The Early History of Quantum Mechanics
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Unit 1 Old Quantum Theory
UNIT 1 OLD QUANTUM THEORY Structure Introduction Objectives li;,:overy of Sub-atomic Particles Earlier Atom Models Light as clectromagnetic Wave Failures of Classical Physics Black Body Radiation '1 Heat Capacity Variation Photoelectric Effect Atomic Spectra Planck's Quantum Theory, Black Body ~diation. and Heat Capacity Variation Einstein's Theory of Photoelectric Effect Bohr Atom Model Calculation of Radius of Orbits Energy of an Electron in an Orbit Atomic Spectra and Bohr's Theory Critical Analysis of Bohr's Theory Refinements in the Atomic Spectra The61-y Summary Terminal Questions Answers 1.1 INTRODUCTION The ideas of classical mechanics developed by Galileo, Kepler and Newton, when applied to atomic and molecular systems were found to be inadequate. Need was felt for a theory to describe, correlate and predict the behaviour of the sub-atomic particles. The quantum theory, proposed by Max Planck and applied by Einstein and Bohr to explain different aspects of behaviour of matter, is an important milestone in the formulation of the modern concept of atom. In this unit, we will study how black body radiation, heat capacity variation, photoelectric effect and atomic spectra of hydrogen can be explained on the basis of theories proposed by Max Planck, Einstein and Bohr. They based their theories on the postulate that all interactions between matter and radiation occur in terms of definite packets of energy, known as quanta. Their ideas, when extended further, led to the evolution of wave mechanics, which shows the dual nature of matter -
Arxiv:1206.1084V3 [Quant-Ph] 3 May 2019
Overview of Bohmian Mechanics Xavier Oriolsa and Jordi Mompartb∗ aDepartament d'Enginyeria Electr`onica, Universitat Aut`onomade Barcelona, 08193, Bellaterra, SPAIN bDepartament de F´ısica, Universitat Aut`onomade Barcelona, 08193 Bellaterra, SPAIN This chapter provides a fully comprehensive overview of the Bohmian formulation of quantum phenomena. It starts with a historical review of the difficulties found by Louis de Broglie, David Bohm and John Bell to convince the scientific community about the validity and utility of Bohmian mechanics. Then, a formal explanation of Bohmian mechanics for non-relativistic single-particle quantum systems is presented. The generalization to many-particle systems, where correlations play an important role, is also explained. After that, the measurement process in Bohmian mechanics is discussed. It is emphasized that Bohmian mechanics exactly reproduces the mean value and temporal and spatial correlations obtained from the standard, i.e., `orthodox', formulation. The ontological characteristics of the Bohmian theory provide a description of measurements in a natural way, without the need of introducing stochastic operators for the wavefunction collapse. Several solved problems are presented at the end of the chapter giving additional mathematical support to some particular issues. A detailed description of computational algorithms to obtain Bohmian trajectories from the numerical solution of the Schr¨odingeror the Hamilton{Jacobi equations are presented in an appendix. The motivation of this chapter is twofold. -
Walther Nernst, Albert Einstein, Otto Stern, Adriaan Fokker
Walther Nernst, Albert Einstein, Otto Stern, Adriaan Fokker, and the Rotational Specific Heat of Hydrogen Clayton Gearhart St. John’s University (Minnesota) Max-Planck-Institut für Wissenschaftsgeschichte Berlin July 2007 1 Rotational Specific Heat of Hydrogen: Widely investigated in the old quantum theory Nernst Lorentz Eucken Einstein Ehrenfest Bohr Planck Reiche Kemble Tolman Schrödinger Van Vleck Some of the more prominent physicists and physical chemists who worked on the specific heat of hydrogen through the mid-1920s. See “The Rotational Specific Heat of Molecular Hydrogen in the Old Quantum Theory” http://faculty.csbsju.edu/cgearhart/pubs/sel_pubs.htm (slide show) 2 Rigid Rotator (Rotating dumbbell) •The rigid rotator was among the earliest problems taken up in the old (pre-1925) quantum theory. • Applications: Molecular spectra, and rotational contri- bution to the specific heat of molecular hydrogen • The problem should have been simple Molecular • relatively uncomplicated theory spectra • only one adjustable parameter (moment of inertia) • Nevertheless, no satisfactory theoretical description of the specific heat of hydrogen emerged in the old quantum theory Our story begins with 3 Nernst’s Heat Theorem Walther Nernst 1864 – 1941 • physical chemist • studied with Boltzmann • 1889: lecturer, then professor at Göttingen • 1905: professor at Berlin Nernst formulated his heat theorem (Third Law) in 1906, shortly after appointment as professor in Berlin. 