Atlas Der Krystallformen
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Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
Thirty-Fourth List of New Mineral Names
MINERALOGICAL MAGAZINE, DECEMBER 1986, VOL. 50, PP. 741-61 Thirty-fourth list of new mineral names E. E. FEJER Department of Mineralogy, British Museum (Natural History), Cromwell Road, London SW7 5BD THE present list contains 181 entries. Of these 148 are Alacranite. V. I. Popova, V. A. Popov, A. Clark, valid species, most of which have been approved by the V. O. Polyakov, and S. E. Borisovskii, 1986. Zap. IMA Commission on New Minerals and Mineral Names, 115, 360. First found at Alacran, Pampa Larga, 17 are misspellings or erroneous transliterations, 9 are Chile by A. H. Clark in 1970 (rejected by IMA names published without IMA approval, 4 are variety because of insufficient data), then in 1980 at the names, 2 are spelling corrections, and one is a name applied to gem material. As in previous lists, contractions caldera of Uzon volcano, Kamchatka, USSR, as are used for the names of frequently cited journals and yellowish orange equant crystals up to 0.5 ram, other publications are abbreviated in italic. sometimes flattened on {100} with {100}, {111}, {ill}, and {110} faces, adamantine to greasy Abhurite. J. J. Matzko, H. T. Evans Jr., M. E. Mrose, lustre, poor {100} cleavage, brittle, H 1 Mono- and P. Aruscavage, 1985. C.M. 23, 233. At a clinic, P2/c, a 9.89(2), b 9.73(2), c 9.13(1) A, depth c.35 m, in an arm of the Red Sea, known as fl 101.84(5) ~ Z = 2; Dobs. 3.43(5), D~alr 3.43; Sharm Abhur, c.30 km north of Jiddah, Saudi reflectances and microhardness given. -
Geology of Greenland Survey Bulletin 190, 25-33
List of all minerals identified in the Ilímaussaq alkaline complex, South Greenland Ole V. Petersen About 220 minerals have been described from the Ilímaussaq alkaline complex. A list of all minerals, for which proper documentation exists, is presented with formulae and references to original publications. The Ilímaussaq alkaline complex is the type locality for 27 minerals including important rock-forming minerals such as aenigmatite, arfvedsonite, eudialyte, poly- lithionite, rinkite and sodalite. Nine minerals, chalcothallite, karupmøllerite-Ca, kvanefjeldite, nabesite, nacareniobsite-(Ce), naujakasite, rohaite, semenovite and sorensenite appear to be unique to the Ilímaussaq complex. Geological Museum, University of Copenhagen, Øster Voldgade 5–7, DK-1350 Copenhagen K, Denmark. E-mail: [email protected] Keywords: agpaite, Ilímaussaq, mineral inventory, minerals type locality The agpaitic complexes Ilímaussaq (South Greenland), world. Most of the minerals for which Ilímaussaq is Khibina and Lovozero (Kola Peninsula, Russia), and the type locality have later been found in other com- Mont Saint-Hilaire (Quebec, Canada) are among the plexes of agpaitic rocks. areas in the world which are richest in rare minerals. Two minerals were described simultaneously from About 700 minerals have been found in these com- Ilímaussaq and the Kola Peninsula, tugtupite and vi- plexes which hold the type localities for about 200 tusite. Tugtupite was published from the Lovozero minerals. complex by Semenov & Bykova (1960) under the name About 220 minerals have been found in the Ilímaus- beryllosodalite and from Ilímaussaq by Sørensen (1960) saq complex of which 27 have their type localities under the preliminary name beryllium sodalite which within the complex. In comparison Khibina and Lov- was changed to tugtupite in later publications (Søren- ozero hold the type localities for 127 minerals (Pekov sen 1962, 1963). -
Combined Single-Crystal X-Ray and Neutron Powder Diffraction Structure
