , biphenyl, chloroneb , and N - ( cyclopropylmethoxyimino - ( 6 -difluoro -methoxy - 2 , etridiazole ; 3 - difluoro - phenyl) - methyl ) - 2 - phenyl acetamide, N '- ( 4 [0389 ] III- F .VII3 phospholipid biosynthesis and cell wall ( 4 - chloro -3 - trifluoromethyl- phenoxy )- 2 , 5- dimethyl deposition : dimethomorph , flumorph , mandipropamid , phenyl) - N - ethyl- N -methyl formamidine, N '- ( 4 - ( 4 pyrimorph , benthiavalicarb , iprovalicarb , valifenalate , fluoro - 3 - trifluoromethyl- phenoxy ) - 2 , 5 - dimethyl and N -( 1 -( 1 -( 4 -cyano - phenyl) ethanesulfonyl ) - but - 2 - yl) phenyl) - N - ethyl- N -methyl formamidine , N '- (2 -methyl carbamic acid - ( 4 - fluorophenyl ) ester ; 5 - trifluoromethyl- 4 - ( 3 - trimethylsilanyl- propoxy ) [0390 ] III - F . VII4 compounds affecting cell membrane per phenyl) - N - ethyl- N -methyl formamidine , N ' - ( 5 meability and fatty acides: propamocarb ; and difluoromethyl- 2 -methyl - 4 - ( 3 - trimethylsilanyl [0391 ] III - F . VII5 fatty acid amide hydrolase inhibitors : propoxy ) -phenyl ) -N - ethyl- N -methyl formamidine, oxathiapiprolin , 2 - { 3 - [ 2 - ( 1 - { [ 3 ,5 -bis (difluoromethyl - 1H methoxy - acetic acid 6 - tert- butyl - 8 - fluoro - 2 , 3 - dimeth pyrazol- 1 - yl] acetyl} piperidin - 4 - yl) - 1 , 3 - thiazol- 4 - yl) - 4 , 5 ylquinolin - 4 -yl ester, 3 -[ 5 - (4 -methylphenyl )- 2 ,3 - dim dihydro - 1 , 2 - oxazol- 5 -yl } phenyl methanesulfonate, 2 - 3 ethyl- isoxazolidin - 3 - yl] -pyridine , 3 - [ 5 - ( 4 - chloro -phe [ 2 -( 1 - { [3 ,5 -bis ( difluoromethyl ) - 1H -pyrazol - 1- yl] nyl) - 2 ,3 -dimethyl - isoxazolidin - 3 -yl ) -pyridine acetyl} piperidin - 4 - yl) , and 1 , 3 -thiazol - 4 - yl] - 4 , 5 - dihydro (pyrisoxazole ), N -( 6 -methoxy -pyridin - 3 - yl) cyclopro 1 , 2 - oxazol- 5 - yl) - 3 - chlorophenyl methanesulfonate ; panecarboxylic acid amide, 5 -chloro - 1- ( 4 ,6 -dime [0392 ] III -F . VIII Inhibitors with Multi Site Action : thoxy -pyrimidin - 2 -yl ) - 2 -methyl - 1H -benzoimidazole , [ 0393 ) III - F .VIII1 inorganic active substances : Bordeaux 2 - ( 4 - chloro - phenyl) - N - [ 4 - ( 3 , 4 -dimethoxy -phenyl ) mixture , copper acetate , copper hydroxide, copper oxy isoxazol- 5 - yl) - 2 -prop - 2 - ynyloxy - acetamide, ethyl ( Z ) chloride , basic copper sulfate , and sulfur; 3 - amino - 2 -cyano -3 -phenyl - prop -2 -enoate , picarbutra [0394 ] III - F . VIII2 thio - and dithiocarbamates: ferbam , zox , pentyl N - [ 6 - [ [ ( Z ) - [ ( 1 -methyltetrazol - 5 -yl ) mancozeb , maneb , metam , metiram , propineb , thiram , phenyl- methylene ] amino ] oxymethyl] - 2 -pyridyl ] zineb , and ziram ; carbamate , 2 - [ 2 - [ ( 7 , 8 - difluoro - 2 -methyl - 3 - quinolyl) [0395 ] III - F . VIII3 organochlorine compounds from the oxy ] -6 - fluoro - phenyl] propan - 2 - ol, 2 - [ 2 - fluoro - 6 - [ (8 class of phthalimides , sulfamides , and chloronitriles : fluoro - 2 -methyl - 3 - quinolyl ) oxy ]phen - yl] propan - 2 - ol, anilazine , chlorothalonil, captafol, captan , folpet, dichlo 3 - (5 - fluoro - 3 ,3 ,4 , 4 - tetramethyl- 3 , 4 -dihydroisoquino fluanid , dichlorophen , hexachlorobenzene , pentachlo lin - 1- yl) quinoline , 3 - (4 ,4 -difluoro -3 , 3 -dimethyl - 3 , 4 rphenole and its salts , phthalide, tolylfluanid , and N - ( 4 dihydroisoquinolin - 1 -yl ) quinoline , 3 - ( 4 , 4 , 5 - trifluoro chloro - 2 - nitro -phenyl ) - N - ethyl- 4 -methyl 3 , 3 - dimethyl- 3 , 4 - dihydroisoquinolin - 1 - yl) quinoline , benzenesulfonamide; and and 9 - fluoro - 2 , 2 - dimethyl- 5 - ( 3 - quinolyl) -3H - 1 , 4 -ben [0396 ] III - F. VIII4 guanidines and others : guanidine, zoxazepine ; dodine , dodine free base , guazatine , guazatineacetate , [0405 ] in a synergistically effective amount. iminoctadine , iminoctadine- triacetate , iminoctadine - tris [ 0406 ] In a further embodiment of the invention there is (albesilate ) , dithianon , and 2 , 6 - dimethyl- 1H ,5H - [ 1 , 4 ] provided seed , comprising the mixture of the invention in an dithiino [ 2 , 3 - c : 5 , 6 - c ' ] dipyrrole - 1 , 3 , 5 , 7 ( 2H ,6H ) tetraone ; amount of from 0 . 1 g to 100 kg per 100 kg of seeds. [0397 ] III - F. IX Cell wall synthesis inhibitors: [ 0407 ] The invention provides for a pesticidal composi [0398 ] III- F . IX1 inhibitors of glucan synthesis : validamy tion , comprising a liquid or solid carrier and a novel mixture cin , and polyoxin B ; according to the invention . [0399 ] III -F .1X2 melanin synthesis inhibitors: pyroquilon , [ 0408 ] The simultaneous (that is joint or separate appli tricyclazole , carpropamid , dicyclomet, and fenoxanil ; cation of one ormore active compound ( s ) I and one or more [0400 ] III - F .X Plant defence inducers compound ( s ) II and / or III ) , or successive application ( that is [0401 ] III - F . X1 acibenzolar - S -methyl , probenazole , iso immediately one after another and thereby creating the tianil , tiadinil, prohexadione -calcium ; mixture “ in - situ ” on the desired location , as e . g . the plant, of [ 0402 ] III -F .X2 phosphonates: fosetyl, fosetyl- aluminum , one or more active compound ( s ) I and one or more active phosphorous acid and its salts ; potassium or sodium compound ( s ) II and /or III ) allows enhanced control of pests , bicarbonate ; and in particular Pentatomidae pests , and fungi compared to the 10403) III - F .XI Unknown mode of action : control rates that are possible with the individual com [0404 ) bronopol, chinomethionat, cyflufenamid , pounds . cymoxanil, dazomet , debacarb , diclomezine , difenzo [0409 ] The prior art does not disclose pesticidal mixtures quat , difenzoquat- methylsulfate , diphenylamin , fen for the control of Pentatomidae pests , particularly stink pyrazamine , flumetover , flusulfamide, flutianil, metha bugs , comprising such compounds I in combination with the sulfocarb , nitrapyrin , nitrothal- isopropyl, other pesticidically and /or fungicidally active compounds . oxathiapiprolin , tolprocarb , oxin -copper , proquinazid , [0410 ] The compound I of formula (1 ) includes its tau tebufloquin , tecloftalam , triazoxide , 2 -butoxy - 6 - iodo tomers , racemic mixtures, individual pure enantiomers and 3 - propylchromen - 4 -one , 2 - [ 3 , 5 -bis ( difluoromethyl) diasteroemers and the optically active mixtures . US 2019 / 0281835 A1 Sep . 19 , 2019 13

[ 0411 ] Preferred as compound I are bilobalide, ginkgolide [ 0425 ] b ) Ginkgolides : A and a mixture of bilobalide and ginkgolide A . Further preferred are mixtures comprising bilobalide and /or gink golide A and at least one further compound I which is different from bilobalide and ginkgolide A . 0412 ] In one preferred embodiment compound ( I) is LCHE bilobalide . [ 0413 ] In another preferred embodiment compound (I ) is HzCH10 ginkgolide A . [ 0414 ] In another preferred embodiment compound ( 1) is ginkgolide B . 02 [0415 ] In another preferred embodiment compound (I ) is Ginkgolide R R2 R3 CAS ginkgolide C . Ginkgolide A - H OH - H 15291 - 75 - 5 Ginkgolide B - H OH ?? 15291 - 77 - 7 [0416 ] In another preferred embodiment compound ( I) is Ginkgolide C OH OH OH 15291 - 76 - 6 ginkgolide I. Ginkgolide J OH OH - ? 15291 - 79 - 9 Ginkgolide M - OH - H — ?? 15291 - 78 - 8 [ 0417 ] In another preferred embodiment compound (1 ) is ginkgolide M . [0426 ] The above compounds can be used in pure form , as [ 0418 ] In another preferred embodiment compound ( I) is mixtures or in the form of extracts of ginkgo leaves, which may be enriched with the above compounds to a certain a mixture of bilobalide and ginkgolide A . degree . [ 0419 ] In one preferred embodiment compound (I ), pref [0427 ] The compounds are commercially available , or can erably, bilobalide and/ or ginkgolide A , is mixed with one or be obtained , preferably from ginkgo leaves by methods more pesticidally compounds ( II ) , in particular preferred known in the art and described e . g . in U . S . Pat. No . embodiments thereof, in particular the compounds listed in 5 ,700 , 468 , EP - A 360 556 , EP - A 0 431 535 and JP - A Table A and the working examples . 09 - 110713 . [0428 ] Further, the compounds Bilobalide (in enantiopure [ 0420 ] In another preferred embodiment compound (I ) , form ), Ginkgolide A ( in its racemic form ) and Ginkgolide B preferably bilobalide and / or ginkgolide A , is mixed with one ( in its racemic form ) can be obtained by chemical synthesis , or more fungicidally active compounds (III ) , in particular as disclosed e . g . in Tetrahedron Letters ( 1988 ) , 29 ( 28 ) , preferred embodiments thereof, in particular the compounds 3423 - 6 , Tetrahedron Letters ( 1988 ) , 29 ( 26 ) , 3205- 6 and Journal of the American Chemical Society (2000 ) , 122 (35 ), listed in Table A and the working examples . 8453 - 8463 , respectively . [0421 ] In another preferred embodiment compound (I ) , [0429 ) Pesticidal Compounds II [0430 ] The commercially available compounds of the preferably bilobalide and /or ginkgolide A , is mixed with one group M listed above may be found in The Pesticide Manual , or more pesticidally compounds ( II ) , in particular preferred 16th Edition , C . MacBean , British Crop Protection Council embodiments thereof, in particular the compounds in Table ( 2013 ) among other publications . The online Pesticide 1 and the working examples, and with one or more fungi Manual is updated regularly and is accessible through http : / / cidally active compounds ( III ) , in particular preferred bcpcdata . com /pesticide -manual . html . embodiments thereof, in particular the compounds listed in 10431 ] Another online data base for pesticides providing the ISO common names is http : // www .alanwood .net / pesti Table 1 and the working examples . cides . [0422 ] Bilobalide and the ginkgolides are known compo [0432 ] The M . 4 neonicotinoid cycloxaprid is known from WO2010 /069266 and WO2011 / 069456 , the neonicotinoid nents of the ginkgo tree having the following structures: M .4A . 2 , sometimes also to be named as guadipyr, is known [0423 ] a ) Bilobalide: from WO2013 /003977 , and the neonicotinoid M . 4A . 3 ( ap proved as paichongding in China ) is known from WO2007 / 101369 . The metaflumizone analogue M . 22B . 1 is described in CN10171577 and the analogue M . 22B . 2 in 0 HzÇ CH CN102126994 . The phthalamides M . 28 . 1 and M . 28 . 2 are - CH3 both known from WO2007/ 101540 . The anthranilamide VILLOH M . 28 . 3 is described in WO2005/ 077934 . The hydrazide etili - OH compound M .28 . 4 is described in WO2007 /043677 . The anthranilamides M . 28 .5a ) to M . 28 .5d ) and M . 28 . 5h ) are described in WO 2007/ 006670 , WO2013 / 024009 and WO2013 /024010 , the anthranilamide M . 28 . 5i ) is described in WO2011 /085575 , M . 28 . 5j) in WO2008 / 134969, M .28 . 5k ) in US2011 /046186 and M .28 .51 ) in WO2012 /034403 . 10424 ] Bilobalide is the common name for (3a8 ,5aR , SaS , The diamide compound M .28 .6 can be found in WO2012 / 9R ,10aR )- 9 - tert -butyl - 8 , 9 -dihydroxydihydro - 9H - furo [ 2 , 3 034472 . The spiroketal - substituted cyclic ketoenol deriva b ] furo [ 3 ' , 2 ' ; 2 , 3 ]cyclopenta [ 1 , 2 - c ] furan - 2 , 4 , 7 (3H , 8H ) - trione tive M . 29 . 3 is known from WO2006 /089633 and the biphe ( CAS 33570 -04 - 6 ). nyl- substituted spirocyclic ketoenol derivative M .29 .4 from US 2019 / 0281835 A1 Sep . 19 , 2019 14 .

WO2008 / 067911 . The triazoylphenylsulfide M . 29 . 5 is [0439 ] The biopesticides may also have insecticidal , fun described in WO2006 /043635 , and biological control agents gicidal , acaricidal, molluscidal, viricidal, bactericidal , on the basis of Bacillus firmus are described in WO2009 / pheromone, nematicidal, plant defense activator, plant stress 124707 . The compounds M .29 .6a ) to M .29 . 6i ) listed under reducing , plant growth regulator, plant growth promoting , M .29 .6 are described in WO2012 /029672 , and M . 29 .6j ) and plant growth regulator and / or yield enhancing activity . M .29 . 6k ) in WO2013 / 129688 . The nematicide M .29 . 8 is [0440 ] Many of these biopesticides are registered and /or known from WO2013 /055584 . The isoxazoline M .29 . 9 .a ) is are commercially available . E . g . Beauveria bassiana ATCC described in WO2013 /050317 . The isoxazoline M . 29 . 9 . b ) is 74040 (e .g . in Naturalis® from CBC ( Europe ) S .r . l . , Italy ), described in WO2014 / 126208 . The pyridalyl- type analogue B . bassiana DSM 12256 (US 200020031495 ; e . g . Bio Ex M .29 . 10 is known from WO2010 /060379 . The carboxam pert® SC from Live Sytems Technology S . A . , Colombia ) , B . ides broflanilide and M .29 . 11. b ) to M . 29 .11 . h ) are described bassiana GHA (BotaniGard® 22WGP from Laverlam Int. in WO2010 /018714 , and the carboxamides M . 29 . 11i) to Corp ., USA ) , and B . bassiana PPRI 5339 ( ARSEF number M .29 . 11 . p ) in WO2010 / 127926 . The pyridylthiazoles M . 29 . 5339 in the USDA ARS collection of entomopathogenic 12 .a ) to M . 29. 12 . c ) are known from WO2010 / 006713 , fungal cultures ; NRRL 50757 ) ( e . g . BroadBand® from M .29 . 12 . d ) and M .29 . 12 . e ) are known from WO2012 / Becker Underwood , South Africa ). 000896 , and M .29 . 12 .f ) to M .29 .12 .m ) from WO2010 / 129497 . The compounds M .29 . 14a ) and M . 29 . 14b ) are PREFERRED EMBODIMENTS known from WO2007 / 101369 . The pyrazoles M . 29 . 16 . a ) to [0441 ] In one preferred embodiment of the method of the M . 29 . 16h ) are described in WO2010 /034737 , WO2012 / invention the at least one pesticidally active compound II is 084670 , and WO2012 / 143317 , respectively, and the pyra selected from group M consisting of zoles M .29 . 16i) and M .29 . 16j) are described in U . S . 61/ 891 , 10442 ) II - M . 1 Acetylcholine esterase ( AChE ) inhibitors 437 . The pyridinylindazoles M . 29 . 17a ) to M . 29 . 17 .j ) are from the class of described in WO2015 /038503 . The pyridylpyrazoles M . 29 . [0443 ] II -M . 1A carbamates, for example aldicarb , alany 18a ) to M . 29 . 18d ) are described in US2014 /0213448 . The carb , bendiocarb , benfuracarb , butocarboxim , butoxycar isoxazoline M . 29 . 19 is described in WO2014 /036056 . The boxim , carbaryl, carbofuran , carbosulfan , ethiofencarb , isoxazoline M . 29. 20 is known from WO2014 /090918 . fenobucarb , formetanate , furathiocarb , isoprocarb , [ 0433] The biopesticides of group II -L are disclosed fur methiocarb , methomyl, metolcarb , oxamyl, pirimicarb , ther below in the paragraphs about biopesticides II- L ) . propoxur, thiodicarb , thiofanox , trimethacarb , XMC , [0434 ] Fungicidal Compounds III xylylcarb and triazamate ; or from the class of [ 0435 ] The fungicides described by common names, their [0444 ] M . 1B organophosphates, for example acephate, preparation and their activity e . g . against harmful fungi is azamethiphos, azinphos - ethyl, azinphosmethyl, cadusa known (cf . : http :/ /www .alanwood .net /pesticides / ) ; these fos, chlorethoxyfos, chlorfenvinphos, chlormephos, chlo substances are commercially available . rpyrifos , chlorpyrifos -methyl , coumaphos , cyanophos , [ 0436 ] The fungicides described by IUPAC nomenclature , demeton - S -methyl , diazinon , dichlorvos/ DDVP , dicroto their preparation and their pesticidal activity is also known phos , dimethoate , dimethylvinphos, disulfoton , EPN , ( cf. Can . J . Plant Sci. 48 ( 6 ) , 587 - 94 , 1968 ; EP - A 141 317 ; ethion , ethoprophos , famphur, fenamiphos , fenitrothion , EP - A 152 031 ; EP - A226 917 ; EP - A 243 970 ; EP - A 256 503 ; fenthion , fosthiazate, heptenophos, imicyafos , isofen EP - A 428 941 ; EP - A 532 022 ; EP -A1 028 125 ; EP - A 1 035 phos , isopropyl O - methoxyaminothio - phosphoryl) 122 ; EP - A 1 201 648 ; EP - A 1 122 244, JP 2002316902; DE salicylate , isoxathion , malathion , mecarbam , methami 19650197 ; DE 10021412 ; DE 102005009458 ; U . S . Pat . dophos , methidathion , mevinphos, monocrotophos , naled , Nos. 3 ,296 ,272 ; 3, 325 ,503 ; WO 98/ 46608 ; WO 99/ 14187 ; omethoate , oxydemeton -methyl , parathion , parathion WO 99 / 24413 ; WO 99 /27783 ; WO 00 / 29404 ; WO methyl, phenthoate , phorate , phosalone , phosmet, phos 00 / 46148 ; WO 00 /65913 ; WO 01 / 54501 ; WO 01/ 56358 ; phamidon , phoxim , pirimiphos -methyl , profenofos, pro WO 02/ 22583 ; WO 02 /40431 ; WO 03 / 10149 ; WO petamphos, prothiofos, pyraclofos, pyridaphenthion , 03 / 11853 ; WO 03 / 14103 ; WO 03 / 16286 ; WO 03 / 53145 ; quinalphos , sulfotep , tebupirimfos , temephos , terbufos , WO 03 /61388 ; WO 03 /66609 ; WO 03 / 74491 ; WO tetrachlorvinphos, thiometon , triazophos , trichlorfon and 04 /49804 ; WO 04 /83193 ; WO 05 / 120234 ; WO 05 / 123689 ; vamidothion ; WO 05 / 123690 ; WO 05 /63721 ; WO 05 /87772 ; WO [0445 ] II - M . 2 GABA -gated chloride channel antagonists 05 /87773 ; WO 06 / 15866 ; WO 06 /87325 ; WO 06 /87343 ; such as : WO 07 /82098 ; WO 07 / 90624 , WO 11 /028657 , WO2012 / [ 044 ] II- M . 2A cyclodiene organochlorine compounds, as 168188 , WO 2007 / 006670 , WO 2011/ 77514 ; W013 / for example endosulfan or chlordane ; or 047749 , WO 10 /069882 , WO 13 / 047441 , WO 03 / 16303 , [0447 ] II - M .2B fiproles (phenylpyrazoles ), as for example WO 09 / 90181, WO 13 /007767 , WO 13 /010862 , WO ethiprole, fipronil, flufiprole, pyrafluprole and pyriprole ; 13 / 127704 , WO 13 /024009 , WO 13 /024010 and WO [0448 ] M . 3 Sodium channel modulators from the class of 13/ 047441 , WO 13 / 162072, WO 13 /092224 , WO [0449 ] M .34 pyrethroids, for example acrinathrin , 11 / 135833 ) . allethrin , d - cis - trans allethrin , d - trans allethrin , bifenthrin , [0437 ] Biopesticides bioallethrin , bioallethrin S - cylclopentenyl, bioresmethrin , [0438 ] The biopesticides from their preparation and their cycloprothrin , cyfluthrin , beta - cyfluthrin , cyhalothrin , pesticidal activity e . g . against harmful fungi or insects are lambda -cyhalothrin , gamma - cyhalothrin , cypermethrin , known ( e -Pesticide Manual V 5 . 2 ( ISBN 978 1 901396 85 alpha - cypermethrin , beta - cypermethrin , theta -cyper 0 ) (2008 - 2011 ) ; http :/ /www .epa . gov / opp00001/ biopesti methrin , zeta -cypermethrin , cyphenothrin , deltamethrin , cides / , see product lists therein ; http : // www .omri . org/ omril empenthrin , esfenvalerate , etofenprox , fenpropathrin , ists , see lists therein ; Bio - Pesticides Database BPDB http : // fenvalerate, flucythrinate , flumethrin , tau - fluvalinate , hal sitem . herts . ac. uk /aeru / bpdb / , see A to Z link therein ) . fenprox , heptafluthrin , imiprothrin , meperfluthrin , meto US 2019 /0281835 A1 Sep . 19 , 2019 15

