Cellulose Was Discovered in 1838 by the French Chemist Anselme Payen, Who Isolated It from Plant Matter and Determined Its Chemical Formula

Total Page:16

File Type:pdf, Size:1020Kb

Cellulose Was Discovered in 1838 by the French Chemist Anselme Payen, Who Isolated It from Plant Matter and Determined Its Chemical Formula Cellulose structure: The history of cellulose: Cellulose was discovered in 1838 by the French chemist Anselme Payen, who isolated it from plant matter and determined its chemical formula. Cellulose was used to produce the first successful thermoplastic polymer, celluloid, by Hyatt Manufacturing Company in 1870. Production of rayon ("artificial silk") from cellulose began in the 1890s and cellophane was invented in 1912. Hermann Staudinger determined the polymer structure of cellulose in 1920. The compound was first chemically synthesized (without the use of any biologically derived enzymes) in 1992, by Kobayashi and Shoda How it is synthesized commercially or biologically: Cellulose is a source of energy for several types of microbes. Large amounts of cellulose is degraded to glucose by both bacterial and fungal microbes. The glucose derived from cellulose degradation is then used by other microbes as a carbon source to produce energy. Many fungi, specifically the members of Basidiomycetes perform critical ecological function by degrading cellulose present in decaying wood. Some animals can digest cellulose. When an herbivore, say a cow, consumes a plant, like grass, bacteria in their intestinal tract are able to break down the cellulose into smaller parts that the cow's own digestive system can absorb. Some bacteria can actually produce their own cellulose, making a kind of film. The acetic acid bacteria used in the production of wine and beers is one of these types. The synthesized cellulose forms a film around the bacterial cell and becomes a kind of matrix, called a pellicle, which helps the acetic acid bacteria to float on the surface and access oxygen needed for their survival. Cellulose’s properties: Cellulose, with the formula (C6H10O5) is an organic compound which consists of a linear chain made up from 'several hundred to over ten thousand β(1→4) linked D-glucose units'’or in simpler terms, it is made of repeated units of the monomer glucose. It is the ability of these chains to hydrogen-bond together into fibres (microfibrils) that gives cellulose its unique properties of mechanical strength and chemical stability.created by both plants and animals. About 33% of all plant mater is cellulose (the cellulose content of cotton is 90% and that of wood is 40-50%),although usually considered a plant material, it can also be produced by some bacteria. Cellulose uses in society: Cellulose is mainly used to produce paperboard and paper. Smaller quantities are converted into a wide variety of derivative products such as cellophane and rayon. Conversion of cellulose from energy crops into biofuels such as cellulosic ethanol is under investigation as an alternative fuel source. Cellulose for industrial use is mainly obtained from wood pulp and cotton. Some animals, particularly ruminants and termites, can digest cellulose with the help of symbiotic micro-organisms that live in their guts, such as Trichonympha. In humans, cellulose acts as a hydrophilic bulking agent for feces and is often referred to as a "dietary fiber". Some problems associated with cellulose: Cellulose is a popular insulation material that is also environmentally friendly. However, it can cause some problems, including respiratory issues ① Loose Cellulose is Heavier than Fiberglass.The weight of the insulation material may cause problems, especially when it is meant for locations like ceilings. Loose cellulose weighs more than the same amount of rockwool or fiberglass. It is said that the amount of cellulose required to cover a given area weighs three times more than loose fiberglass required for that area. This could be a problem, if you choose cellulose insulation for weak ceilings. ② Wet Spray Cellulose Requires Proper Drying Time.If you opt for wet spray cellulose, you must have sufficient time to wait till it dries properly. Some people use large space heaters for drying the insulation. The insulation has to be dry, before you apply a drywall or sheet-rock. A moisture meter can be used to check the moisture levels, before installation. Though it requires some time to dry, wet spray cellulose provides a better seal and may not settle. ③ Dry-blown Cellulose may Sag and Settle.It has been noticed that dry-blown cellulose insulation settles over time and gets compact, thereby creating air spaces and reducing the R-value. It is also prone to moisture problems, which can lead to mold and mildew. This in turn affects the durability of the insulation. However, the problem of settling can be overcome with dense packing, which has to be done by an experienced person. ④ Blown-in Cellulose Insulation Releases Dust.Being made of minutely shredded newspaper, cellulose insulation may release dust through small holes. Mostly, this happens in case of inadequate or improper sealing. Dust that stays indoors for longer duration may cause health problems in the inhabitants. It may also carry particles of chemicals like borax. Exposure to dust is a common problem that is encountered during installation of cellulose insulation. Certified breathing masks have to be used in such cases. Another option is to use low-dust cellulose, which contains dampeners. ⑤ Cellulose Insulation Health Hazards.While exposure to dust is a cause of concern, the chemicals in cellulose insulation may also cause some health problems. Chemicals in inks and dyes of newspaper and those in additives like fire retardants and adhesives, may cause allergic reactions in sensitive people. If exposed to the dust laced with chemical particles, symptoms like irritation of the eyes, nose, and throat may develop. Some people may experience cough and skin dryness. Long-term exposure to a high concentration of these chemicals may cause severe symptoms..
