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1 Abietic Acid R Abrasive Silica for Polishing DR Acenaphthene M (LC
1 abietic acid R abrasive silica for polishing DR acenaphthene M (LC) acenaphthene quinone R acenaphthylene R acetal (see 1,1-diethoxyethane) acetaldehyde M (FC) acetaldehyde-d (CH3CDO) R acetaldehyde dimethyl acetal CH acetaldoxime R acetamide M (LC) acetamidinium chloride R acetamidoacrylic acid 2- NB acetamidobenzaldehyde p- R acetamidobenzenesulfonyl chloride 4- R acetamidodeoxythioglucopyranose triacetate 2- -2- -1- -β-D- 3,4,6- AB acetamidomethylthiazole 2- -4- PB acetanilide M (LC) acetazolamide R acetdimethylamide see dimethylacetamide, N,N- acethydrazide R acetic acid M (solv) acetic anhydride M (FC) acetmethylamide see methylacetamide, N- acetoacetamide R acetoacetanilide R acetoacetic acid, lithium salt R acetobromoglucose -α-D- NB acetohydroxamic acid R acetoin R acetol (hydroxyacetone) R acetonaphthalide (α)R acetone M (solv) acetone ,A.R. M (solv) acetone-d6 RM acetone cyanohydrin R acetonedicarboxylic acid ,dimethyl ester R acetonedicarboxylic acid -1,3- R acetone dimethyl acetal see dimethoxypropane 2,2- acetonitrile M (solv) acetonitrile-d3 RM acetonylacetone see hexanedione 2,5- acetonylbenzylhydroxycoumarin (3-(α- -4- R acetophenone M (LC) acetophenone oxime R acetophenone trimethylsilyl enol ether see phenyltrimethylsilyl... acetoxyacetone (oxopropyl acetate 2-) R acetoxybenzoic acid 4- DS acetoxynaphthoic acid 6- -2- R 2 acetylacetaldehyde dimethylacetal R acetylacetone (pentanedione -2,4-) M (C) acetylbenzonitrile p- R acetylbiphenyl 4- see phenylacetophenone, p- acetyl bromide M (FC) acetylbromothiophene 2- -5- -
Tungstovanadate Heteropoly Complexes. 11. Products of Acidification of V2w&Lg4
TUNGSTOVANADATEHETEROPOLY COMPLEXES Inorganic Chemistry, Vol. 10, No. 12, 1971 2745 Then, assuming that the difference is also reflected in line widths were somewhat broader than those of the Tze,much broader epr lines are expected for the mono- VO(H20)42+spectrum. That observation is compatible chloro species, which would be difficult to detect in the with a decreased re relative to that of the aquo complex, presence of the sharper spectrum of VO(H20)2C12. but a much more detailed investigation of the relaxa- The liquid solution epr spectra for a number of tion processes would be necessary for quantitative HC1 concentrations were also observed in this labora- comparison. tory. The intensity of the spectrum attributed to VO (H~0)4~+appeared to follow qualitatively the rela- Acknowledgments.-We are indebted to Dr. W. tive concentrations indicated in Tables I1 and I11 and Burton Lewis and others for helpful comments during Figure 4. However, no attempt was made to do an discussions of the work reported here. We also wish absolute spin count. In 12 M HC1 solution the (g) to thank Dr. B. B. McInteer and Mr. R. M. Potter of and (A) values obtained corresponded well with the Los Alamos Scientific Laboratory for supplying those reported by Kon and Sharpless and the observed the enriched "'0. CONTRIBUTIONFROM THE DEPARTMENTOF CHEMISTRY, GEORGETOWNUNIVERSITY, WASHINGTON, D. C. 20007 Tungstovanadate Heteropoly Complexes. 11. Products of Acidification of v2w&lg4- BY C. M. FLY", JR., AND M. T. POPE* Receiz'ed April 30, 1971 Acidification of solutions of VzW40104- is an efficient means of preparing the red complex V~WQO~O~-,isolated as K, "4, Na, N(CH3)4, C(NHZ)~,and C~H~(NH~)Zsalts. -
Tungsten-Based Nanocomposites by Chemical Methods