fluthrin , momfluorothrin , permethrin , phenothrin , pral- [0480 ] II- M . 13 Uncouplers of oxidative phosphorylation lethrin , profluthrin , pyrethrin (pyrethrum ) , resmethrin , via disruption of the proton gradient, for example chlo silafluofen , tefluthrin , tetramethylfluthrin , tetramethrin , rfenapyr , DNOC or sulfluramid ; tralomethrin and transfluthrin ; or [0481 ] II - M . 14 Nicotinic acetylcholine receptor (nACHR ) [0450 ] M .3B sodium channel modulators such as DDT or channel blockers, for example nereistoxin analogues as methoxychlor; bensultap , cartap hydrochloride , thiocyclam or thiosultap [0451 ] Il -M .4 Nicotinic acetylcholine receptor agonists sodium ; (nACHR ) from the class of [ 0482 ] II - M . 15 Inhibitors of the chitin biosynthesis type 0 , [0452 ] II - M .4A neonicotinoids, for example acetamiprid , such as benzoylureas as for example bistrifluron , chlo chlothianidin , cycloxaprid , dinotefuran , imidacloprid , rfluazuron , diflubenzuron , flucycloxuron , flufenoxuron , nitenpyram , thiacloprid and thiamethoxam ; or the com hexaflumuron , lufenuron , novaluron , noviflumuron , pounds teflubenzuron or triflumuron ; [ 0453 ] II- M .4A . 2 : ( 2E - ) - 1 - [ (6 -Chloropyridin - 3 - yl ) [0483 ] II - M . 16 Inhibitors of the chitin biosynthesis type 1 , methyl] -N '- nitro -2 -pentylidenehydrazinecarboximid as for example buprofezin ; amide ; or [ 0484 ] II- M . 17 Moulting disruptors , Dipteran , as for [0454 ] II - M .4A .3 : 1- [( 6 - Chloropyridin - 3 -yl ) methyl ] - 7 example cyromazine; methyl - 8 - nitro - 5 - propoxy - 1, 2 , 3 , 5 , 6 , 7 -hexahydroimidazo [0485 ) II - M . 18 Ecdyson receptor agonists such as diacyl [ 1 , 2 - a ]pyridine ; or from the class hydrazines , for example methoxyfenozide , tebufenozide , [0455 ] Il - M .4B nicotine ; halofenozide , fufenozide or chromafenozide ; [0456 ] II -M . 5 Nicotinic acetylcholine receptor allosteric [0486 ] II - M . 19 Octopamin receptor agonists , as for activators from the class of spinosyns, for example example amitraz ; spinosad or spinetoram ; [0487 ] II - M .20 Mitochondrial complex III electron trans [0457 ] Il - M .6 Chloride channel activators from the class port inhibitors , for example of avermectins and milbemycins, for example abamectin , [0488 ] II -M .20A hydramethylnon , or emamectin benzoate , ivermectin , lepimectin or milbe [ 0489 ] II- M . 20B acequinocyl, or mectin ; [ 0490 ] II- M . 20C fluacrypyrim ; [ 0458 ] II- M .7 Juvenile hormone mimics , such as [0491 ] II- M .21 Mitochondrial complex I electron trans [0459 ] II- M .7A juvenile hormone analogues as hydro port inhibitors , for example prene , kinoprene and methoprene ; or others as [0492 ] II - M .21A METI acaricides and insecticides such as [0460 ] II - M .7B fenoxycarb , or fenazaquin , fenpyroximate, pyrimidifen , pyridaben , [0461 ] II - M .7C pyriproxyfen ; tebufenpyrad or tolfenpyrad , or [ 0462 ] II - M . 8 miscellaneous non -specific (multi - site ) [0493 ] 11 - M .21B rotenone ; inhibitors , for example [ 0494 ] II- M . 22 Voltage - dependent sodium channel block [0463 ] II - M .8A alkyl halides as methyl bromide and other ers , for example alkyl halides , or [0495 ] II - M .22A indoxacarb , or [ 0464 ] II - M . 8B chloropicrin , or [0496 ) II - M .22B metaflumizone, or [0497 ] II- M .22B .1 : 2 -[ 2 -( 4 -Cyanophenyl ) - 1 -[ 3- (trifluo [ 0465 ] II- M . 8C sulfuryl fluoride, or romethyl) phenyl ] ethylidene ] - N - [ 4 - ( difluoromethoxy ) [0466 ] Il - M .8D borax , or phenyl] - hydrazinecarboxamide or [ 0467 ] II- M .8E tartar emetic ; [ 0498 ] II- M . 22B . 2 : N - ( 3 - Chloro - 2 -methylphenyl ) - 2 - [ (4 [0468 ] II - M . 9 Selective homopteran feeding blockers , for chlorophenyl) [ 4 - [methyl (methylsulfonyl ) amino ] phenyl] example methylene] -hydrazinecarboxamide ; [0469 ] II - M . 9B pymetrozine , or [0499 ] II- M .23 Inhibitors of the of acetyl COA carboxy 0470 ] II- M . 9C flonicamid ; lase , such as tetronic and tetramic acid derivatives, for [0471 ] II - M . 10 Mite growth inhibitors , including example spirodiclofen , spiromesifen or spirotetramat; 10472 ] II - M . 10A clofentezine , hexythiazox and 105001 II - M . 24 Mitochondrial complex IV electron trans diflovidazin , or port inhibitors , for example [0473 ] II - M . 10B etoxazole ; [0501 ] II- M .24A phosphine such as aluminium phosphide , [0474 ] Il - M .11 Microbial disruptors of insect midgut calcium phosphide , phosphine or zinc phosphide, or membranes , for example Bacillus thuringiensis or Bacil [ 0502] II - M . 24B cyanide ; lus sphaericus and the insecticdal proteins they produce [ 0503 ] II- M . 25 Mitochondrial complex II electron trans such as Bacillus thuringiensis subsp . israelensis , Bacillus port inhibitors , such as beta -ketonitrile derivatives, for sphaericus , Bacillus thuringiensis subsp . aizawai and example cyenopyrafen or cyflumetofen ; Bacillus thuringiensis subsp . tenebrionis , or the Bt crop (0504 ] II - M . 28 Ryanodine receptor -modulators from the proteins: Cry1Ab , Cry1Ac , Cry1Fa , Cry2Ab , mCry3A , class of diamides, as for example flubendiamide , chlo Cry3Ab , Cry3Bb and Cry34 /35Abl ; rantraniliprole (Rynaxypyr® ) , cyantraniliprole (Cyazy [0475 ] II - M . 12 Inhibitors of mitochondrial ATP synthase , pyr® ) , or the phthalamide compounds for example [0505 ] II - M . 28 . 1 : ( R ) - 3 -Chlor - N1 - { 2 -methyl - 4 - [ 1 , 2 , 2 , 2 [0476 ] Il - M .12A diafenthiuron , or tetrafluor- 1 - (trifluormethyl ) ethyl] phenyl} - N2 -( 1 -methyl [0477 ] II - M . 12B organotin miticides such as azocyclotin , 2 -methylsulfonylethyl ) phthalamid and cyhexatin or fenbutatin oxide , or [0506 ] Il - M . 28 . 2 : ( S ) - 3 - Chlor -N1 - 2 -methyl - 4 - [ 1 , 2 , 2 , 2 [0478 ] II - M . 12C propargite , or tetrafluor - 1 - ( trifluormethyl) ethyl] phenyl) -N2 - ( 1 -methyl [0479 ] II- M . 12D tetradifon ; 2 -methylsulfonylethyl ) phthalamid , or the compound US 2019 / 0281835 A1 Sep . 19 , 2019

[ 0507 ] II - M . 28 . 3 : 3 - bromo- N - { 2 - bromo - 4 - chloro -6 - [ ( 1 nat, cryolite , dicofol, flufenerim , flometoquin , fluensul cyclopropylethyl) carbamoyl] phenyl ) - 1 -( 3 - chlorpyridin fone , fluopyram , flupyradifurone , fluralaner , metoxadiaz 2 - yl) - 1H - pyrazole - 5 - carboxamide ( proposed ISO name: one , piperonyl butoxide , pyflubumide , pyridalyl , cyclaniliprole) , or the compound pyrifluquinazon , sulfoxaflor, tioxazafen , triflumezopyrim , [0508 ] II - M .28 . 4 : methyl- 2 - [ 3 , 5 - dibromo- 2 - ( { [ 3 -bromo or the compounds 1 -( 3 -chlorpyridin -2 - yl) - 1H -pyrazol - 5 -yl ] [0528 ] II - M .UN . 3 : 11 - ( 4 - chloro - 2 , 6 - dimethylphenyl) - 12 carbonyl} amino ) benzoyl ]- 1 , 2 - dimethylhydrazinecar hydroxy - 1 , 4 -dioxa - 9 - azadispiro [ 4 . 2 . 4 . 2 ] - tetradec - 11 - en boxylate ; 10 - one, or the compound [0509 ] or a compound selected from M .28 . 5a ) to M . 28 . 51) : (0529 ] II- M .UN . 4 : 3 - ( 4 ' - fluoro - 2 , 4 - dimethylbiphenyl- 3 [0510 ] II - M .28 .5a ) N - [ 4 , 6 -dichloro - 2 - [ (diethyl - lambda - 4 yl) -4 -hydroxy -8 -oxa - 1 -azaspiro [ 4 .5 ]dec -3 -en -2 -one , or sulfanylidene ) carbamoyl] -phenyl ] - 2 - ( 3 - chloro - 2 the compound pyridyl) - 5 - ( trifluoromethyl )pyrazole - 3 - carboxamide ; [0530 ] II - M .UN . 5 : 1 - [ 2 - fluoro - 4 -methyl - 5 - [ ( 2 , 2 , 2 -trifluo [0511 ] Il - M . 28 . 5b ) N - [ 4 - chloro - 2 - [ (diethyl - lambda - 4 - sul roethyl) sulfinyl ] phenyl ] - 3 -( trifluoromethyl) - 1H - 1 ,2 , 4 - tri fanylidene )carbamoyl ] -6 -methyl - phenyl ] - 2 -( 3 -chloro - 2 azole - 5 -amine ; or a compound selected from the group of pyridyl) - 5 - ( trifluoromethyl) pyrazole - 3 - carboxamide ; M .UN . 6 , wherein the compound is selected from M .UN . [ 0512 ] II - M .28 .5c ) N - [4 - chloro - 2 -[ (di - 2- propyl - lambda 6a ) to M .UN .6k ) : 4 - sulfanylidene ) carbamoyl ]- 6 -methyl - phenyl ] - 2 - ( 3 [0531 ] II - M .UN .6a ) ( E /Z )- N - [ 1- [ (6 -chloro - 3 -pyridyl ) chloro - 2 -pyridyl ) - 5 - ( trifluoromethyl) pyrazole - 3 - carbox methyl] -2 -pyridylidene ] -2 , 2, 2 -trifluoro - acetamide ; amide ; [0532 ] II - M .UN .6b ) ( E / Z ) - N - [ 1 - [ (6 - chloro - 5 - fluoro - 3 [ 0513] II - M . 28 . 5d ) N - [ 4 ,6 - dichloro - 2 - [ ( di- 2 -propyl pyridyl) methyl ) - 2 - pyridylidene )- 2 ,2 ,2 - trifluoro -acet lambda - 4 - sulfanylidene ) carbamoyl] -phenyl ] - 2 - ( 3 - chloro amide ; 2 - pyridyl ) - 5 - ( trifluoromethyl) pyrazole - 3 - carboxamide ; [0533 ] II - M .UN .6c ) ( E / Z ) - 2 , 2 , 2 - trifluoro - N - [ 1 - [ (6 - fluoro [ 0514 ] II - M . 28 . 5e ) N - [ 4 , 6 -dichloro - 2 - [ (diethyl - lambda - 4 3 -pyridyl ) methyl ) - 2 -pyridylidene ] acetamide; sulfanylidene ) carbamoyl] - phenyl] - 2 - ( 3 -chloro - 2 [ 0534 ] II - M .UN .6d ) ( E / Z ) - N - [ 1 - [ (6 - bromo - 3 - pyridyl ) pyridyl ) - 5 - ( difluoromethyl) pyrazole - 3 - carboxamide; methyl] - 2 -pyridylidene )- 2 , 2 , 2 - trifluoro - acetamide ; [0515 ] II -M . 28 .5f ) N -[ 4, 6 -dibromo -2 -[ ( di -2 -propyl [0535 ] II - M .UN .6e ) ( E / Z ) -N - [1 -[ 1 -( 6 -chloro - 3 -pyridyl ) lambda - 4 - sulfanylidene ) carbamoyl ] -phenyl ] - 2 - ( 3 -chloro ethyl) - 2 -pyridylidene ) -2 , 2, 2 - trifluoro - acetamide; 2 - pyridyl) - 5 - (trifluoromethyl ) pyrazole - 3 -carboxamide ; [ 0536 ] II - M .UN .6f ) ( E / Z ) - N - [ 1 - [ (6 - chloro - 3 - pyridyl ) [ 0516 ] II - M . 28 . 5g ) N - [ 4 - chloro - 2 - [ ( di- 2 - propyl -lambda methyl) - 2 - pyridylidene ] - 2 , 2 - difluoro - acetamide ; 4 - sulfanylidene )carbamoyl ] -6 -cyano -phenyl ]- 2 -( 3 [0537 ] II - M .UN .6g ) ( E / Z ) - 2 - chloro - N - [ 1 - [ (6 - chloro - 3 chloro - 2 -pyridyl ) - 5 - ( trifluoromethyl) pyrazole - 3 - carbox pyridyl )methyl ] - 2 -pyridylidene ) - 2 , 2 - difluoro - acetamide ; amide ; [0538 ] Il - M .UN .6h ) ( E / Z ) - N - [ 1 - [ ( 2 - chloropyrimidin - 5 [0517 ] II - M .28 .5h ) N -[ 4 ,6 -dibromo - 2 -[ ( diethyl - lambda -4 yl) methyl ] - 2 -pyridylidene ) - 2 , 2 , 2 - trifluoro -acetamide ; sulfanylidene ) carbamoyl] -phenyl ] - 2 - ( 3 - chloro - 2 [ 0539 ] II- M .UN . 6i) ( E / Z ) - N - [ 1 - [ (6 - chloro - 3 - pyridyl) pyridyl) -5 - (trifluoromethyl ) pyrazole - 3 -carboxamide ; methyl] - 2 -pyridylidene ] - 2 , 2 , 3 , 3 , 3 -pentafluoropropana [0518 ] II - M . 28 .5i ) N -[ 2 -( 5 - Amino - 1 ,3 , 4 -thiadiazol - 2 -yl ) mide . ) ; 4 - chloro - 6 -methylphenyl ] - 3 -bromo - 1 - ( 3 - chloro - 2 -pyridi [0540 ] II - M .UN .6j ) N - [ 1 - [ ( 6 -chloro - 3 - pyridyl )methyl ] - 2 nyl) - 1H -pyrazole - 5 -carboxamide ; pyridylidene] - 2 , 2 , 2 - trifluoro - thioacetamide or of the [0519 ] II - M . 28 . 5j) 3 -Chloro - 1 - ( 3 - chloro - 2 -pyridinyl ) - N compound [2 ,4 -dichloro -6 - [[ ( 1 -cyano - 1 -methylethyl ) amino ]carbo [ 0541 ] II- M .UN . 6k ) N - [ 1 - [ (6 - chloro - 3 -pyridyl ) methyl ) - 2 nyl] phenyl ]- 1H -pyrazole - 5 -carboxamide ; pyridylidene ] -2 , 2 ,2 - trifluoro - N '- isopropyl - acetamidine or [0520 ] II - M .28 .5k ) 3 - Bromo - N - [ 2 , 4 - dichloro -6 - (methyl the compounds carbamoyl) phenyl] - 1 - ( 3 , 5 -dichloro - 2 - pyridyl ) - 1H -pyra [0542 ] Il - M .UN . 8 : 8 - chloro - N - [ 2 - chloro - 5 -methoxyphe zole - 5 -carboxamide ; nyl) sulfonyl] -6 - trifluoromethyl) - imidazo [ 1 , 2 - a ]pyridine [ 0521 ] II - M . 28 . 51) N - [ 4 - Chloro - 2 - [ [ ( 1 , 1 - dimethylethyl) 2 -carboxamide ; or amino ]carbonyl ] -6 -methylphenyl ] -1 - (3 -chloro - 2- pyridi - [0543 ] II- M .UN .9 : 4 - [5 -( 3 ,5 -dichlorophenyl ) - 5 - ( trifluo nyl) - 3 -( fluoromethoxy )- 1H -pyrazole -5 -carboxamide ; romethyl) -4H - isoxazol- 3 - yl) - 2 -methyl - N - ( 1 -oxothietan [0522 ] or a compound selected from 3 - yl) benzamide ; or [0523 ] II - M . 28 .6 : N - ( 2 - cyanopropan - 2 -yl ) - N - ( 2 , 4 - dim [0544 ] II - M .UN . 10 : 5 - [3 - [2 ,6 -dichloro -4 - ( 3, 3 -dichloroal ethylphenyl) - 3 - iodobenzene - 1 , 2 -dicarboxamide ; or lyloxy )phenoxy ]propoxy ) - 1H -pyrazole ; or a compound [ 0524 ] II- M . 28. 7 : 3 -Chloro - N - ( 2 - cyanopropan - 2 - yl) - N selected from the group of M .UN . 12 , wherein the com ( 2 , 4 - dimethylphenyl) -benzene - 1 , 2 -dicarboxamide ; pound is selected from M .UN . 12a ) to M .UN . 12m ) : [0525 ] Il - M .28 .8a ) 1- ( 3 - Chloro - 2 -pyridinyl ) - N - [4 -cyano [0545 ] II- M .UN . 12 .a ) 2 -( 1, 3 -Dioxan - 2 -yl ) -6 - [2 - (3 -pyridi 2 -methyl - 6 - [ (methylamino )carbonyl ] phenyl ] - 3 - [ [ 5 - ( trif nyl) - 5 - thiazolyl] - pyridine ; luoromethyl) -2H - tetrazol - 2 -yl ] methyl ] - 1H -pyrazole - 5 [0546 ] II -M .UN .12 . b ) 2 -[ 6 -[ 2 - (5 - Fluoro - 3 -pyridinyl ) - 5 carboxamide (proposed ISO name: tetraniliprole ); or thiazolyl) - 2 - pyridinyl] -pyrimidine ; [ 0526 ] II - M . 28 . 8b ) 1 - ( 3 - Chloro - 2 -pyridinyl ) - N - [ 4 - cyano [ 0547 ] II- M .UN . 12 . c ) 2 - [ 6 - [ 2 - ( 3 -Pyridinyl ) - 5 - thiazolyl] 2 -methyl - 6 - [ (methylamino ) carbonyl] phenyl ] - 3 - [ [ 5 - ( trif - 2 -pyridinyl ] -pyrimidine ; luoromethyl) - 1H - tetrazol -1 -yl ] methyl ] - 1H -pyrazole - 5 - (0548 ] II- M .UN .12 . d ) N -M ethylsulfonyl -6 -[ 2 -( 3 -pyridyl ) carboxamide ; thiazol- 5 -yl ) pyridine -2 - carboxamide [0527 ] II- M .UN Insecticidally active compounds of [ 0549 ] II -M .UN . 12 . e) N -M ethylsulfonyl- 6 - [2 - (3 -pyridyl ) unknown or uncertain mode of action , as for example thiazol - 5 -yl ] pyridine - 2 - carboxamide afidopyropen , afoxolaner , azadirachtin , amidoflumet , [ 0550 ) II - M .UN . 12 .f ) N - Ethyl- N - [ 4 -methyl - 2 - ( 3 - pyridyl ) benzoximate , bifenazate , bromopropylate , chinomethio thiazol- 5 - yl) - 3 -methylthio - propanamide US 2019 / 0281835 A1 Sep . 19 , 2019 17

[0551 ] II- M .UN .12 . g ) N -Methyl - N -[ 4 -methyl -2 -( 3 methyl, mandestrobine, metominostrobin , orysastrobin , pyridyl) thiazol- 5 - yl] - 3 -methylthio -propanamide picoxystrobin , pyraclostrobin , pyrametostrobin , pyraox [0552 ] Il - M .UN . 12 .h ) N ,2 -Dimethyl - N - [4 -methyl - 2 -( 3 ystrobin , trifloxystrobin and 2 - ( 2 - ( 3 - ( 2 , 6 - dichlorophe pyridyl) thiazol - 5 -yl ] - 3 -methylthio -propanamide nyl) - 1 -methyl -allylideneaminooxymethyl )- phenyl )- 2 [ 0553 ] II- M .UN . 12. i) N - Ethyl- 2 -methyl - N - [ 4 -methyl - 2 methoxyimino - N -methyl - acetamide , pyribencarb , ( 3 -pyridyl ) thiazol- 5 -yl ] - 3 -methylthio - propanamide triclopyricarb /chlorodincarb , famoxadone , fenamidone; (0554 ] II - M .UN . 12 . j ) N - [ 4 - Chloro - 2 - ( 3 -pyridyl ) thiazol- 5 [0569 ] F .I 2 ) inhibitors of complex III at Q ; site : cyazof yl] - N - ethyl - 2 -methyl - 3 -methylthio - propanamide amid , amisulbrom , [( 38 ,68 ,7R ,8R )- 8 -benzyl - 3 -[ ( 3 -ac [0555 ] II -M .UN .12 . k ) N -[ 4 - Chloro - 2- (3 -pyridyl )thiazol etoxy - 4 -methoxy - pyridine - 2 - carbonyl) amino ] -6 -methyl 5 - yl] - N , 2 -dimethyl - 3 -methylthio - propanamide 4 , 9 -dioxo - 1 , 5 - dioxonan - 7 - yl] 2 -methylpropanoate , [ (3S , [0556 ] II -M .UN .12 . 1) N -[ 4 -Chloro -2 - (3 - pyridyl )thiazol - 5 65 ,7R ,8R )- 8 -benzyl - 3 - [[ 3 -( acetoxymethoxy )- 4 -methoxy yl ]- N -methyl - 3 - methylthio -propanamide pyridine - 2 - carbonyl ] amino ] -6 -methyl - 4 , 9 - dioxo - 1 , 5 [ 0557 ] II- M .UN . 12 . m ) N - [ 4 -Chloro - 2 - ( 3 - pyridyl ) thiazol dioxonan - 7 - yl] 2 -methylpropanoate , [ ( 35 ,68 ,7R ,8R ) - 8 5 - yl] - N - ethyl- 3 -methylthio - propanamide; or the com benzyl - 3 - [ ( 3 - isobutoxycarbonyloxy - 4 -methoxy -pyridine pound 2 - carbonyl) amino ] -6 -methyl - 4 , 9 - dioxo - 1 , 5 -dioxonan - 7 [0558 ] II -M .UN .13 : 2 -( 4 -methoxyiminocyclohexyl )- 2 -( 3 , yl] 2 -methylpropanoate , [ ( 35 ,6S , 7R , 8R ) - 8 -benzyl - 3 - [ [ 3 3 ,3 -trifluoropropylsulfonyl )acetonitrile ; or the com ( 1 ,3 -benzodioxol - 5 -ylmethoxy )- 4 -methoxy -pyridine -2 pounds carbonyl ] amino ] -6 - methyl- 4 , 9 - dioxo - 1 , 5 -dioxonan - 7 -yl ] [ 0559 ] II - M .UN . 14a ) 1 - [ (6 -Chloro - 3 - pyridinyl) methyl ) - 1 , 2 -methylpropanoate ; (35 ,6S ,7R , 8R ) -3 - [[ ( 3 -hydroxy - 4 2 , 3 , 5 , 6 , 7 - hexahydro - 5 -methoxy - 7 -methyl - 8 - nitro - imi methoxy -2 -pyridinyl ) carbonyl ]amino ]- 6 -methyl - 4 ,9 -di dazo [ 1 , 2 - a ]pyridine ; or oxo - 8 -( phenylmethyl ) - 1, 5 -dioxonan -7 - yl 2 -methylpro [0560 ] II - M .UN . 14b ) 1- [( 6 -Chloropyridin -3 -yl )methyl ] panoate ; 7 -methyl -8 -nitro - 1 ,2 ,3 ,5 ,6 , 7- hexahydroimidazo [1 ,2 - a ] [0570 ] F . I 3 ) inhibitors of complex II (e . g . carboxamides ): pyridin - 5 -ol ; or the compound benodanil, benzovindiflupyr, bixafen , boscalid , carboxin , [0561 ] II -M .UN . 15 : 1 - [( 2 -Chloro - 1, 3 -thiazol - 5 -yl ) fenfuram , fluopyram , flutolanil , fluxapyroxad , furamet methyl] - 3 - ( 3 , 5 - dichlorophenyl) - 9 -methyl - 4 -oxo - 4H pyr, isofetamid , isopyrazam ,mepronil , oxycarboxin , pen pyrido [ 1, 2 - a ]pyrimidin - 1 - ium - 2 -olate ; or flufen , penthiopyrad , sedaxane , tecloftalam , thifluzamide , [0562 ] Il - M .BP Biopesticides , being pesticidal com N - ( 4 -trifluoromethylthiobiphenyl - 2 - yl) - 3 - difluorom pounds of biological origin with insecticidal , acaricidal, ethyl- 1 -methyl - 1H -pyrazole - 4 - carboxamide , N - ( 2 - ( 1 , 3 , 3 molluscidal and/ or nematicidal activity , including trimethyl- butyl ) -phenyl ) - 1 , 3 -dimethyl - 5 - fluoro - 1H -pyra [0563 ] II - M .BP - 1 : Microbial pesticides: Bacillus firmus, zole - 4 - carboxamide , 3 - ( difluoromethyl) - 1 -methyl - N - ( 1 , B . thuringiensis ssp . israelensis , B . t . ssp . galleriae , B . t . 1 , 3 - trimethylindan - 4 - yl) pyrazole - 4 - carboxamide , ssp . kurstaki , Beauveria bassiana , Burkholderia sp ., 3 - ( trifluoromethyl) - 1 -methyl - N - ( 1 , 1 , 3 - trimethylindan - 4 Chromobacterium subtsugae, Cydia pomonella granulo yl) pyrazole - 4 - carboxamide , 1 , 3 -dimethyl - N - ( 1 , 1 , 3 - trim sis virus , Isaria fumosorosea , Lecanicillium longisporum , ethylindan - 4 - yl) pyrazole- 4 - carboxamide, 3 - (trifluorom L . muscarium (formerly Verticillium lecanii ), Metarhi ethyl) - 1 , 5 - dimethyl- N - ( 1 , 1 , 3 - trimethylindan - 4 - yl) zium anisopliae , M . anisopliae var. acridum , Paecilomy pyrazole - 4 -carboxamide , 1 , 3 , 5 - trimethyl- N - ( 1 , 1 , 3 ces fumosoroseus, P . lilacinus , Paenibacillus poppiliae , trimethylindan - 4 - yl) pyrazole - 4 -carboxamide , N - ( 7 Pasteuria spp ., P . nishizawae , P . reneformis , P . usagae , fluoro -1 , 1 ,3 - trimethyl- indan -4 - yl) -1 , 3 -dimethyl Pseudomonas fluorescens, Steinernema feltiae , Streptom pyrazole -4 -carboxamide , N - [ 2 - (2 , 4 - dichlorophenyl) - 2 ces galbus ; or methoxy - 1- methyl - ethyl] -3 - (difluoromethyl ) - 1 [0564 ] II - M .BP - 2 : Biochemical pesticides: L - carvone , methylpyrazole -4 -carboxamide , N - [2 - ( 2, 4 citral, ( E , Z ) - 7 , 9 - dodecadien - 1 - yl acetate, ethyl formate , difluorophenyl) phenyl ] - 3 - ( trifluoromethyl) pyrazine - 2 ( E , Z ) - 2 , 4 - ethyl decadienoate (pear ester ), ( Z , Z , E ) - 7 , 11 , carboxamide ; 13 - hexadecatrienal, heptyl butyrate , isopropyl myristate , [ 0571 ] F . I 4 ) other respiration inhibitors ( e . g . complex I , lavanulyl senecioate , 2 -methyl 1 - butanol, methyl euge uncouplers ) : diflumetorim , ( 5 , 8 - difluoroquinazolin - 4 - yl) nol, methyl jasmonate , ( E , Z ) - 2 ,13 -octadecadien - 1 - ol, { 2 - [ 2 - fluoro - 4 - ( 4 - trifluoromethylpyridin - 2 - yloxy ) - phe ( E , Z ) - 2 , 13 - octadecadien - 1 -ol acetate , ( E , Z ) - 3 , 13 - octa nyl] -ethyl ) -amine ; nitrophenyl derivates: binapacryl, decadien - 1 - ol, R - 1 - octen - 3 - ol, pentatermanone, potas dinobuton , dinocap , fluazinam ; ferimzone ; organometal sium silicate , sorbitol actanoate , ( E , Z , Z ) - 3 , 8 , 11 - tetrade compounds : fentin salts , such as fentin - acetate , fentin catrienyl acetate , ( Z , E ) - 9 , 12 - tetradecadien - 1 - yl acetate , chloride or fentin hydroxide ; ametoctradin ; and silthio Z -7 - tetradecen -2 -one , Z - 9 -tetradecen - 1 -yl acetate , Z - 11 fam ; tetradecenal, Z - 11 - tetradecen - 1 -ol , Acacia negra extract , [0572 ] F .II ) Sterol biosynthesis inhibitors (SBI fungicides) extract of grapefruit seeds and pulp , extract of Chenopo [0573 ] F . II 1 ) C14 demethylase inhibitors (DMI fungi dium ambrosiodae, Catnip oil , Neem oil , Quillay extract , cides ) : triazoles: azaconazole , bitertanol, bromuconazole , Tagetes oil, cyproconazole , difenoconazole , diniconazole , dinicon [ 0565 ] and / or azole - M , epoxiconazole , fenbuconazole , fluquinconazole , [0566 ] the at least one fungicidally active compound III is flusilazole , flutriafol, hexaconazole , imibenconazole , selected from group F consisting of: ipconazole , metconazole , myclobutanil , oxpoconazole , [0567 ] F . I ) Respiration inhibitors paclobutrazole, penconazole , propiconazole , prothiocon [0568 ] F .I 1 ) Inhibitors of complex III at le site (e . g . azole , simeconazole , tebuconazole , tetraconazole , triadi strobilurins ): azoxystrobin , coumethoxystrobin , coumox mefon , triadimenol, triticonazole , uniconazole, 1 - [ rel ystrobin , dimoxystrobin , enestroburin , fenaminstrobin , (2S ; 3R ) - 3 - ( 2 - chlorophenyl) - 2 - ( 2 ,4 -difluorophenyl ) fenoxystrobin / flufenoxystrobin , fluoxastrobin , kresoxim oxiranylmethyl) - 5 -thiocyanato - 1H [ 1 ,2 , 4 ]triazole , 2 - [rel US 2019 / 0281835 A1 Sep . 19 , 2019