Recommended publications
  • Corrugated Board Structure: a Review M.C
    ISSN: 2395-3594 IJAET International Journal of Application of Engineering and Technology Vol-2 No.-3 Corrugated Board Structure: A Review M.C. Kaushal1, V.K.Sirohiya2 and R.K.Rathore3 1 2 Assistant Prof. Mechanical Engineering Department, Gwalior Institute of Information Technology,Gwalior, Assistant Prof. Mechanical Engineering 3 Departments, Gwalior Engineering College, Gwalior, M. Tech students Maharanapratap College of Technology, Gwalior, [email protected] [email protected] [email protected] ABSTRACT Corrugated board is widely used in the packing industry. The main advantages are lightness, recyclability and low cost. This makes the material the best choice to produce containers devoted to the shipping of goods. Furthermore examples of structure design based on corrugated boards can be found in different fields. Structural analysis of paperboard components is a crucial topic in the design of containers. It is required to investigate their strength properties because they have to protect the goods contained from lateral crushing and compression loads due to stacking. However in this paper complete and detailed information are presented. Keywords: - corrugated boards, recyclability, compression loads. Smaller flutes offer printability advantages as well as I. INTRODUCTION structural advantages for retail packaging. Corrugated board is essentially a paper sandwich consisting of corrugated medium layered between inside II. HISTORY and outside linerboard. On the production side, corrugated In 1856 the first known corrugated material was patented is a sub-category of the paperboard industry, which is a for sweatband lining in top hats. During the following four sub-category of the paper industry, which is a sub-category decades other forms of corrugated material were used as of the forest products industry.
    [Show full text]
  • The Use of Old Corrugated Board in the Manufacture of High Quality White Papers
    Western Michigan University ScholarWorks at WMU Paper Engineering Senior Theses Chemical and Paper Engineering 12-1983 The Use of Old Corrugated Board in the Manufacture of High Quality White Papers Rene H. Kapik Western Michigan University Follow this and additional works at: https://scholarworks.wmich.edu/engineer-senior-theses Part of the Wood Science and Pulp, Paper Technology Commons Recommended Citation Kapik, Rene H., "The Use of Old Corrugated Board in the Manufacture of High Quality White Papers" (1983). Paper Engineering Senior Theses. 209. https://scholarworks.wmich.edu/engineer-senior-theses/209 This Dissertation/Thesis is brought to you for free and open access by the Chemical and Paper Engineering at ScholarWorks at WMU. It has been accepted for inclusion in Paper Engineering Senior Theses by an authorized administrator of ScholarWorks at WMU. For more information, please contact wmu- [email protected]. THE USE OF OLD CORRUGATED BOARD IN THE MANUFACTURE OF HIGH QUALITY WHITE PAPERS by Rene' H. Kapik A Thesis submitted in partial fulfillment of the course requirements for The Bachelor of Science Degree Western Michigan University Kalamazoo, Michigan December, 1983 ABSTRACT Clean corrugated board waste was fractionated into its softwood/ hardwood fiber components, repulped using a kraft pulping process, and bleached using a CEHD bleaching sequence in an effort to produce high brightness fiber suitable for use in medium to high quality white paper. The papers produced had almost equivalent mechanical strengths and opacity, but possessed unsatisfactory brightness and cleanliness when compared to commercially manufactured,:. bleached kraft pulps of identical softwood/hardwood contents. Based on this experimental data, the use of recycled fiber from corrugated board as a fiber substitute in the manufacture of high quality printing and writing papers is not recommended due to its inferior brightness and cleanliness.
