Exploring Light Emitting Processess
Total Page:16
File Type:pdf, Size:1020Kb
Load more
Recommended publications
-
Article Soot Photometer Using Supervised Machine Learning
Atmos. Meas. Tech., 12, 3885–3906, 2019 https://doi.org/10.5194/amt-12-3885-2019 © Author(s) 2019. This work is distributed under the Creative Commons Attribution 4.0 License. Classification of iron oxide aerosols by a single particle soot photometer using supervised machine learning Kara D. Lamb1,2 1Cooperative Institute for Research in Environmental Sciences, University of Colorado Boulder, Boulder, CO, USA 2NOAA Earth System Research Laboratory Chemical Sciences Division, Boulder, CO, USA Correspondence: Kara D. Lamb ([email protected]) Received: 15 March 2019 – Discussion started: 22 March 2019 Revised: 20 June 2019 – Accepted: 21 June 2019 – Published: 15 July 2019 Abstract. Single particle soot photometers (SP2) use laser- each class are compared with the true class for those particles induced incandescence to detect aerosols on a single particle to estimate generalization performance. While the specific basis. SP2s that have been modified to provide greater spec- class approach performed well for rBC and Fe3O4 (≥ 99 % tral contrast between their narrow and broad-band incandes- of these aerosols are correctly identified), its classification of cent detectors have previously been used to characterize both other aerosol types is significantly worse (only 47 %–66 % refractory black carbon (rBC) and light-absorbing metallic of other particles are correctly identified). Using the broader aerosols, including iron oxides (FeOx). However, single par- class approach, we find a classification accuracy of 99 % for ticles cannot be unambiguously identified from their incan- FeOx samples measured in the laboratory. The method al- descent peak height (a function of particle mass) and color lows for classification of FeOx as anthropogenic or dust-like ratio (a measure of blackbody temperature) alone. -
Chemiluminescence Western Blotting Technical Guide and Protocols
TECH TIP Chemiluminescent substrates Chemiluminescence western blotting technical guide and protocols Introduction Types and considerations of chemiluminescence Western blotting is a powerful and commonly used tool western blotting to identify and quantify a specific protein in a complex HRP is the most popular enzyme used in western mixture. As originally conceived by Towbin et al., the blotting and will be discussed throughout this document technique enables indirect detection of protein samples as our example. The most suitable western blotting immobilized on a nitrocellulose or polyvinylidene fluoride substrates for HRP are luminol-based, and they produce (PVDF) membrane. In a conventional western blot, a chemiluminescent signal. Chemiluminescence is a protein samples are first resolved by sodium dodecyl chemical reaction that produces energy released in the sulfate–polyacrylamide gel electrophoresis (SDS-PAGE) form of light. In the presence of HRP and a peroxide buffer, and then electrophoretically transferred to the membrane. luminol oxidizes and forms an excited-state product that Following a blocking step, the membrane is probed emits light as it decays to the ground state. Light emission with a primary antibody (polyclonal or monoclonal) occurs only during the enzyme–substrate reaction and, that was raised against the antigen in question. After a therefore, once the substrate in proximity to the enzyme is subsequent washing step, the membrane is incubated with exhausted, signal output ceases. In contrast, colorimetric a secondary antibody conjugated to an enzyme that is substrates, such as diaminobenzidine (DAB), produce reactive toward the primary antibody. An enzyme such as precipitate that remains visible on the membrane even alkaline phosphatase (AP) or horseradish peroxidase (HRP) after the reaction has terminated. -
Introduction 1