American Mineralogist, Volume 95, pages 519–526, 2010 Combined single-crystal X-ray and neutron powder diffraction structure analysis exemplified through full structure determinations of framework and layer beryllate minerals JENNIFER A. ARMSTRONG ,1 HENRIK FRIIS,2 ALEX A NDR A LIEB ,1,* ADRI A N A. FINC H ,2 A ND MA RK T. WELLER 1,† 1School of Chemistry, University of Southampton, Highfield, Southampton, Hampshire SO17 1BJ, U.K. 2School of Geography and Geosciences, Irvine Building, University of St. Andrews, North Street, St. Andrews, Fife KY16 9AL, U.K. ABSTR A CT Structural analysis, using neutron powder diffraction (NPD) data on small quantities (<300 mg) and in combination with single-crystal X-ray diffraction (SXD) data, has been employed to determine accurately the position of hydrogen and other light atoms in three rare beryllate minerals, namely bavenite, leifite/IMA 2007-017, and nabesite. For bavenite, leifite/IMA 2007-017, and nabesite, sig- nificant differences in the distribution of H, as compared to the literature using SXD analysis alone, have been found. The benefits of NPD data, even with small quantities of H-containing materials, and, more generally, in applying a combined SXD-NPD method to structure analysis of minerals are discussed, with reference to the quality of the crystallographic information obtained. Keywords: Hydrogen, beryllium, minerals, powder neutron diffraction INTRODUCTION lower cation charge, Be2+ vs. Si4+. Thus, a bridging or terminal Information on crystal structure of minerals, including the O forming part of a Beϕ4 tetrahedron is under-bonded compared localization of light atoms such as H and Be, is of considerable to the equivalent Siφ4 unit leading to the prevalence of Be-OH importance because it allows a better understanding of the min- and Be-F in beryllate minerals (Hawthorne and Huminicki eral behavior under natural conditions. -
GEUS No 190.Pmd
G E O L O G Y O F G R E E N L A N D S U R V E Y B U L L E T I N 1 9 0 · 2 0 0 1 The Ilímaussaq alkaline complex, South Greenland: status of mineralogical research with new results Edited by Henning Sørensen Contributions to the mineralogy of Ilímaussaq, no. 100 Anniversary volume with list of minerals GEOLOGICAL SURVEY OF DENMARK AND GREENLAND MINISTRY OF THE ENVIRONMENT 1 Geology of Greenland Survey Bulletin 190 Keywords Agpaite, alkaline, crystallography, Gardar province, geochemistry, hyper-agpaite, Ilímaussaq, mineralogy, nepheline syenite, peral- kaline, Mesoproterozoic, rare-element minerals, South Greenland. Cover Igneous layering in kakortokites in the southern part of the Ilímaussaq alkaline complex, South Greenland. The central part of the photograph shows the uppermost part of the layered kakortokite series and the overlying transitional kakortokites and aegirine lujavrite on Laksefjeld (680 m), the dark mountain in the left middle ground of the photograph. The cliff facing the lake in the right middle ground shows the kakortokite layers + 4 to + 9. The kakortokite in the cliff on the opposite side of the lake is rich in xenoliths of roof rocks of augite syenite and naujaite making the layering less distinct. On the skyline is the mountain ridge Killavaat (‘the comb’), the highest peak 1216 m, which is made up of Proterozoic granite which was baked and hardened at the contact to the intrusive complex. The lake (987 m) in the foreground is intensely blue and clear because it is practically devoid of life. -
Synthesis and Molecular Transport Studies in Zeolites and Nanoporous Membranes
University of Massachusetts Amherst ScholarWorks@UMass Amherst Doctoral Dissertations Dissertations and Theses March 2019 Synthesis and Molecular Transport Studies in Zeolites and Nanoporous Membranes Vivek Vattipalli University of Massachusetts Amherst Follow this and additional works at: https://scholarworks.umass.edu/dissertations_2 Part of the Catalysis and Reaction Engineering Commons, Inorganic Chemistry Commons, Materials Chemistry Commons, Membrane Science Commons, Other Materials Science and Engineering Commons, and the Transport Phenomena Commons Recommended Citation Vattipalli, Vivek, "Synthesis and Molecular Transport Studies in Zeolites and Nanoporous Membranes" (2019). Doctoral Dissertations. 