    [Show full text]
  • Judging Permanence for Reformatting Projects: Paper and Inks
    ConserveO Gram September 1995 Number 19/14 Judging Permanence For Reformatting Projects: Paper And Inks Many permanently valuable NPS documents fibered, high alpha-cellulose cotton and linen such as correspondence, drawings, maps, plans, rags. Early rag papers were strong, stable, and reports were not produced using permanent and durable with relatively few impurities. and durable recording media. When selecting In the mid-17th century, damaging alum paper items for preservation duplication, items sizing was added to control bacteria and marked on the list below with a " - " are at mold growth in paper. By 1680, shorter highest risk and should have special priority for fiber rag papers were being produced due to duplication. Document types marked with a the use of mechanical metal beaters to shred "+" are lower priorities for reformatting as they the rag fibers. By about 1775, damaging tend to be more stable and durable. See chlorine bleaches were added to rag papers Conserve O Gram 19/10, Reformatting for to control the paper color. Acidic alum Preservation and Access: Prioritizing Materials rosin sizing was introduced around 1840 to for Duplication, for a full discussion of how to speed the papermaking process thus leading select materials for duplication. NOTE: Avoid to even shorter-lived papers. Rag papers using materials and processes marked " - " when became less common after the introduction producing new documents. of wood pulp paper around 1850. Compared to rag paper, most wood pulp papers have Paper much poorer chemical chemical and mechanical strength, durability, and stability. All permanently valuable original paper - documents should be produced on lignin-free, Ground or mechanical wood pulp paper: high alpha-cellulose papers with a pH between After 1850, most paper produced was 7.5 and 8.0, specifically those papers meeting machine-made paper with a high proportion the American National Standards Institute of short-fibered and acidic wood pulp.
    [Show full text]
  • Conservation of Coated and Specialty Papers
    RELACT HISTORY, TECHNOLOGY, AND TREATMENT OF SPECIALTY PAPERS FOUND IN ARCHIVES, LIBRARIES AND MUSEUMS: TRACING AND PIGMENT-COATED PAPERS By Dianne van der Reyden (Revised from the following publications: Pigment-coated papers I & II: history and technology / van der Reyden, Dianne; Mosier, Erika; Baker, Mary , In: Triennial meeting (10th), Washington, DC, 22-27 August 1993: preprints / Paris: ICOM , 1993, and Effects of aging and solvent treatments on some properties of contemporary tracing papers / van der Reyden, Dianne; Hofmann, Christa; Baker, Mary, In: Journal of the American Institute for Conservation, 1993) ABSTRACT Museums, libraries, and archives contain large collections of pigment-coated and tracing papers. These papers are produced by specially formulated compositions and manufacturing procedures that make them particularly vulnerable to damage as well as reactive to solvents used in conservation treatments. In order to evaluate the effects of solvents on such papers, several research projects were designed to consider the variables of paper composition, properties, and aging, as well as type of solvent and technique of solvent application. This paper summarizes findings for materials characterization, degradative effects of aging, and some effects of solvents used for stain reduction, and humidification and flattening, of pigment-coated and modern tracing papers. Pigment-coated papers have been used, virtually since the beginning of papermaking history, for their special properties of gloss and brightness. These properties, however, may render coated papers more susceptible to certain types of damage (surface marring, embedded grime, and stains) and more reactive to certain conservation treatments. Several research projects have been undertaken to characterize paper coating compositions (by SEM/EDS and FTIR) and appearance properties (by SEM imaging of surface structure and quantitative measurements of color and gloss) in order to evaluate changes that might occur following application of solvents used in conservation treatments.