Tungsten-Based Nanocomposites by Chemical Methods Sverker Wahlberg Doctoral Thesis in Materials Chemistry Stockholm 2014 KTH Royal Institute of Technology SE-100 44 Stockholm, Sweden TRITA-ICT/MAP AVH Report 2014:20 KTH School of Information and ISSN 1653-7610 Communication Technology ISRN KTH/ICT-MAP/AVH-2014:20-SE SE-164 40, Kista, Sweden ISBN 978-91-7595-368-7 Akademisk avhandling som med tillstånd av KTH i Stockholm framlägges till offentlig granskning för avläggande av teknisk doktorsexamen torsdagen den 11 december kl 10.00 i sal 205, Electrum, KTH, Isafjordsgatan 22, Kista. © Sverker Wahlberg, 2014 Universitetsservice US-AB, Stockholm 2014 2 Abstract Tungsten based-materials find use in many different fields of engineering, particularly in applications where good temperature and/or erosion resistance is important. Nanostructuring of tungsten composites is expected to dramatically improve the materials’ properties and enhancing the performance in present applications but also enabling totally new possibilities. Nanostructured WC-Co materials have been the focus of researchers and engineers for over two decades. New fabrication methods have been developed. But, the fabrication of true nanograined WC-Co composites is still a challenge. Nanostructured tungsten-based materials for applications as plasma facing materials in fusion reactors have attracted a growing interest. This Thesis summarizes work on the development of chemical methods for the fabrication of two different types of nanostructured tungsten-based materials; WC-Co composites mainly for cutting tools applications and W-ODS materials with yttria particles, intended as plasma facing materials in fusion reactors. The approach has been to prepare powders in two steps: a) synthesis of uniform powder precursors containing ions of tungsten and cobalt or yttrium by precipitation from aqueous solutions and b) processing of the precursors into WC- or W-based nano-composite powders. -
Sodium Sulfate - Wikipedia, the Free Encyclopedia Page 1 of 7
Sodium sulfate - Wikipedia, the free encyclopedia Page 1 of 7 Sodium sulfate From Wikipedia, the free encyclopedia Sodium sulfate is the sodium salt of Sodium sulfate sulfuric acid. When anhydrous, it is a white crystalline solid of formula Na2SO4 known as the mineral thenardite; the decahydrate Na2SO4·10H2O has been known as Glauber's salt or, historically, sal mirabilis since the 17th century. Another Other names solid is the heptahydrate, which transforms Thenardite (mineral) to mirabilite when cooled. With an annual Glauber's salt (decahydrate) production of 6 million tonnes, it is a major Sal mirabilis (decahydrate) commodity chemical and one of the most Mirabilite (decahydrate) damaging salts in structure conservation: when it grows in the pores of stones it can Identifiers achieve high levels of pressure, causing CAS number 7757-82-6 , structures to crack. 7727-73-3 (decahydrate) Sodium sulfate is mainly used for the PubChem 24436 manufacture of detergents and in the Kraft ChemSpider 22844 process of paper pulping. About two-thirds UNII 36KCS0R750 of the world's production is from mirabilite, the natural mineral form of the decahydrate, RTECS number WE1650000 and the remainder from by-products of Jmol-3D images Image 1 chemical processes such as hydrochloric (http://chemapps.stolaf.edu/jmol/jmol.php? acid production. model=%5BNa%2B%5D.%5BNa%2B% 5D.%5BO-%5DS%28%5BO-%5D%29% 28%3DO%29%3DO) Contents SMILES InChI ■ 1History ■ 2 Physical and chemical properties Properties ■ 3 Production Molecular Na2SO4 ■ 3.1 Natural sources formula -