(2S , 3R ) - 3 - ( 2 -chlorophenyl ) - 2 - ( 2 , 4 - difluorophenyl) [0592 ] F .VII 4 ) compounds affecting cell membrane per oxiranylmethyl] -2H - [ 1 , 2 , 4 ] triazole - 3 - thiol, 2 - [ 2 -chloro meability and fatty acides: propamocarb , propamocarb 4 - ( 4 - chlorophenoxy ) phenyl] - 1 - ( 1, 2 , 4 - triazol- 1 - yl) hydrochlorid ; pentan - 2 - ol, 1 - [ 4 - ( 4 - chlorophenoxy ) - 2 - ( trifluoromethyl ) [0593 ] F .VII 5 ) fatty acid amide hydrolase inhibitors : phenyl ]- 1 -cyclopropyl - 2 -( 1 ,2 , 4 - triazol- 1 -yl ) ethanol, oxathiapiprolin ; 2 - [ 4 - ( 4 - chlorophenoxy ) - 2 - ( trifluoromethyl) phenyl ] - 1 - ( 1 , [ 0594 ] F . VIII ) Inhibitors with Multi Site Action 2 , 4 - triazol- 1 -yl ) butan - 2 -ol , 2 - [ 2 -chloro - 4 - ( 4 - chlorophe [ 0595 ] F . VIII 1 ) inorganic active substances : Bordeaux noxy ) phenyl] - 1 - ( 1 , 2 , 4 -triazol - 1 - yl) butan - 2 - ol , 2 -[ 4 - ( 4 mixture , copper acetate , copper hydroxide , copper oxy chlorophenoxy ) - 2 - ( trifluoromethyl) phenyl ] - 3 -methyl - 1 chloride , basic copper sulfate , sulfur ; ( 1 , 2 ,4 - triazol - 1 - yl) butan - 2 - 01, 2 - [ 4 - ( 4 - chlorophenoxy ) - 2 [0596 ] F . VIII 2 ) thio - and dithiocarbamates: ferbam , man ( trifluoromethyl) phenyl] - 1 - ( 1 , 2 , 4 - triazol - 1 - yl) propan - 2 cozeb , maneb , metam , metiram , propineb , thiram , zineb , ol, 2 - [2 - chloro -4 - (4 -chlorophenoxy )phenyl ] -3 -methyl - 1 ziram ; ( 1, 2 ,4 - triazol- 1- yl) butan - 2 - ol, 2 - [ 4 -( 4 - chlorophenoxy ) - 2 [0597 ] F . VIII 3 ) organochlorine compounds ( e . g . phthal ( trifluoromethyl) phenyl ]- 1 - ( 1 , 2 , 4 - triazol - 1 - yl) pentan - 2 imides, sulfamides , chloronitriles ) : anilazine , chlorotha ol, 2 - [4 - (4 - fluorophenoxy )- 2 -( trifluoromethyl) phenyl ] - 1 lonil , captafol , captan , folpet , dichlofluanid , dichloro ( 1 , 2 , 4 - triazol- 1 - yl) propan - 2 - ol; imidazoles : imazalil, phen , hexachlorobenzene, pentachlorphenole and its salts , pefurazoate , prochloraz , triflumizol; pyrimidines, pyri phthalide , tolylfluanid , N - ( 4 - chloro - 2 -nitro -phenyl ) - N dines and piperazines : fenarimol, nuarimol, pyrifenox , ethyl- 4 -methyl - benzenesulfonamide ; triforine, [ 3 - ( 4 - chloro - 2 - fluoro -phenyl ) - 5 - ( 2 , 4 -difluoro [0598 ] F .VIII 4 ) guanidines and others : guanidine , dodine , phenyl) isoxazol- 4 - yl] - (3 -pyridyl ) methanol ; dodine free base , guazatine , guazatineacetate , iminocta [0574 ] F. II 2 ) Delta14 -reductase inhibitors : aldimorph , dine , iminoctadine - triacetate , iminoctadine - tris ( albesi dodemorph , dodemorph - acetate, fenpropimorph , tride late ) , dithianon , 2 ,6 - dimethyl - 1H ,5H - [ 1 , 4 ] dithiino [ 2 , 3 - c : morph , fenpropidin , piperalin , spiroxamine ; 5 , 6 - c ' ] dipyrrole - 1 , 3 , 5 , 7 ( 2H ,6H ) - tetraone ; [0575 ] F . II 3 ) Inhibitors of 3 -keto reductase : fenhexamid ; [0599 ] F. IX ) Cell wall synthesis inhibitors [ 0576 ] F . III) Nucleic acid synthesis inhibitors [ 0600 ] F . IX 1 ) inhibitors of glucan synthesis : validamycin , [ 0577 ] F .III 1) phenylamides or acyl amino acid fungi polyoxin B ; cides: benalaxyl, benalaxyl- M , kiralaxyl, metalaxyl, [0601 ] F .IX 2 ) melanin synthesis inhibitors : pyroquilon , metalaxyl- M ( mefenoxam ) , ofurace , oxadixyl; tricyclazole , carpropamid , dicyclomet, fenoxanil ; [ 0578 ] F . III 2 ) others : hymexazole , octhilinone , oxolinic [0602 ] F . X ) Plant defence inducers acid , bupirimate , 5 - fluorocytosine , 5 - fluoro - 2 - ( p - tolyl [0603 ] F . X 1 ) acibenzolar - S -methyl , probenazole, iso methoxy ) pyrimidin - 4 - amine, 5 - fluoro - 2 - ( 4 - fluorophenyl tianil , tiadinil, prohexadione - calcium ; methoxy )pyrimidin - 4 -amine ; [0604 ] F . X 2 ) phosphonates: fosetyl, fosetyl- aluminum , [ 0579 ] F . IV ) Inhibitors of cell division and cytoskeleton phosphorous acid and its salts , 4 - cyclopropyl- N - ( 2 , 4 [0580 ] F . IV 1 ) tubulin inhibitors, such as benzimidazoles , dimethoxyphenyl) thiadiazole - 5 - carboxamide ; thiophanates: benomyl, carbendazim , fuberidazole , thi 10605 ] F . XI) Unknown mode of action abendazole , thiophanate -methyl ; triazolopyrimidines: [ 0606 ] bronopol, chinomethionat, cyflufenamid , cymoxa 5 - chloro - 7 - ( 4 -methylpiperidin - 1 - yl) - 6 - ( 2 , 4 ,6 -trifluoro nil, dazomet , debacarb , diclomezine, difenzoquat , difen phenyl) -[ 1 , 2 , 4 ] triazolo [ 1 , 5 - a ] pyrimidine ; zoquat -methylsulfate , diphenylamin , fenpyrazamine , flu [ 0581 ] F . IV 2 ) other cell division inhibitors : diethofen metover, flusulfamide , flutianil , methasulfocarb , carb , ethaboxam , pencycuron , fluopicolide, zoxamide , nitrapyrin , nitrothal- isopropyl , oxathiapiprolin , picar metrafenone , pyriofenone; butrazox , tolprocarb , 2 - [ 3 , 5 -bis ( difluoromethyl) - 1H [0582 ] F . V ) Inhibitors of amino acid and protein synthesis pyrazol - 1 -yl ] - 1 - [ 4 - ( 4 - 5 - [ 2 - (prop - 2 - yn - 1 - yloxy )phenyl ] [0583 ] F . V 1) methionine synthesis inhibitors (anilino 4 , 5 - dihydro - 1 , 2 - oxazol- 3 - yl ) - 1 , 3 - thiazol- 2 - yl) piperidin pyrimidines) : cyprodinil , mepanipyrim , pyrimethanil ; 1 -yl ] ethanone , 2 - [ 3 , 5 -bis ( difluoromethyl) - 1H -pyrazol - 1 [ 0584 ] F . V 2 ) protein synthesis inhibitors : blasticidin - S , yl] - 1 - [ 4 - ( 4 - 5 - [ 2 - fluoro -6 - (prop - 2 - yn - 1 - yloxy )phenyl ] - 4 , kasugamycin , kasugamycin hydrochloridehydrate , mil 5 - dihydro - 1 , 2 - oxazol- 3 - yl) - 1 , 3 - thiazol - 2 - yl) piperidin - 1 diomycin , streptomycin , oxytetracyclin , polyoxine, val yl] ethanone, 2 - [ 3 , 5 - bis ( difluoromethyl) - 1H -pyrazol - 1 idamycin A ; yl] - 1- [4 - (4 - {5 - [2 - chloro - 6 - (prop - 2 -yn - 1- yloxy )phenyl ] [0585 ] F .VI ) Signal transduction inhibitors 4 , 5 -dihydro - 1, 2 - oxazol - 3 - yl} - 1, 3 - thiazol- 2 - yl) piperidin [0586 ] F .VI 1 ) MAP/ histidine kinase inhibitors : fluor 1 - yl ] ethanone, oxin - copper , proquinazid , tebufloquin , oimid , iprodione , procymidone, vinclozolin , fenpiclonil , tecloftalam , triazoxide, 2 -butoxy -6 - iodo - 3 -propyl fludioxonil ; chromen - 4 - one , N -( cyclopropylmethoxyimino - (6 - dif [0587 ] F. VI 2 ) G protein inhibitors : quinoxyfen ; luoro -methoxy - 2 , 3 -difluoro - phenyl) -methyl ) - 2 - phenyl [0588 ] F . VII ) Lipid and membrane synthesis inhibitors acetamide , N '- ( 4 - ( 4 -chloro - 3 - trifluoromethyl- phenoxy ) [0589 ] F . VII 1 ) Phospholipid biosynthesis inhibitors : 2 , 5 - dimethyl- phenyl) - N - ethyl- N -methyl formamidine , edifenphos, iprobenfos, pyrazophos, isoprothiolane ; N ' -( 4 -( 4 - fluoro - 3 - trifluoromethyl -phenoxy ) - 2 , 5 - dim [0590 ] F .VII 2 ) lipid peroxidation : dicloran , quintozene , ethyl- phenyl) - N -ethyl - N -methyl formamidine , N - ( 2 tecnazene, tolclofos -methyl , biphenyl, chloroneb , etridi methyl - 5 -trifluoromethyl - 4 -( 3 -trimethylsilanyl azole; propoxy ) -phenyl ) - N - ethyl- N -methyl formamidine , N ' - ( 5 [ 0591 ] F .VII 3 ) phospholipid biosynthesis and cell wall difluoromethyl- 2 -methyl - 4 - ( 3 - trimethylsilanyl- propoxy ) deposition : dimethomorph , flumorph , mandipropamid , phenyl) - N - ethyl- N -methyl formamidine , methoxy -acetic pyrimorph , benthiavalicarb , iprovalicarb , valifenalate and acid 6 - tert -butyl - 8 - fluoro - 2 , 3 - dimethyl- quinolin - 4 -yl N - ( 1 - ( 1 - ( 4 - cyanophenyl) ethanesulfonyl) - but- 2 - yl) car ester, 3 - [ 5 - ( 4 -methylphenyl ) - 2 , 3 - dimethyl- isoxazolidin bamic acid - ( 4 - fluorophenyl) ester ; 3 -yl ] - pyridine , 3 - [5 - ( 4 -chloro -phenyl ) - 2, 3 -dimethyl - isox US 2019 / 0281835 A1 Sep . 19 , 2019 19

azolidin - 3- yl ] - pyridine (pyrisoxazole ), N - (6 -methoxy [ 0616 ] Il -M .3 Sodium channel modulators selected from pyridin - 3 -yl ) cyclopropanecarboxylic acid amide , sodium channel modulators such as DDT or methoxy 5 - chloro - 1 - ( 4 ,6 - dimethoxy -pyrimidin - 2 - yl) - 2 -methyl chlor; 1H - benzoimidazole , 2 - ( 4 - chloro -phenyl ) - N - [ 4 - ( 3 , 4 - di [ 0617] II -M . 4 Nicotinic acetylcholine receptor agonists methoxy -phenyl ) - isoxazol -5 - yl )- 2 -prop -2 -ynyloxy - acet (nACHR ) from the class of amide , ethyl ( Z ) - 3 - amino - 2 - cyano - 3 - phenyl- prop - 2 [ 0618 ] II - M .4A neonicotinoids, for example acetamiprid , enoate , pentyl N - [6 - [ [ ( Z ) - [ ( 1 -methyltetrazol - 5 - yl) phenyl chlothianidin , cycloxaprid , dinotefuran , imidacloprid , methylene ]amino ]oxymethyl ] - 2 -pyridyl ] carbamate , 2 - [ 2 nitenpyram , thiacloprid and thiamethoxam ; or the com [ ( 7 , 8 - difluoro - 2 -methyl - 3 -quinolyl ) oxy ] -6 - fluoro pounds phenyl] propan - 2 -ol , 2 -[ 2 - fluoro - 6 - [( 8 - fluoro - 2 -methyl - 3 [0619 ] II - M .4A .2 : ( 2E -) - 1 - [( 6 - Chloropyridin - 3 -yl ) quinolyl ) oxylphenyl] propan - 2 - ol, 3 - ( 5 - fluoro - 3 , 3 , 4 ,4 methyl] -N '- nitro -2 -pentylidenehydrazinecarboximid tetramethyl- 3 , 4 -dihydroisoquinolin - 1 -yl ) quinoline , 3 - ( 4 , amide ; or 4 - difluoro - 3 , 3 - dimethyl- 3 , 4 - dihydroisoquinolin - 1 - yl) [0620 ] II -M4A . 3 : 1 -[ ( 6 -Chloropyridin - 3 -yl ) methyl ] - 7 quinoline , 3 - ( 4 , 4 , 5 - trifluoro - 3 , 3 - dimethyl- 3 , 4 methyl- 8 -nitro - 5 -propoxy - 1 , 2, 3, 5 ,6 , 7 -hexahydroimidazo dihydroisoquinolin - 1 -yl ) quinoline ; [ 1 , 2 - a ]pyridine ; or from the class [ 0607 ] F .XII ) Biopesticides 10621 ] II- M . 4B nicotine ; [ 0608 ] F . XII 1 ) Microbial pesticides with fungicidal , bac [ 0622 ] II- M .5 Nicotinic acetylcholine receptor allosteric tericidal, viricidal and / or plant defense activator activity : activators from the class of spinosyns, for example Ampelomyces quisqualis , Aspergillus flavus, Aureoba spinosad or spinetoram ; sidium pullulans, Bacillus amyloliquefaciens, B . mojav [0623 ] II - M .6 Chloride channel activators from the class ensis , B . simplex , B . solisalsi, B . subtilis , B . subtilis var. of avermectins and milbemycins, for example abamectin , amyloliquefaciens , Candida oleophila , C . saitoana , emamectin benzoate , ivermectin , lepimectin or milbe Clavibacter michiganensis (bacteriophages ) , Coniothy mectin ; rium minitans, Cryphonectria parasitica , Cryptococcus [0624 ] II - M . 7 Juvenile hormone mimics, such as albidus , Dilophosphora alopecuri, Fusarium oxysporum , [0625 ] II- M .7A juvenile hormone analogues as hydro Clonostachys rosea f . catenulate (also named Gliocla prene, kinoprene and methoprene ; or others as dium catenulatum ), Gliocladium roseum , Lysobacter anti bioticus, L . enzymogenes, Metschnikowia fructicola , [0626 ] II- M .7B fenoxycarb , or Microdochium dimerum , Microsphaeropsis ochracea , [0627 ] II - M .7C pyriproxyfen ; Muscodor albus, Paenibacillus polymyxa, Pantoea [ 0628 ] II- M .8 miscellaneous non - specific (multi - site ) vagans, Phlebiopsis gigantea , Pseudomonas sp ., inhibitors , for example Pseudomonas chloraphis , Pseudozyma flocculosa, Pichia [0629 ] II -M .8A alkylhalides as methyl bromide and other anomala , Pythium oligandrum , Sphaerodes mycopara alkyl halides , or sitica , Streptomyces griseoviridis , S . lydicus, S . violaceus [0630 ] II - M .8B chloropicrin , or niger , Talaromyces flavus, Trichoderma atroviride , T . fer [0631 ] II - M .8C sulfuryl fluoride , or tile , T . gamsii , T . harmatum , T . harzianum ; mixture of T . [0632 ] II - M .8D borax , or harzianum and T. viride; mixture of T. polysporum and T. [0633 ] II - M .8E tartar emetic ; harzianum ; T . stromaticum , T . virens ( also named Glio [0634 ] II - M . 9 Selective homopteran feeding blockers , for cladium virens ), T. viride , Typhula phacorrhiza , Ulocla example dium oudemansii , Verticillium dahlia , zucchini yellow [ 0635 ] II - M . 9B pymetrozine, or mosaic virus (avirulent strain ); 10636 II - M . 9C flonicamid ; [ 0609 ] F .XII 2 ) Biochemical pesticides with fungicidal , [0637 ] II - M . 10 Mite growth inhibitors , including bactericidal , viricidal and / or plant defense activator activ [ 0638 ] II- M . 10A clofentezine , hexythiazox and ity : chitosan (hydrolysate ), harpin protein , laminarin , diflovidazin , or Menhaden fish oil , natamycin , Plum pox virus coat pro [0639 ] II - M . 10B etoxazole ; tein , potassium or sodium bicarbonate , Reynoutria [0640 ] Il - M . 11 Microbial disruptors of insect midgut sachlinensis extract, salicylic acid , tea tree oil membranes , for example Bacillus thuringiensis or Bacil [0610 ] In one preferred embodiment of the mixtures of the lus sphaericus and the insecticdal proteins they produce invention compounds II and / or III are selected from : such as Bacillus thuringiensis subsp . israelensis , Bacillus [0611 ] III - M . 1 Acetylcholine esterase (ACHE ) inhibitors sphaericus, Bacillus thuringiensis subsp . aizawai, bacil from the class of lus thuringiensis subsp . kurstaki and Bacillus thuringien [0612 ] II - M .1A carbamates, for example aldicarb , alany sis subsp . tenebrionis , or the Bt crop proteins: Cry1Ab , carb , bendiocarb , benfuracarb , butocarboxim , butoxycar Cry1Ac, Cry1Fa , Cry2Ab , mCry3A , Cry3Ab , Cry3Bb boxim , carbaryl, carbofuran , carbosulfan , ethiofencarb , and Cry34 / 35Abl ; fenobucarb , formetanate , furathiocarb , isoprocarb , [0641 ] II - M . 12 Inhibitors of mitochondrial ATP synthase , methiocarb , methomyl, metolcarb , oxamyl, pirimicarb , for example propoxur, thiodicarb, thiofanox , trimethacarb , XMC , [0642 ] II- M . 12A diafenthiuron , or xylylcarb and triazamate ; or from the class of [0643 ] II - M . 12B organotin miticides such as azocyclotin , [ 0613] II - M . 2 GABA - gated chloride channel antagonists cyhexatin or fenbutatin oxide, or such as : 10644 ] II -M . 12C propargite , or [ 0614 ] II - M .2A cyclodiene organochlorine compounds, as [0645 ] Il - M .12D tetradifon ; for example endosulfan or chlordane; or [ 0646 ] II - M .13 Uncouplers of oxidative phosphorylation [ 0615 ] II - M . 2B fiproles (phenylpyrazoles ) , as for example via disruption of the proton gradient, for example chlo ethiprole , fipronil, flufiprole , pyrafluprole and pyriprole ; rfenapyr, DNOC or sulfluramid ; US 2019 / 0281835 A1 Sep . 19 , 2019 20