    [Show full text]
  • Cellulose Containerboard US Safety Data Sheet Section 1. Product And
    Cellulose Containerboard US Safety Data Sheet Section 1. Product and Company Identification Product Group : Cellulose Containerboard Trade Names or Grades : EnduraLiner™, EnduraLiner™ HP Max, EnduraLiner™ Wet Strength, EnduraLiner™ GR, DiamondTop™, DiamondTop™ HP, DiamondTop™ 1C, DiamondTop™ 2C, DiamondTop™ GR, EnduraFlute™, TechniFlute™, Linerboard, White Top Liner, Medium, Bleached Linerboard, Coated White Top Linerboard, RockmaX, Grease Resistant Liner, White Top Grease Resistant Liner, Natural Kraft Linerboard, Bleached Linerboard, Wet Strength linerboard, Premium White Top Liner, Recycled Linerboard, Recycled Medium, Fluting, White Top Kraft Liner Synonyms : Corrugating Medium, Linerboard Chemical Name/Class : Cellulose Paperboard Company : WestRock 1000 Abernathy Road NE Atlanta GA 30328 770-448-2193 Emergency Phone : (800) 424-9300 (CHEMTREC) Section 2. Hazards Identification This product as sold is a solid product which is not regulated under WHMIS 2015. During processing, combustible dust may be generated and the following information applies under OSHA HazCom 2012: GHS Classification : Combustible Dust (OSHA Defined Hazard) Signal Word : Warning Hazard Statement(s) : May form combustible dust concentrations in air, if small particles are formed during processing, handling, or by other means. Hazard Pictogram : None Precautionary Statement(s) : Keep away from all ignition sources including heat, sparks and open flames. Prevent dust accumulations to minimize explosion hazard. Hazards Not Otherwise : None. Classified Ingredients of Unknown : Not applicable Acute Toxicity (>1%) Section 3. Composition and Information on Ingredients No hazardous ingredients. SDS WR001 Page 1 of 8 Rev. 02/12/2019 Cellulose Containerboard US Safety Data Sheet Section 4. First Aid Measures Inhalation : Excessive dust concentrations may cause unpleasant obstruction in the nasal passages. Remove to fresh air.
    [Show full text]
  • Changes in Print Paper During the 19Th Century
    Purdue University Purdue e-Pubs Charleston Library Conference Changes in Print Paper During the 19th Century AJ Valente Paper Antiquities, [email protected] Follow this and additional works at: https://docs.lib.purdue.edu/charleston An indexed, print copy of the Proceedings is also available for purchase at: http://www.thepress.purdue.edu/series/charleston. You may also be interested in the new series, Charleston Insights in Library, Archival, and Information Sciences. Find out more at: http://www.thepress.purdue.edu/series/charleston-insights-library-archival- and-information-sciences. AJ Valente, "Changes in Print Paper During the 19th Century" (2010). Proceedings of the Charleston Library Conference. http://dx.doi.org/10.5703/1288284314836 This document has been made available through Purdue e-Pubs, a service of the Purdue University Libraries. Please contact [email protected] for additional information. CHANGES IN PRINT PAPER DURING THE 19TH CENTURY AJ Valente, ([email protected]), President, Paper Antiquities When the first paper mill in America, the Rittenhouse Mill, was built, Western European nations and city-states had been making paper from linen rags for nearly five hundred years. In a poem written about the Rittenhouse Mill in 1696 by John Holme it is said, “Kind friend, when they old shift is rent, Let it to the paper mill be sent.” Today we look back and can’t remember a time when paper wasn’t made from wood-pulp. Seems that somewhere along the way everything changed, and in that respect the 19th Century holds a unique place in history. The basic kinds of paper made during the 1800s were rag, straw, manila, and wood pulp.
    [Show full text]
  • The Paperboard Product
    The paperboard product The paperboard product Since the mid-19th century the primary source of cellu- exceeds the amount of timber that is harvested. lose fibre has been wood. The fibre is separated by either This careful forest management ensures that even in the chemical or mechanical means from naturally occurring future the forests will form part of the sustainable cycle of species. In the case of Iggesund these species are mainly nature and be a permanent source of raw materials. spruce, pine and birch from managed forests in Scandina- The fibres in a tree trunk run parallel to its length. The via and elsewhere in Europe. Such forests are maintained fibre length varies according to the tree species. The rela- and expanded by the industries that rely on good access tionship is indicated by the table below. to timber. As a result of these efforts the stock of growing trees is increasing every year. In many areas growth now 4QSVDFæCSFrMPOHBOEçBU #JSDIæCSFrTIPSUBOEDZMJOESJDBM 1JOFæCSFrMPOHBOEçBU .JYFEæCSFTPGTQSVDF QJOFBOECJSDI Species Fibre length mm Fibre width μm Shape Spruce 3.1 – 3.5 19 – 50 Ribbon flat Pine 2.0 – 3.0 22 – 50 Ribbon flat Birch 0.9 – 1.2 20 – 35 Cylindrical with pointed ends IGGESUND PAPERBOARD | Reference Manual 17 The paperboard product Cellulose and the laws of nature Carbon dioxide and water are converted into simple glucose-based sugars by the action of sunlight on the OXYGEN (O2) CARBON DIOXIDE (CO2) green chlorophyll-containing cells of the plant kingdom. SUNLIGHT This process is known as photosynthesis and is accompa- nied by the emission of oxygen.