In Accurately Assessing the Development Of
28 . 5 . 84 Official Journal of the European Communities No L 141 / 1 I (Acts whose publication is obligatory) COUNCIL REGULATION (EEC) No 1410/84 of 15 May 1984 temporarily suspending the autonomous Common Customs Tariff duties on a number of industrial products THE COUNCIL OF THE EUROPEAN taken only temporarily with their term of validity COMMUNITIES, fixed to coincide with the interests of Community production , Having regard to the Treaty establishing the Euro pean Economic Community, and in particular HAS ADOPTED THIS REGULATION : Article 28 thereof, Having regard to the draft Regulation submitted by Article 1 the Commission, The autonomous Common Customs Tariff duties Whereas production of the products referred to in for the products listed in the tables annexed to this this Regulation is at present inadequate or non Regulation shall be suspended as the level indicated existent within the Community and producers are in respect of each of them . thus unable to meet the needs of user industries in the Community ; These suspensions shall be valid : Whereas it is in the Community's interest to sus — from 1 July to 31 December 1984 for the prod pend the autonomous Common Customs Tariff ucts listed in Table I , duties only partially in certain cases , due particu — from 1 July 1984 to 30 June 1985 for the prod larly to the existence of Community production , and ucts listed in Table II . to suspend them completely in other cases ; Whereas , taking account of the difficulties involved Article 2 in accurately assessing the development of the economic situation in the sectors concerned in the This Regulation shall enter into force on 1 July near future, these suspension measures should be 1984 . -
Chemical Names and CAS Numbers Final
Chemical Abstract Chemical Formula Chemical Name Service (CAS) Number C3H8O 1‐propanol C4H7BrO2 2‐bromobutyric acid 80‐58‐0 GeH3COOH 2‐germaacetic acid C4H10 2‐methylpropane 75‐28‐5 C3H8O 2‐propanol 67‐63‐0 C6H10O3 4‐acetylbutyric acid 448671 C4H7BrO2 4‐bromobutyric acid 2623‐87‐2 CH3CHO acetaldehyde CH3CONH2 acetamide C8H9NO2 acetaminophen 103‐90‐2 − C2H3O2 acetate ion − CH3COO acetate ion C2H4O2 acetic acid 64‐19‐7 CH3COOH acetic acid (CH3)2CO acetone CH3COCl acetyl chloride C2H2 acetylene 74‐86‐2 HCCH acetylene C9H8O4 acetylsalicylic acid 50‐78‐2 H2C(CH)CN acrylonitrile C3H7NO2 Ala C3H7NO2 alanine 56‐41‐7 NaAlSi3O3 albite AlSb aluminium antimonide 25152‐52‐7 AlAs aluminium arsenide 22831‐42‐1 AlBO2 aluminium borate 61279‐70‐7 AlBO aluminium boron oxide 12041‐48‐4 AlBr3 aluminium bromide 7727‐15‐3 AlBr3•6H2O aluminium bromide hexahydrate 2149397 AlCl4Cs aluminium caesium tetrachloride 17992‐03‐9 AlCl3 aluminium chloride (anhydrous) 7446‐70‐0 AlCl3•6H2O aluminium chloride hexahydrate 7784‐13‐6 AlClO aluminium chloride oxide 13596‐11‐7 AlB2 aluminium diboride 12041‐50‐8 AlF2 aluminium difluoride 13569‐23‐8 AlF2O aluminium difluoride oxide 38344‐66‐0 AlB12 aluminium dodecaboride 12041‐54‐2 Al2F6 aluminium fluoride 17949‐86‐9 AlF3 aluminium fluoride 7784‐18‐1 Al(CHO2)3 aluminium formate 7360‐53‐4 1 of 75 Chemical Abstract Chemical Formula Chemical Name Service (CAS) Number Al(OH)3 aluminium hydroxide 21645‐51‐2 Al2I6 aluminium iodide 18898‐35‐6 AlI3 aluminium iodide 7784‐23‐8 AlBr aluminium monobromide 22359‐97‐3 AlCl aluminium monochloride -