[0647 ] Il - M .14 Nicotinic acetylcholine receptor (nACHR ) [0674 ] II - M . 28 . 4 : methyl- 2 - [ 3, 5 -dibromo -2 - {{ [ 3 -bromo channel blockers , for example nereistoxin analogues as 1 - ( 3 - chlorpyridin - 2 - yl) - 1H -pyrazol - 5 - yl] bensultap , cartap hydrochloride , thiocyclam or thiosultap carbonyl} amino )benzoyl ] - 1 , 2 - dimethylhydrazinecar sodium ; boxylate ; [ 0648 ] II- M . 15 Inhibitors of the chitin biosynthesis type 0 , [ 0675 ] or a compound selected from M .28 . 5a ) to M . 28 . 51) : such as benzoylureas as for example bistrifluron , chlo [0676 ] II - M . 28 . 5a ) N - [ 4 , 6 - dichloro - 2 - [ (diethyl - lambda - 4 rfluazuron , diflubenzuron , flucycloxuron , flufenoxuron , sulfanylidene )carbamoyl ] -phenyl ) - 2 - ( 3 - chloro - 2 hexaflumuron , lufenuron , novaluron , noviflumuron , pyridyl) -5 - (trifluoromethyl ) pyrazole - 3 - carboxamide ; teflubenzuron or triflumuron ; [ 0649] II - M . 16 Inhibitors of the chitin biosynthesis type 1 , [0677 ] Il - M . 28 . 5b ) N - [ 4 - chloro - 2 - [ ( diethyl- lambda - 4 - sul as for example buprofezin ; fanylidene )carbamoyl ] -6 -methyl - phenyl ] - 2 - (3 -chloro - 2 [ 0650 ] II - M . 17 Moulting disruptors , Dipteran , as for pyridyl) -5 - ( trifluoromethyl) pyrazole -3 - carboxamide; example cyromazine ; [ 0678 ] II- M . 28. 5c ) N - [ 4 - chloro - 2 - [ ( di- 2 -propyl - lambda [ 0651 ] II- M . 18 Ecdyson receptor agonists such as diacyl 4 - sulfanylidene ) carbamoyl ]- 6 -methyl -phenyl ] - 2 - ( 3 hydrazines , for example methoxyfenozide , tebufenozide, chloro - 2 -pyridyl ) - 5 - ( trifluoromethyl )pyrazole - 3 - carbox halofenozide , fufenozide or chromafenozide ; amide ; [0652 ] II- M . 19 Octopamin receptor agonists , as for [0679 ] Il -M .28 .5d ) N -[ 4 ,6 -dichloro -2 -[ ( di - 2- propyl example amitraz ; lambda - 4 -sulfanylidene carbamoyl] -phenyl ] - 2 - ( 3 -chloro [0653 ] II - M . 20 Mitochondrial complex III electron trans 2 -pyridyl ) - 5 - ( trifluoromethyl) pyrazole - 3 -carboxamide ; port inhibitors, for example [0680 ] Il -M .28 .5e ) N -[ 4 ,6 -dichloro - 2 -[ ( diethyl - lambda- 4 [0654 ] II - M .20A hydramethylnon , or sulfanylidene ) carbamoyl ] -phenyl ] - 2 - ( 3 - chloro - 2 [0655 ] II- M .20B acequinocyl, or pyridyl) - 5 - ( difluoromethyl) pyrazole - 3 - carboxamide; 10656 ). II- M . 20C fluacrypyrim ; [0681 ] II - M .28 .5f ) N - [ 4 ,6 - dibromo - 2 - [ (di - 2 -propyl [ 0657] II - M .21 Mitochondrial complex I electron trans lambda -4 - sulfanylidene ) carbamoyl] - phenyl] - 2 - ( 3 - chloro port inhibitors , for example 2 - pyridyl) - 5 - ( trifluoromethyl) pyrazole - 3 - carboxamide ; [0658 ] Il - M .21A METI acaricides and insecticides such as [0682 ] II -M .28 .5g ) N -[ 4 -chloro - 2 - [( di - 2 -propyl - lambda fenazaquin , fenpyroximate, pyrimidifen , pyridaben , 4 - sulfanylidene )carbamoyl ]- 6 -cyano -phenyl ] -2 - (3 tebufenpyrad or tolfenpyrad , or chloro -2 -pyridyl ) - 5 -( trifluoromethyl) pyrazole- 3 -carbox [0659 ] II - M .21B rotenone; amide ; [0660 ] Il - M .22 Voltage -dependent sodium channel block [0683 ] II - M . 28 . 5h ) N - [ 4 , 6 - dibromo - 2 - [ (diethyl - lambda - 4 ers , for example sulfanylidene )carbamoyl ]- phenyl ] - 2 -( 3 - chloro -2 [0661 ] II - M .22A indoxacarb , or pyridyl) - 5 - ( trifluoromethyl) pyrazole -3 - carboxamide; [0662 ] II- M .22B metaflumizone, or [0684 ] II - M . 28 . 5i) N -[ 2 - ( 5 - Amino - 1 , 3 , 4 - thiadiazol- 2 - yl) [0663 ] II - M .22B . 1 : 2 - [ 2 - ( 4 -Cyanophenyl ) - 1 - [ 3 - ( trifluo 4 - chloro - 6 -methylphenyl ] - 3 -bromo - 1 - ( 3 - chloro - 2 - pyridi romethyl) phenyl] ethylidene ]- N -[ 4 -( difluoromethoxy ) nyl) - 1H - pyrazole - 5 - carboxamide ; phenyl] -hydrazinecarboxamide or [0685 ] Il -M .28 .5j ) 3 -Chloro - 1 -( 3 -chloro -2 -pyridinyl ) - N [0664 ] II - M .22B .2 : N -( 3 - Chloro -2 -methylphenyl ) -2 -[ ( 4 [ 2 , 4 - dichloro -6 - [ [ ( 1 - cyano - 1 -methylethyl ) amino ] carbo chlorophenyl) [ 4 - [methyl ( methylsulfonyl ) amino ]phenyl ] nyl] phenyl] - 1H -pyrazole -5 -carboxamide ; methylene] -hydrazinecarboxamide ; [0665 ] II - M .23 Inhibitors of the of acetyl CoA carboxy [0686 ] II - M . 28 .5k ) 3 - Bromo- N -[ 2, 4 -dichloro -6 -( methyl lase , such as tetronic and tetramic acid derivatives, for carbamoyl) phenyl] - 1 - ( 3 , 5 -dichloro - 2 -pyridyl ) - 1H - pyra example spirodiclofen , spiromesifen or spirotetramat ; zole - 5 -carboxamide ; [ 0666 ] II -M .24 Mitochondrial complex IV electron trans [ 0687 ] II- M . 28. 51 ) N -[ 4 -Chloro - 2 - [ [ ( 1 , 1 - dimethylethyl) port inhibitors , for example amino ]carbonyl ] -6 -methylphenyl ] - 1 - (3 -chloro - 2 -pyridi [0667 ] II - M .24A phosphine such as aluminium phosphide , nyl) - 3 -( fluoromethoxy )- 1H -pyrazole - 5 -carboxamide ; calcium phosphide, phosphine or zinc phosphide, or [0688 ] or a compound selected from [ 0668 ] II- M . 24B cyanide ; [0689 ] Il - M . 28 .6 : N - ( 2 - cyanopropan - 2 - yl) - N - ( 2 , 4 -dim [0669 ] II - M . 25 Mitochondrial complex II electron trans ethylphenyl) - 3 -iodobenzene - 1 , 2 - dicarboxamide; or port inhibitors , such as beta -ketonitrile derivatives , for [ 0690 ] II- M . 28. 7 : 3 -Chloro - N - ( 2 - cyanopropan - 2 - yl) - N example cyenopyrafen or cyflumetofen ; ( 2 ,4 -dimethylphenyl ) - benzene - 1, 2 -dicarboxamide ; [ 0670 ] II - M . 28 Ryanodine receptor- modulators from the [ 0691 ] II - M . 28 . 8a ) 1 - ( 3 - Chloro - 2 -pyridinyl ) - N - [ 4 - cyano class of diamides, as for example flubendiamide , chlo 2 -methyl - 6 -[ ( methylamino ) carbonyl] phenyl ] - 3 -[ [ 5 -( trif rantraniliprole (Rynaxypyr® ), cyantraniliprole (Cyazy luoromethyl) - 2H - tetrazol- 2 - yl] methyl ] - 1H -pyrazole - 5 pyr® ) , or the phthalamide compounds carboxamide; or [ 0671] II - M .28 .1 : ( R ) -3 - Chlor -N1 - { 2 -methyl - 4 -[ 1, 2 ,2 , 2 [ 0692 ] Il -M .28 . 8b ) 1- ( 3 - Chloro -2 - pyridinyl ) - N -[ 4 -cyano tetrafluor - 1 - ( trifluormethyl) ethyl] phenyl} - N2 - ( 1 -methyl 2 -methyl - 6 - [ (methylamino )carbonyl ] phenyl ] - 3 - [ [ 5 - ( trif 2 -methylsulfonylethyl ) phthalamid and luoromethyl) - 1H - tetrazol- 1 - yl] methyl ) - 1H - pyrazole - 5 [0672 ] Il - M .28 .2 : ( S ) - 3 - Chlor -N1 - {2 -methyl - 4 - [ 1 ,2 ,2 , 2 carboxamide; tetrafluor- 1 - ( trifluormethyl) ethyl ]phenyl ) -N2 - ( 1 -methyl [0693 ] II - M .UN Insecticidally active compounds of 2 -methylsulfonylethyl ) phthalamid , or the compound unknown or uncertain mode of action , as for example [0673 ] II - M .28 .3 : 3 -bromo - N - { 2 -bromo - 4 -chloro -6 -[ ( 1 afidopyropen , afoxolaner , azadirachtin , amidoflumet , cyclopropylethyl ) carbamoyl] phenyl) - 1 - ( 3 - chlorpyridin benzoximate , bifenazate , bromopropylate , chinomethio 2 -yl ) - 1H - pyrazole - 5 -carboxamide (proposed ISO name: nat, cryolite , dicofol, flufenerim , flometoquin , fluensul cyclaniliprole ), or the compound fone, fluopyram , flupyradifurone, fluralaner , metoxadiaz US 2019 / 0281835 A1 Sep . 19 , 2019

one , piperonyl butoxide , pyflubumide , pyridalyl, [ 0718 ] II- M .UN . 12 . h ) N , 2 - Dimethyl- N - [ 4 -methyl - 2 - ( 3 pyrifluquinazon , sulfoxaflor , tioxazafen , triflumezopyrim , pyridyl) thiazol- 5 - yl] - 3 -methylthio -propanamide or the compounds [0719 ] II - M .UN .12 .i ) N - Ethyl- 2 -methyl - N - [4 -methyl - 2 [ 0694 ] II - M .UN .3 : 11- (4 -chloro - 2 ,6 -dimethylphenyl ) - 12 (3 -pyridyl ) thiazol - 5 -yl ] - 3 -methylthio - propanamide hydroxy - 1, 4 -dioxa - 9 -azadispiro [ 4 .2 .4 . 2 ]- tetradec - 11 - en [ 0720 ] II- M .UN . 12. j) N - [ 4 - Chloro - 2 - ( 3 - pyridyl) thiazol - 5 10 -one , or the compound yl] - N -ethyl - 2 -methyl - 3 -methylthio - propanamide [0695 ] II - M .UN . 4 : 3 - ( 4 '- fluoro - 2 , 4 -dimethylbiphenyl - 3 [0721 ] II -M .UN . 12 .k ) N -[ 4 -Chloro - 2 - (3 -pyridyl ) thiazol yl) - 4 -hydroxy - 8 -oxa - 1 - azaspiro [4 .5 ]dec -3 -en - 2 -one , or 5 -yl ]- N , 2 -dimethyl - 3 -methylthio -propanamide the compound [ 0722 ] II- M .UN . 12. 1) N - [ 4 - Chloro - 2 - ( 3 - pyridyl) thiazol -5 [ 0696 ] II - M .UN . 5 : 1 - [ 2 - fluoro - 4 -methyl - 5 - [ ( 2 , 2 , 2 - trifluo yl] -N -methyl -3 -methylthio -propanamide roethyl) sulfinyl ] phenyl ] - 3 - (trifluoromethyl ) - 1H - 1 , 2 , 4 - tri [ 0723] II - M .UN . 12 .m ) N -[ 4 - Chloro - 2 - ( 3 - pyridyl) thiazol azole - 5 -amine ; or a compound selected from the group of 5 - yl ] -N - ethyl- 3 -methylthio -propanamide ; or the com M . UN . 6 , wherein the compound is selected from II - II- M . pound UN .6a ) to M .UN . 6k ) : [ 0724 ] II- M .UN . 13 : 2 - ( 4 -methoxyiminocyclohexyl ) - 2 - ( 3 , [ 0697] II - M .UN .6a ) ( E / Z )- N - [ 1 - [ (6 - chloro - 3 -pyridyl ) 3 , 3 - trifluoropropylsulfonyl ) acetonitrile ; or the com methyl] - 2 -pyridylidene ] - 2 , 2 , 2 - trifluoro - acetamide ; pounds [0698 ] II - M .UN .6b ) ( E / Z ) - N - [ 1 - [ (6 - chloro - 5 - fluoro - 3 [0725 ] II - M .UN . 14a ) 1 - [ ( 6 -Chloro - 3 - pyridinyl) methyl ) - 1 , pyridyl) methyl ] - 2 -pyridylidene )- 2 ,2 ,2 - trifluoro -acet 2 , 3 , 5 , 6 , 7 -hexahydro - 5 -methoxy - 7 -methyl - 8 -nitro - imi amide ; dazo [ 1 , 2 - a ] pyridine; or [ 0699 ] II - M .UN .6c ) (E /Z ) - 2, 2 ,2 - trifluoro - N -[ 1 - [ (6 - fluoro [0726 ] II -M .UN .14b ) 1- [( 6 -Chloropyridin - 3- yl )methyl ] 3 -pyridyl )methyl ] - 2 -pyridylidene ]acetamide ; 7 - methyl- 8 -nitro - 1 , 2 , 3 , 5 ,6 , 7 - hexahydroimidazo [ 1 , 2 - a ] [0700 ] Il - M .UN .6d ) ( E / Z ) - N - [ 1 - [ (6 -bromo - 3 -pyridyl ) pyridin - 5 - ol; or the compound methyl] - 2 -pyridylidene ]- 2 , 2 , 2 - trifluoro - acetamide ; [ 0727 ] II- M .UN . 15 : 1 - [ ( 2 - Chloro - 1 , 3 - thiazol- 5 - yl) [ 0701 ] II - M .UN .6 ) ( E / Z ) - N - [ 1 - [ 1 - (6 - chloro - 3 -pyridyl ) methyl] - 3 - ( 3 , 5 - dichlorophenyl) - 9 -methyl - 4 - oxo - 4H ethyl] - 2 -pyridylidene ] - 2 , 2 , 2 - trifluoro -acetamide ; pyrido [ 1 ,2 - a ]pyrimidin - 1 - ium - 2 -olate ; or [0702 ] II - M .UN .6f ) ( E / Z ) - N - [ 1 - [ (6 -chloro - 3 - pyridyl) [0728 ] II - M .BP Biopesticides , being pesticidal com methyl) - 2 -pyridylidene ] -2 ,2 -difluoro - acetamide; pounds of biological origin with insecticidal, acaricidal, [0703 ] II - M .UN .6g ) ( E / Z ) - 2 - chloro - N - [ 1 - [ (6 - chloro - 3 molluscidal and / or nematicidal activity , including pyridyl) methyl ] - 2 -pyridylidene ) - 2, 2 -difluoro -acetamide ; [0729 ] II- M .BP - 1: Microbial pesticides : Bacillus firmus, [0704 ] II - M .UN .6h ) ( E / Z ) - N - [ 1 - [ ( 2 - chloropyrimidin - 5 B . thuringiensis ssp . israelensis , B . t . ssp . galleriae , B . t . yl) methyl ] - 2 -pyridylidene ) - 2 , 2 , 2 - trifluoro - acetamide; ssp . kurstaki, Beauveria bassiana , Burkholderia sp . , [0705 ] II - M .UN .6i ) ( E / Z ) - N - [ 1 - [ (6 -chloro - 3 - pyridyl) Chromobacterium subtsugae , Cydia pomonella granulo methyl] -2 - pyridylidene )- 2 ,2 , 3, 3, 3 -pentafluoropropana sis virus , Isaria fumosorosea , Lecanicillium longisporum , mide . ); L . muscarium ( formerly Verticillium lecanii ) , Metarhi [0706 ] II - M .UN .6j ) N - [ 1 - [ ( 6 -chloro - 3 - pyridyl) methyl] - 2 zium anisopliae , M . anisopliae var . acridum , Paecilomy pyridylidene )- 2 , 2 , 2 -trifluoro - thioacetamide or of the ces fumosoroseus, P . lilacinus, Paenibacillus poppiliae, compound Pasteuria spp ., P . nishizawae, P . reneformis, P. usagae, [ 0707 ] II - M .UN .6k ) N - [1 - [( 6 -chloro - 3 -pyridyl ) methyl ) - 2 Pseudomonas fluorescens, Steinernema feltiae , Streptom pyridylidene] - 2 , 2 , 2 - trifluoro - N ' - isopropyl- acetamidine or ces galbus ; or the compounds 10730 ] II - M . BP - 2 : Biochemical pesticides : L - carvone , [ 0708 ) II - M .UN . 8 : 8 - chloro - N - [ 2 - chloro - 5 -methoxyphe citral, (E ,Z )- 7 , 9 -dodecadien - 1 -yl acetate, ethyl formate , nyl) sulfonyl] - 6 - trifluoromethyl) - imidazo [ 1 , 2 - a ]pyridine ( E , Z ) - 2 , 4 - ethyl decadienoate ( pear ester ), ( Z , Z , E ) - 7 , 11, 2 - carboxamide ; or 13 -hexadecatrienal , heptyl butyrate , isopropyl myristate , [0709 ] II - M .UN . 9 : 4 - [ 5 - ( 3 , 5 -dichlorophenyl ) - 5 - (trifluo lavanulyl senecioate , 2 -methyl 1 -butanol , methyl euge romethyl) -4H - isoxazol- 3 -yl ] - 2 -methyl - N - (1 -oxothietan nol, methyl jasmonate , ( E , Z ) - 2 ,13 -octadecadien - 1 - ol, 3 - yl )benzamide ; or ( E , Z )- 2 ,13 - octadecadien - 1- ol acetate , ( E , Z )- 3 ,13 - octa [0710 ] Il - M .UN . 10 : 5 - [ 3 - [ 2 ,6 - dichloro - 4 - ( 3 , 3 -dichloroal decadien - 1- ol , R - 1 - octen - 3 -ol , pentatermanone, potas lyloxy ) phenoxy ] propoxy ] -1H - pyrazole ; or a compound sium silicate , sorbitol actanoate, ( E , Z , Z )- 3 , 8 ,11 -tetrade selected from the group of M .UN . 12 , wherein the com catrienyl acetate , ( Z , E ) - 9 , 12 - tetradecadien - 1 - yl acetate , pound is selected from M .UN . 12a ) to M . UN . 12m ) : Z - 7 - tetradecen - 2 -one , Z - 9 - tetradecen - 1 - yl acetate, Z - 11 [0711 ] II - M .UN . 12 .a ) 2 - (1 , 3 -Dioxan -2 - yl) -6 - [ 2 - (3 - pyridi tetradecenal, Z - 11 -tetradecen - 1 -ol , Acacia negra extract , nyl) - 5 - thiazolyl] -pyridine ; extract of grapefruit seeds and pulp , extract of Chenopo [0712 ] II - M .UN . 12 . b ) 2 - [6 - [ 2 - ( 5 - Fluoro - 3 -pyridinyl ) - 5 dium ambrosiodae, Catnip oil, Neem oil , Quillay extract, thiazolyl ] - 2 -pyridinyl ] -pyrimidine ; Tagetes oil, [ 0713 ] II- M .UN . 12. c ) 2 - [6 - [ 2 - ( 3 -Pyridinyl ) - 5 - thiazolyl] [ 0731 ] and /or 2 - pyridinyl] -pyrimidine ; [ 0732 ] F . I ) Respiration inhibitors [ 0714 ] II- M .UN . 12 . d ) N - M ethylsulfonyl- 6 - [ 2 - ( 3 - pyridyl) [0733 ] F .I 1 ) Inhibitors of complex III at Q . site ( e . g . thiazol- 5 -yl ] pyridine - 2 - carboxamide strobilurins ) : azoxystrobin , coumethoxystrobin , coumox [0715 ] Il -M .UN .12 . e ) N -M ethylsulfonyl -6 - [2 -( 3 -pyridyl ) ystrobin , dimoxystrobin , enestroburin , fenaminstrobin , thiazol - 5 - yl] pyridine - 2 - carboxamide fenoxystrobin / flufenoxystrobin , fluoxastrobin , kresoxim [ 0716 ] II- M .UN . 12. f ) N - Ethyl - N - [ 4 -methyl - 2 -( 3 - pyridyl) methyl, mandestrobine , metominostrobin , orysastrobin , thiazol - 5 - yl] - 3 -methylthio - propanamide picoxystrobin , pyraclostrobin , pyrametostrobin , pyraox [0717 ] II - M .UN . 12 . g ) N - M ethyl - N - [ 4 -methyl - 2 - ( 3 ystrobin , trifloxystrobin and 2 - ( 2 - ( 3 - ( 2 , 6 -dichlorophe pyridyl ) thiazol- 5 -yl ) - 3 - methylthio -propanamide nyl) - 1 -methyl - allylideneaminooxymethyl )- phenyl )- 2 US 2019 /0281835 A1 Sep . 19 , 2019

methoxyimino - N -methyl - acetamide , pyribencarb , phenyl] - 1 - cyclopropyl - 2 - ( 1 , 2 , 4 - triazol- 1 - yl )ethanol , triclopyricarb / chlorodincarb , famoxadone , fenamidone ; 2 - [4 -( 4 -chlorophenoxy ) -2 -( trifluoromethyl ) phenyl] - 1 -( 1 , [ 0734 ] F . I 2 ) inhibitors of complex III at Qi site : cyazof 2 ,4 - triazol- 1 -yl ) butan - 2 -ol , 2 -[ 2 -chloro - 4 - ( 4 -chlorophe amid , amisulbrom , [ ( 35 ,65 , 7R , 8R ) - 8 - benzyl- 3 - | ( 3 - ac noxy ) phenyl] - 1 - ( 1 , 2 , 4 -triazol - 1 - yl) butan - 2 - ol, 2 -[ 4 - ( 4 etoxy - 4 -methoxy -pyridine - 2 -carbonyl ) amino ]- 6 -methyl chlorophenoxy )- 2 -( trifluoromethyl) phenyl ] - 3 -methyl - 1 4 , 9 -dioxo - 1 , 5 - dioxonan - 7 - yl] 2 -methylpropanoate , [ ( 3S , ( 1 , 2 ,4 - triazol- 1 -yl ) butan - 2 -ol , 2 - [ 4 - ( 4 - chlorophenoxy ) - 2 65 , 7R ,8R ) - 8 -benzyl - 3 - [ [ 3 - ( acetoxymethoxy ) - 4 -methoxy ( trifluoromethyl) phenyl] - 1 - ( 1 , 2 , 4 - triazol - 1 - yl) propan - 2 pyridine - 2 - carbonyl ] amino ] - 6 -methyl - 4 , 9 - dioxo - 1 , 5 ol, 2 - [ 2 - chloro - 4 - ( 4 - chlorophenoxy ) phenyl] - 3 - methyl - 1 dioxonan -7 -yl ] 2 -methylpropanoate , [( 35 ,6S ,7R ,8R )- 8 ( 1 , 2 , 4 -triazol - 1 - yl) butan - 2 - 01, 2 - [ 4 -( 4 - chlorophenoxy ) - 2 benzyl- 3 - [ ( 3 - isobutoxycarbonyloxy - 4 -methoxy -pyridine ( trifluoromethyl ) phenyl] - 1 - ( 1 , 2 , 4 - triazol- 1 - yl) pentan - 2 2 - carbonyl) amino ] - 6 -methyl - 4 , 9 - dioxo - 1 , 5 -dioxonan - 7 ol, 2 - [ 4 - ( 4 - fluorophenoxy ) - 2 - ( trifluoromethyl) phenyl] - 1 yl] 2 -methylpropanoate , [ (38 ,6S , 7R , 8R ) - 8 -benzyl - 3 - [ [ 3 ( 1 , 2 ,4 - triazol- 1 -yl ) propan - 2 -ol ; imidazoles: imazalil , ( 1 , 3 -benzodioxol - 5 - ylmethoxy ) - 4 -methoxy -pyridine - 2 pefurazoate , prochloraz, triflumizol; pyrimidines, pyri carbonyl ]amino ]- 6 -methyl - 4 ,9 -dioxo - 1 ,5 -dioxonan - 7 -yl ] dines and piperazines : fenarimol, nuarimol, pyrifenox , 2 -methylpropanoate ; (38 ,6S ,7R ,8R )- 3 - [[ ( 3 -hydroxy - 4 triforine , [ 3 - ( 4 - chloro - 2 - fluoro - phenyl) -5 - ( 2 ,4 -difluoro methoxy - 2 -pyridinyl ) carbonyl] amino ] - 6 -methyl -4 , 9 -di phenyl) isoxazol- 4 -yl ) - ( 3 -pyridyl )methanol ; oxo - 8 - ( phenylmethyl) - 1 , 5 - dioxonan - 7 - yl 2 -methylpro [0740 ] F . II 2 ) Delta14 - reductase inhibitors : aldimorph , panoate ; dodemorph , dodemorph -acetate , fenpropimorph , tride [ 0735 ] F . I 3 ) inhibitors of complex II ( e . g . carboxamides ): morph , fenpropidin , piperalin , spiroxamine ; benodanil , benzovindiflupyr , bixafen , boscalid , carboxin , [0741 ] F . II 3 ) Inhibitors of 3 -keto reductase : fenhexamid ; fenfuram , fluopyram , flutolanil, fluxapyroxad , furamet [0742 ] F. III ) Nucleic acid synthesis inhibitors pyr, isofetamid , isopyrazam , mepronil, oxycarboxin , pen - [ 0743 ] F . II 1 ) phenylamides or acyl amino acid fungicides: flufen , penthiopyrad , sedaxane, tecloftalam , thifluzamide , benalaxyl, benalaxyl- M , kiralaxyl, metalaxyl, metal N - ( 4 ' - trifluoromethylthiobiphenyl- 2 - yl) - 3 - difluorom axyl - M (mefenoxam ), ofurace , oxadixyl; ethyl- 1 -methyl -1H -pyrazole - 4 - carboxamide, N - ( 2 - ( 1 , 3 , 3 [0744 ] F. II 2) others : hymexazole , octhilinone , oxolinic trimethyl -butyl ) -phenyl ) - 1 , 3 -dimethyl - 5 - fluoro - 1H -pyra acid , bupirimate , 5 - fluorocytosine, 5 - fluoro - 2 - p - tolyl zole - 4 - carboxamide , 3 - ( difluoromethyl ) - 1 -methyl - N - ( 1 , methoxy )pyrimidin - 4 - amine, 5 - fluoro - 2 - ( 4 - fluorophenyl 1 , 3 - trimethylindan - 4 - yl) pyrazole - 4 - carboxamide, methoxy ) pyrimidin -4 -amine ; 3 -( trifluoromethyl ) - 1 -methyl - N -( 1 , 1, 3 - trimethylindan -4 [0745 ] F. IV ) Inhibitors of cell division and cytoskeleton yl) pyrazole -4 - carboxamide, 1 ,3 - dimethyl- N -( 1 ,1 ,3 - trim [0746 ] F .IV 1 ) tubulin inhibitors, such as benzimidazoles , ethylindan - 4 - yl) pyrazole - 4 - carboxamide , 3 - ( trifluorom thiophanates: benomyl, carbendazim , fuberidazole , thi ethyl) - 1 , 5 - dimethyl- N -( 1 , 1 , 3 -trimethylindan - 4 -yl ) abendazole , thiophanate- methyl ; triazolopyrimidines : pyrazole - 4 - carboxamide, 1 , 3 , 5 - trimethyl- N - ( 1 , 1 , 3 5 - chloro - 7 - ( 4 -methylpiperidin - 1 - yl) - 6 - ( 2 , 4 , 6 - trifluoro trimethylindan - 4 - yl) pyrazole - 4 -carboxamide , N - ( 7 phenyl) - [ 1, 2 ,4 ] triazolo [ 1, 5 - a )pyrimidine ; fluoro - 1 , 1 , 3 - trimethyl- indan - 4 -yl ) - 1 , 3 -dimethyl [0747 ] F . IV 2 ) other cell division inhibitors: diethofen pyrazole- 4 -carboxamide , N - [2 - (2 , 4 -dichlorophenyl ) - 2 carb , ethaboxam , pencycuron , fluopicolide , zoxamide , methoxy - 1- methyl - ethyl] -3 - (difluoromethyl ) - 1 metrafenone, pyriofenone ; methylpyrazole- 4 - carboxamide , N -[ 2 -( 2 ,4 difluorophenyl) phenyl ] - 3 -( trifluoromethyl) pyrazine -2 [ 0748 ] F . V ) Inhibitors of amino acid and protein synthesis carboxamide ; [0749 ] F . V 1 ) methionine synthesis inhibitors ( anilino [0736 ] F. I 4 ) other respiration inhibitors ( e. g . complex I, pyrimidines ) : cyprodinil , mepanipyrim , pyrimethanil ; uncouplers ): diflumetorim , (5 , 8 -difluoroquinazolin -4 - yl) [0750 ] F . V 2 ) protein synthesis inhibitors : blasticidin - S , { 2 - [ 2 - fluoro - 4 - ( 4 - trifluoromethylpyridin - 2 - yloxy ) -phe kasugamycin , kasugamycin hydrochloridehydrate , mil nyl] - ethyl) - amine; nitrophenyl derivates : binapacryl, diomycin , streptomycin , oxytetracyclin , polyoxine, val dinobuton , dinocap , fluazinam ; ferimzone; organometal idamycin A ; compounds: fentin salts , such as fentin - acetate , fentin [0751 ] F .VI ) Signal transduction inhibitors chloride or fentin hydroxide; ametoctradin ; and silthio [0752 ] F .VI 1 ) MAP /histidine kinase inhibitors : fluor fam ; oimid , iprodione , procymidone , vinclozolin , fenpiclonil , [ 0737 ] F .II ) Sterol biosynthesis inhibitors (SBI fungicides) fludioxonil ; [0738 ] F . II 1 ) C14 demethylase inhibitors ( DMI fungi 0753 ] F . VI 2 ) G protein inhibitors : quinoxyfen ; cides ) : triazoles : azaconazole , bitertanol, bromuconazole , [0754 ] F .VII ) Lipid and membrane synthesis inhibitors cyproconazole , difenoconazole , diniconazole, dinicon [0755 ] F. VII 1 ) Phospholipid biosynthesis inhibitors: azole - M , epoxiconazole, fenbuconazole , fluquinconazole , edifenphos , iprobenfos, pyrazophos, isoprothiolane ; flusilazole , flutriafol, hexaconazole , imibenconazole , [0756 ] F .VII 2 ) lipid peroxidation : dicloran , quintozene , ipconazole , metconazole , myclobutanil , oxpoconazole , tecnazene , tolclofos -methyl , biphenyl, chloroneb , etridi paclobutrazole , penconazole , propiconazole , prothiocon azole; azole , simeconazole , tebuconazole , tetraconazole , triadi [0757 ] F . VII 3 ) phospholipid biosynthesis and cell wall mefon , triadimenol, triticonazole , uniconazole , deposition : dimethomorph , flumorph , mandipropamid , [0739 ] 1- [ rel- ( 2S ;3R )- 3 -( 2 - chlorophenyl) - 2 -( 2 ,4 -difluoro pyrimorph , benthiavalicarb , iprovalicarb , valifenalate and phenyl) -oxiranylmethyl ] - 5 - thiocyanato - 1H [ 1 , 2 , 4 ] triaz N - ( 1 - ( 1 - ( 4 - cyano - phenyl) ethanesulfonyl) -but - 2 - yl) car ole , 2 -[ rel- ( 2S ,3R )- 3 -( 2 -chlorophenyl ) - 2 -( 2 ,4 -difluoro bamic acid - ( 4 - fluorophenyl) ester , phenyl) -oxiranylmethyl ] - 2H -[ 1 ,2 , 4 ] triazole - 3 -thiol , 2 -[ 2 [0758 ] F. VII 4 ) compounds affecting cell membrane per chloro - 4 - ( 4 - chlorophenoxy ) phenyl] - 1 - ( 1 , 2 , 4 - triazol- 1 - yl) meability and fatty acides : propamocarb , propamocarb pentan - 2 -ol , 1 - [ 4 - ( 4 - chlorophenoxy ) - 2 - (trifluoromethyl ) hydrochlorid ; US 2019 / 0281835 A1 Sep . 19 , 2019

