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Mechanical Properties for Polyester Resin Reinforce with Fe Weave Wire
International Journal of Application or Innovation in Engineering & Management (IJAIEM) Web Site: www.ijaiem.org Email: [email protected] Volume 3, Issue 7, July 2014 ISSN 2319 - 4847 Mechanical Properties for Polyester resin Reinforce with Fe Weave Wire Alaa A. Abdul-Hamead 1, Thekra Kasim2, and Awattiff A.Mohammed 3 1 Materials Eng. Department University of Technology 2Department of Physics, College of Science, University of Baghdad, Baghdad, Iraq 3Department of Physics, College of Science, University of Baghdad, Baghdad, Iraq ABSTRACT In the present work we prepared and study a polymer composite using from and polyester polymer with iron weave wire ratios (5,10,15,20%) .At first was studied and examined with chemical composition analyzing, then some of physical and mechanical properties of the composite were studied stress –strain , impact strength, fracture toughness , hardness and thermal conductivity. Results show an improvement in these mechanical properties after reinforcement by metals the value of mechanical properties will increase with increasing percentage of reinforcement. Keywords: polymer composite, polyester , Fe weave wire , impact strength, fracture toughness, hardness & thermal conductivity. 1. INTRODUCTION Composite materials were created as a result of an intensive search for materials which offer high reinforcement levels, with good mechanical properties and light weight.[1] Polymer composites can be classified as :Macro-composites ,Micro- composites and Nanocomposites according to fillers size[2,3]. Unsaturated polymers (UPE) resin is used for a wide variety of industrial and consumer applications. This consumption can be split into two major categories of applications: reinforced and nonreinforced. In reinforced applications, resin and reinforcement, such as fiberglass, are used together to produce a composite with improved physical properties. -
Poly (Ethylene Terephthalate) Recycling for High Value Added Textiles Sang Ho Park and Seong Hun Kim*
Park and Kim Fashion and Textiles 2014, 1:1 http://link.springer.com/article/10.1186/s40691-014-0001-x REVIEW Open Access Poly (ethylene terephthalate) recycling for high value added textiles Sang Ho Park and Seong Hun Kim* * Correspondence: [email protected] Abstract Department of Organic anc Nano Engineering, College of This study reviews the problems in the use and disposal of poly (ethylene Engineering, Hanyang University, 17 terephthalate) (PET) and includes the concise background of virgin and recycled PET Haengdang-dong, Sungdong-gu, as well as their possible applications. The current state of knowledge with respect to Seoul 133-791, Korea PET recycling method is presented. Recycling of PET is the most desirable method for waste management, providing an opportunity for reductions in oil usage, carbon dioxide emissions and PET waste requiring disposal because of its non-degradability. Advanced technologies and systems for reducing contamination, mechanical and chemical recycling, and their applications are discussed, and the possibility of diverting the majority of PET waste from landfills or incineration to recycling is suggested. Keywords: Polyethylene terephthalate; Mechanical recycle; Chemical recycle Introduction Poly (ethylene terephthalate) (PET), commonly referred to as ‘polyester’ in the textile industry, is considered to be one of the most important thermoplastic polyesters (Incornato et al. 2000). It is widely used for various applications such as bottles, fibers, moldings, and sheets because of its excellent tensile and impact strength, clarity, pro- cessability, chemical resistance, and thermal stability (Pawlak et al. 2000; Kong and Hay 2003; Avila-Orta et al. 2003). The PET fiber patented originally by DuPont (DuPont, 1997) dominates over 50% of the world synthetic fiber market. -
Role of Thermosetting Polymer in Structural Composite