MY SIXTY YEARS in MINERALOGY Ulyanov, Whose Name Kazan State University Bore from 1925 to 2009
3. The main building of Kazan Federal University 3 (right), opposite a monument to student Vladimir I. Speaking in the First Person MY SIXTY YEARS IN MINERALOGY Ulyanov, whose name Kazan State University bore from 1925 to 2009. Monument by V.E. Tsigal and V.V. Kalinin, opened on the 21 st November, 1954, during the celebration of the university’s 150 th an - Georgiy A. Yurgenson niversary (bronze, grey polished granite). Institute of Natural Resources, Ecology and Cryology, Siberian Branch of RAS, Chita , [email protected] 1 t all started in 1946 with the discovery of two fascinating books at a school library in Tuymazy, Bashkortostan. One of them was titled “Traces on a IRock” . Its author Leonid Saveliev wrote an engaging account of the po - tential of studying and interpreting rocks. The other book taught precisely that. geological museum. In October after several geological lectures and tutorials, we It was a course book on mineralogy and geology by M.P. Potemkin and boarded a retro ferryboat “Volgar” to reach the coveted right bank of the Volga V.V. Malinko aimed at final-year school students, published in 1939. Much of it River. uncovered a whole new perspective onto the world beneath our feet. A simple We were mesmerised by the incredible beauty of the sky-blue celestine crystals rock had become a source of knowledge about the origins of the Earth, the for - from the Permian dolomites, which formed Volga’s steep embankments in the mation of its continents and oceans, the rise of mountains, the activity of volca - Uslon area outside Kazan and sparkled against the fine black velvety layers of noes, the origin of life itself, and, most importantly, these books talked about the chalcedony in its cavities; by quartz shimmering with the multitude of its tiny fundamental properties of minerals and crystals and the beauty of symmetry. -
Ammonium Paratungstate and Tungstic Acid from the People's Republic of China, Provided for in Items
AMMONIUM PARATUNGSTATEAND. · TUNG.STIC ACID F·ROM THE . PEOPL~S ·REPUBLIC· OF CHINA Report to the President on Investigation No. TA-408-11 Under Section 406 of the Trade Act of 1974 USITC PUBLICATION ·1982 JUNE 1987 United States International Trade Commission I Washington, DC 20436 UNITED STATES INTERNATIONAL TRADE COMMISSION COMMISSIONERS Susan Liebeler, Chairman Anne E. Brunsdale, Vice Chairman Alfred E. Eckes Seeley G. Lodwick David B.. Rohr Staff Assigned Rebecca Woodings, Office of Investigations Jack Greenblatt, Office of Industries Elizabeth Henning, Office of Economics Chandrakant Mehta, Office of Investigations Edwin Madaj,· Office of the General Counsel Robert Carpenter, Supervisory Investigator· Address all communications to .. (:..,, - Kenneth R. Mason, Secretary to the Commission United States International Trade Commission Washington, DC 20436 i C 0 N T E N T S Determination-----7---~--------------------------------------------------- 1 Vtews of Commissioners Eckes, Lodwick, and Rohr-------------------------- 3 Views of Chairman Liebeler and Vice Chairman Brunsdale------------------- 23 Information obtained in the investigation: ,Introduction--------------------------------------------------------- A-1 Background- -------- -·- ------------------------------------------------- A-1 The products: Description and uses--------------------------------------------- A-2 .Manufacturing process-------------------------------------------- A-3 U.S. tariff treatment--------------------------------------------- A-7 U. S. producers--·- -