[0759 ] F. VII 5 ) fatty acid amide hydrolase inhibitors: 1H -benzoimidazole , 2 - ( 4 - chloro - phenyl) - N - [ 4 -( 3 , 4 - di oxathiapiprolin ; methoxy -phenyl ) - isoxazol- 5 -yl ] - 2 -prop -2 - ynyloxy -acet [0760 ] F .VIII ) Inhibitors with Multi Site Action amide, ethyl ( Z ) - 3 - amino - 2 - cyano - 3 - phenyl- prop - 2 [ 0761 ] F .VIII 1 ) inorganic active substances : Bordeaux enoate , pentyl N - [6 - [[ ( Z ) -[ ( 1- methyltetrazol - 5 -yl ) phenyl mixture , copper acetate , copper hydroxide , copper oxy methyleneJamino ] oxymethyl] - 2 -pyridyl ] carbamate , 2 -[ 2 chloride , basic copper sulfate , sulfur ; [ ( 7 , 8 - difluoro - 2 -methyl - 3 -quinolyl ) oxy ] -6 - fluoro [0762 ] F .VIII 2 ) thio - and dithiocarbamates: ferbam , man phenyl] propan - 2 - ol , 2 - [ 2 - fluoro - 6 - [ ( 8 - fluoro - 2 - methyl - 3 cozeb , maneb , metam , metiram , propineb , thiram , zineb , quinolyl) oxy ]phenyl ] propan - 2 -ol , 3 - ( 5 - fluoro - 3 , 3 , 4 , 4 ziram ; tetramethyl- 3 ,4 -dihydroisoquinolin - 1 - yl) quinoline , 3 - ( 4 , [ 0763] F .VIII 3 ) organochlorine compounds ( e . g . phthal 4 - difluoro -3 ,3 - dimethyl- 3 ,4 -dihydroisoquinolin - 1- yl) imides, sulfamides , chloronitriles ) : anilazine, chlorotha quinoline , 3 - ( 4 , 4 , 5 - trifluoro - 3 , 3 -dimethyl - 3 , 4 lonil , captafol, captan , folpet, dichlofluanid , dichloro dihydroisoquinolin - 1 - yl) quinoline ; phen , hexachlorobenzene , pentachlorphenole and its salts , [ 0773] F .XII ) Biopesticides phthalide , tolylfluanid , N -( 4 - chloro - 2 -nitro -phenyl ) - N [0774 ] F .XII 1 ) Microbial pesticides with fungicidal, bac ethyl- 4 -methyl - benzenesulfonamide ; tericidal, viricidal and / or plant defense activator activity : [ 0764 ] F . VIII 4 ) guanidines and others : guanidine, dodine , Ampelomyces quisqualis , Aspergillus flavus , Aureoba dodine free base , guazatine , guazatineacetate , iminocta sidium pullulans, Bacillus amyloliquefaciens, B . mojav dine , iminoctadine - triacetate , iminoctadine- tris (albesi ensis , B . pumilus, B . simplex , B . solisalsi, B . subtilis , B . late ), dithianon , 2 ,6 - dimethyl- 11 ,5H - [ 1 , 4 ]dithiino [ 2 , 3 - c : subtilis var . amyloliquefaciens, Candida oleophila , C . 5 ,6 - c ' ] dipyrrole - 1 , 3 , 5 , 7 (2H ,6H ) -tetraone ; saitoana , Clavibacter michiganensis (bacteriophages ) , [0765 ] F .IX ) Cell wall synthesis inhibitors Coniothyrium minitans, Cryphonectria parasitica , Cryp [ 0766 ] F . IX 1) inhibitors of glucan synthesis : validamycin , tococcus albidus, Dilophosphora alopecuri , Fusarium polyoxin B ; oxysporum , Clonostachys rosea f . catenulate ( also named [0767 ] F .IX 2 ) melanin synthesis inhibitors : pyroquilon , Gliocladium catenulatum ) , Gliocladium roseum , Lyso tricyclazole , carpropamid , dicyclomet , fenoxanil ; bacter antibioticus, L . enzymogenes, Metschnikowia fruc [0768 ] F . X ) Plant defence inducers ticola , Microdochium dimerum , Microsphaeropsis ochra [0769 ] F . X 1) acibenzolar - S -methyl , probenazole , iso cea , Muscodor albus, Paenibacillus polymyxa, Pantoea tianil, tiadinil , prohexadione -calcium ; vagans, Phlebiopsis gigantea, Pseudomonas sp. , [0770 ] F. X 2 ) phosphonates : fosetyl, fosetyl- aluminum , Pseudomonas chloraphis , Pseudozyma flocculosa , Pichia phosphorous acid and its salts , 4 - cyclopropyl- N - (2 , 4 anomala , Pythium oligandrum , Sphaerodes mycopara dimethoxyphenyl) thiadiazole - 5 - carboxamide ; sitica , Streptomyces griseoviridis , S . lydicus, S . violaceus [0771 ] F .XI ) Unknown mode of action niger, Talaromyces flavus, Trichoderma atroviride , T . fer [ 0772 ] bronopol, chinomethionat , cyflufenamid , cymoxa tile , T . gamsii , T. harmatum , T . harzianum ; mixture of T . nil, dazomet, debacarb , diclomezine, difenzoquat , difen harzianum and T. viride; mixture of T. polysporum and T. zoquat- methylsulfate , diphenylamin , fenpyrazamine , flu harzianum ; T . stromaticum , T . virens ( also named Glio metover, flusulfamide , flutianil, methasulfocarb , cladium virens ) , T . viride, Typhula phacorrhiza , Ulocla nitrapyrin , nitrothal- isopropyl, oxathiapiprolin , picar dium oudemansii , Verticillium dahlia , zucchini yellow butrazox , tolprocarb , 2 - [ 3 , 5 - bis ( difluoromethyl) - 1H mosaic virus (avirulent strain ) ; pyrazol - 1 - yl] - 1 - [ 4 - ( 4 - { 5 - [ 2 - ( prop - 2 - yn - 1 - yloxy) phenyl ] [0775 ] F. XII 2) Biochemical pesticides with fungicidal, 4 , 5 - dihydro - 1 , 2 -oxazol - 3 - yl ) - 1 , 3 - thiazol - 2 - yl) piperidin bactericidal, viricidal and / or plant defense activator activ 1 -yl ] ethanone , 2 - [ 3 , 5 -bis (difluoromethyl ) - 1H -pyrazol - 1 ity : chitosan (hydrolysate ), harpin protein , laminarin , yl] - 1 - [ 4 - ( 4 - { 5 - [ 2 - fluoro - 6 - ( prop - 2 - yn - 1 - yloxy ) phenyl] - 4 , Menhaden fish oil , natamycin , Plum pox virus coat pro 5 - dihydro - 1 , 2 - oxazol- 3 - yl) - 1 , 3 - thiazol - 2 - yl) piperidin - 1 tein , potassium or sodium bicarbonate , Reynoutria yl] ethanone, 2 - [ 3 , 5 - bis (difluoromethyl ) - 1H -pyrazol - 1 sachlinensis extract, salicylic acid , tea tree oil. yl] - 1 - [ 4 - ( 4 - 5 - [ 2 - chloro - 6 - (prop - 2 - yn - 1 -yloxy )phenyl ] [0776 ] Preferred compounds I are stated above . 4 , 5 - dihydro - 1 , 2 -oxazol - 3 - yl ) - 1 , 3 - thiazol - 2 - yl) piperidin 1 - yl] ethanone, oxin -copper , proquinazid , tebufloquin , [0777 ] The methods and mixtures of the invention pref tecloftalam , triazoxide , 2 -butoxy - 6 - iodo - 3 - propyl erably include one or more pesticidal compounds II. More chromen - 4 - one , N - ( cyclopropylmethoxyimino - (6 - dif preferred the active compounds II and III employed in the luoro -methoxy - 2 , 3 - difluoro - phenyl) -methyl ) - 2 - phenyl methods and mixtures of the inventions consist of one or acetamide , N '- ( 4 -( 4 - chloro -3 - trifluoromethyl- phenoxy ) more compounds II, or of one or more compounds II and /or 2 , 5 - dimethyl- phenyl ) - N - ethyl- N -methyl formamidine , one or more compounds III . If more than one compound of N ' - ( 4 - ( 4 - fluoro - 3 - trifluoromethyl- phenoxy ) - 2 , 5 - dim formula II and / or III is employed it is preferably 2 or 3 ethyl- phenyl ) - N - ethyl- N -methyl formamidine, N '- ( 2 compounds that are used . methyl- 5 -trifluoromethyl - 4 - (3 - trimethylsilanyl [0778 ] Preferred active compounds II selected from propoxy) -phenyl ) - N - ethyl- N -methyl formamidine , N '- ( 5 groups M and L : difluoromethyl- 2 - methyl- 4 - ( 3 - trimethylsilanyl- propoxy ) [0779 ] For each of the following the preferred combina phenyl) - N - ethyl- N -methyl formamidine, methoxy - acetic tion partner I is bilobalide , ginkgolide A or a mixture of acid 6 -tert - butyl- 8 - fluoro - 2 , 3 -dimethyl - quinolin - 4 - yl bilobalide and ginkgolide A . ester, 3 -[ 5 - (4 -methylphenyl ) - 2, 3 -dimethyl - isoxazolidin [0780 ] With respect to their use in the methods and 3 - yl] - pyridine, 3 - [ 5 - ( 4 -chloro -phenyl ) - 2 , 3 - dimethyl- isox pesticidal mixtures of the present invention preference is azolidin - 3 - yl) - pyridine ( pyrisoxazole ) , N - ( 6 -methoxy given to compounds II selected from the groups II - M . 2B , pyridin - 3 -yl ) cyclopropanecarboxylic acid amide, II -M .3A , II- M .4A , II- M .5 , II -M .6 , II - M . 10 , II- M . 13 , II- M . 5 -chloro - 1 - (4 , 6 - dimethoxy -pyrimidin -2 -yl ) - 2 -methyl 21A , II - M . 25 , II - M . 22 , II -M23 , II - M .28 , II - M .UN and II - L . US 2019 / 0281835 A1 Sep . 19 , 2019 24

3 . Particular preference is given to the groups II - M and L [ 0802 ] More preferably the compound II is thiamethoxam . wherein the at least one active compound II is selected from [ 0803] More preferably the compound II is dinotefuran . [0781 ] II - M .2B within the class of fiproles from fipronil or [0804 ] With regard to the use in a method and pesticidal ethiprole ; mixture of the present invention , the compound II is pref [0782 ] Il - M .3A within the class of pyrethroids from alpha erably selected from group M - II .5 as defined above and is cypermethrin and pyrethrum ; preferably spinosad . [ 0783] II - M .4A within the class of neonicotinoids from [0805 ] With regard to the use in a method and pesticidal acetamiprid , chlothianidin , dinotefuran , imidacloprid , mixture of the present invention , the compound II is pref nitenpyram , thiacloprid or thiamethoxam ; erably selected from group M - 11 . 6 as defined above and is [ 0784 ] II - M . 5 within the class of spinosyns from spinosad preferably abamectin , emamectin benzoate , lepimectin or or spinetoram ; milbemectin . 10785 ] Il- M .6 within the class of mectins from abamectin [0806 ] More preferably the compound II is abamectin . or emamectin ; [0807 ] More preferably the compound II is emamectin . [0786 ]. II - M . 10 within the mite growth inhibitors from [ 0808 ] Most preferably the compound II is abamectin . etoxazole ; [08091 . With regard to the use in a pesticidalmixture of the [0787 ] II - M . 13 within the uncouplers of oxidative phos present invention , the compound II is preferably selected phorylation from chlorfenapyr; from group M - II . X ( compounds of unknown or uncertain [ 0788 ] II - M .21A within the class of mitochondrial com mode of action ) as defined above and is preferably flupyra plex I electron transport inhibitors from pyridaben , difurone or sulfoxaflor. tebufenpyrad , tolfenpyrad or flufenerim ; [0810 ] With regard to the use in a method and pesticidal [ 0789] II - M . 25 within the class of mitochondrial complex mixture of the present invention , the compound II is pref II electron transport inhibitors from cyenopyrafen and erably selected from group II - L . 3 (biopesticides ) . cyflumetofen ; [0811 ] More preferably the compound II is a microbial [0790 ] II - M .22 within the voltage - dependent sodium pesticide , most preferably Beauveria bassiana . channel blockers from indoxacarb or metaflumizone ; [0812 ] In a further embodiment compound (I ) is not [0791 ] II - M .23 within the inhibitors of the lipid synthesis Beauveria bassiana . from spirodiclofen , spiromesifen or spirotetramat; [0813 ] Especially preferred are methods employing pesti [0792 ] II - M .28 within the class of diamides from fluben cidal mixtures containing alpha -cypermethrin as compound diamide, chlorantraniliprole , cyantraniliprole , cyclanilip II. role or tetraniliprole ; [0814 ] Especially preferred are methods employing pesti [0793 ] II - M .UN within the compounds of unknown or cidal mixtures containing pyrethrum as compound II . uncertain mode of action from afidopyropene , afoxolaner , [0815 ] Especially preferred are pesticidal mixtures con bifenazate , flupyradifurone , fluralaner, piperonyl butox taining fipronil or ethiprole as compound II . ide , pyridalyl, pyrifluquinazon , sulfoxaflor or triflum [0816 ] Especially preferred are pesticidal mixtures con ezopyrim ; taining imidacloprid as compound II . [0794 ] II - M .BP - 1 within the class of microbial pesticides [0817 ] Especially preferred are pesticidal mixtures con from Bacillus firmus, B . thuringiensis ssp . israelensis , B . taining acetamiprid as compound II . t . ssp . galleriae , B . t . ssp . kurstaki, Beauveria bassiana , [0818 ] Especially preferred are pesticidal mixtures con Burkholderia sp . or Paenibacillus poppiliae . taining chlothianidine as compound II . [0795 ] With regard to the use in a method and pesticidal [ 0819 ] Especially preferred are pesticidal mixtures con mixture of the present invention , the compound II is pref taining dinotefuran as compound II . erably selected from group M - II. 2 . B as defined above and is [0820 ] Especially preferred are pesticidal mixtures con preferably fipronil or ethiprole , more preferably fipronil . taining nitenpyram as compound II . [0796 ] With regard to the use in a method of the present [ 0821] Especially preferred are pesticidal mixtures con invention , the compound II is preferably selected from taining thiacloprid as compound II . group M - II .3A defined above and is preferably alpha -cyper [0822 ] Especially preferred are pesticidal mixtures con methrin , acrinathrin , bifenthrin , cyfluthrin , lambda - cyhalo taining spinosad as compound II . thrin , cypermethrin , beta - cypermethrin , zeta - cypermethrin , [0823 ] Especially preferred are pesticidal mixtures con deltamethrin , esfenvalerate , etofenprox , fenpropathrin , flu taining abamectin as compound II . cythrinate , tau - fluvalinate , silafluofen or tralomethrin . Fur [0824 ] Especially preferred are pesticidal mixtures con ther preferred is pyrethrum . taining sulfoxaflor as compound II . [ 0797 ] More preferably the compound II is alpha -cyper [0825 ] Especially preferred are pesticidal mixtures con methrin , lambda - cyhalothrin , bifenthrin , pyrethrum or del taining flupyradifurone as compound II . tamethrin , most preferably it is alpha -cypermethrin or pyre [ 0826 ] Especially preferred are pesticidal mixtures con thrum . taining the compound Beauveria bassiana as compound II . [0798 ] With regard to the use in a method and pesticidal [0827 ] Preferred fungicidal active compounds III selected mixture of the present invention , the compound II is pref from group F erably selected from group M - II. 4A as defined above and is [0828 ]. With respect to their use in the pesticidal mixtures preferably acetamiprid , chlothianidin , dinotefuran , imida of the present invention , particular preference is given to cloprid , nitenpyram , thiacloprid or thiamethoxam . certain fungicidal active compounds III listed in the para [0799 ] More preferably the compound II is acetamiprid . graphs below . [0800 ] More preferably the compound II is clothianidin . [0829 ] In a further preferred embodiment compound III is [ 0801 ] More preferably the compound II is imidacloprid . preferably selected from group F . Ia ). US 2019 /0281835 A1 Sep . 19 , 2019 25

[0830 ] More preferably the compound III is azoxystrobin , TABLE A -continued fluoxastrobin , picoxystrobin , pyraclostrobin or triflox ystrobin . Preferred mixtures of the invention [ 0831 ] Most preferably the compound III is pyra No Compound I Compound II Compound III clostrobin . [ 0832] In a further preferred embodiment compound III is 23 . ginkgolide A dinotefuran 24 . ginkgolide A imidaclorid preferably selected from group F . Ic ) . 25 . ginkgolide A nitenpyram 0833 ] More preferably the compound III is bixafen , 26. ginkgolide A thiacloprid boscalid , fluopyram , fluxapyroxad , isopyrazam , penflufen , 27 . ginkgolide A thiamethoxam penthiopyrad or sedaxane . 28 . ginkgolide A spinosad 29 . ginkgolide A abamectin [0834 ] More preferably the compound III is fluxapyroxad . 30 . ginkgolide A flupyradifurone [0835 ] More preferably the compound III is boscalid . 31 . ginkgolide A sulfoxaflor [0836 ] Most preferably the compound III is fluxapyroxad . 32 . ginkgolide A Beauveria bassiana [ 0837 ] In a further preferred embodiment compound ( III ) 33 . ginkgolide A pyraclostrobin 34 . ginkgolide A fluxapyroxad is a thio or dithiocarbamate (F .VIII2 ), in particular manco 35 . bilobalide and ginkgolide A alpha -cypermethrin zeb . 36 . bilobalide and ginkgolide A fipronil [ 0838 ] In a further preferred embodiment compound ( III ) 37 . bilobalide and ginkgolide A ethiprole is a respiratory inhibitor ( F . 14 ), preferably a nitrophenyl 38 . bilobalide and ginkgolide A acetamiprid 39 . bilobalide and ginkgolide A chlothianidin derivative , in particular amectotradin . 40 . bilobalide and ginkgolide A dinotefuran [ 0839] In a further preferred embodiment compound ( III ) 41 . bilobalide and ginkgolide A imidaclorid is a tubulin inhibitor ( F . IV2) , in particular carbendazim . 42 . bilobalide and ginkgolide A nitenpyram [0840 ] In a further preferred embodiment compound ( III) 43 . bilobalide and ginkgolide A thiacloprid 44 . bilobalide and ginkgolide A thiamethoxam is a signal transduction inhibitor ( F . VI) , preferably a MAP / 45 . bilobalide and ginkgolide A spinosad histidine kinase inhibitor, in particular iprodione. 46 . bilobalide and ginkgolide A abamectin [ 0841 ] In a further preferred embodiment compound ( III ) 47 . bilobalide and ginkgolide A flupyradifurone is a C14 demethylase inhibitor ( F . II) , preferably a triazole, in 48 . bilobalide and ginkgolide A sulfoxaflor 49 . bilobalide and ginkgolide A Beauveria bassiana particular epoxiconazole or difenoconazole , or a imidazole, 50 . bilobalide and ginkgolide A pyraclostrobin in particular prochloraz . 51 . bilobalide and ginkgolide A fluxapyroxad [ 0842] In a further preferred embodiment compound ( III ) 52 . ginkgolide B alpha- cypermethrin is a organochlorine compound ( F . VIII3 ) , in particular chlo 53 . ginkgolide B fipronil 54 . ginkgolide B ethiprole rothalonit . 55 . ginkgolide B acetamiprid [0843 ] In a further preferred embodiment compound ( III ) 56 . ginkgolide B chlothianidin is a inhibitor of 3 -keto reductage ( F . 113 ) , in particular 57 . ginkgolide B dinotefuran fenhexamid . 58 . ginkgolide B imidaclorid 59 . ginkgolide B nitenpyram [ 0844 ] In a further preferred embodiment compound ( III ) 60 . ginkgolide B thiacloprid is a methionine synthesis inhibitor ( F . V1) , in particular 61. ginkgolide B thiamethoxam pyrimethanil . 62 . ginkgolide B spinosad [0845 ] Preferred for application in the method of the 63 . ginkgolide B abamectin 64 . ginkgolide B flupyradi furone invention or as mixture of the invention are the mixtures 65 . ginkgolide B sulfoxaflor shown in Table A . 66 . ginkgolide B Beauveria bassiana 67. ginkgolide B pyraclostrobin 68 . ginkgolide B fluxapyroxad TABLE A 69 . ginkgolide C alpha- cypermethrin 70 . ginkgolide C fipronil Preferred mixtures of the invention 71. ginkgolide C ethiprole No Compound I Compound II Compound III 72 . ginkgolide C acetamiprid 73. ginkgolide C chlothianidin 1 . bilobalide alpha - cypermethrin 74 . ginkgolide C dinotefuran 2 . bilobalide fipronil 75 . ginkgolide C imidaclorid 3 . bilobalide ethiprole 76 . ginkgolide C nitenpyram 4 . bilobalide acetamiprid 77 . ginkgolide C thiacloprid 5 . bilobalide chlothianidin 78 . ginkgolide C thiamethoxam 6 . bilobalide dinotefuran 79 . ginkgolide C spinosad 7 . bilobalide imidaclorid 80 . ginkgolide C abamectin 8 . bilobalide nitenpyram 81 . ginkgolide C flupyradifurone 9 . bilobalide thiacloprid 82. ginkgolide C sulfoxaflor 10 . bilobalide thiamethoxam 83 . ginkgolide C Beauveria bassiana 11 . bilobalide spinosad 84 . ginkgolide C pyraclostrobin 12 . bilobalide abamectin 85 . ginkgolide C fluxapyroxad 13 . bilobalide flupyradifurone 86 . ginkgolide J alpha -cypermethrin 14 . bilobalide sulfoxaflor 87 . ginkgolide J fipronil 15 . bilobalide Beauveria bassiana 88 . ginkgolide J ethiprole 16 . bilobalide pyraclostrobin 89 . ginkgolide J acetamiprid 17 . bilobalide fluxapyroxad 90 . ginkgolide J chlothianidin 18 . ginkgolide A alpha -cypermethrin 91 . ginkgolide J dinotefuran 19 . ginkgolide A fipronil 92 . ginkgolide J imidaclorid 20 . ginkgolide A ethiprole 93 . ginkgolide J nitenpyram 21. ginkgolide A acetamiprid 94 . ginkgolide J thiacloprid 22. ginkgolide A chlothianidin 95 . ginkgolide J thiamethoxam US 2019 /0281835 A1 Sep . 19 , 2019 26 .