1525. https://doi.org/10.7275/13141751 https://scholarworks.umass.edu/dissertations_2/1525 This Open Access Dissertation is brought to you for free and open access by the Dissertations and Theses at ScholarWorks@UMass Amherst. It has been accepted for inclusion in Doctoral Dissertations by an authorized administrator of ScholarWorks@UMass Amherst. For more information, please contact [email protected]. SYNTHESIS AND MOLECULAR TRANSPORT STUDIES IN ZEOLITES AND NANOPOROUS MEMBRANES A Dissertation Presented by VIVEK VATTIPALLI Submitted to the Graduate School of the University of Massachusetts Amherst in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY February 2019 Department of Chemical Engineering i © Copyright by Vivek Vattipalli 2019 All Rights Reserved ii SYNTHESIS AND MOLECULAR TRANSPORT -
NABESITE, Na2besi4o10•4H2O, a NEW MINERAL SPECIES
173 The Canadian Mineralogist Vol. 40, pp. 173-181 (2002) NABESITE, Na2BeSi4O10•4H2O, A NEW MINERAL SPECIES FROM THE ILÍMAUSSAQ ALKALINE COMPLEX, SOUTH GREENLAND* OLE V. PETERSEN§ Geologisk Museum, Øster Voldgade 5–7, DK-1350 København K, Denmark GERALD GIESTER Institut für Mineralogie und Kristallographie, Geozentrum, Universität Wien, Althanstr. 14, A-1090 Wien, Austria FRANZ BRANDSTÄTTER AND GERHARD NIEDERMAYR Naturhistorisches Museum Wien, Mineralogisch-Petrographische Abteilung, Postfach 417, A-1014 Wien, Austria ABSTRACT Nabesite is found in complex tugtupite-bearing albitites on the Kvanefjeld Plateau, in the northwesternmost part of the Ilímaussaq alkaline complex, South Greenland. It occurs in cavities, covered with albite crystals, in association with gmelinite, neptunite, analcime, gonnardite, lovdarite, trona(?) and opal(?). Nabesite forms aggregates of thin platy crystals, in parallel or subparallel orientation, the individual crystals show the pinacoids {100}, {010}, {001}, and {111} and {1¯11}, both sphenoids, and range in size from 0.05 0.5 0.5 to 0.2 5 5 mm. The mineral is colorless and transparent, it has a white streak, and the luster is vitreous. The Mohs hardness is 5–6, it is brittle and shows good cleavage on {110} and {001}, and the fracture is uneven. Nabesite is biaxial negative with n␣ = 1.499(1), n = 1.507(1) and n␥ = 1.511(1), 2V␣ (measured) 65(5)°, 2V␣ (calculated) 3 3 70°, and has X = a, Y = c and Z = b. Dmeas = 2.16(2) g/cm , Dcalc = 2.21 and 2.22 g/cm for V derived from powder and single- crystal diffraction data, respectively. Data from EMP, SEM–EDS and results of the refinement of the crystal structure gave: Na2O 13.8, K2O 0.34, BeO 6.26, CaO 0.13, SiO2 62.4, H2O 18.05, total 100.98 wt%. -
( 12 ) United States Patent
US010150904B1 (12 ) United States Patent ( 10 ) Patent No. : US 10 , 150, 904 B1 Rahman et al. ( 45 ) Date of Patent : Dec . 11 , 2018 (54 ) NANO ZEOLITE CEMENT ADDITIVE AND ( 56 ) References Cited METHODS OF USE U . S . PATENT DOCUMENTS (71 ) Applicant : King Fahd University of Petroleum 6 , 989 ,057 B2 1 / 2006 Getzlaf et al. and Minerals , Dhahran (SA ) 8 , 940 ,670 B2 1 / 2015 Patil et al . 2004 / 0112600 A1 * 6 /2004 Luke . .. C04B 14 /047 ( 72 ) Inventors : Muhammad Kalimur Rahman , 166 /295 Dhahran (SA ) ; Mirza Talha Baig , 2007/ 0029088 A1* 2 / 2007 Di Lullo Arias .. .. C04B 14 / 047 Dhahran (SA ) ; Abdulaziz Al- Majed , 166 /292 2007 /0056732 A1 3 /2007 Roddy et al. Dhahran (SA ) 2014 /0332217 AL 11 /2014 Rahman et al . ( 73 ) Assignee : King Fahd University of Petroleum 2017/ 0240469 AL 8 / 2017 Rahman et al. and Minerals , Dhahran (SA ) OTHER PUBLICATIONS ( * ) Notice : Subject to any disclaimer, the term of this patent is extended or adjusted under 35 Mirza Talha Baig , et al. , “ Application of Nanotechnology in Oil U . S . C . 154 ( b ) by 0 days . Well Cementing ” , Society of Petroleum Engineers , SPE Kuwait Oil & Gas Show and Conference , Oct . 1 - 18 , Kuwait City , Kuwait , 2017 , ( 21 ) Appl. No .: 15 / 941, 350 pp . 1 - 3 . Hossein Mola - Abasi, et al ., “ Effect of Natural Zeolite and Cement Additive on the Strength of Sand ” , Geotechnical and Geological ( 22 ) Filed : Mar. 30 , 2018 Engineering, vol . 34 , Issue 5 , Oct . 2016 , pp . 1539 -1551 . (51 ) Int . CI. (Continued ) CO9K 8 / 46 ( 2006 .01 ) CO9K 8 / 467 ( 2006 .01 ) Primary Examiner — Catherine Loikith C04B 28 /02 ( 2006 .01 ) Assistant Examiner — Ashish K Varma C04B 28 /04 ( 2006 .01 ) ( 74 ) Attorney, Agent, or Firm — Oblon , McClelland , C04B 22 /06 ( 2006 . -