    [Show full text]
  • Papermaking History Papermaking Spread Across Asia, Middle East, and Europe
    AD 105 Chinese Han Dynasty: the birthplace of paper as we know it today. AD 610 PAPERMAKING HISTORY Papermaking spread across Asia, Middle East, and Europe. Of all the writing materials mankind has employed down through the ages, paper has become the most widely used around the world. Paper has a long history stretching back to ancient Fibres were created Egypt in the third millennium BC. The word ‘paper’ is derived from papyrus, a plant that was by beating. once abundant in Egypt. Paper as we know it traces its roots back to China at the beginning of the first millennium AD. Originally intended purely for writing and printing purposes, a dazzling array of paper products are available to today’s consumer. Use of water to th power machinery. 14 century A stamping mill was developed Export of the papermaking to produce pulp more efficiently. technique to Europe and a series of improvements to the process. 16th century Primarily rags were used as raw material and later The advantages of mill-based de-fibred bamboo. papermaking spread throughout Europe. A number of types were developed, such as sized, coated and dyed paper. 19th century The Arabs coated paper with More machines were starch paste that gave paper invented and improved good writing properties and leading to increased a fine appearance. production speed, for instance the cylinder machines. More paper Wood became the main raw th is created material for paper making, 17 and thanks to better thanks to the invention of th machinery. the wood-grinding machine. 18 century Sheets are dried Invention of machines to on ropes.
    [Show full text]
  • 1 Fibre Box Handbook Glossary Adhesive
    Fibre Box Handbook Glossary A Adhesive: Substance capable of adhering one surface to another. For fiberboard boxes, the substance is used to hold plies of solid fiberboard together, to hold linerboard to the tips of flutes of corrugated medium, or to hold overlapping flaps together to form the joint or to close a box. Anilox System: Inking system used in flexographic presses. B Bale: A shaped unit, usually containing compressible articles or materials, enclosed in a fiberboard container not conforming to the carriers’ rules for a box, or enclosed in other wrapping, and bound by strapping, rope or wire under tension. Banded Unit: A package or palletized load that has a band or bands (usually plastic) applied to it. Bar Code: An identification symbol. Alpha or alpha-numeric information is encoded in a sequence of high-contrast, rectangular bars and blank spaces. The relative widths of these bars and spaces and their sequence differentiate the individual characters that make up the encoded information. Bar codes are “read” by electronic scanners. Basis Weight (of Containerboard): Weight of linerboard or corrugating medium expressed in terms of pounds per 1,000 square feet (msf). Bending: In the expression "proper bending qualities," the ability of containerboard or combined board to be folded along score lines without rupture of the surface fibers to the point of seriously weakening the structure. Blank or Box Blank: A flat sheet of corrugated or solid fiberboard that has been cut, slotted and scored so that, when folded along the score lines and joined, it will take the form of a box.