TABLE A -continued TABLE A -continued Preferred mixtures of the invention Preferred mixtures of the invention No Compound I Compound II Compound III No Compound I Compound II Compound III 96 . ginkgolide J spinosad 169 . ginkgolide A thiamethoxam fluxapyroxad 97 . ginkgolide J abamectin 170 . ginkgolide A spinosad pyraclostrobin 98 . ginkgolide J flupyradifurone 171 . ginkgolide A spinosad fluxapyroxad 99 . ginkgolide J sulfoxaflor 172 . ginkgolide A abamectin pyraclostrobin 100 . ginkgolide J Beauveria bassiana 173 . ginkgolide A abamectin fluxapyroxad 101. ginkgolide J pyraclostrobin 174 . ginkgolide A flupyradifurone pyraclostrobin 102 . ginkgolide J fluxapyroxad 175 . ginkgolide A flupyradifurone fluxapyroxad 103 . ginkgolide M alpha - cypermethrin 176 . ginkgolide A sulfoxaflor pyraclostrobin 104 . ginkgolide M fipronil 177 . ginkgolide A sulfoxaflor fluxapyroxad 105. ginkgolide M ethiprole 178 . ginkgolide A Beauveria bassiana pyraclostrobin 106 . ginkgolide M acetamiprid 179 . ginkgolide A Beauveria bassiana fluxapyroxad 107 . ginkgolide M chlothianidin 180 . bilobalide pyrethrum 108 . ginkgolide M dinotefuran 181 . ginkgolide A pyrethrum 109. ginkgolide M imidaclorid 182 . bilobalide + ginkgolide A pyrethrum 110 . ginkgolide M nitenpyram 183 . bilobalide pyraclostrobin 111 . ginkgolide M thiacloprid 184 . ginkgolide A pyraclostrobin 112 . ginkgolide M thiamethoxam 185 . bilobalide + ginkgolide A pyraclostrobin 113. ginkgolide M spinosad 186 . bilobalide fluxapyroxad 114 . ginkgolide M abamectin 187 . ginkgolide A fluxapyroxad 115 . ginkgolide M flupyradifurone 188 . bilobalide + ginkgolide A fluxapyroxad 116 . ginkgolide M sulfoxaflor 189 . bilobalide mancozeb 117 . ginkgolide M Beauveria bassiana 190 . ginkgolide A mancozeb 118 . ginkgolide M pyraclostrobin 191 . bilobalide + ginkgolide A mancozeb 119 . ginkgolide M fluxapyroxad 192 . bilobalide ametoctradin 120 . bilobalide alpha -cypermethrin pyraclostrobin 193 . ginkgolide A ametoctradin 121. bilobalide alpha -cypermethrin fluxapyroxad 194 . bilobalide + ginkgolide A ametoctradin 122 . bilobalide fipronil pyraclostrobin 195 . bilobalide carbendazim 123 . bilobalide fipronil fluxapyroxad 196 . ginkgolide A carbendazim 124 . bilobalide ethiprole pyraclostrobin 197 . bilobalide + ginkgolide A carbendazim 125 . bilobalide ethiprole fluxapyroxad 198 . bilobalide iprodion 126 . bilobalide acetamiprid pyraclostrobin 199 . ginkgolide A iprodion 127 . bilobalide acetamiprid fluxapyroxad 200 . bilobalide + ginkgolide A iprodion 128 . bilobalide chlothianidin pyraclostrobin 201. bilobalide prochloraz 129 . bilobalide chlothianidin fluxapyroxad 202. ginkgolide A prochloraz 130 . bilobalide dinotefuran pyraclostrobin 203. bilobalide + ginkgolide A prochloraz 131 . bilobalide dinotefuran fluxapyroxad 204 . bilobalide chlorothalonil 132 . bilobalide imidaclorid pyraclostrobin 205. ginkgolide A chlorothalonil 133 . bilobalide imidaclorid fluxapyroxad 206 . bilobalide + ginkgolide A chlorothalonil 134 . bilobalide nitenpyram pyraclostrobin 207 . bilobalide azoxystrobin 135 . bilobalide nitenpyram fluxapyroxad 208. ginkgolide A azoxystrobin 136 . bilobalide thiacloprid pyraclostrobin 209 . bilobalide + ginkgolide A azoxystrobin 137 . bilobalide thiacloprid fluxapyroxad 210 . bilobalide trifloxystrobin 138 . bilobalide thiamethoxam pyraclostrobin 211 . ginkgolide A trifloxystrobin 139 . bilobalide thiamethoxam fluxapyroxad 212 . bilobalide + ginkgolide A trifloxystrobin 140 . bilobalide spinosad pyraclostrobin 213 . bilobalide fenhexamid 141. bilobalide spinosad fluxapyroxad 214 . ginkgolide A fenhexamid 142 . bilobalide abamectin pyraclostrobin 215 . bilobalide + ginkgolide A fenhexamid 143 . bilobalide abamectin fluxapyroxad 216 . bilobalide pyrimethanil 144 . bilobalide flupyradifurone pyraclostrobin 217 . ginkgolide A pyrimethanil 145 . bilobalide flupyradifurone fluxapyroxad 218 . bilobalide + ginkgolide A pyrimethanil 146 . bilobalide sulfoxaflor pyraclostrobin 219 . bilobalide epoxiconazol 147. bilobalide sulfoxaflor fluxapyroxad 220 . ginkgolide A epoxiconazol 148 . bilobalide Beauveria bassiana pyraclostrobin 221 . bilobalide + ginkgolide A epoxiconazol 149 . bilobalide Beauveria bassiana fluxapyroxad 222. bilobalide picoxystrobin 150 . ginkgolide A alpha -cypermethrin pyraclostrobin 223 . ginkgolide A picoxystrobin 151 . ginkgolide A alpha -cypermethrin fluxapyroxad 224 . bilobalide + ginkgolide A picoxystrobin 152 . ginkgolide A fipronil pyraclostrobin 225 . bilobalide difenoconazol 153. ginkgolide A fipronil fluxapyroxad 226 . ginkgolide A difenoconazol 154 . ginkgolide A ethiprole pyraclostrobin 227 . bilobalide + ginkgolide A difenoconazol 155 . ginkgolide A ethiprole fluxapyroxad 156 . ginkgolide A acetamiprid pyraclostrobin 157 . ginkgolide A acetamiprid fluxapyroxad 158. ginkgolide A chlothianidin pyraclostrobin [0846 ] Pests 159. ginkgolide A chlothianidin fluxapyroxad 160 . ginkgolide A dinotefuran pyraclostrobin [0847 ] The compounds applied in the methods of the 161 . ginkgolide A dinotefuran fluxapyroxad invention are used , preferably on soybean and / or maize (Zea 162. ginkgolide A imidaclorid pyraclostrobin mays ), to control pests from the family of Pentatomidae , 163. ginkgolide A imidaclorid fluxapyroxad particularly stinkbugs , e . g . Nezara spp . ( e . g . Nezara 164 . ginkgolide A nitenpyram pyraclostrobin 165 . ginkgolide A nitenpyram fluxapyroxad viridula , Nezara antennata , Nezara hilaris ) , Piezodorus spp . 166 . ginkgolide A thiacloprid pyraclostrobin ( e . g . Piezodorus guildinii ), Acrosternum spp . ( e . g . Acroster 167. ginkgolide A thiacloprid fluxapyroxad num hilare ), Euchistus spp . ( e. g . Euchistus heros, Euschistus 168. ginkgolide A thiamethoxam pyraclostrobin servus ) , Halyomorpha halys, Megacopta cribaria , Plautia crossota , Riptortus clavatus, Rhopalus msculatus, Antesti US 2019 / 0281835 A1 Sep . 19 , 2019 27

opsis orbitalus, Dectes texanus, Dichelops spp . ( e . g . Dich - ( 0870 ] Some of them are systemically effective and can be elops furcatus, Dichelops melacanthus ), Eurygaster spp . employed in crop protection as foliar fungicides, as fungi ( e . g . Eurygaster intergriceps, Eurygaster maurd ) , Oebalus cides for seed dressing and as soil fungicides . They can also spp . (e .g . Oebalus mexicana , Oebalus poecilus, Oebalus be used for treating seed . pugnase , Scotinophara spp . ( e . g . Scotinophara lurida , Sco [0871 ] They are particularly important in the control of a tinophara coarctatd ) . Preferred targets include Acrosternum multitude of fungi on various cultivated plants, such as hilare, Antestiopsis orbitalus, Dichelops furcatus, Dichelops maize , wheat, rye , barley , oats , rice , corn , lawns , bananas , melacanthus, Euchistus heros , Euschistus servus, Mega cotton , soybean , lima bean , coffee, sugar cane , grapevines , copta cribaria , Nezara viridula , Nezara hilare , Piezodorus fruits and ornamental plants and vegetables such as cucum guildinii, Halyomorpha halys . In one embodiment the stink bers , beans , tomatoes , potatoes and curcurbits , and on the bug target is Nezara viridula , Piezodorus spp . , Acrosternum seeds of these plants . spp , Euchistus heros. Euschistus and in particular Euchistus heros are preferred targets . [0872 ] Formulations [ 0848 ] Further pests in particular of soybeans and /or [0873 ] The mixtures according to the invention and maize that can be controlled with the mixtures of the applied in the methods of the invention can be converted into invention include Elasmopalpus lignosellus, Diloboderus the customary formulations , for example solutions , emul abderus, Diabrotica speciosa , Sternechus subsignatus , For sions , suspensions, dusts , powders, pastes and granules. The micidae , Agrotis ipsilon , Julus ssp ., Anticarsia gemmatalis , use form depends on the particular intended purpose; in each Megacopta spp ., Megascelis ssp . , Procornitermes ssp . , case , it should ensure a fine and even distribution of the Gryllotalpidae, Nezara viridula , Neomegalotomus spp ., compounds according to the invention . Cerotoma trifurcata , Popillia japonica , Edessa spp . , Liog [0874 ]. Therefore the invention also relates to agrochemi enys fuscus, stem borer, Dectes spp , stalk borer, Scaptocoris cal compositions comprising an auxiliary and a mixture of at castanea , phyllophaga spp . , Pseudoplusia includens , least one compound I of formula I and of at least one Spodoptera spp ., Bemisia tabaci, Agriotes spp ., Thripidae , compound II and /or one compound III according to the preferably Diloboderus abderus, Diabrotica speciosa , present invention . Piezodorus spp ., Cerotoma trifurcata , Popillia japonica , [0875 ] An agrochemical composition comprises a pesti Phyllophaga spp . Agriotes spp . cidally effective amount of a compound I . The term " effec [ 0849] Depending on the spectrum of activity of the tive amount” denotes an amount of the composition or of the compounds II , mixtures of the invention can be used for the compounds I, which is sufficient for controlling harmful control of: pests on cultivated plants or in the protection of materials and which does not result in a substantial damage to the [ 0850 ] insects from the order of the lepidopterans (Lepi treated plants. Such an amount can vary in a broad range and doptera ), such as Heliothis spp ., e. g . Heliothis virescens, is dependent on various factors , such as the fungal species [0851 ] beetles (Coleoptera ), such as Anthonomus spp ., e. g . and /or the pest species to be controlled , the treated cultivated Anthonomus grandis, flies, mosquitoes (Diptera ), such as plant or material, the climatic conditions and the specific Ceratitis spp ., e . g . Ceratitis capitata , Aedes spp ., e. g . compound I used . [ 0852] Aedes aegypti, [0876 ] The active compounds I and II and /or III , their [ 0853 ] termites ( Isoptera ) , N -oxides and salts can be converted into customary types of [ 0854 ] cockroaches (Blattaria -Blattodea ) , agrochemical compositions, e . g . solutions, emulsions, sus [ 0855 ] bugs , aphids , leafhoppers , whiteflies, scale insects , pensions, dusts, powders , pastes , granules , pressings, cap cicadas (Hemiptera ), sules , and mixtures thereof. Examples for composition types [ 0856 ] ants , bees, wasps, sawflies (Hymenoptera ), are suspensions ( e . g . SC , OD , FS ) , emulsifiable concentrates [ 0857] crickets , grasshoppers , locusts (Orthoptera ), ( e . g . EC ), emulsions ( e . g . EW , EO , ES , ME ), capsules ( e . g . 0858 ] arachnids ( Arachnida ) , CS , ZC ) , pastes, pastilles, wettable powders or dusts ( e . g . [0859 ] fleas ( Siphonaptera) , WP, SP, WS, DP, DS) , pressings ( e . g . BR , TB , DT) , granules [ 0860 ] silverfish , firebrat ( Thysanura ), ( e . g . WG , SG , GR , FG , GG , MG ) , insecticidal articles ( e . g . [ 0861] centipedes ( Chilopoda ) , LN ) , as well as gel formulations for the treatment of plant propagation materials such as seeds ( e . g . GF) . These and [ 0862 ] millipedes (Diplopoda ) , further compositions types are defined in the “ Catalogue of [0863 ] earwigs ( Dermaptera) , pesticide formulation types and international coding sys [ 0864 ] lice (Phthiraptera ), tem ” , Technical Monograph No . 2 , 6th Ed . May 2008 , [ 0865 ] springtails (Collembola ) , CropLife International. [ 0866 ] and [0877 ] The compositions are prepared in a knownmanner , [ 0867] plant parasitic nematodes. such as described by Mollet and Grubemann , Formulation [ 0868 ] Depending on the spectrum of activity of the technology , Wiley VCH , Weinheim , 2001 ; or Knowles , New compounds III , mixtures of the invention can be used for the developments in crop protection product formulation , control of phytopathogenic fungi and fungus - like eukaryotic Agrow Reports DS243, T & F Informa, London , 2005 . microorganisms from Ascomycetes , Basidiomycetes , Deu [ 0878 ] Suitable auxiliaries are solvents , liquid carriers , teromycetes and Peremosporomycetes ( syn . Domycetes ) . solid carriers or fillers , surfactants , dispersants , emulsifiers , [0869 ] Phytophtora such as Examples of pathogens are wetters , adjuvants, solubilizers , penetration enhancers, pro Phytophtora infestans, Botrytis, such as Botrytis cinerea , tective colloids, adhesion agents , thickeners , humectants , Pyricularia such as Pyricularia oryzae, Septoria such as repellents , attractants , feeding stimulants , compatibilizers , Septoria tritici, Alternaria such as Alternaria solani and bactericides, anti - freezing agents , anti - foaming agents , colo Leptosphaeria , such as Leptosphaeria nodorum . rants , tackifiers and binders . US 2019 / 0281835 A1 Sep . 19 , 2019

[0879 ] Suitable solvents and liquid carriers are water and polymers of the A - B or A - B - A type comprising blocks of organic solvents, such as mineral oil fractions ofmedium to polyethylene oxide and polypropylene oxide , or of the high boiling point, e . g . kerosene , diesel oil ; oils of vegetable A - B - C type comprising alkanol, polyethylene oxide and or animal origin ; aliphatic , cyclic and aromatic hydrocar polypropylene oxide. Suitable polyelectrolytes are polyacids bons, e . g. toluene , paraffin , tetrahydronaphthalene , alky or polybases . Examples of polyacids are alkali salts of lated naphthalenes; alcohols , e . g . ethanol, propanol, butanol, polyacrylic acid or polyacid comb polymers . Examples of benzylalcohol, cyclohexanol; glycols ; DMSO ; ketones , e . g . polybases are polyvinylamines or polyethyleneamines . cyclohexanone; esters , e . g . lactates , carbonates , fatty acid [0885 ) Suitable adjuvants are compounds , which have a esters , gamma- butyrolactone ; fatty acids; phosphonates ; neglectable or even no pesticidal activity themselves , and amines ; amides, e. g . N -methylpyrrolidone , fatty acid dim which improve the biological performance of the compound ethylamides ; and mixtures thereof. I on the target . Examples are surfactants , mineral or veg [ 0880 ] Suitable solid carriers or fillers are mineral earths , etable oils , and other auxilaries . Further examples are listed e . g . silicates, silica gels , talc , kaolins, limestone , lime, chalk , by Knowles , Adjuvants and additives , Agrow Reports clays , dolomite , diatomaceous earth , bentonite , calcium sul DS256 , T & F Informa UK , 2006 , chapter 5 . fate , magnesium sulfate , magnesium oxide ; polysaccha [ 0886 ] Suitable thickeners are polysaccharides ( e . g . xan rides , e . g . cellulose , starch ; fertilizers, e . g . ammonium sul than gum , carboxymethylcellulose ), anorganic clays (or fate , ammonium phosphate , ammonium nitrate , ureas ; ganically modified or unmodified ), polycarboxylates, and products of vegetable origin , e . g . cereal meal, tree bark silicates . meal , wood meal, nutshell meal, and mixtures thereof. [ 0887 ] Suitable bactericides are bronopol and isothiazoli [ 0881 ] Suitable surfactants are surface -active compounds, none derivatives such as alkylisothiazolinones and benziso such as anionic , cationic , nonionic and amphoteric surfac tants , block polymers , polyelectrolytes , and mixtures thiazolinones. thereof. Such surfactants can be used as emulsifier , disper [0888 ] Suitable anti- freezing agents are ethylene glycol, sant, solubilizer , wetter, penetration enhancer, protective propylene glycol, urea and glycerin . colloid , or adjuvant. Examples of surfactants are listed in [ 0889 ] Suitable anti - foaming agents are silicones , long McCutcheon ' s , Vol. 1 : Emulsifiers & Detergents ,McCutch chain alcohols , and salts of fatty acids . eon ' s Directories , Glen Rock , USA , 2008 ( International Ed . [ 0890 ] Suitable colorants ( e . g . in red , blue , or green ) are or North American Ed .) . pigments of low water solubility and water - soluble dyes . [ 0882 ] Suitable anionic surfactants are alkali , alkaline Examples are inorganic colorants ( e . g . iron oxide , titan earth or ammonium salts of sulfonates , sulfates , phosphates , oxide , iron hexacyanoferrate ) and organic colorants (e . g . carboxylates , and mixtures thereof. Examples of sulfonates alizarin -, azo - and phthalocyanine colorants ). are alkylarylsulfonates , diphenylsulfonates, alpha - olefin sul [0891 ] Suitable tackifiers or binders are polyvinylpyrroli fonates , lignine sulfonates, sulfonates of fatty acids and oils , dons, polyvinylacetates , polyvinyl alcohols , polyacrylates , sulfonates of ethoxylated alkylphenols , sulfonates of biological or synthetic waxes , and cellulose ethers . alkoxylated arylphenols , sulfonates of condensed naphtha [0892 ] The agrochemical compositions generally com lenes , sulfonates of dodecyl- and tridecylbenzenes , sul prise between 0 .01 and 95 % , preferably between 0 . 1 and fonates of naphthalenes and alkylnaphthalenes, sulfosucci 90 % , and in particular between 0 . 5 and 75 % , by weight of nates or sulfosuccinamates . Examples of sulfates are sulfates active substance . The active substances are employed in a of fatty acids and oils , of ethoxylated alkylphenols , of purity of from 90 % to 100 % , preferably from 95 % to 100 % alcohols , of ethoxylated alcohols , or of fatty acid esters . (ac - cording to NMR spectrum ) . Examples of phosphates are phosphate esters . Examples of [0893 ] Solutions for seed treatment (LS ) , Suspoemulsions carboxylates are alkyl carboxylates, and carboxylated alco (SE ), flowable concentrates (FS ), powders for dry treatment hol or alkylphenol ethoxylates . (DS ) , water - dispersible powders for slurry treatment (WS ) , [ 0883] Suitable nonionic surfactants are alkoxylates , water- soluble powders (SS ), emulsions (ES ), emulsifiable N - substituted fatty acid amides , amine oxides , esters , sugar concentrates (EC ) and gels (GF ) are usually employed for based surfactants , polymeric surfactants , and mixtures the purposes of treatment of plant propagation materials , thereof. Examples of alkoxylates are compounds such as particularly seeds . The compositions in question give , after alcohols , alkylphenols , amines , amides, arylphenols , fatty two - to - tenfold dilution , active substance concentrations of acids or fatty acid esters which have been alkoxylated with from 0 .01 to 60 % by weight, preferably from 0 . 1 to 40 % by 1 to 50 equivalents . Ethylene oxide and / or propylene oxide weight, in the ready -to - use preparations . Application can be may be employed for the alkoxylation , preferably ethylene carried out before or during sowing . Methods for applying oxide . Examples of N - substituted fatty acid amides are fatty compound I and compositions thereof, respectively , on to acid glucamides or fatty acid alkanolamides. Examples of plant propagation material , especially seeds include dress esters are fatty acid esters , glycerol esters or monoglycer ing , coating, pelleting , dusting , soaking and in - furrow appli ides . Examples of sugar -based surfactants are sorbitans , cation methods of the propagation material. Preferably , ethoxylated sorbitans , sucrose and glucose esters or alkyl compound I or the compositions thereof, respectively , are polyglucosides . Examples of polymeric surfactants are applied on to the plant propagation material by a method homo- or copolymers of vinylpyrrolidone , vinylalcohols , or such that germination is not induced , e . g . by seed dressing , vinylacetate . pelleting , coating and dusting . [0884 ] Suitable cationic surfactants are quaternary surfac [0894 ] When employed in plant protection , the amounts of tants , for example quaternary ammonium compounds with active substances applied are , depending on the kind of one or two hydrophobic groups , or salts of long - chain effect desired , from 0 .001 to 2 kg per ha , preferably from primary amines . Suitable amphoteric surfactants are alkyl - 0 . 005 to 2 kg per ha, more preferably from 0 . 05 to 0 . 9 kg per betains and imidazolines. Suitable block polymers are block ha , and in particular from 0 . 1 to 0 .75 kg per ha . US 2019 / 0281835 A1 Sep . 19 , 2019