1 1 Introduction . ex arte calcinati, et illuminato aeri [ . properly calcinated, and illuminated seu solis radiis, seu fl ammae either by sunlight or fl ames, they conceive fulgoribus expositi, lucem inde sine light from themselves without heat; . ] calore concipiunt in sese; . Licetus, 1640 (about the Bologna stone) 1.1 What Is Luminescence? The word luminescence, which comes from the Latin (lumen = light) was fi rst introduced as luminescenz by the physicist and science historian Eilhardt Wiede- mann in 1888, to describe “ all those phenomena of light which are not solely conditioned by the rise in temperature,” as opposed to incandescence. Lumines- cence is often considered as cold light whereas incandescence is hot light. Luminescence is more precisely defi ned as follows: spontaneous emission of radia- tion from an electronically excited species or from a vibrationally excited species not in thermal equilibrium with its environment. 1) The various types of lumines- cence are classifi ed according to the mode of excitation (see Table 1.1 ). Luminescent compounds can be of very different kinds: • Organic compounds : aromatic hydrocarbons (naphthalene, anthracene, phenan- threne, pyrene, perylene, porphyrins, phtalocyanins, etc.) and derivatives, dyes (fl uorescein, rhodamines, coumarins, oxazines), polyenes, diphenylpolyenes, some amino acids (tryptophan, tyrosine, phenylalanine), etc. + 3 + 3 + • Inorganic compounds : uranyl ion (UO 2 ), lanthanide ions (e.g., Eu , Tb ), doped glasses (e.g., with Nd, Mn, Ce, Sn, Cu, Ag), crystals (ZnS, CdS, ZnSe, CdSe, 3 + GaS, GaP, Al 2 O3 /Cr (ruby)), semiconductor nanocrystals (e.g., CdSe), metal clusters, carbon nanotubes and some fullerenes, etc. 1) Braslavsky , S. et al . ( 2007 ) Glossary of terms used in photochemistry , Pure Appl. -
Transmission of Near-Resonant Light Through a Dense Slab of Cold Atoms
PHYSICAL REVIEW A 96, 053629 (2017) Transmission of near-resonant light through a dense slab of cold atoms L. Corman,* J. L. Ville, R. Saint-Jalm, M. Aidelsburger,† T. Bienaimé, S. Nascimbène, J. Dalibard, and J. Beugnon‡ Laboratoire Kastler Brossel, Collège de France, CNRS, ENS-PSL Research University, UPMC-Sorbonne Universités, 11 place Marcelin-Berthelot, 75005 Paris, France (Received 30 June 2017; revised manuscript received 4 October 2017; published 27 November 2017) The optical properties of randomly positioned, resonant scatterers is a fundamentally difficult problem to address across a wide range of densities and geometries. We investigate it experimentally using a dense cloud of rubidium atoms probed with near-resonant light. The atoms are confined in a slab geometry with a subwavelength thickness. We probe the optical response of the cloud as its density and hence the strength of the light-induced dipole-dipole interactions are increased. We also describe a theoretical study based on a coupled dipole simulation which is further complemented by a perturbative approach. This model reproduces qualitatively the experimental observation of a saturation of the optical depth, a broadening of the transition, and a blueshift of the resonance. DOI: 10.1103/PhysRevA.96.053629 I. INTRODUCTION than solid-state systems, strong attenuation of the transmission can be observed at resonance. Third, inhomogeneous Doppler The interaction of light with matter is a fundamental broadening can be made negligible using ultracold atomic problem which is relevant for simple systems, such as an atom clouds. Finally, the geometry and the density of the gases strongly coupled to photons [1–3], as well as for complex can be varied over a broad range. -
2. Making Fires Burn Or Go out 1: Introduction to the Fire Triangle
2. Making Fires Burn or Go Out 1: Introduction to the Fire Triangle Lesson Overview: In this activity, students describe and organize what they already know Subjects: Science, Mathematics, Writing, about fire so it fits into the conceptual model of Speaking and Listening, Health and the Fire Triangle. They examine the geometric Safety stability of a triangle and how that property Duration: one half-hour session applies to fire. Group size: Whole class. Students work in groups of 2-3. Lesson Goal: Increase students’ understanding of Setting: Indoors how fires burn and why they go out. Vocabulary: Fire