Structural Evolution of Ammonium Paratungstate During Thermal Decomposition
Structural Evolution of Ammonium Paratungstate During Thermal Decomposition vorgelegt von Diplom-Chemikerin Olga Kirilenko aus Weissrussland Fakultät II - Mathematik und Naturwissenschaften der Technischen Universität Berlin zur Erlangung des akademischen Grades Doktor der Naturwissenschaften - Dr. rer.nat. - genehmigte Dissertation Promotionsausschuss: Vorsitzender: Prof. Dr. P. Hildebrandt Berichter/Gutachter: Prof. Dr. M. Lerch Berichter/Gutachter: Priv.-Doz. Dr. T. Ressler Tag der wissenschaftlichen Aussprache: 4. Februar 2005 Berlin 2005 D 83 Table of contents Zusammenfassung…………………………………………………………... 4 Abstract……………………………………………………………………… 5 Danksagung…………………………………………………………………. 6 1 Introduction…………………………………………………………………. 7 1.1 Motivation and strategy…………………………………………………….. 7 1.2 Chemistry of tungsten………………………………………………………. 11 1.2.1 Tungsten…………………………………………………………………….. 11 1.2.2 Tungsten oxide……………………………………………………………… 11 1.2.3 Tungsten bronzes…………………………………………………………… 13 1.2.4 Ammonium paratungstate (APT)………………………………………….. 15 1.2.5 Heteropolytungstate………………………………………………………… 16 1.3 The results of the study of APT decomposition from selected 17 publications…………………………………………………………………… 1.4 The investigation of WO3 with respect to its catalytic properties………... 18 2 Theoretical and Experimental Details……………………………………… 20 2.1 Introduction………………………………………………………………….. 20 2.2 X-ray Diffraction (XRD)…………………………………………………….. 20 2.2.1 Theory of XRD……………………………………………………………….. 20 2.2.2 XRD measurements………………………………………………………….. 21 2.2.3 Data evaluation………………………………………………………………. -
Spectra Library Index Ichem/SDBS Raman Library
Ichem / SDBS Raman スタンダードライブラリー 株式会社 エス・ティ・ジャパン S p e c t r a L i b r a r y I n d e x (Ver. 40) Ichem / SDBS Raman Library ライブラリー名:ラマンスタンダードライブラリー 商品番号:60001-40 株式会社 エス・ティ・ジャパン 〒103-0014 東京都中央区日本橋蛎殻町 1-14-10 Tel: 03-3666-2561 Fax:03-3666-2658 http://www.stjapan.co.jp 1 【販売代理店】(株)テクノサイエンス Tel:043-206-0155 Fax:043-206-0188 https://www.techno-lab-co.jp/ Ichem / SDBS Raman スタンダードライブラリー 株式会社 エス・ティ・ジャパン ((1,2-DIETHYLETHYLENE)BIS(P-PHENYLENE))DIACETATE ((2-(3-BENZYLSULFONYL-4-METHYLCYCLOHEXYL)PROPYL)SULFONYLMETHYL)BENZENE ((2,4,6-TRIOXOHEXAHYDRO-5-PYRIMIDINYL)IMINO)DIACETIC ACID ((2-CARBOXYETHYL)IMINO)DIACETIC ACID ((2-HYDROXYETHYL)IMINO)DIACETIC ACID ((2-NITROBENZYL)IMINO)DIACETIC ACID ((2-SULFOETHYL)IMINO)DIACETIC ACID ((3-(1-BROMO-1-METHYLETHYL)-7-OXO-1,3,5-CYCLOHEPTATRIEN-1-YL)OXY)DIFLUOROBORANE ((N-BENZYLOXYCARBONYL-L-ISOLEUCYL)-L-PROLYL-L-PHENYLALANYL)-N(OMEGA)-NITRO-L-ARGININE 4-NITROBENZYL ESTER (-)-2-AMINO-1-BUTANOL (-)-2-AMINO-6-MERCAPTOPURINE RIBOSIDE (-)-6,8-P-MENTHADIEN-2-OL (-)-DIACETYL-L-TARTARIC ACID (-)-DIBENZOYL-L-TARTARIC ACID (-)-DI-P-ANISOYL-L-TARTARIC ACID (-)-DI-P-TOLUOYL-L-TARTARIC ACID (-)-KAURENE (-)-MENTHOL (-)-MYRTENOL (-)-N,N,N',N'-TETRAMETHYL-D-TARTARDIAMIDE (-)-N,N'-DIBENZYL-D-TARTRAMIDE (+)-1,3,3-TRIMETHYLNORBORNANE-2-ONE (+)-2-(2,4,5,7-TETRANITRO-9-FLUORENYLIDENEAMINOOXY)PROPIONIC ACID (+)-2-AMINO-1-BUTANOL (+)-2-PINENE (+)-3,9-DIBROMOCAMPHOR (+)-3-CARENE (+)-5-BROMO-2'-DEOXYURIDINE (+)-AMMONIUM 3-BROMO-8-CAMPHORSULFONATE (+)-CAMPHOR (+)-CAMPHOR OXIME (+)-CAMPHORIC ACID (+)-CATECHIN (+)-DI-P-ANISOYL-D-TARTARIC -
Sampling and Analysis of Soluble Metal Compounds