View metadata, citation and similar papers at core.ac.uk brought to you by CORE provided by Ivy Union Publishing (E-Journals) American Journal of Polymer Science & Engineering Kausar A. American Journal of Polymer Sciencehttp://www.ivyunion.org/index.php/ajpse/ & Engineering 2017, 5:1-12 Page 1 of 12 Review Article Role of Thermosetting Polymer in Structural Composite Ayesha Kausar1 1 Nanoscience and Technology Department, National Center For Physics, Quaid-i-Azam University Campus, Islamabad, Pakistan Abstract Thermosetting resins are network forming polymers with highly crosslinked structure. In this review article, thermoset of epoxy, unsaturated polyester resin, phenolic, melamine, and polyurethane resin have been conversed. Thermosets usually have outstanding tensile strength, impact strength, and glass transition temperature (Tg). Epoxy is the most widely explored class of thermosetting resins. Owing to high stiffness and strength, chemical resistance, good dielectric behavior, corrosion resistance, low shrinkage during curing, and good thermal features, epoxy form the most important class of thermosetting resins for several engineering applications. Here, essential features of imperative thermosetting resins have been discussed such as mechanical, thermal, and non-flammability. At the end, employment of thermosetting resins in technical applications like sporting goods, adhesives, printed circuit board, and aerospace have been included. Keywords: Thermoset; epoxy; mechanical; non-flammability; application Received : November 14, 2016; Accepted: January 8, 2017; Published: January 16, 2017 Competing Interests: The authors have declared that no competing interests exist. Copyright: 2017 Kausar A. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited. -
4.4 Polyester Resin Plastic Products Fabrication 4.4.1 General
4.4 Polyester Resin Plastic Products Fabrication 4.4.1 General Description1-2 A growing number of products are fabricated from liquid polyester resin reinforced with glass fibers and extended with various inorganic filler materials such as calcium carbonate, talc, mica, or small glass spheres. These composite materials are often referred to as fiberglass-reinforced plastic (FRP), or simply "fiberglass". The Society Of The Plastics industry designates these materials as "reinforced plastics/composites" (RP/C). Also, advanced reinforced plastics products are now formulated with fibers other than glass, such as carbon, aramid, and aramid/carbon hybrids. In some processes, resin products are fabricated without fibers. One major product using resins with fillers but no reinforcing fibers is the synthetic marble used in manufacturing bathroom countertops, sinks, and related items. Other applications of nonreinforced resin plastics include automobile body filler, bowling balls, and coatings. Fiber-reinforced plastics products have a wide range of application in industry, transportation, home, and recreation. Industrial uses include storage tanks, skylights, electrical equipment, ducting, pipes, machine components, and corrosion resistant structural and process equipment. In transportation, automobile and aircraft applications are increasing rapidly. Home and recreational items include bathroom tubs and showers, boats (building and repair), surfboards and skis, helmets, swimming pools and hot tubs, and a variety of sporting goods. The thermosetting polyester resins considered here are complex polymers resulting from the cross-linking reaction of a liquid unsaturated polyester with a vinyl type monomer, list often styrene. The unsaturated polyester is formed from the condensation reaction of an unsaturated dibasic acid or anhydride, a saturated dibasic acid or anhydride, and a polyfunctional alcohol. -
Jacobsen Declaration Exhibit AA Case 3:06-Cv-01905-JSW Document 237-28 Filed 10/03/2008 Page 2 of 18
Case 3:06-cv-01905-JSW Document 237-28 Filed 10/03/2008 Page 1 of 18 Jacobsen Declaration Exhibit AA Case 3:06-cv-01905-JSW Document 237-28 Filed 10/03/2008 Page 2 of 18 CLINIC SCHEDULE Ames, Stan EMERGING ADVANCED TOPICS IN DCC Schedule of clinics is listed by clincian name As DCC advances there are now several new capabilities that are Albers, Gerry just beginning to emerge. Topics to be discussed are Bi-Directional CAD MODEL RAILROAD DESIGN DCC, Asymmetrical DCC, and Signal Controlled Influence. These emerging technologies combine to significantly enhance model Advantages, disadvantages, and benefits of using Computer Aided railroad operations. Stan Ames is one of three co-authors of "Digital Design (CAD) for model railroad design are presented, including Command Control: A comprehensive guide to DCC". Stan was the what to look for in a CAD program. This clinic is pragmatic in nature original chair of the DCC working group and was also a former chair and includes a "live" demonstration of CADrail 8. A list of all of the NMRA Conformance and Inspection