[ 0895 ] In treatment of plant propagation materials such as before and after the infection of the plants, plant propagation seeds, e . g . by dusting, coating or drenching seed , amounts materials , such as seeds, soil , surfaces, materials or rooms of active substance of from 0 . 1 to 1000 g , preferably from by the insects . 1 to 1000 g , more preferably from 1 to 100 g and most [0905 ] In the mixtures and compositions according to the preferably from 5 to 100 g, per 100 kilogram of plant invention , the weight ratio of the compound I and compound propagation material (preferably seeds) are generally II or III generally depends from the properties of the required . In some cases the amount for seed treatment may compounds II or III used , usually it is in the range of from be up to 100 kilogram per 100 kilogram of seeds, or may 10 000 : 1 to 1 : 10 , regularly in the range of from 7500 : 1 to even excess the seed weight. 1: 5 , preferably in the range of from 5000 : 1 to 1 :5 , more [ 0896 ] When used in the protection of materials or stored preferably in the range of from 1000 : 1 to 1 : 2 , even more products, the amount of active substance applied depends on preferably in the range of from 500 : 1 to 5 : 1 and in particular the kind of application area and on the desired effect. in the range of from 300 : 1 to 5 : 1 . Amounts customarily applied in the protection of materials [0906 ]. According to further embodiments of the mixtures are 0 .001 g to 2 kg , preferably 0 . 005 g to 1 kg , of active according to the invention , the weight ratio of compound I substance per cubic meter of treated material. to compound II usually is in the range of from 10 000 : 1 to [0897 ) Various types of oils , wetters , adjuvants , fertilizer, 1 : 10 , regularly in the range of from 5000 : 1 to 1 : 5 , preferably or micronutrients , and further pesticides ( e .g . herbicides, in the range of from 3000 : 1 to 1 : 2 , more preferably in the insecticides , fungicides, growth regulators, safeners ) may be range of from 1000 : 1 to 1 : 1 , even more preferably in the added to the active substances or the compositions compris range of from 500 : 1 to 1 : 1 and in particular in the range of ing them as premix or, if appropriate not until immediately from 250 : 1 to 5 : 1 . prior to use ( tank mix ) . These agents can be admixed with 10907 ] According to further embodiments of the mixtures the compositions according to the invention in a weight ratio according to the invention , the weight ratio of compound I of 1 : 100 to 100 : 1 , preferably 1 : 10 to 10 : 1 . to compound III usually is in the range of from 5000 : 1 to [0898 ] The user applies the composition according to the 1 : 5 , regularly in the range of from 2000 : 1 to 1 : 1 , preferably invention usually from a predosage device , a knapsack in the range of from 1500 : 1 to 1 : 1 , more preferably in the sprayer, a spray tank , a spray plane , or an irrigation system . range of from 1000 : 1 to 2 : 1 , even more preferably in the Usually , the agrochemical composition is made up with range of from 500 : 1 to 5 : 1 and in particular in the range of water, buffer , and /or further auxiliaries to the desired appli from 300 : 1 to 1 : 10 . cation concentration and the ready - to - use spray liquor or the [0908 ] In the ternary mixtures, i. e . compositions according agrochemical composition according to the invention is thus to the invention comprising compound I (component 1 ) and obtained . Usually , 20 to 2000 liters , preferably 50 to 400 a compound II ( component 2 ) and a compound III ( compo liters , of the ready -to -use spray liquor are applied per hectare nent 3 ) , the weight ratio of component 1 ) and component 2 ) of agricultural useful area . depends from the properties of the active substances used . In [0899 ] According to one embodiment , individual compo one embodiment the amounts of compounds I , II and III are nents of the composition according to the invention such as derived from the above values for the weight ratios of parts of a kit or parts of a binary or ternary mixture may be compounds I and compounds II and III respectively . mixed by the user himself in a spray tank and further [0909 . Typical values for certain classes of compounds auxiliaries may be added , if appropriate . (with compound (I ) being preferably bilobalide or gink [ 0900 ] In a further embodiment, either individual compo golide A ) are : Neonicotinoids , such as dinotefuran , mida nents of the composition according to the invention or cloprid and thiamethoxam (weight ratio compound ( I ) to partially premixed components , e . g . components compris compound ( III ) 10 000 : 1 to 1: 1, preferably 7500 : 1 to 50 to ing active compound I and active compounds II ( and option 1 , more preferred 5000 : 1 to 100 to 1 , in particular 4500 to ally active compounds III ) , may be mixed by the user in a 1 to 150 to 1 . spray tank and further auxiliaries and additives may be [0910 ] For synthetic pyrethroids, such as a - cypermethrin added , if appropriate . the ratios for neonicotinoids are applicable . [0901 ] In a further embodiment, either individual compo [0911 ] The same applies for chloride channel activators , nents of the composition according to the invention or preferably avermectins such as abamectin . partially premixed components , e . g . components compris [ 0912 ] For pyrethrum and nicotinic acetylcholine receptor ing active compound I and active compounds II and / or III , allosteric activators , preferably spinosyns, such as spinosad , can be applied jointly ( e . g . after tank mix ) or consecutively . a typical ratio is ( I : II ) : 100 : 1 to 1 to 100 , preferably 10 : 1 to [0902 ] Applications 1 : 50 , more preferably 5 : 1 to 1 : 10 , in particular 1 : 2 to 1 : 5 , [0903 ] The compound I and the one or more compound (s ) specifically 1 : 1 to 1: 3 . II and /or III can be applied simultaneously , that is jointly or [0913 ] Strobilurines, such as pyraclostrobin , azoxystrobin , separately , or in succession , that is immediately one after trifluxystrobin and picoxystrobin ( I: III ) 5000 : 1 to 1 : 1 , pref another and thereby creating the mixture “ in -situ ” on the erably 2000 : 1 to 10 : 1 , more preferably 1000 : 1 to 1 :50 . desired location , as e .g . the plant , the sequence, in the case [ 0914 ] For other fungicides such as fluxapyroxad ,manco of separate application , generally not having any effect on zeb , ametoctradin , carbendazim , iprodion , prochloraz , chlo the result of the control measures . rothalonil , fenhexamid , pyrimethanil , epoxiconazol and [ 0904 ] Themixtures of the invention are employed as such difenoconazol, as well as for the classes of fungicides they or in form of compositions by treating the insects or the represent typical weight ratios (I : III ) are 250 :1 to 1 : 5 , plants, plant propagation materials , such as seeds, soil , preferably 200 : 1 to 1 : 1 , more preferred 150 : 1 to 1 : 2 , in surfaces, materials or rooms to be protected from insecti particular 100 : 1 to 1 : 2 , especially 80 : 1 to 1 : 5 . cidal attack with an insecticidally effective amount of the [0915 ] In a further embodiment, the weight ratio of the active compounds. The application can be carried out both compound I and compound II or III is in the range of from US 2019 / 0281835 A1 Sep . 19 , 2019 30

1 : 100 to 100 : 1 , regularly in the range of from 1 :50 to 50 : 1, tion rates of the mixtures according to the invention are from preferably in the range of from 1 :20 to 20 : 1 , more preferably 5 g /ha to 2000 g /ha , preferably from 50 to 1500 g /ha , in in the range of from 1 : 10 to 10 : 1 , even more preferably in particular from 50 to 750 g / ha . the range of from 1 : 4 to 4 : 1 and in particular in the range of [0925 ] The mixtures according to the invention are effec from 1 : 2 to 2 : 1 . tive through both contact and ingestion . [0916 ] According to further embodiments of the mixtures according to the invention , the weight ratio of compound I [0926 ] According to a preferred embodiment of the inven to compound II or III usually is in the range of from 100 : 1 tion , the mixtures according to the present invention are to 1 :1 , regularly in the range of from 50 : 1 to 1: 1, preferably employed via soil application . Soil application is especially in the range of from 20 : 1 to 1 : 1 , more preferably in the range favorable for use against ants , termites , crickets, or cock of from 10 : 1 to 1 : 1 , even more preferably in the range of roaches . from 4 : 1 to 1 : 1 and in particular in the range of from 2 : 1 to [0927 ] According to another preferred embodiment of the 1 : 1 . invention , for use against non - crop pests such as ants , [0917 ] According to further embodiments of the mixtures termites , wasps, flies , mosquitoes , crickets, locusts, or cock according to the invention , the weight ratio of compound I roaches the mixtures according to the present invention are to compound II or III usually is in the range of from 1 : 1 to prepared into a bait preparation . 1 : 100 , regularly in the range of from 1 : 1 to 1 :50 , preferably [0928 ] The bait can be a liquid , a solid or a semisolid in the range of from 1 : 1 to 1 : 20 , more preferably in the range of from 1 : 1 to 1 : 10 , even more preferably in the range of preparation ( e . g . a gel) . from 1 : 1 to 1 : 4 and in particular in the range of from 1 : 1 to [0929 ] Another aspect of the present invention is when 1 : 2 . preparing the mixtures, it is preferred to employ the pure [0918 ] In one embodiment compound 1 is used in excess active compounds I and II , to which further active com as compared to compound II or III , i . e . the weight ratio of pounds, e . g . against harmful fungi or having herbicidal compound I to compound II or III usually is in the range of activity , or growth - regulating agents or fertilizers can be from 100 : 1 to 1 : 1 , regularly in the range of from 50 : 1 to 1 : 1 , added . preferably in the range of from 20 : 1 to 1 : 1 , more preferably [ 0930 ] Compositions of this invention may further contain in the range of from 10 :1 to 1 :1 , even more preferably in the other active ingredients than those listed above . For example range of from 4 : 1 to 1 : 1 , e . g . of from 3 : 1 to 1 : 1 , and in fungicides , herbicides , fertilizers such as ammonium nitrate , particular in the range of from 2: 1 to 1: 1 . urea , potash , and superphosphate , phytotoxicants and plant [ 0919 ] In a further embodiment of ternary mixtures , i .e . growth regulators and safeners. These additional ingredients compositions according to the invention comprising com may be used sequentially or in combination with the above pound I ( component 1 ) and a compound II (component 2 ) described compositions , if appropriate also added only and a compound III ( component 3 ) , the weight ratio of immediately prior to use ( tank mix ) . For example , the component 1 ) and component 2 ) usually it is in the range of plant( s ) may be sprayed with a composition of this invention from 1 : 100 to 100 : 1 , regularly in the range of from 1 : 50 to either before or after being treated with other active ingre 50 : 1 , preferably in the range of from 1 : 20 to 20 : 1 , more dients . preferably in the range of from 1: 10 to 10 : 1 and in particular [0931 ] The mixtures according to the invention can be in the range of from 1 : 4 to 4 : 1 , and the weight ratio of applied to any and all developmental stages, such as egg , component 1 ) and component 3 ) usually it is in the range of larva , pupa , and adult . The pests may be controlled by from 1: 100 to 100 :1 , regularly in the range of from 1 :50 to contacting the target pest, its food supply , habitat , breeding 50 : 1 , preferably in the range of from 1 : 20 to 20 : 1 , more ground or its locus with a pesticidally effective amount of preferably in the range of from 1 : 10 to 10 : 1 and in particular the inventive mixtures or of compositions comprising the in the range of from 1 : 4 to 4 : 1 . mixtures . [ 0920 ] Any further active components are , if desired , added in a ratio of from 20 : 1 to 1 : 20 to compound I. [0932 ] “ Locus” means a plant, seed , soil , area, material or [ 0921 ] In further embodiments of the invention the com environment in which a pest is growing or may grow . pound I and the one or more compound ( s ) II and / or III are [0933 ] In general, " pesticidally effective amount” means applied in a weight ratio of from 500 : 1 to 1 : 100 , preferably the amount of the inventive mixtures or of compositions from 20 : 1 to 1 :50 , in particular from 5 : 1 to 1 :20 . comprising the mixtures needed to achieve an observable [ 0922 ] For microbial pesticides in one embodiment the effect on growth , including the effects of necrosis , death , ratio of microbial pesticide to compound ( I ) is from 1x10E4 retardation , prevention , and removal, destruction , or other CFU /ml to 1x10E8 CFU /ml per ppm , preferably from wise diminishing the occurrence and activity of the target 1x10E4 CFU /ml to 1x10E7 CFU /ml per ppm , more pref organism . The pesticidally effective amount can vary for the erably from 5x10E4 CFU /ml to 5x10E6 CFU /ml per ppm , various mixtures and/ or compositions used in the invention . in particular 7 .5x10E4 CFU /ml to 7 .5x10E5 CFU /ml per A pesticidally effective amount of the mixtures and /or ppm . compositions will also vary according to the prevailing [ 0923] This may apply e. g . if compound ( II) is Beauveria conditions such as desired pesticidal effect and duration , basiana . weather, target species , locus , mode of application , and the [ 09241 In a further embodiment, the ratio of microbial like . pesticide to compound (I ) is from 1x10E4 CFU /ml to [0934 ] The inventive mixtures or compositions of these 1x10E8 CFU /ml per ppm , preferably from 1x10E % CFU / mixtures can also be employed for protecting plants from ml to 1x10E7 CFU /ml per ppm , more preferably from attack or infestation by insects , acarids or nematodes com 5x10E % CFU /ml to 5x10E6 CFU /ml per ppm (CFU - colony prising contacting a plant, or soil or water in which the plant forming unit ) Depending on the desired effect, the applica is growing. US 2019 / 0281835 A1 Sep . 19 , 2019 31

[ 0935 ] The inventive mixtures are effective through both [ 0946 ] For use in treating crop plants , the rate of applica contact (via soil , glass , wall, bed net , carpet, plant parts or tion of the mixture of the active ingredients of this invention animal parts ) , and ingestion (bait , or plant part ) and through may be in the range of 0 . 1 g to 4000 g per hectare, desirably trophallaxis and transfer. from 25 g to 600 g per hectare , more desirably from 50 g to [0936 ] Preferred application methods are into water bod 500 g per hectare . ies , via soil, cracks and crevices, pastures, manure piles, [0947 ] In the context of the present invention , the term sewers , into water , on floor, wall, or by perimeter spray plant refers to an entire plant, a part of the plant or the plant application and bait . propagation material. [ 0937 ) According to another preferred embodiment of the [0948 ) The mixtures of the present invention and the invention , for use against non - crop pests such as ants , compositions comprising them are particularly important in termites , wasps, flies , mosquitoes , crickets , locusts , or cock the control of a multitude of insects on various cultivated roaches the inventive mixtures are prepared into a bait plants . preparation . [ 0949 ] Plants which can be treated with the inventive [ 0938 ] The bait can be a liquid , a solid or a semisolid mixtures include all genetically modified plants or trans preparation ( e . g . a gel) . The bait employed in the composi genic plants , e . g . crops which tolerate the action of herbi tion is a product which is sufficiently attractive to incite cides or fungicides or insecticides owing to breeding , insects such as ants , termites, wasps , flies , mosquitoes , including genetic engineering methods , or plants which have crickets etc . or cockroaches to eat it . This attractant may be modified characteristics in comparison with existing plants , chosen from feeding stimulants or para and / or sex phero which can be generated for example by traditional breeding mones readily known in the art. methods and /or the generation of mutants , or by recombi 10939 ] Methods to control infectious diseases transmitted nant procedures . by insects ( e . g . malaria , dengue and yellow fever, lymphatic [0950 ] The term " plant propagation material ” is to be filariasis , and leishmaniasis ) with the inventive mixtures and understood to denote all the generative parts of the plant their respective compositions also comprise treating sur such as seeds and vegetative plant material such as cuttings faces of huts and houses, air spraying and impregnation of and tubers ( e . g . potatoes ), which can be used for the curtains , tents , clothing items, bed nets , tsetse - fly trap or the multiplication of the plant. This includes seeds, roots, fruits , like . Insecticidal compositions for application to fibers, tubers, bulbs, rhizomes, shoots, sprouts and other parts of fabric , knit goods , non -wovens , netting material or foils and plants . Seedlings and young plants , which are to be trans tarpaulins preferably comprise a composition including the planted after germination or after emergence from soil , may inventive mixtures , optionally a repellent and at least one also be mentioned . These young plants may also be pro binder. tected before transplantation by a total or partial treatment [ 0940 ] The inventive mixtures and the compositions com by immersion or pouring. prising them can be used for protecting wooden materials [0951 ] The term “ cultivated plants ” is to be understood as such as trees , board fences , sleepers , etc . and buildings such including plants which have been modified by breeding , as houses , outhouses , factories , but also construction mate mutagenesis or genetic engineering . Genetically modified rials , furniture , leathers , fibers , vinyl articles , electric wires plants are plants , which genetic material has been so modi and cables etc . from ants and / or termites , and for controlling fied by the use of recombinant DNA techniques that under ants and termites from doing harm to crops or human being natural circumstances cannot be obtained by cross breeding , ( e . g . when the pests invade into houses and public facilities ) . mutations or natural recombination . Typically , one or more [ 0941 ] In the case of soil treatment or of application to the genes have been integrated into the genetic material of a pests dwelling place or nest , the quantity of active ingredient genetically modified plant in order to improve certain prop ( s ) ranges from 0 .0001 to 500 g per 100 m², preferably from erties of the plant . 0 .001 to 20 g per 100 m². [0952 ] The term " cultivated plants ” is to be understood [ 0942 ] Customary application rates in the protection of also including plants that have been rendered tolerant to materials are, for example , from 0 .01 g to 1000 g of active applications of specific classes of herbicides, such as compound ( s) per m² treated material , desirably from 0 .1 g to hydroxyphenylpyruvate dioxygenase (HPPD ) inhibitors ; 50 g per m². acetolactate synthase (ALS ) inhibitors , such as sulfonyl [0943 ] Insecticidal compositions for use in the impregna ureas ( see e . g . U . S . Pat. No . 6 , 222 , 100 , WO 01 /82685 , WO tion ofmaterials typically contain from 0 .001 to 95 weight 00 / 26390 , WO 97 /41218 , WO 98 /02526 , WO 98 /02527 , % , preferably from 0 . 1 to 45 weight % , and more preferably WO 04 / 106529, WO 05 /20673 , WO 03 /14357 , WO from 1 to 25 weight % of at least one repellent and /or 03 / 13225 , WO 03 / 14356 , WO 04 / 16073 ) or imidazolinones insecticide. (see e . g . U . S . Pat . No . 6 ,222 , 100 , WO 01/ 82685 , WO [0944 ] For use in bait compositions, the typical content of 00 /26390 , WO 97 / 41218 , WO 98 / 02526 , WO 98 /02527 , active ingredient( s ) is from 0 .0001 weight % to 15 weight % , WO 04 / 106529 , WO 05 /20673 , WO 03 / 14357 , WO desirably from 0 . 001 weight % to 5 weight % of active 03/ 13225, WO 03 / 14356 , WO 04 / 16073 ) ; enolpyruvylshi compound . The composition used may also comprise other kimate - 3 - phosphate synthase (EPSPS ) inhibitors , such as additives such as a solvent of the active material, a flavoring glyphosate (see e . g . WO 92 /00377 ) ; glutamine synthetase agent, a preserving agent , a dye or a bitter agent. Its (GS ) inhibitors , such as glufosinate ( see e . g . EP - A attractiveness may also be enhanced by a special color , 0242236 , EP - A - 242246 ) or oxynil herbicides (see e . g . U . S . shape or texture . Pat . No. 5 ,559 , 024 ) as a result of conventional methods of [ 0945 ] For use in spray compositions , the content of the breeding or genetic engineering . Several cultivated plants mixture of the active ingredients is from 0 .001 to 80 weight have been rendered tolerant to herbicides by conventional % , preferably from 0 .01 to 50 weight % and most preferably methods of breeding (mutagenesis ) , for example Clear from 0 .01 to 15 weight % . field® summer rape (Canola ) being tolerant to imidazolino US 2019 / 0281835 A1 Sep . 19 , 2019 32 nes, e . g . imazamox . Genetic engineering methods have [0955 ) The term “ cultivated plants ” is to be understood been used to render cultivated plants , such as soybean , also including plants that are by the use of recombinant cotton , corn , beets and rape , tolerant to herbicides , such as DNA techniques capable to synthesize one or more proteins glyphosate and glufosinate , some of which are commercially to increase the productivity (e . g. bio mass production , grain available under the trade names RoundupReady® ( glypho yield , starch content, oil content or protein content) , toler sate ) and Liberty Link® ( glufosinate ) . ance to drought, salinity or other growth - limiting environ [0953 ] The term “ cultivated plants ” is to be understood mental factors or tolerance to pests and fungal, bacterial or also including plants that are by the use of recombinant viral pathogens of those plants. DNA techniques capable to synthesize one or more insec 10956 ] The term " cultivated plants ” is to be understood ticidal proteins , especially those known from the bacterial also including plants that contain by the use of recombinant genus Bacillus, particularly from Bacillus thuringiensis , DNA techniques a modified amount of substances of content such as ä - endotoxins , e . g . CryIA ( b ) , CryIA ( C ), CryIF , or new substances of content, specifically to improve human CryIF ( a2 ), CryIIA ( b ), CryIIIA , CryIIIB (bl ) or Cry9c ; veg or animal nutrition , for example oil crops that produce etative insecticidal proteins (VIP ), e . g . VIP1 , VIP2 , VIP3 or health - promoting long -chain omega - 3 fatty acids or unsatu VIP3A ; insecticidal proteins of bacteria colonizing nema rated omega - 9 fatty acids ( e . g . Nexera? rape ). todes, for example Photorhabdus spp . or Xenorhabdus spp . ; 0957 ] The term " cultivated plants” is to be understood toxins produced by animals , such as scorpion toxins , arach also including plants that contain by the use of recombinant nid toxins, wasp toxins , or other insect -specific neurotoxins ; DNA techniques a modified amount of substances of content toxins produced by fungi, such Streptomycetes toxins, plant or new substances of content , specifically to improve raw lectins , such as pea or barley lectins ; agglutinins ; proteinase material production , for example potatoes that produce inhibitors , such as trypsin inhibitors , serine protease inhibi increased amounts of amylopectin ( e . g. Amflora® potato ). tors , patatin , cystatin or papain inhibitors; ribosome- inacti [0958 ] Some of the mixtures of the invention have sys vating proteins (RIP ), such as ricin , maize - RIP , abrin , luffin , temic action and can therefore be used for the protection of saporin or bryodin ; steroid metabolism enzymes, such as the plant shoot against foliar pests as well as for the 3 - hydroxysteroid oxidase , ecdysteroid -IDP - glycosyl- trans treatment of the seed and roots against soil pests . ferase , cholesterol oxidases , ecdysone inhibitors or HMG [0959 ] Seed Treatment COA - reductase ; ion channel blockers , such as blockers of sodium or calcium channels ; juvenile hormone esterase ; [0960 ] Mixtures according to the present invention with diuretic hormone receptors (helicokinin receptors ); stilben systematic action are suitable for the treatment of seeds in synthase , bibenzyl synthase , chitinases or glucanases . In the order to protect the seed from insect pest, in particular from context of the present invention these insecticidal proteins or soil -living insect pests and the resulting plant' s roots and toxins are to be understood expressly also as pre - toxins, shoots against soil pests and foliar insects . hybrid proteins , truncated or otherwise modified proteins . [ 0961 ] The protection of the resulting plant ' s roots and Hybrid proteins are characterized by a new combination of shoots is preferred . protein domains , ( see, for example WO 02/ 015701 ). Further [0962 ] More preferred is the protection of resulting plant' s examples of such toxins or genetically -modified plants shoots from piercing and sucking insects . capable of synthesizing such toxins are disclosed , for [09631 The present invention therefore comprises a example , in EP - A 374 753 , WO 93 / 007278 , WO 95 / 34656 , method for the protection of seeds from insects, in particular EP - A 427 529 , EP - A 451 878 , WO 03 /018810 und WO from soil insects and of the seedlings ' roots and shoots from 03 /052073 . The methods for producing such genetically insects , in particular from soil and foliar insects , said method modified plants are generally known to the person skilled in comprising contacting the seeds before sowing and /or after the art and are described , for example , in the publications pregermination with mixtures according to the present mentioned above . These insecticidal proteins contained in invention . Particularly preferred is a method , wherein the the genetically modified plants impart to the plants produc plant' s roots and shoots are protected , more preferably a ing these proteins tolerance to harmful pests from all taxo method , wherein the plants shoots are protected from pierc nomic groups of insects , especially to beetles (Coeloptera ), ing and sucking insects , most preferably a method , wherein two -winged insects (Diptera ), and butterflies (Lepidoptera ). the plants shoots are protected from aphids . [0954 ] The term “ cultivated plants ” is to be understood [0964 ] The term seed embraces seeds and plant propagules also including plants that are by the use of recombinant of all kinds including but not limited to true seeds, seed DNA techniques capable to synthesize one or more proteins pieces, suckers , corms, bulbs , fruit , tubers, grains , cuttings , to increase the resistance or tolerance of those plants to cut shoots and the like and means in a preferred embodiment bacterial, viral or fungal pathogens. Examples of such true seeds . proteins are the so -called “ pathogenesis -related proteins” [0965 ] The term seed treatment comprises all suitable seed (PR proteins, see, for example EP - A 0 392 225) , plant treatment techniques known in the art, such as seed dressing , disease resistance genes ( for example potato cultivars, seed coating, seed dusting, seed soaking and seed pelleting . which express resistance genes acting against Phytophthora [0966 ] The present invention also comprises seeds coated infestans derived from the mexican wild potato Solanum with or containing the active compound ( s ) . The term “ coated bulbocastanum ) or T4 - lysozym ( e . g . potato cultivars with and /or containing ” generally signifies that the active capable of synthesizing these proteins with increased resis ingredient ( s ) are for the most part on the surface of the tance against bacteria such as Erwinia amylvora ) . The propagation product at the time of application , although a methods for producing such genetically modified plants are greater or lesser part of the ingredient may penetrate into the generally known to the person skilled in the art and are propagation product , depending on the method of applica described , for example , in the publications mentioned tion . When the said propagation product is (re )planted , it above . may absorb the active ingredient. US 2019 / 0281835 A1 Sep . 19 , 2019 33