Triangle, fuel, heat, ignition, oxygen, model Objectives: • Students can construct a triangle out of toothpicks and gumdrops, and can label its legs with the three components of the Fire Triangle. • Students can demonstrate that removing one side of the triangle makes it collapse. • Students can identify the component(s) of the Fire Triangle that are removed in various scenarios, and explain how this makes the fire go out. Standards: 1st 2nd 3rd 4th 5th CCSS Writing 2, 7, 8 2, 7, 8 2, 7, 10 2,7, 9, 10 2,7, 9, 10 Speaking/Listening 1, 2, 4, 6 1, 2, 4, 6 1, 2, 4, 6 1, 2, 4, 6 1, 2, 4, 6 1, 2, 3, 4, Language 1, 2, 4, 6 1, 2, 4, 6 6 1, 2, 3, 4, 6 1, 2, 3, 4, 6 MP.4, MP.4, MP.4, MP.4, Math MP.5 MP.5, MP.5 MP.5 MP.4, MP.5 Matter and Its PS1.A, NGSS Interactions PS1.B PS1.B From Molecules to Organisms: Structure/Processes LS1.C Engineering Design ETS1.B ETS1.B EEEGL Strand 1 A, B, C, E, F, G A, B, C, E, F, G Teacher Background: This activity explores the chemistry of combustion as described by a conceptual model called the Fire Triangle. -
Energy Efficiency Lighting Hearing Committee On
S. HRG. 110–195 ENERGY EFFICIENCY LIGHTING HEARING BEFORE THE COMMITTEE ON ENERGY AND NATURAL RESOURCES UNITED STATES SENATE ONE HUNDRED TENTH CONGRESS FIRST SESSION TO RECEIVE TESTIMONY ON THE STATUS OF ENERGY EFFICIENT LIGHT- ING TECHNOLOGIES AND ON S. 2017, THE ENERGY EFFICIENT LIGHT- ING FOR A BRIGHTER TOMORROW ACT SEPTEMBER 12, 2007 ( Printed for the use of the Committee on Energy and Natural Resources U.S. GOVERNMENT PRINTING OFFICE 39–385 PDF WASHINGTON : 2007 For sale by the Superintendent of Documents, U.S. Government Printing Office Internet: bookstore.gpo.gov Phone: toll free (866) 512–1800; DC area (202) 512–1800 Fax: (202) 512–2104 Mail: Stop IDCC, Washington, DC 20402–0001 VerDate 0ct 09 2002 11:58 Feb 20, 2008 Jkt 040443 PO 00000 Frm 00001 Fmt 5011 Sfmt 5011 G:\DOCS\39385.XXX SENERGY2 PsN: MONICA COMMITTEE ON ENERGY AND NATURAL RESOURCES JEFF BINGAMAN, New Mexico, Chairman DANIEL K. AKAKA, Hawaii PETE V. DOMENICI, New Mexico BYRON L. DORGAN, North Dakota LARRY E. CRAIG, Idaho RON WYDEN, Oregon LISA MURKOWSKI, Alaska TIM JOHNSON, South Dakota RICHARD BURR, North Carolina MARY L. LANDRIEU, Louisiana JIM DEMINT, South Carolina MARIA CANTWELL, Washington BOB CORKER, Tennessee KEN SALAZAR, Colorado JOHN BARRASSO, Wyoming ROBERT MENENDEZ, New Jersey JEFF SESSIONS, Alabama BLANCHE L. LINCOLN, Arkansas GORDON H. SMITH, Oregon BERNARD SANDERS, Vermont JIM BUNNING, Kentucky JON TESTER, Montana MEL MARTINEZ, Florida ROBERT M. SIMON, Staff Director SAM E. FOWLER, Chief Counsel FRANK MACCHIAROLA, Republican Staff Director JUDITH K. PENSABENE, Republican Chief Counsel (II) VerDate 0ct 09 2002 11:58 Feb 20, 2008 Jkt 040443 PO 00000 Frm 00002 Fmt 5904 Sfmt 5904 G:\DOCS\39385.XXX SENERGY2 PsN: MONICA C O N T E N T S STATEMENTS Page Bingaman, Hon. -
Chem 257 Lecture for Exp. 8, 2004 1. Exp. 7 Report: to Be Handed in This Week, Along With: • Relevant Notebook Pages • Vial
Chem 257 Lecture for Exp. 8, 2004 1. Exp. 7 Report: To be handed in this week, along with: • Relevant notebook pages • Vial containing triphenyl carbinol labeled with your notebook code, i.e., JST-I-38a 2. Exp. 8 Quiz. Be prepared for Quiz. 3. Required Reading. Lab Manual 8.1-10. 4. Relevant Material in Wade (5th): Ultraviolet spectroscopy 15-13 (p 666-672), 16-15 p(711-713), 18-5E (p 785-6). Friedel Crafts Alkylation: 17-11 (p 746-748) & p 980. Exp. 8. Fluorescence and Chemiluminescence. Purpose of the experiment: 1. Synthetic Organic Chemistry • Acquaint you with Friedel-Crafts acylation chemistry 2. Physical Organic Chemistry • Introduce you to photophysics • Acquaint you with chemiluminescent reactions 1 Photochemical Terms and Principles. Useful to consider a ground and excited state energy diagram for an organic molecule. Energy Level Diagram ISC S = singlet S T = triplet 1 A = Absorption F = Fluorescence T IC 1 P = Phosphorescence A ISC = Intersystem crossing E F P IC = Internal Conversion ISC Absorption of a photon Emmission of a photon Vibrational energy loss So Singlet State (S) • Spin paired. • Ground state usually a singlet (So). • First excited singlet state = S1 So S1 • Nth excited singlet state = S n ground excited Triplet State (T) • Spin unpaired. • Lowest triplet state is usually an excited state (T1). • Nth excited triplet state = Tn T T Exceptions: 0 1 • Oxygen is a ground state Ground excited triplet! (O2) 2 Selection rules. • Spin allowed transitions do not involve a change in spin state (Sn → Sm, Tn → Tm). • Thus ground singlet states are most easily excited to their first excited singlet states (So → S1). -