4 Nernst’s Heat Theorem and Quantum Theory • Initially, had nothing to do with quantum theory. • Understand the equilibrium point of chemical reactions. • Nernst’s theorem had implications for specific heats at low temperatures. • 1906–1910: Nernst and his students undertook extensive measurements of specific heats of solids at low (down to liquid hydrogen) temperatures. -
Analysis of Nonlinear Dynamics in a Classical Transmon Circuit
Analysis of Nonlinear Dynamics in a Classical Transmon Circuit Sasu Tuohino B. Sc. Thesis Department of Physical Sciences Theoretical Physics University of Oulu 2017 Contents 1 Introduction2 2 Classical network theory4 2.1 From electromagnetic fields to circuit elements.........4 2.2 Generalized flux and charge....................6 2.3 Node variables as degrees of freedom...............7 3 Hamiltonians for electric circuits8 3.1 LC Circuit and DC voltage source................8 3.2 Cooper-Pair Box.......................... 10 3.2.1 Josephson junction.................... 10 3.2.2 Dynamics of the Cooper-pair box............. 11 3.3 Transmon qubit.......................... 12 3.3.1 Cavity resonator...................... 12 3.3.2 Shunt capacitance CB .................. 12 3.3.3 Transmon Lagrangian................... 13 3.3.4 Matrix notation in the Legendre transformation..... 14 3.3.5 Hamiltonian of transmon................. 15 4 Classical dynamics of transmon qubit 16 4.1 Equations of motion for transmon................ 16 4.1.1 Relations with voltages.................. 17 4.1.2 Shunt resistances..................... 17 4.1.3 Linearized Josephson inductance............. 18 4.1.4 Relation with currents................... 18 4.2 Control and read-out signals................... 18 4.2.1 Transmission line model.................. 18 4.2.2 Equations of motion for coupled transmission line.... 20 4.3 Quantum notation......................... 22 5 Numerical solutions for equations of motion 23 5.1 Design parameters of the transmon................ 23 5.2 Resonance shift at nonlinear regime............... 24 6 Conclusions 27 1 Abstract The focus of this thesis is on classical dynamics of a transmon qubit. First we introduce the basic concepts of the classical circuit analysis and use this knowledge to derive the Lagrangians and Hamiltonians of an LC circuit, a Cooper-pair box, and ultimately we derive Hamiltonian for a transmon qubit. -
Path Integrals in Quantum Mechanics
Path Integrals in Quantum Mechanics Emma Wikberg Project work, 4p Department of Physics Stockholm University 23rd March 2006 Abstract The method of Path Integrals (PI’s) was developed by Richard Feynman in the 1940’s. It offers an alternate way to look at quantum mechanics (QM), which is equivalent to the Schrödinger formulation. As will be seen in this project work, many "elementary" problems are much more difficult to solve using path integrals than ordinary quantum mechanics. The benefits of path integrals tend to appear more clearly while using quantum field theory (QFT) and perturbation theory. However, one big advantage of Feynman’s formulation is a more intuitive way to interpret the basic equations than in ordinary quantum mechanics. Here we give a basic introduction to the path integral formulation, start- ing from the well known quantum mechanics as formulated by Schrödinger. We show that the two formulations are equivalent and discuss the quantum mechanical interpretations of the theory, as well as the classical limit. We also perform some explicit calculations by solving the free particle and the harmonic oscillator problems using path integrals. The energy eigenvalues of the harmonic oscillator is found by exploiting the connection between path integrals, statistical mechanics and imaginary time. Contents 1 Introduction and Outline 2 1.1 Introduction . 2 1.2 Outline . 2 2 Path Integrals from ordinary Quantum Mechanics 4 2.1 The Schrödinger equation and time evolution . 4 2.2 The propagator . 6 3 Equivalence to the Schrödinger Equation 8 3.1 From the Schrödinger equation to PI’s . 8 3.2 From PI’s to the Schrödinger equation . -