program. Stan is a Life known (to the author) current CAD products is provided. Note: an Member of the NMRA and past NER Trustee. article in MR Planning 2005 will parallel this clinic. SUNDAY 2 :30 PM - 3 :30 PM ROOM 262 WEDNESDAY 6 :30 PM - 7 :30 PM ROOM 204 MONDAY 10:30 AM - 11:30 AM ROOM 208 THURSDAY 6 :30 PM - 7 :30 PM ROOM 212 SIGNAL SYSTEMS IN MODEL RAILROADING- SELECTING A DCC SYSTEM The modeler is led gradually through topics from basic prototype Thinking of going DCC? In 1992 the NMRA initiated an effort to signal practices to advanced electronic techniques, including a generate standards for a whole new generation of model railroad detailed description of Allen McClelland's original Virginian & Ohio control, which has become known as NMRA Digital Command signal system and a description of a modern DCC system. -
Materials for Polymer Composites
Module 2 - Materials For Polymer Composites Module 2 - Materials for Polymer Composites Introduction Major constituents in a fiber-reinforced composite material are the reinforcing fibers and a matrix, which acts as a binder for the fibers. Other constituents that may also be found are coupling agents, coatings, and fillers. Coupling agents and coatings are applied on the fibers to improve their wetting with the matrix as well as to promote bonding across the fiber–matrix interface. Both in turn promote a better load transfer between the fibers and the matrix. Fillers are used with some polymeric matrices primarily to reduce cost and improve their dimensional stability. Manufacturing of a composite structure starts with the incorporation of a large number of fibers into a thin layer of matrix to form a lamina (ply). The thickness of a lamina is usually in the range of 0.1–1 mm. If continuous (long) fibers are used in making the lamina, they may be arranged either in a unidirectional orientation (i.e., all fibers in one direction, Figure 2.1a), in a bidirectional orientation (i.e., fibers in two directions, usually normal to each other, Figure 2.1b), or in a multidirectional orientation (i.e., fibers in more than two directions, Figure 2.1c). The bi- or multidirectional orientation of fibers is obtained by weaving or other processes used in the textile industry. For a lamina containing unidirectional fibers, the composite material has the highest strength and modulus in the longitudinal direction of the fibers. However, in the transverse direction, its strength and modulus are very low. -
Fundamentals of the Chemical Cross-Linking of 2-Pack Systems
TI 15/12: Fundamentals of the chemical cross-linking of 2-pack systems A large part of the lacquers and casting compounds employed in the production of printed circuit boards and in electrical engineering are 2-pack systems. These products are well established in the market, not least because of their adaptability to the individual application. On the one hand, this “individual adaptability“ is rendered possible by the highly developed chemical technology of the resin manufacturers and, on the other hand, by the cleverly devised formulation of the raw materials, so that tailored, so-called “custom-made“, end products are available. Not least on account of the long lasting experience and the good and intensive cooperation with resin suppliers, Lackwerke Peters are in a position to convert these resin raw materials into products with outstanding final properties that can be processed in the best possible manner. Another great advantage of the 2-pack systems is the possibility to operate with substantially reduced solvent contents and possibly even with solvent-free systems while the good processing properties remain unchanged. This TI explains in a readily comprehensible manner the term cross-linking and expounds - by means of some examples - which types of cross-linking of 2-pack systems are mainly used in the production of printed circuit boards and in electrical engineering, such as the different cross-linking mechanisms of our photoimageable 2- pack solder resists of the series Elpemer 2467 and 2469. Cross-linking The term “cross-linking” or “polymerization” describes the chemical poly-reaction of basic modules (molecules) into a network of “interconnected” molecules/basic modules. -
Polyester Resin Hazards by L