    [Show full text]
  • Handmade Paper: a Review of Its History, Craft, and Science
    REVIEW ARTICLE bioresources.com HANDMADE PAPER: A REVIEW OF ITS HISTORY, CRAFT, AND SCIENCE Martin A. Hubbe a* and Cindy Bowden b For over 2000 years the manual craft of papermaking has been practiced all over the world utilizing a variety of techniques. This review describes the evolution of hand papermaking and its cultural significance. Paper’s evolution has been shaped by the structure and chemical composition of the fibers. Almost every aspect of modern papermaking technology has been foreshadowed by traditional practices. Such practices were passed down for many generations within families of papermakers. The main sources of cellulosic fiber evolved as the ancient craft migrated from its birthplace in China to Korea and Japan, the Islamic world, and then to Europe and America. Though most paper made today comes from automated, continuous production systems, handmade paper has enjoyed a resurgence, both as a traditional craft and as an art-form. In addition, traditional papermaking methods can provide insights to help in modern applications involving cellulosic fibers. Keywords: Handmade paper; History; Handcraft; Science; Cellulosic fibers Contact information: a: Department of Forest Biomaterials; North Carolina State University; Campus Box 8005; Raleigh, NC 27695-8005 USA; b: Robert C. Williams American Museum of Papermaking, Inst. of Paper Science and Technology, Mail Code 0620, Georgia Tech., Atlanta, GA 30332-0620; *Corresponding author: [email protected] INTRODUCTION Whenever people engage their hands and minds to make paper, there is a continuing opportunity for evolution of the craft. Each maker adopts or selectively omits parts of the methods that have been passed down to them, sometimes inventing new techniques.
    [Show full text]
  • Paper & Cardboard
    Paper & cardboard Exam expectations Knowledge about materials is always tested in the written paper. You are expected to know about paper/card and at least one other material area. Know about paper/card • Where it comes from • How it is made • How products are cut from paper/card Materials and components • In what stock sizes and forms is paper/board supplied? • Is it a renewable/non-renewable material? • How are papers and cardboards classified (grouped)? • What properties do different papers/boards have? • What are components and why are they used? • What are combined materials? Standard stock forms Most materials are supplied in standard stock forms. When specifying paper and cardboard you would choose the size (A1, A2, A3, A4 etc.) then you would choose the weight (grams per square metre). It is usually best to use standard stock forms: • The printing industry need consistent sizes and qualities • Makes it cheaper to buy in this form • Non-standard can greatly increase the costs Paper • Paper is a web-like material made from very fine vegetable fibres. • These fibres usually come from wood pulp although sometimes plants such as flax and hemp are used. • The fibres are made of cellulose and they stick to each other to form a strong web • Recycled fibres are often mixed with new or “virgin” materials Making Paper Papermaking has been around for 2,000 years although it is now highly automated Boiled up to make wood pulp Trees cut & Water added shredded Chemicals and dyes added Pulp poured over fine mesh and squeezed between rollers Fibres • When plants are used to make paper, it is usually necessary to use a special chemical process to break down the lignin found inside the cell walls of the plant.
    [Show full text]
  • Bioengineering Cellulose-Hemicellulose Networks in Plants
    Bioengineering cellulose-hemicellulose networks in plants Olawole O. Obembe 1 Promotoren: Prof. dr. ir. E. Jacobsen, Hoogleraar in de Plantenveredeling, Prof. dr. R.G.F.Visser, Hoogleraar in de Plantenveredeling, Co-promotor: Dr. ir. J-P. Vincken Universitair docent, Laboratorium voor Plantenveredeling Promotiecommissie: Prof. dr. ir. A.G.J. Voragen (Wageningen Universiteit) Mw. Prof. dr. A.M.C. Emons (Wageningen Universiteit) Prof. dr. L.H.W. van der Plas (Wageningen Universiteit) Dr. ir. H.C.P.M. van der Valk (Wageningen Universiteit) Dit onderzoek is uitgevoerd binnen de onderzoeksschool ‘Experimental Plant Sciences’. 2 Bioengineering cellulose-hemicellulose networks in plants Olawole O. Obembe Proefschrift Ter verkrijging van de graad van doctor op gezag van de rector magnificus van Wageningen Universiteit, Prof. Dr. M.J. Kropff, in het openbaar te verdedigen op maandag 30 januari 2006 des namiddags te half twee in de Aula 3 CIP-DATA Koninklijke Bibliotheek, Den Haag Bioengineering cellulose-hemicellulose networks in plants Olawole O. Obembe PhD thesis, Wageningen University, the Netherlands With references – with summaries in Dutch and English ISBN 90-8504-352-2 4 Contents Chapter 1 General introduction……………………………………………………. 7 Chapter 2 Irregular deposition of cell wall polymers resulting from defective cellulose synthase complexes………………………………………… 31 Chapter 3 Promiscuous, non-catalytic, tandem carbohydrate-binding modules alter development of tobacco plants……………………………………51 Chapter 4 Constitutive expression of a Cellulomonas fimi
    [Show full text]