The Search for Exomoons and the Characterization of Exoplanet Atmospheres
Corso di Laurea Specialistica in Astronomia e Astrofisica The search for exomoons and the characterization of exoplanet atmospheres Relatore interno : dott. Alessandro Melchiorri Relatore esterno : dott.ssa Giovanna Tinetti Candidato: Giammarco Campanella Anno Accademico 2008/2009 The search for exomoons and the characterization of exoplanet atmospheres Giammarco Campanella Dipartimento di Fisica Università degli studi di Roma “La Sapienza” Associate at Department of Physics & Astronomy University College London A thesis submitted for the MSc Degree in Astronomy and Astrophysics September 4th, 2009 Università degli Studi di Roma ―La Sapienza‖ Abstract THE SEARCH FOR EXOMOONS AND THE CHARACTERIZATION OF EXOPLANET ATMOSPHERES by Giammarco Campanella Since planets were first discovered outside our own Solar System in 1992 (around a pulsar) and in 1995 (around a main sequence star), extrasolar planet studies have become one of the most dynamic research fields in astronomy. Our knowledge of extrasolar planets has grown exponentially, from our understanding of their formation and evolution to the development of different methods to detect them. Now that more than 370 exoplanets have been discovered, focus has moved from finding planets to characterise these alien worlds. As well as detecting the atmospheres of these exoplanets, part of the characterisation process undoubtedly involves the search for extrasolar moons. The structure of the thesis is as follows. In Chapter 1 an historical background is provided and some general aspects about ongoing situation in the research field of extrasolar planets are shown. In Chapter 2, various detection techniques such as radial velocity, microlensing, astrometry, circumstellar disks, pulsar timing and magnetospheric emission are described. A special emphasis is given to the transit photometry technique and to the two already operational transit space missions, CoRoT and Kepler. -
Measuring Peroxyoxalate Chemiluminescence Using a Spectrofluorophotometer No.A493
LAAN-A-RF-E003 Application Spectrophotometric Analysis News Measuring Peroxyoxalate Chemiluminescence Using a Spectrofluorophotometer No.A493 Chemiluminescence is a phenomenon where molecules n Fluorescent Dyes Used in Glow Sticks are excited by a chemical reaction and then emit light Commercially marketed glow sticks are shown in Fig. 2. energy as they return to ground state. Chemiluminescence The oxalate ester and fluorescent dye solution are placed based on using oxalate esters features high-emission in a sealed thin-walled glass container and the glass efficiency and long emission time and provides container is placed inside a polyethylene tube together illumination for long periods without any electricity. with hydrogen peroxide solution to which a catalyst is Consequently, it is used for recreational, fishing, and many added. Bending the polyethylene tube breaks the glass other applications where it is commonly called glow sticks. container, which causes both solutions to mix together The following describes the luminescent process of and emit light. peroxyoxalate chemiluminescence and gives an example Examples of the fluorescent dyes used in glow sticks are of using an RF-6000 spectrofluorophotometer to measure shown in Fig. 3. Polycyclic aromatic fluorescent dyes are the emission spectra of glow sticks. used, which emit different colors based on the wavelength of light emitted when the fluorescent dyes change from excited to ground state. n Luminescent Process of Peroxyoxalate Chemiluminescence Peroxyoxalate chemiluminescence is caused by a chemical O RO O reaction between an oxalate ester and hydrogen peroxide O C within a fluorescent dye solution. As shown in Fig. 1, the C C + H2O2 2ROH + O C oxalate ester is oxidized by hydrogen peroxide to produce O OR O ROH and 1,2-dioxetanedione. -