Phyllosilicate from the Wessels Mine, Kalahari Manganese Field, South Africa
Eur. J. Mineral. 2016, 28, 495–505 Published online 5 January 2016 Cairncrossite, a new Ca-Sr (-Na) phyllosilicate from the Wessels Mine, Kalahari Manganese Field, South Africa 1, 1 1 1 2 GERALD GIESTER *,CHRISTIAN L. LENGAUER ,HELMUT PRISTACZ ,BRANKO RIECK ,DAN TOPA and 3 KARL-LUDWIG VON BEZING 1 Institut fu¨r Mineralogie und Kristallographie, Universita¨t Wien, Althanstr. 14, 1090 Wien, Austria *Corresponding author, e-mail: [email protected] 2 Zentrale Forschungslaboratorien, Naturhistorisches Museum, Burgring 7, 1010 Wien, Austria 3 Wolseley Street 19, Kimberley 8301, South Africa Abstract: Cairncrossite is a new phyllosilicate species found in manganese ore on dumps of the Wessels Mine, Kalahari Manganese Field, South Africa. Associated minerals are richterite, sugilite, lizardite and fibrous pectolite. It occurs as radiating platy micaceous aggregates of up to 1 cm in size. Cairncrossite is colourless, appearing white, and the crystals are translucent to transparent with a white streak and vitreous to pearly lustre. The crystals are sectile before brittle fracture, with a Mohs hardness of 3. A perfect cleavage parallel À3 (001) is observed. The calculated density is 2.486 g cm . The mineral is biaxial positive with na ¼ 1.518(2), nb ¼ 1.522(2), ng ¼ 1.546(2), 2Vobs ¼ 33.9(6) (2Vcalc ¼ 44.97 ) at 589.3 nm and 24 C. The orientation of the indicatrix is Z ^ c* ¼ 10 . The dispersion is weak (r , v) and no pleochroism is observed. An intense light-blue fluorescence is emitted under shortwave UV radiation. Cairncrossite is triclinic, space group P1, a ¼ 9.6265(5), b ¼ 9.6391(5), c ¼ 15.6534(10) A˚ , a ¼ 100.89(1), b ¼ 91.27(1), g ¼ 119.73(1), V ¼ 1227.08(13) A˚ 3, Z ¼ 1. -
Determination of the H2O Content in Minerals, Especially Zeolites, from Their Refractive Indices Based on Mean Electronic Polarizabilities of Cations
Eur. J. Mineral., 32, 27–40, 2020 https://doi.org/10.5194/ejm-32-27-2020 © Author(s) 2020. This work is distributed under the Creative Commons Attribution 4.0 License. Determination of the H2O content in minerals, especially zeolites, from their refractive indices based on mean electronic polarizabilities of cations Reinhard X. Fischer1, Manfred Burianek1, and Robert D. Shannon2 1FB 5 Geowissenschaften, Universität Bremen, Klagenfurter Str. 2, 28359 Bremen, Germany 2Geological Sciences/CIRES, University of Colorado, Boulder, Colorado 80309, USA Correspondence: Reinhard X. Fischer (rfi[email protected]) Received: 10 September 2019 – Revised: 14 October 2019 – Accepted: 28 October 2019 – Published: 15 January 2020 Abstract. It is shown here that the H2O content of hydrous minerals can be determined from their mean re- fractive indices with high accuracy. This is especially important when only small single crystals are avail- able. Such small crystals are generally not suitable for thermal analyses or for other reliable methods of measuring the amount of H2O. In order to determine the contribution of the H2O molecules to the opti- cal properties, the total electronic polarizability is calculated from the anhydrous part of the chemical com- position using the additivity rule for individual electronic polarizabilities of cations and anions. This an- hydrous contribution is then compared with the total observed electronic polarizability