Chemical Variation in Hercynian Basalts Relative to Plate Tectonics
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J. geol. Soc. London, Vol. 139, 1982, pp. 505-520, 7 figs., 2 tables. Printed in Northern Ireland. Chemical variation in Hercynian basalts relative to plate tectonics P. A. Floyd SUMMARY:The geochemistry of Hercynianbasalts is reviewed with special reference to SW England. Hercynian basalts have thefollowing chemical features: (1) relative enrichment in incompatible elements, (2) fractionated rare earth element (REE) patterns ranging from mild to strongly light-REE enriched, and(3) generally low large-ion-lithophile (L1L)ihigh field strength (HFS)element ratios. High and variable alkali contents and KiRb ratios are indicative of low-gradealteration. Basalts are predominantlytholeiites, although alkali basalts maybe developed on some trough margins. Basalts fromdifferent sedimentary troughs within the main Hercynian tectonic zones are characterized by specific incompatible element abundances and ratios. These variations are interpreted in terms of variable fractional crystallization, partial melting and mantle heterogeneity. Hercynian volcanism was typically bimodal with basic and acid products characterizing the Rheno-Hercynian and Saxo-Thuringian zones. Activity in the Moldanubian zone wasmore variable with a high proportion of calc-alkaliandesites. Two systematic chemical changes throughout the Devonian and Carboniferous have been recognized, with both lightiheavyREE and LIL/HFS element ratios increasing with time. These featuresmay relate to the introduction of LIL-enriched fluids derived by dehydration of subducted lithosphere that caused progressive metasomatism of the overlying mantle wedge. Chemical discrimination of tectonic setting demonstrates that most of the basalts typify the continental intra-plate environment, although early Devonian basalts produced in the initial stages of continent rifting have someof the chemical features of incompatible element enriched oceanic basalts. An ensialic back-arc basin model underlain by a shallow northward-dipping subduction zone provides a possible explanation for the spatial and temporal variation in the Hercynian volcanic rocks. The Hercynian fold belt has been subjected to many 1972) and also a Palaeozoic ocean (now represented different interpretations in termsof plate tectonics (for by theIle de Groix blueschists, Hanmer 1977) be- referencesand reviews see Ager 1975; Krebs 1976; tween Armorica and N Iberia (Lefort 1979). Windley 1977; Ziegler 1978; Anderton et al. 1979). The problem is compounded by the general lack of For someworkers the particular tectonic, metamor- magmatic plate margin characteristics such as typical phic and magmatic characters of this belt have led to ophiolite sequences, island arc or continental margin non-plate tectonic models involving lithospheric ther- volcanic rocks (in particular andesites) and voluminous maldisturbances (e.g. Krebs & Wachendorf1973; intermediate plutonics. This has led to other models Zwart & Dornsiepen1978). Much of theplate tec- involvingoblique collision or passive lateralsliding tonic argument has been concerned with the location betweenopposing continental masses (Badham & of former oceans and related subduction zones down Halls1975; Arthaud & Matte1977), although sub- which oceaniccrust disappeared prior to continent- duction and collision arestill involved at a late stage. continent collision. Interpretations generally fall into two main groups, either presented singly or in combi- nation, concerning the location of the suture relative Objectives. Thispaper outlines the chemical charac- to the Hercynian tectonic zones (Fig. 1): teristics. of basaltic lavas and high-level intrusives in (1)Within ornear the southern margin of the different Hercynian sedimentary troughs and tectonic Rheno-Hercynian (R-H) zone with either southward zones with regard to: (1) chemical variations in space (under continental Europe) or northward (under the and time, and (2) their tectonic settingby analogy with OldRed Sandstone continent) dipping subduction modern volcanic rocks. In general the chemical data zones-the vanished ocean (with the possible excep- lendsupport to ensialic rifting models with the de- tion of theLizard ophiolite, Kirby 1979) being the velopment of back-arcbasins (e.g. Reading1973; Mid-European ocean of Johnson (1973). Leeder1976; BCbien et al. 1977;Anderton et al. (2) S of theMoldanubian zone with a northward 1979), although the lack of suitable or sufficient trace dipping subduction zone under continental Europe- elementdata means that only a crude geochemical the subducted ocean being the proto-Tethys (Nicholas model can be presented. 