Relativistic Quantum Mechanics 1
Relativistic Quantum Mechanics 1 The aim of this chapter is to introduce a relativistic formalism which can be used to describe particles and their interactions. The emphasis 1.1 SpecialRelativity 1 is given to those elements of the formalism which can be carried on 1.2 One-particle states 7 to Relativistic Quantum Fields (RQF), which underpins the theoretical 1.3 The Klein–Gordon equation 9 framework of high energy particle physics. We begin with a brief summary of special relativity, concentrating on 1.4 The Diracequation 14 4-vectors and spinors. One-particle states and their Lorentz transforma- 1.5 Gaugesymmetry 30 tions follow, leading to the Klein–Gordon and the Dirac equations for Chaptersummary 36 probability amplitudes; i.e. Relativistic Quantum Mechanics (RQM). Readers who want to get to RQM quickly, without studying its foun- dation in special relativity can skip the first sections and start reading from the section 1.3. Intrinsic problems of RQM are discussed and a region of applicability of RQM is defined. Free particle wave functions are constructed and particle interactions are described using their probability currents. A gauge symmetry is introduced to derive a particle interaction with a classical gauge field. 1.1 Special Relativity Einstein’s special relativity is a necessary and fundamental part of any Albert Einstein 1879 - 1955 formalism of particle physics. We begin with its brief summary. For a full account, refer to specialized books, for example (1) or (2). The- ory oriented students with good mathematical background might want to consult books on groups and their representations, for example (3), followed by introductory books on RQM/RQF, for example (4). -
Feynman Quantization
3 FEYNMAN QUANTIZATION An introduction to path-integral techniques Introduction. By Richard Feynman (–), who—after a distinguished undergraduate career at MIT—had come in as a graduate student to Princeton, was deeply involved in a collaborative effort with John Wheeler (his thesis advisor) to shake the foundations of field theory. Though motivated by problems fundamental to quantum field theory, as it was then conceived, their work was entirely classical,1 and it advanced ideas so radicalas to resist all then-existing quantization techniques:2 new insight into the quantization process itself appeared to be called for. So it was that (at a beer party) Feynman asked Herbert Jehle (formerly a student of Schr¨odinger in Berlin, now a visitor at Princeton) whether he had ever encountered a quantum mechanical application of the “Principle of Least Action.” Jehle directed Feynman’s attention to an obscure paper by P. A. M. Dirac3 and to a brief passage in §32 of Dirac’s Principles of Quantum Mechanics 1 John Archibald Wheeler & Richard Phillips Feynman, “Interaction with the absorber as the mechanism of radiation,” Reviews of Modern Physics 17, 157 (1945); “Classical electrodynamics in terms of direct interparticle action,” Reviews of Modern Physics 21, 425 (1949). Those were (respectively) Part III and Part II of a projected series of papers, the other parts of which were never published. 2 See page 128 in J. Gleick, Genius: The Life & Science of Richard Feynman () for a popular account of the historical circumstances. 3 “The Lagrangian in quantum mechanics,” Physicalische Zeitschrift der Sowjetunion 3, 64 (1933). The paper is reprinted in J. -
Realism About the Wave Function