calculated from the mean refractive index of the hydrous compound using the Anderson–Eggleton relationship. The difference be- tween the two values represents the contribution of H2O. The amount can be derived by solving the equation 0 N 1 − j × C 1:2 1:2 .nj nW / D P C P o × Vm C × αcalc niαicat @αj 10 A nw αW for the number nw of H2O molecules per for- i j o mula unit (pfu), with the electronic polarizabilities αcat for cations, the values N and α describing the anion 3 polarizabilities, the number n of cations and anions, and the molar volume Vm, using a value of αW D 1:62 Å for the electronic polarizability of H2O. -
Lead-Tellurium Oxysalts from Otto Mountain Near Baker, California: III
American Mineralogist, Volume 95, pages 1548–1553, 2010 Lead-tellurium oxysalts from Otto Mountain near Baker, California: III. Thorneite, 6+ Pb6(Te2 O10)(CO3)Cl2(H2O), the first mineral with edge-sharing octahedral tellurate dimers ANTHONY R. KA MPF ,1,* ROBE R T M. HOUSLEY,2 A ND JOSEPH MAR TY 3 1Mineral Sciences Department, Natural History Museum of Los Angeles County, 900 Exposition Blvd., Los Angeles, California 90007, U.S.A. 2Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California 91125, U.S.A. 33457 E. Silver Oak Road, Salt Lake City, Utah 84108, U.S.A. ABST RA CT 6+ Thorneite, Pb6(Te2 O10)(CO3)Cl2(H2O), is a new tellurate from Otto Mountain near Baker, Califor- nia, named in honor of Brent Thorne. The new mineral occurs on fracture surfaces and in small vugs in brecciated quartz veins. Thorneite is directly associated with acanthite, cerussite, gold, hessite, iodargyrite, khinite, wulfenite, and three other new tellurates: housleyite, markcooperite, and ottoite. Various other secondary minerals occur in the veins, including three other new secondary tellurium minerals: paratimroseite, telluroperite, and timroseite. Thorneite is monoclinic, space group C2/c, a = 21.305(1), b = 11.059(1), c = 7.564(1) Å, β = 101.112(4)°, V = 1748.8(4) Å3, and Z = 4. Crystals are prismatic to bladed with elongation and striations parallel to c and typically occur in parallel and random aggregates. It is yellow and transparent, with pale yellow streak and adamantine luster. Mohs hardness is estimated at 2. The mineral is brittle, with an irregular to splintery fracture and good {100} cleavage. -
Bluebellite and Mojaveite, Two New Minerals from the Central Mojave Desert, California, USA
Mineralogical Magazine, October 2014, Vol. 78(5), pp. 1325–1340 Bluebellite and mojaveite, two new minerals from the central Mojave Desert, California, USA 1, 2 3 4 4 5 S. J. MILLS *, A. R. KAMPF ,A.G.CHRISTY ,R.M.HOUSLEY ,G.R.ROSSMAN ,R.E.REYNOLDS AND 6 J. MARTY 1 Geosciences, Museum Victoria, GPO Box 666, Melbourne 3001, Victoria, Australia 2 Mineral Sciences Department, Natural History Museum of Los Angeles County, 900 Exposition Boulevard, Los Angeles, CA 90007, USA 3 Centre for Advanced Microscopy, Australian National University, Canberra, ACT 0200, Australia 4 Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA 91125, USA 5 220 South Buena Vista Street, Redlands, CA 92373, USA 6 5199 E. Silver Oak Road, Salt Lake City, UT 84108, USA [Received 6 March 2014; Accepted 5 May 2014; Associate Editor: G. D. Gatta] ABSTRACT 5+ 6+ Bluebellite, Cu6[I O3(OH)3](OH)7Cl and mojaveite, Cu6[Te O4(OH)2](OH)7Cl, are new secondary copper minerals from the Mojave Desert. The type locality for bluebellite is the D shaft, Blue Bell claims, near Baker, San Bernardino County, California, while cotype localities for mojaveite are the E pit at Blue Bell claims and also the Bird Nest drift, Otto Mountain, also near Baker. The two minerals are very similar in their properties. Bluebellite is associated particularly with murdochite, but also with calcite, fluorite, hemimorphite and rarely dioptase in a highly siliceous hornfels. It forms bright bluish- green plates or flakes up to ~20 mm 620 mm 65 mm in size that are usually curved.