0016-7649/82/0700-0505$02.00 @ 1982 The Geological Society Downloaded from http://pubs.geoscienceworld.org/jgs/article-pdf/139/4/505/4887555/gsjgs.139.4.0505.pdf by guest on 02 October 2021 5 06 P. A. Floyd Si02 distribution RHENO-HERCYNIAN 1 SAX0 -THURINGIAN Vosges - Iberian Pyrite FIG. 1. Location of Upper Palaeozoic volcanic rocks within the Hercynian massifs and tectonic zones of Europe. Characteristic features of zones summarized by Read & Watson (1975). Numbers refer to localities mentioned in text.Distribution of magmatypes (AB =alkali basalt,TB = tholeiiticbasalt, CA = calc-alkali)and nature of volcanism (triangles = pre-orogenic bimodal; squares = pre-orogenic bimodal +synorogenic unimodal andesite- dominated; dots = synorogenic intermediateiacid-dominated) also indicated. Volcanic nature partly after Btbien et al. (1977). SiO, distribution: various sources and author (unpubl), except Vosges Meridionales from Btbien (1976) with b = pre-orogenic bimodal and a = synorogenic andesite-dominated. Chemical problems Y, Nb, rare earth elements, REE) are largely used to characterize the Hercynian magmatic suites. In thispaper the incompatible elements will be Chemical mobility during low-grade divided according to their respective ionic potential or metamorphism field strength (ionic charge/size ratio) into two groups All the volcanicrocks preserved in the Hercynian which show differential behaviour in destructive mar- troughs have been eithermildly metamorphosed in the gin settings (cf. Saunders et al. 1979): (1) Large-ion- very low-grade anchizone (based on illite crystallinity lithophile (LIL) elements (K, Rh, CS,Ba, Sr) together in sedimentary rocks, e.g. Weber 1972; Brazier et al. with the light REE (La, Ce, Nd) that have relatively 1979) or more commonly in the prehnite-pumpellyite low field strength and represent the least mobile ele- facies to greenschist facies of regional metamorphism mentsin this group. (2) High field strength(HFS) (based on meta-basaltassemblages). As low-grade elements (Ti, P, Zr, Nb, Hf, Ta) which are immobile metamorphism causes changes in the bulk chemistryof duringalteration. Owing to thelack of full REE basalts (e.g. Hart et al. 1974; Humphris &L Thompson analyses fractionation between light and heavy REE 1978) selected stable incompatible elements (Ti,P, Zr, will be demonstrated using the Ce/Y ratio (elements Downloaded from http://pubs.geoscienceworld.org/jgs/article-pdf/139/4/505/4887555/gsjgs.139.4.0505.pdf by guest on 02 October 2021 Chemical variation in Hercynian basalts relative to platetectonics 5 07 determined by XRF) where Y has a similar behaviour have higher incompatible element contents (but lower to the heavy REE. LIL and HFS element decoupling Y),exhibit well fractionated REE patternswith will be indicated by changes in the La/Nb ratio. (Ce/Y),>4.5 and more restricted La/Nb ratios 21.0. Alkaline pillow lavas and intrusive suites may overlap compositionally, but are chemically unrelated by low- environment discrimination Tectonic pressure fractionation. Modernvolcanic rocks (in particularbasalts) with One major feature to emerge from a study of the specific chemical features characterize particular tec- chemicalcomposition of the volcanicrocks from tonic environments and as such form the basis for the different stratigraphic belts is that each geographically tectonic designation of ancient basalts (e.g. Pearce & separate volcanic centre has its own incompatible ele- Cann 1973; Wood et al. 1979). However, basalts with ment identity. Variation within each volcanic centreis a similar chemistry may be produced in different tec- governed by low-pressurecrystal fractionation as tonic regimes, since their compositions reflect the na- exemplified by the decrease in both Ni and Cr with ture of the particular mantle and the melting processes progressive fractionation, measured by the Zr content. operatingrather than the regime in which they are As seenin Fig. 2 incompatibleelement ratios (all found. This may often make the chemical designation relativeto Zr) remain constant over much of the of ancient basalts less certain. For example, in the Ti- compositional range for each volcanic centre and iden- Zr-Y diagram (Pearce & Cann 1973) certain incom- tify one magmatic suite relative to others with differ- patible element enriched oceanic basalts can also plot ent ratios. Variation in such ratios for trace elements in the intra-plate field, whereas primitive continental with low distribution coefficients (K,<< 1) can be ac- rift basalts may plot in the ocean-floor field. For the counted for by variable partial melting and/or, mantle Hercynianvolcanic rocks numbera of chemical source composition (Floyd, in press). criteria are used, which together with the geological environment, provide a reasonable, although specula- tive, interpretation of the tectonic situation throughout Compositional changes in space and time the Upper Palaeozoic. Fig.