Realism about the Wave Function Eddy Keming Chen* Forthcoming in Philosophy Compass Penultimate version of June 12, 2019 Abstract A century after the discovery of quantum mechanics, the meaning of quan- tum mechanics still remains elusive. This is largely due to the puzzling nature of the wave function, the central object in quantum mechanics. If we are real- ists about quantum mechanics, how should we understand the wave function? What does it represent? What is its physical meaning? Answering these ques- tions would improve our understanding of what it means to be a realist about quantum mechanics. In this survey article, I review and compare several realist interpretations of the wave function. They fall into three categories: ontological interpretations, nomological interpretations, and the sui generis interpretation. For simplicity, I will focus on non-relativistic quantum mechanics. Keywords: quantum mechanics, wave function, quantum state of the universe, sci- entific realism, measurement problem, configuration space realism, Hilbert space realism, multi-field, spacetime state realism, laws of nature Contents 1 Introduction 2 2 Background 3 2.1 The Wave Function . .3 2.2 The Quantum Measurement Problem . .6 3 Ontological Interpretations 8 3.1 A Field on a High-Dimensional Space . .8 3.2 A Multi-field on Physical Space . 10 3.3 Properties of Physical Systems . 11 3.4 A Vector in Hilbert Space . 12 *Department of Philosophy MC 0119, University of California, San Diego, 9500 Gilman Dr, La Jolla, CA 92093-0119. Website: www.eddykemingchen.net. Email: [email protected] 1 4 Nomological Interpretations 13 4.1 Strong Nomological Interpretations . 13 4.2 Weak Nomological Interpretations . -
The Concept of the Photon—Revisited
The concept of the photon—revisited Ashok Muthukrishnan,1 Marlan O. Scully,1,2 and M. Suhail Zubairy1,3 1Institute for Quantum Studies and Department of Physics, Texas A&M University, College Station, TX 77843 2Departments of Chemistry and Aerospace and Mechanical Engineering, Princeton University, Princeton, NJ 08544 3Department of Electronics, Quaid-i-Azam University, Islamabad, Pakistan The photon concept is one of the most debated issues in the history of physical science. Some thirty years ago, we published an article in Physics Today entitled “The Concept of the Photon,”1 in which we described the “photon” as a classical electromagnetic field plus the fluctuations associated with the vacuum. However, subsequent developments required us to envision the photon as an intrinsically quantum mechanical entity, whose basic physics is much deeper than can be explained by the simple ‘classical wave plus vacuum fluctuations’ picture. These ideas and the extensions of our conceptual understanding are discussed in detail in our recent quantum optics book.2 In this article we revisit the photon concept based on examples from these sources and more. © 2003 Optical Society of America OCIS codes: 270.0270, 260.0260. he “photon” is a quintessentially twentieth-century con- on are vacuum fluctuations (as in our earlier article1), and as- Tcept, intimately tied to the birth of quantum mechanics pects of many-particle correlations (as in our recent book2). and quantum electrodynamics. However, the root of the idea Examples of the first are spontaneous emission, Lamb shift, may be said to be much older, as old as the historical debate and the scattering of atoms off the vacuum field at the en- on the nature of light itself – whether it is a wave or a particle trance to a micromaser. -
Quantum Mechanics in 1-D Potentials
MASSACHUSETTS INSTITUTE OF TECHNOLOGY Department of Electrical Engineering and Computer Science 6.007 { Electromagnetic Energy: From Motors to Lasers Spring 2011 Tutorial 10: Quantum Mechanics in 1-D Potentials Quantum mechanical model of the universe, allows us describe atomic scale behavior with great accuracy|but in a way much divorced from our perception of everyday reality. Are photons, electrons, atoms best described as particles or waves? Simultaneous wave-particle description might be the most accurate interpretation, which leads us to develop a mathe- matical abstraction. 1 Rules for 1-D Quantum Mechanics Our mathematical abstraction of choice is the wave function, sometimes denoted as , and it allows us to predict the statistical outcomes of experiments (i.e., the outcomes of our measurements) according to a few rules 1. At any given time, the state of a physical system is represented by a wave function (x), which|for our purposes|is a complex, scalar function dependent on position. The quantity ρ (x) = ∗ (x) (x) is a probability density function. Furthermore, is complete, and tells us everything there is to know about the particle. 2. Every measurable attribute of a physical system is represented by an operator that acts on the wave function. In 6.007, we're largely interested in position (x^) and momentum (p^) which have operator representations in the x-dimension @ x^ ! x p^ ! ~ : (1) i @x Outcomes of measurements are described by the expectation values of the operator Z Z @ hx^i = dx ∗x hp^i = dx ∗ ~ : (2) i @x In general, any dynamical variable Q can be expressed as a function of x and p, and we can find the expectation value of Z h @ hQ (x; p)i = dx ∗Q x; : (3) i @x 3. -