Br J Ind Med: first published as 10.1136/oem.20.2.100 on 1 April 1963. Downloaded from Brit. J. industr. Med., 1963, 20, 100. POLYESTER RESIN HAZARDS BY L. B. BOURNE and F. J. M. MILNER From the Cossor Group of Companies (RECEIVED FOR PUBLICATION AUGUST 15, 1962) Polyester resins are being increasingly used in industry. These resins require the addition of catalysts and accelerators. The handling of polyester resin system materials may give rise to skin irritations, allergic reactions, and bums. The bums are probably due to styrene and organic peroxides. Atmospheric pollution from styrene and explosion and fire risks from organic peroxides must be prevented. Where dimethylaniline is used scrupulous cleanliness and no-touch technique must be enforced. Handling precautions are suggested. For some 20 years polyester resins have been investigate glycol maleates, further work being available and during this time they have been used carried out by Kienle and Hovey (1930) and in in increasing quantities; the annual output in this Britain patents relating to polyester resins were taken country is now of the order of 9,000 tons. Polyesters out in 1932 (British Patent 393034). Further are unsaturated thermo-setting resins which can be development in the United States proved that these moulded in almost any shape and size. Alone they had excellent properties for radar work. It was are usually not strong enough for commercial pur- eventually found that they had valuable laminating poses but when combined with a reinforcing material, properties particularly when used with glass fibre. such as glass fibre, or fillers, such as glass dust or The growth in popularity of the resin is shown by sand, they offer considerable possibilities. -
CHAPTER I Introduction 1.1 Thermosets Thermosetting
Ph.D. Thesis Savitribai Phule Rune University CHAPTER I Introduction 1.1 Thermosets Thermosetting polymers/resins are pre-polymers in a soft solid or viscous liquid state. They change irreversibly into an infusible, insoluble three dimensional polymer network of covalent bonds as a result of a chemical reaction taking place in presence of a curing agent/hardener. The resultant structure is known as a thermosetting plastic or thermoset. They can be heated and shaped only once. If re-heated they cannot soften as polymer chains are interlinked. Thus, these polymers are synthesized as a final material of desired shape (polymerization and final shaping is done in the same process or mould is the true chemical reactor). They offer high thermal stability, good rigidity, hardness, and resistance to creep [1]. A good solvent can swell the thermoset but cannot dissolve it. Thermosets are usually amorphous (crosslinks inhibit the movement of polymer chains to pack or crystallize and restrict ordering of network structure) in nature. Thermosets do often exhibit high glass transition temperatures. Their glass transition temperature is higher than the temperature at which they are used (Tuse), therefore, they behave as glasses during their use [2]. The main thermosetting resins are epoxy, melamine formaldehyde, polyester, polyurethane and urea formaldehyde. Thermosets find applications where thermoplasfics cannot compete because of their properties and cost. When fire resistance is required, phenolics are the first choice. Urea formaldehyde is the material used as an adhesive for wood. Melamine formaldehyde is an excellent quality and low cost material used for furniture coating. Polyester resin is used to make fiber reinforced structural parts and epoxy resins constitute a very important class of thermosets used in aeronautical applications. -
Chemical Shrinkage Characterization Techniques for Thermoset Resins and Associated Composites Yasir Nawab, Salma Shahid, Nicolas Boyard, Frédéric Jacquemin
Chemical shrinkage characterization techniques for thermoset resins and associated composites Yasir Nawab, Salma Shahid, Nicolas Boyard, Frédéric Jacquemin To cite this version: Yasir Nawab, Salma Shahid, Nicolas Boyard, Frédéric Jacquemin. Chemical shrinkage characterization techniques for thermoset resins and associated composites. Journal of Materials Science, Springer Verlag, 2013, 48 (16), pp.5387-5409. 10.1007/s10853-013-7333-6. hal-01005857 HAL Id: hal-01005857 https://hal.archives-ouvertes.fr/hal-01005857 Submitted on 11 Jan 2019 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Chemical shrinkage characterization techniques for thermoset resins and associated composites Yasir Nawab • Salma Shahid • Nicolas Boyard • Fre´de´ric Jacquemin Abstract Control and optimization of curing process is In this article, all the techniques used in the literature for very important for the production of high quality composite the characterization of Sh of resin and composite are parts. Crosslinking of molecules of thermoset resin occurs reported briefly with their respective advantages, disad- in this phase, which involves exothermy of reaction, vantage and important results. chemical shrinkage (Sh) and development of thermo- physical and thermo-mechanical properties. Exact knowl- edge of the evolution of all these parameters is required for Introduction the better understanding and improvement of the fabrica- tion process. -