[ 0967 ] Suitable seeds are seeds of cereals , root crops, oil [0982 ] Conventional seed treatment formulations include crops, vegetables , spices , ornamentals , for example seed of for example flowable concentrates FS , solutions LS , pow durum and other wheat, barley, oats , rye , maize ( fodder ders for dry treatment DS, water dispersible powders for maize and sugar maize /sweet and field corn ), soybeans, lima slurry treatment WS, water- soluble powders SS and emul beans, oil crops, crucifers , cotton , sunflowers , bananas, rice , sion ES and EC and gel formulation GF. These formulations oilseed rape , turnip rape , sugarbeet, fodder beet , eggplants , can be applied to the seed diluted or undiluted . Application potatoes, grass , lawn , turf, fodder grass , tomatoes , leeks, to the seeds is carried out before sowing , either directly on pumpkin / squash , cabbage , iceberg lettuce , pepper, cucum the seeds or after having pregerminated the latter bers , melons, Brassica species , melons, beans, peas , garlic , onions , carrots, tuberous plants such as potatoes, sugar cane , (0983 ] In a preferred embodiment a FS formulation is used tobacco , grapes , petunias, geranium /pelargoniums , pansies for seed treatment. Typically , a FS formulation may com and impatiens. prise 1 - 800 g / l of active ingredient( s ), 1 - 200 g / 1 Surfactant, [0968 ] These crops are also particularly suitable for appli 0 to 200 g /l antifreezing agent, 0 to 400 g/ l of binder , 0 to cation of the mixtures of the invention to growing plants . 200 g /l of a pigment and up to 1 liter of a solvent, preferably [ 0969 ] In addition , themixtures according to the invention water. may also be used for the treatment seeds from plants, which tolerate the action of herbicides or fungicides or insecticides [0984 ] Preferred FS formulations of compounds of for owing to breeding , including genetic engineering methods . mula I for seed treatment usually comprise from 0 . 1 to 80 % [0970 ] For example , the active mixtures can be employed by weight ( 1 to 800 g / l ) of the active ingredient ( s ) , from 0 . 1 in treatment of seeds from plants , which are resistant to to 20 % by weight ( 1 to 200 g / l ) of at least one surfactant, e . g . herbicides from the group consisting of the sulfonylureas, 0 .05 to 5 % by weight of a wetter and from 0 . 5 to 15 % by imidazolinones , glufosinate - ammonium or glyphosate -iso weight of a dispersing agent, up to 20 % by weight, e . g . from propylammonium and analogous active substances ( see for 5 to 20 % of an anti- freeze agent, from 0 to 15 % by weight, example , EP - A -0242236 , EP - A - 242246 ) (WO 92 / 00377 ) e .g . 1 to 15 % by weight of a pigment and /or a dye , from 0 ( EP - A - 0257993 , U . S . Pat. No. 5 , 013 ,659 ) or in transgenic to 40 % by weight, e . g . 1 to 40 % by weight of a binder crop plants , for example cotton , with the capability of ( sticker/ adhesion agent) , optionally up to 5 % by weight, e . g . producing Bacillus thuringiensis toxins (Bt toxins ) which from 0 . 1 to 5 % by weight of a thickener , optionally from 0 . 1 make the plants resistant to certain pests (EP - A0142924 , to 2 % of an anti - foam agent, and optionally a preservative EP - A -0193259 ). such as a biocide , antioxidant or the like , e . g . in an amount [ 0971 ] Furthermore, the mixtures according to the present from 0 .01 to 1 % by weight and a filler /vehicle up to 100 % invention can be used also for the treatment of seeds from by weight plants, which have modified characteristics in comparison 109851 Seed treatment formulations may additionally also with existing plants consist, which can be generated for comprise binders and optionally colorants . Binders can be example by traditional breeding methods and / or the genera added to improve the adhesion of the active materials on the tion of mutants , or by recombinant procedures ) . For seeds after treatment. Suitable binders are block copolymers example , a number of cases have been described of recom EO /PO surfactants but also polyvinylalcoholsl, polyvi binant modifications of crop plants for the purpose of nylpyrrolidones, polyacrylates , polymethacrylates, poly modifying the starch synthesized in the plants ( e . g . WO butenes , polyisobutylenes , polystyrene , polyethyleneam 92/ 11376 , WO 92/ 14827, WO 91 / 19806 ) or of transgenic ines , polyethyleneamides, polyethyleneimines (Lupasol® , crop plants having a modified fatty acid composition (WO Polymin® ) , polyethers, polyurethans, polyvinylacetate , 91 / 13972 ) . tylose and copolymers derived from these polymers . [ 0972 ] The seed treatment application of the mixtures is carried out by spraying or by dusting the seeds before [ 0986 ] Optionally , also colorants can be included in the formulation . Suitable colorants or dyes for seed treatment sowing of the plants and before emergence of the plants . formulations are Rhodamin B , C .I . Pigment Red 112 , C .I . [ 0973] In the treatment of seeds the corresponding formu Solvent Red 1 , pigment blue 15 : 4 , pigment blue 15 : 3 , lations are applied by treating the seeds with an effective pigment blue 15 : 2 , pigment blue 15 : 1 , pigment blue 80 , amount of the mixture according to the present invention . pigment yellow 1 , pigment yellow 13 , pigment red 112 , Herein , the application rates of the active compound ( s ) are pigment red 48 : 2 , pigment red 48 : 1 , pigment red 57 : 1 , generally from 0 . 1 g to 10 kg per 100 kg of seed , preferably pigment red 53 : 1 , pigment orange 43 , pigment orange 34 , from 1 g to 5 kg per 100 kg of seed , in particular from 1 g pigment orange 5 , pigment green 36 , pigment green 7 , to 2 . 5 kg per 100 kg of seed . For specific crops such as pigment white 6 , pigment brown 25 , basic violet 10 , basic lettuce the rate can be higher . violet 49 , acid red 51 , acid red 52 , acid red 14 , acid blue 9 , [ 0974 ] Compositions, which are especially useful for seed acid yellow 23 , basic red 10 , basic red 108 . treatment, are e .g .: [ 0975 ] A Soluble concentrates (SL , LS ) [ 0987 ] The invention also relates to seed comprising mix tures according to the present invention . The amount of the [ 0976 ] D Emulsions (EW , EO , ES ) compound I or the agriculturally useful salt thereof will in [ 0977 ] E Suspensions (SC , OD , FS ) general vary from 0 . 1 g to 100 kg per 100 kg of seed , [0978 ] F Water- dispersible granules and water -soluble preferably from 1 g to 5 kg per 100 kg of seed , in particular granules (WG , SG ) from 1 g to 1000 g per 100 kg of seed . For specific crops , [ 0979 ] G Water- dispersible powders and water- soluble e . g . such as lettuce , the rate can be higher . Also in some other powders (WP , SP, WS ) cases the amount for seed treatment may be up to 100 [ 0980 ] H Gel -Formulations (GF ) kilogram of the active compound ( s ) per 100 kilogram of [0981 ] I Dustable powders (DP , DS) seeds , or may even excess the seed weight. US 2019 / 0281835 A1 Sep . 19 , 2019 34

EXAMPLES TABLE 1 - continued 10988 ] A . Compounds Calculated [ 0989 ] Bilobalide, ginkgolide A , ginkgolide B , ginkgolide Active Observed efficacy C and ginkgolide J are commercially available (e . g. from compound / Concentration efficacy according to Interchim ) . active mixture (ppm ) Ratio ( % ) Colby ( % ) [ 0990 ] B . Biology [ 0991 ] Synergism can be described as an interaction where Imidacloprid + 0 . 8 1 :2000 the combined effect of two or more compounds is greater Bilobalide 160 Abamectin 0 . 003 - than the sum of the individual effects of each of the Bilobalide 64 compounds . The presence of a synergistic effect in terms of Abamectin + 0 . 003 1 :21333 25 percent control, between two mixing partners ( X and Y ) can Bilobalide 640. 003 1.21333 24 be calculated using the Colby equation (Colby , S . R ., 1967, Imicacloprid 0 . 8 Calculating Synergistic and Antagonistic Responses in Her Ginkgolide A 20 bicide Combinations , Weeds , 15 , 20 - 22 ) : Imidacloprid + 0 . 8 1 : 25 Ginkgloide A 20

XY E = X + Y 100 [ 1002 ] Test 2 [ 1003] For evaluating control of Mediterranean fruitfly [ 0992] When the observed combined control effect is (Ceratitis capitata ) the test unit consisted MTPs containing greater than the expected combined control effect ( E ) , then an insect diet and 50 - 80 C . capitata eggs . The compounds or the combined effect is synergistic . mixtures were formulated using a solution containing 75 % [0993 ] The following tests demonstrate the control effi water and 25 % DMSO . Different concentrations of formu cacy of compounds, mixtures or compositions of this inven lated compounds or mixtures were sprayed onto the insect tion on specific pests . However, the pest control protection afforded by the compounds, mixtures or compositions is not diet at 5 ul, using a custom built micro atomizer, at two limited to these species . In certain instances , combinations replications . For experimental mixtures in these tests iden of a compound of this invention with other invertebrate pest tical volumes of both mixing partners at the desired con control compounds or agents are found to exhibit synergistic centrations respectively , were mixed together. After appli effects against certain important invertebrate pests . cation , MTPs were incubated at 28 + 1° C ., 80 + 5 % room [ 0994 ] The analysis of synergism or antagonism between humidity for 5 days . Egg and larval mortality was then the mixtures or compositions was determined using Colby ' s visually assessed . For the mixture tested the results are listed equation . in Table 2 . [ 0995 ] The following abbreviations were used : 10996 ] MTP : microtiter plate TABLE 2 [0997 ] Test 1 Calculated [0998 ] For evaluating control of boll weevil ( Anthonomus efficacy grandis ) the test unit consisted of microtiter plates (MTPs ) Observed according containing an insect diet and 20 -30 A . grandis eggs. Active compound Concentration efficacy to [ 0999 ) The compounds or mixtures were formulated using active mixture ( ppm ) Ratio ( % ) Colby ( % ) a solution containing 75 % water and 25 % DMSO . Different Thiamethoxam 0 .08 concentrations of formulated compounds or mixtures were Bilobalide 160 |10 Thiamethoxam + 0 .08 1 : 2000 sprayed onto the insect diet at 20 ul, using a custom built Bilobalide 160 micro atomizer , at two replications. Alphacypermethrin 0 . 4 [1000 ] For experimental mixtures in these tests identical Bilobalide 160 volumes of both mixing partners at the desired concentra Alphacypermethrin + 0 . 4 1 : 4000 10 tions respectively , were mixed together . Bilobalide 160 [ 1001 ] After application , MTPs were incubated at 23 - 1° C ., 50 + 5 % room humidity for 5 days . Egg and larval mortality was then visually assessed . For the mixture tested [ 1004 ) Test 3 the results are listed in Table 1 . [ 1005 ] For evaluating control of tobacco budworm (Helio this virescens ) the test unit consisted ofMTPs containing an TABLE 1 insect diet and 15 - 25 H . virescens eggs. The compounds or Calculated mixtures were formulated using a solution containing 75 % Active Observed efficacy water and 25 % DMSO . Different concentrations of formu compound / Concentration efficacy according to lated compounds or mixtures were sprayed onto the insect active mixture (ppm ) Ratio ( % ) Colby (% ) diet at 10 ul, using a custom built micro atomizer , at two Dinotefuran 0 .08 — 0 replications . For experimental mixtures in these tests iden Bilobalide 160 0 tical volumes of both mixing partners at the desired con Dinotofuran + 0 . 08 1 : 2000 Bilobalide 160 centrations respectively , were mixed together . After appli Imidacloprid 0 . 8 11011 cation , MTPs were incubated at 28 - 1° C ., 80 : 5 % room Bilobalide 160 humidity for 5 days. Egg and larval mortality was then visually assessed . The results were listed in Table 3 . US 2019 / 0281835 A1 Sep . 19, 2019 35

TABLE 3 TABLE 5 Calculated Calculated efficacy Active efficacy Observed according compound / Concentration Observed according to Active compound / Concentration efficacy to active mixture (ppm ) Ratio efficacy ( % ) Colby ( % ) active mixture (ppm ) Ratio ( % ) Colby ( % ) Spinosad Dinotefuran 0 .08 Ginkgolide A Bilobalide 400 Spinosad + Dinotefuran + 0 .08 1 :5000 50 0 Ginkgolide A Bilobalide 400 Pyrethrum Alphacypermethrin 0 .08 Ginkgolide A in Bilobalide 400 Pyrethrum + a 68 . 5 Alphacypermethrin + 0 . 08 1 :5000 Ginkgolide A Illä Bilobalide 400 Pyraclostrobin Ginkgolide A Pyraclostrobin + uönövönömÖnönöv? 67 Bilobalide [ 1006 ] Test 4 Fluxapyroxad Ginkgolide A 5 [ 1007 ] For evaluating control of yellow fever mosquito Fluxapyroxad + i (Aedes aegypti ) the test unit consisted of MTPs containing Ginkgloide A 200 ul water per well and 5 - 15 freshly hatched A . aegypti larvae . The compounds or mixtures were formulated using a solution containing 75 % water and 25 % DMSO . Different [ 1010 ] Test 6 concentrations of formulated compounds or mixtures were [ 1011 ] For evaluating control of different pathogens in a sprayed onto the insect diet at 2 . 5 ul, using a custom built microtest the active compounds were formulated separately micro atomizer , at two replications. For experimental mix as a stock solution having a concentration of 10000 ppm in tures in these tests identical volumes of both mixing partners dimethyl sulfoxide . at the desired concentrations respectively , were mixed [1012 ] The percentages were converted into efficacies. An together. After application , MTPs were incubated at 28 - 1° efficacy of O means that the growth level of the pathogens C ., 80 : 5 % room humidity for 2 days. Larval mortality was corresponds to that of the untreated control; an efficacy of then visually assessed . The results were listed in Table 4 . 100 means that the pathogens were not growing . [1013 ] The expected efficacies of active compound mix TABLE 4 tures were determined using Colby ' s formula [ R . S . Colby, “ Calculating synergistic and antagonistic responses of her Calculated efficacy bicide combinations ” , Weeds 15 , 20 - 22 ( 1967 ) ] and com Active compound Concentration Observed according to pared with the observed efficacies . active mixture (ppm ) Ratio efficacy ( % ) Colby (% ) [ 1014 ] Test 6 - 1 . Activity against the late blight pathogen Thiamethoxam 0 . 8 50 Phytophthora infestans The stock solutions were mixed Bilobalide 160 according to the ratios in Table 6 , pipetted onto a MTP and Thiamethoxam + 0 .08 1 : 200 100 diluted with water to the concentrations in Table 6 . A spore Bilobalide 400 suspension of Phytophtora infestans containing a pea juice based aqueous nutrient medium or DDC medium was then added . The plates were placed in a water vapor - saturated [ 1008 ] Test 5 chamber at a temperature of 18° C . Using an absorption [ 1009 ] For evaluating control of southern green stink bug photometer, the MTPs were measured at 405 nm 7 days after ( Nezara viridula ) the compounds or mixtures were formu the inoculation . The results were listed in Table 6 . lated using a solution containing acetone and water (50 : 50 ) and 0 .01 % kinetic . Whole Green Beans are rinsed in a 1 % TABLE 6 bleach solution , triple rinsed with deionised water, and Calculated allowed to air dry at least 30 minutes in the fume hood . Active efficacy Beans were dipped in treatment solutions for 5 seconds and compound / Concentration Observed according to allowed to air dry for 30 minutes in the fume hood . For active mixture ( ppm ) Ratio efficacy ( % ) Colby ( % ) maximum exposure , southern green stink bug ( 4 “ instar ) Mancozeb 0 . 063 I Bilobalide were dipped in treatment solution for 3 seconds and allowed Mancozeb + 0 . 063 1 : 16 con to air dry in a cup lined with filter paper and closed with a Bilobalide vented lid for 10 minutes in the fume hood . Three beans Mancozeb 0 . 016 | were placed in 500 ml deli cups with a 70 mm dry filter Bilobalide 0 . 25 Mancozeb + 0 . 016 1 : 16 paper in the bottom and a 29 . 5 ml portion cup with a cotton Bilobalide 0 . 25 wick for water, and infested with 4 southern green stink bug Mancozeb 0 .004 per cup . Each treatment was replicated 3 - fold . Assay arenas Bilobalide 0 . 063 | Mancozeb + 0 . 016 1 : 16 were held at 27° C . and 45 % room humidity. Data were Bilobalide 0 . 25 recorded after 5 days as number of insects alive , with dead Mancozeb 0 .016 recorded as such and all others recorded as alive . The results Bilobalide | were listed in Table 5 . US 2019 / 0281835 A1 Sep . 19 , 2019 36

TABLE 6 -continued of 18° C . Using an absorption photometer , the MTPs were measured at 405 nm 7 days after the inoculation . The results Calculated Active efficacy were listed in Table 8 . compound / Concentration Observed according to active mixture (ppm ) Ratio efficacy ( % ) Colby ( % ) TABLE 8 Mancozeb + 0 .016 1 :63 Calculated Bilobalide Observed efficacy Mancozeb 0 .004 Active compound / efficacy according to Bilobalide 0 . 25 active mixture Concentration Ratio ( % ) Colby ( % ) Mancozeb + 0 . 004 1 :63 Bilobalide 0 . 25 Pyraclostrobin 0 .016 - 46 | Ametoctradin 0 . 004 Bilobalide 16 Bilobalide 0 . 25 Pyraclostrobin + 0 .016 1 : 1000 Ametoctradin + 0 . 004 1 : 63 Bilobalide 16 Bilobalide 0 . 25 Pyraclostrobin 0 . 016 46 | Carbendazim 0 . 004 Bilobalide Bilobalide 0 .25 Pyraclostrobin + 0 . 016 1 : 250 Carbendazim + 0 .004 1 :63 Bilobalide Bilobalide 0 . 25 Azoxystrobin 0 . 25 4 | Iprodion 0 . 004 Bilobalide 63 Bilobalide 0 . 25 GotnorootorimaiSesong Azoxystrobin + 0 .25 1 : 252 Iprodion + 0 . 004 1 :63 Bilobalide 63 Bilobalide 0 . 25 Azoxystrobin 0. 25 - 45 Prochloraz 0 .016 Bilobalide 16 Bilobalide 0 . 25 Azoxystrobin + 0 . 25 1 : 64 69 Prochloraz + 0 . 016 1 : 16 Bilobalide 16 Bilobalide 0 . 25 Chlorothalonil 0 .25 13 Mancozeb Bilobalide 16 Ginkgolide A Chlorothalonil + 0 . 25 1 : 64 Mancozeb + 1 :63 Bilobalide 16 Ginkgolide A 63 Chlorothalonil 0 .25 Bilobalide Chlorothalonil + 0 . 25 1 : 16 Bilobalide [ 1015 ] Test 6 - 2 . Activity Against the Grey Mold Botrytis Trifloxystrobin 0 .063 24 cinerea Bilobalide 63 Trifloxystrobin + 0 . 063 1 : 1000 [ 1016 ] The stock solutions were mixed according to the Bilobalide 63 Mancozeb ratios in Table 7 , pipetted onto a MTP and diluted with water Bilobalide to the concentrations in Table 7 . A spore suspension of Mancozeb + 1 :63 Botrci cinerea in an aqueous biomalt or yeast - bactopeptone Bilobalide 63 Chlorothalonil 0 . 25 15 . sodiumacetate solution was then added . The plates were Ginkgolide A placed in a water vapor- saturated chamber at a temperature Chlorothalonil + 0 . 25 1 :16 100 of 18° C . Using an absorption photometer, the MTPs were Ginkgolide A o|õlalläilläIlLÀ Chlorothalonil 0 . 25 15 measured at 405 nm 7 days after the inoculation . The results Ginkgolide A 16 were listed in Table 7 . Chlorothalonil + 0 .25 1 :64 100 Ginkgolide A 16 TABLE 7 Trifloxystrobin 0 .063 Ginkgolide A 16 Calculated Chlorothalonil + 0 .063 1 : 1000 efficacy Ginkgolide A Active compound Observed according to Fenhexamid active mixture Concentration Ratio efficacy ( % ) Colby ( % ) Ginkgolide A Fenhexamid + 1 : 16 Chlorothalonil Ginkgolide A Bilobalide Pyrimethalin Chlorothalonil + 4 1 : 16 95 Ginkgolide A Bilobalide Pyrimethalin + 1 : 16 Prochloraz Ginkgolide A Ginkgolide A Prochloraz + 1 : 16 Ginkgolide A [ 1019 ] Test 6 - 4 . Activity Against Leaf Blotch on Wheat Caused by Septoria tritici [ 1017 ] Test 6 -3 . Activity Against Rice Blast Pyricularia [ 1020 ] The stock solutions were mixed according to the oryzae ratios in Table 9 , pipetted onto a MTP and diluted with water to the concentrations in Table 9 . A spore suspension of [1018 ] The stock solutions were mixed according to the Septoria tritici in an aqueous biomalt or yeast- bactopeptone ratios in Table 8 , pipetted onto a MTP and diluted with water glycerine solution was then added . The plates were placed in to the concentrations in Table 8 . A spore suspension of a water vapor -saturated chamber at a temperature of 18° C . Pyricularia oryzae in an aqueous biomalt or yeast- bacto Using an absorption photometer, the MTPs were measured peptone - glycerine solution was then added . The plates were at 405 nm 7 days after the inoculation . The results were placed in a water vapor- saturated chamber at a temperature listed in Table 9 . US 2019 / 0281835 A1 Sep . 19 , 2019 37

TABLE 9 bactopeptone - glycerine solution was then added . The plates were placed in a water vapor -saturated chamber at a tem Calculated efficacy perature of 18° C . Using an absorption photometer , the Active compound Observed according to MTPs were measured at 405 nm 7 days after the inoculation . active mixture Concentration Ratio efficacy ( % ) Colby ( % ) The results were listed in Table 11 . Trifloxystrobin 0. 016 | Bilobalide - TABLE 11 Trifloxystrobin + 0 . 016 1 :250 Bilobalide Calculated Trifloxystrobin 0 .004 efficacy Bilobalide 1 Active compound / Observed according to Trifloxystrobin + 0 . 004 1 : 250 active mixture Concentration Ratio efficacy ( % ) Colby ( % ) Bilobalide Pyraclostrobin 0 . 004 Chlorothalonil - 39 Bilobalide 1 911?ll Ginkgolide A 1o Pyraclostrobin + 0 .004 1 : 250 Chlorothalonil + 1 :63 Bilobalide Ginkgolide A Epoxiconazol 0 . 25 Difenoconazol 21 118119 Bilobalide 16 Bilobalide 24 Epoxiconazol + 0 . 25 1 :64 Difenoconazol + 1 :63 16 Bilobalide Bilobalide Prochloraz Ginkgolide A Prochloraz + 1 : 16 Ginkgolide A [ 1025 ] Test 7 [ 1026 ] Compatibility of bilobalide with Beauveria bassi [ 1021 ] Test 6 - 5 . Activity Against Early Blight Caused by ana strain PPRI 5339 was analyzed . Aqueous mixtures Alternaria solani containing 100 ppm of bilobalide , and 4x10E7 CFU /ml of [ 1022 ] The stock solutions were mixed according to the Beauveria bassiana strain PPRI 5339 were filled in bottles . ratios in Table 10 , pipetted onto a MTP and diluted with Bottles were shaken to assertain complete dilution and water to the concentrations in Table 10 . A spore suspension incubated at room temperature ( 26° C . ) . The aqueous mix of Alternaria solani in an aqueous biomalt or yeast- bacto tures were maintained for 1 hour, or 24 hours . Ten - fold serial peptone - glycerine solution was then added . The plates were dilutions were made for both incubation times from 1 : 10E0 placed in a water vapor- saturated chamber at a temperature to 1 : 10E10 . A fixed volume ( 100 ul) of each dilution was of 18° C . Using an absorption photometer, the MTPs were distributed aseptically onto petri dishes containing Dichlo measured at 405 nm 7 days after the inoculation . The results ran -Rose -Bengal -Chlortetracycline agar for culture . Petri were listed in Table 10 . dishes were incubated in a dark chamber at 28° C . for five days and submitted to visual inspection . Analyzed param TABLE 10 eters were the number of colonies , colony diameter, shape , Calculated color , and speed of growth . The results showed that Beau efficacy veria bassiana strain PPRI 5339 and Bilobalide were com Active compound Observed according to patible under all tested conditions. active mixture Concentration Ratio efficacy ( % ) Colby ( % ) Fenhexamid [ 1027 ] For evaluating control of southern green stink bug Bilobalide (Nezara viridula ) , Bilobalide , Beauveria bassiana strain Fenhexamide + 1 : 4 PPRI 5339, or mixtures thereof were formulated using a Bilobalide solution containing water and acetone ( 98 .75 : 1. 25 ). Beau Difenoconazol Bilobalide veria bassiana strain PPRI 5339 was at room temperature Difenoconazol + 1 :63 for one hour before use . Bilobalide 63 Fluoxastrobin 0 . 25 [1028 ] Seven days old Lima bean plants were dipped into Ginkgolide A 63 each treatment. Once dried , plants were artificially infested Fluoxastrobin + 0 . 25 1 : 252 with four second instar southern green stink bugs . Percent Ginkgolide A 63 Epoxiconazol 0 .25 üle|ELollol age of mortality (sick + death insects ) was evaluated at 5 Ginkgolide A 16 days . The results were listed in Table 12 . Epoxiconazol + 0 . 25 1 :63 Ginkgolide A 16 TABLE 12 Picoxystrobin 0 . 25 Ginkgolide A 63 Calculated Picoxystrobin + 0 . 25 1 : 252 Active efficacy Ginkgolide A 63 compound / Observed according active efficacy to Colby [1023 ] Test 6 - 6 . Activity against wheat leaf spots caused mixture Concentration Ratio ( % ) ( % ) by Leptosphaeria nodorum Beauveria 4 x 10E7 CFU /ml 37 bassiana [ 1024 ] The stock solutions were mixed according to the strain ratios in Table 11 , pipetted onto a MTP and diluted with PPRI 5339 water to the concentrations in Table 11 . A spore suspension Bilobalide 50 ppm 33 of Leptosphaeria nodorum in an aqueous biomalt or yeast US 2019 / 0281835 A1 Sep . 19 , 2019 38

TABLE 12 - continued in a synergistically effective amount , wherein the weight ratio of compound ( I) and compound ( II ) is from 7500 : 1 to Calculated Active efficacy 1 :5 . compound / Observed according 3 . The pesticidal mixture of claim 2 , wherein the weight active efficacy to Colby ratio of compound (I ) to compound ( II ) is from 5000 : 1 to mixture Concentration Ratio ( % ) ( % ) 1: 5 . Beauveria 4 x 10E7 CFU /ml 2 x 10E5 100 58 4 . A seed treated with the mixture of claim 2 in an amount bassiana 50 ppm CFU /ml : 1 ppm of from 0 . 1 g to 100 kg per 100 kg of seed . strain 5 . A pesticidal composition comprising a liquid or solid PPRI 5339 + carrier and the mixture of claim 2 . Bilobalide 6 . A method for controlling pests from the family of Pentatomidae, comprising the step of contacting the pests , 1 . ( canceled ) their food supply , habitat or breeding grounds with the 2 . A pesticidal mixture comprising as active compounds mixture of claim 2 . 1 ) at least one compound ( I) , which is a component of the 7 . The method of claim 6 , wherein the Pentatomidae are ginkgo tree selected from the group consisting of selected from Acrosternum spp ., Euschistus spp . , Nezara bilobalide , ginkgolide A , ginkgolide B , ginkgolide C , sppspp . aand Piezodrus spp . ginkgolide J, and ginkgolide M ; and 8 . The method of claim 6 , wherein the Pentatomidae are 2 ) at least one pesticidally active compound ( II ) selected selected from Acrosternum hilare, Euschistus heros, Nezara from the group of neonicotinoids consisting of acet viridula , Piezodrus guildini , Halyomorpha halys and Dich amiprid , clothianidin , cycloxaprid , dinotefuran , imida elops spp . cloprid , nitenpyram , thiacloprid and thiamethoxam * * * * *