NIOSH Manual of Analytical Methods (NMAM), 5th Edition Sampling and Analysis of Soluble Metal Compounds by Kevin Ashley, Ph.D., NIOSH and Richard Fairfax, CIH, OSHA [Much of this chapter was adapted from Fairfax and Blotzer 1994; and Ashley 2001.] 1 Introduction SM-2 2 Soluble and insoluble metal compounds SM-2 3 Health effects SM-4 4 Sampling considerations SM-5 5 Analytical considerations SM-5 6 ISO procedure for soluble metals and metalloids SM-7 7 Summary SM-10 8 References SM-11 9 Appendix - Solubilities of selected metals and metal compounds SM-14 DEPARTMENT OF HEALTH AND HUMAN SERVICES Centers for Disease Control and Prevention National Institute for Occupational Safety and Health Sampling and Analysis of Soluble Metal Compounds 1 Introduction Workplace exposure standards have been established for several soluble metals and metalloids to take into account the increased bioavailability of some metal compounds. Exposure standards for soluble compounds can be up to 500 times lower than the exposure standards for less soluble compounds for the same metal. However, there is often confusion among chemists, industrial hygienists, and laboratories over what is meant by “soluble” when the metal species, extraction fluid, or solubility conditions are not specified in the exposure standard nor in the supporting exposure standard documentation [Fairfax and Blotzer 1994]. In addition, the metals and metal compounds may interact chemically or physically with the sampling media or with each other [Ashley 2001]. Such complications can affect the stability and speciation of the metals and their compounds, and must be addressed in order to obtain meaningful results. -
Manuscript with Contribution from All the Other Coauthors
1 Interactions of organosulfates with water vapor under sub- and supersaturated 2 conditions 3 4 Chao Peng,1,2 Patricia N. Razafindrambinina,3 Kotiba A. Malek,4 Lanxiadi Chen,1,2,7 Weigang 5 Wang,5 Ru-Jin Huang,6 Yuqing Zhang,1,2 Xiang Ding,1,2 Maofa Ge,5 Xinming Wang,1,2 Akua A. 6 Asa-Awuku,3,4 and Mingjin Tang1,2,7,* 7 8 1 State Key Laboratory of Organic Geochemistry, Guangdong Key Laboratory of Environmental 9 Protection and Resources Utilization, and Guangdong-Hong Kong-Macao Joint Laboratory for 10 Environmental Pollution and Control, Guangzhou Institute of Geochemistry, Chinese Academy of 11 Sciences, Guangzhou 510640, China 12 2 CAS Center for Excellence in Deep Earth Science, Guangzhou 510640, China 13 3 Department of Chemistry and Biochemistry, College of Computer, Mathematical and Natural 14 Sciences, University of Maryland, College Park, MD 20742, USA 15 4 Department of Chemical and Biomolecular Engineering, A. James Clark School of Engineering, 16 University of Maryland, College Park, MD 20742, USA 17 5 State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Beijing National 18 Laboratory for Molecular Sciences, CAS Research/Education Center for Excellence in Molecular 19 Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China 20 6 Key Laboratory of Aerosol Chemistry and Physics, State Key Laboratory of Loess and 21 Quaternary Geology, Institute of Earth and Environment, Chinese Academy of Sciences, Xi'an 22 710061, China 1 23 7 University of Chinese Academy of Sciences, Beijing 100049, China 24 25 *Correspondence: Mingjin Tang ([email protected]) 26 27 2 28 Abstract 29 Organosulfates (OS) are important constituents of secondary organic aerosols, but their 30 hygroscopic properties and cloud condensation nucleation (CCN) activities have not been well 31 understood.