Choosing the Right Resin for the Job
CHOOSING THE RIGHT RESIN FOR THE JOB Polyester and Epoxy resins have certain things in common, but each also has its own characteristics: POLYESTER IS IDEAL: EPOXY RESIN IS IDEAL: -As a repair for all kinds of surfaces, such as plaster, - When superior adhesion and strength is necessary. fiberglass, aluminum and wood (except redwood and Excellent adhesion to metals, woods, glass, rubber, and close-grained woods like oak or cedar. Do not use with fiberglass. Styrofoam.) - Provides excellent bond between non-porous surfaces, - For structural repairs using fiberglass cloth or mat like metals including aluminum. where high impact resistance is critical - As a tough coating or repaid material for most surfaces - As a protective, waterproof coating and sealer. including Styrofoam, redwood, cedar and oak. - The hardener for polyester resin can be increased or - Where a smooth glossy surface is important. Epoxy is decreased according to instructions, depending on however, more expensive than polyester resin and temperature. Cooler temperatures require more requires more care when mixing and applying. catalyst, warmer temperatures less. - Very low shrinkage. 100% reactive. Low VOC - Polyester is economical and easy to use. - Epoxy should be used at room temperature (70-90f); - High shrinkage factor otherwise rate of cure may be affected. The user should not attempt to adjust the ratio of hardener to resin. NOTE: Polyester resins cannot be used to repair thermoplastics; that is, the kind from which Tupperware - The hardener should be used as directed with the or molded toys like “Big Wheels” are made. epoxy resin. The two parts should be measured into a Thermoplastics include polyethylene, polypropylene, mixing container, not simply dumped together, even acrylic, PVC, and ABS. -
Mpdiol® Glycol Use in Producing Unsaturated Polyester Resins (
Application Data MPDiol® Glycol Use in Producing Unsaturated Polyester Resins ( General MPDiol glycol (2-methyl-1,3-propanediol) can be used in production of UPRs with phthalic anhydride, isophthalic acid and terephthalic acid. The unique structure and reactivity of MPDiol glycol makes it particularly useful in combination with terephthalate-type starting materials. Use of MPDiol glycol as the primary source of glycol in making unsaturated polyester resins provides improvements in caustic corrosion resistance and mechanical performance (strength and elongation) compared to typical ortho, iso or terephthalate resins. Key Features and Benefits Increased Production Rates: Because both hydroxyl groups of this glycol are primary, it has an inherently high reactivity. The high boiling point (30oC > PG) makes it possible to run reactions hotter, providing a potential eight-fold increase in reaction (esterification) rates. Improved Styrene Solubility: The unique structure of the MPDiol glycol molecule produces an unsaturated polyester polymer with reduced crystallinity and, therefore, increased styrene solubility. This reduction in crystallinity is particularly noticed in polyester systems that contain high proportions of terephthalate segments, which are typically highly crystalline. Improved Corrosion Performance: The use of MPDiol glycol as the predominant glycol in a polyester resin produces a UPR that demonstrates better corrosion resistance than similar polymers made with propylene glycol (PG), ethylene glycol (EG) or diethylene glycol (DEG). Large improvements are routinely observed in caustic corrosion resistance. Improved Mechanical Performance: The UPRs made with MPDiol glycol demonstrate better mechanical performance (strength and elongation to failure) when compared to similar polymers made with PG. Combined with the excellent corrosion resistance of these polymers, these UPRs routinely retain a very high percentage of their initial properties following environmental exposure.