Theory and Experiment in the Quantum-Relativity Revolution
Theory and Experiment in the Quantum-Relativity Revolution expanded version of lecture presented at American Physical Society meeting, 2/14/10 (Abraham Pais History of Physics Prize for 2009) by Stephen G. Brush* Abstract Does new scientific knowledge come from theory (whose predictions are confirmed by experiment) or from experiment (whose results are explained by theory)? Either can happen, depending on whether theory is ahead of experiment or experiment is ahead of theory at a particular time. In the first case, new theoretical hypotheses are made and their predictions are tested by experiments. But even when the predictions are successful, we can’t be sure that some other hypothesis might not have produced the same prediction. In the second case, as in a detective story, there are already enough facts, but several theories have failed to explain them. When a new hypothesis plausibly explains all of the facts, it may be quickly accepted before any further experiments are done. In the quantum-relativity revolution there are examples of both situations. Because of the two-stage development of both relativity (“special,” then “general”) and quantum theory (“old,” then “quantum mechanics”) in the period 1905-1930, we can make a double comparison of acceptance by prediction and by explanation. A curious anti- symmetry is revealed and discussed. _____________ *Distinguished University Professor (Emeritus) of the History of Science, University of Maryland. Home address: 108 Meadowlark Terrace, Glen Mills, PA 19342. Comments welcome. 1 “Science walks forward on two feet, namely theory and experiment. ... Sometimes it is only one foot which is put forward first, sometimes the other, but continuous progress is only made by the use of both – by theorizing and then testing, or by finding new relations in the process of experimenting and then bringing the theoretical foot up and pushing it on beyond, and so on in unending alterations.” Robert A. -
Quantum Mechanics I - Iii
QUANTUM MECHANICS I - III PHYS 516 - 518 Jan 1 - Dec. 31, 2015 Prof. R. Gilmore 12-918 X-2779 [email protected] office hours: 2:00 ! \1" Course Schedule: (Winter Quarter) MWF 11:00 - 11:50, Disque 919 Objective: To provide the foundations for modern physics. Course Requirements and Obligations Course grading will be based on assigned homework problem sets and a midterm and final exam. Texts Two texts and one supplement will be used for this course. The first text has been chosen from among many admirable texts because it provides a more comprehensive treatment of quantum physics discovered since 1970 than other texts. The second text will be used primarily during the second quarter of this course (PHYS517). It provides hands-on experience for solving binding and scattering problems in one dimension and potentials involving periodic poten- tials, again in one dimension. The third text (optional) is strongly recommended for those who feel their undergratuate experience in this beautiful subject may be deficient in some way. It is out of print but a limited number of copies are often available through Amazon in the event our book store has sold out of their reprinted copies. 1 David H. McIntyre Quantum Mechanics NY: Pearson, 2012 ISBN-10: 0-321-76579-6 R. Gilmore Elementary Quantum Mechanics in One Dimension Baltimore, Johns Hopkins University Press, 2004 ISBN 0-8018-8015-7 R. H. Dicke and J. P. Wittke Introduction to Quantum Mechanics Reading, MA: Addison-Wesley, 1960 ISBN 0-? If it becomes a hardship to acquire this fine text, you can get about the same information from another, later, fine text: David J.