The Electric-Lamp Industry
Massachusetts Institute of Technology Studies of Innovation • GiSma,..=("EaEssormat THE MACMILLAN COMPANY THE ELECTRIC-LAMP INDUSTRY: NEW YORK a BOSTON a CHICAGO DALLAS • ATLANTA • SAN FRANCISCO MACMILLAN AND CO., LIMITED Technological Change and Economic LONDON a BOMBAY a CALCUTTA MADRAS a MELBOURNE Development from 1800 to 1947 THE MACMILLAN COMPANY OF CANADA, LIMITED TORONTO By ARTHUR A. BRIGHT, Jr. THE MACMILLAN COMPANY • NEW YORK 1949 FOREWORD THIS study of the economic development of the electric- lamp industry is the second volume in a series of studies on the economics of innovation, undertaken at the Massachusetts Insti- tute of Technology. The creative role played by science and technology in modern economic life is apparent to everyone. But we know relatively little about the human factors which condition the introduction of technological change into our environment. Are there barriers to innovation inherent in the increasing concentration of power in a few large concerns? Does the patent system, designed as an incentive to invention, act more often as a brake on new develop- ments? What has been the role of key personalities in creating change? Are there lessons to be drawn from the past on how the innovating process can be more effective, not only from the standpoint of achieving a higher standard of material being but from the point of view of smoother human relations? Certainly, material progress at any price is not a satisfactory goal. On the other hand, freedom for creative action in initiating and carrying out new developments is a basic human drive for many individu- als. I believe, personally, that a great society should strive toward a goal which will give to individuals and groups the maximum opportunities for creative expression; yet this means to me that the State must act to prevent the compulsive pressure of some particular group from overriding others to the destruction of human values. -
Biofluorescence
Things That Glow In The Dark Classroom Activities That Explore Spectra and Fluorescence Linda Shore [email protected] “Hot Topics: Research Revelations from the Biotech Revolution” Saturday, April 19, 2008 Caltech-Exploratorium Learning Lab (CELL) Workshop Special Guest: Dr. Rusty Lansford, Senior Scientist and Instructor, Caltech Contents Exploring Spectra – Using a spectrascope to examine many different kinds of common continuous, emission, and absorption spectra. Luminescence – A complete description of many different examples of luminescence in the natural and engineered world. Exploratorium Teacher Institute Page 1 © 2008 Exploratorium, all rights reserved Exploring Spectra (by Paul Doherty and Linda Shore) Using a spectrometer The project Star spectrometer can be used to look at the spectra of many different sources. It is available from Learning Technologies, for under $20. Learning Technologies, Inc., 59 Walden St., Cambridge, MA 02140 You can also build your own spectroscope. http://www.exo.net/~pauld/activities/CDspectrometer/cdspectrometer.html Incandescent light An incandescent light has a continuous spectrum with all visible colors present. There are no bright lines and no dark lines in the spectrum. This is one of the most important spectra, a blackbody spectrum emitted by a hot object. The blackbody spectrum is a function of temperature, cooler objects emit redder light, hotter objects white or even bluish light. Fluorescent light The spectrum of a fluorescent light has bright lines and a continuous spectrum. The bright lines come from mercury gas inside the tube while the continuous spectrum comes from the phosphor coating lining the interior of the tube. Exploratorium Teacher Institute Page 2 © 2008 Exploratorium, all rights reserved CLF Light There is a new kind of fluorescent called a CFL (compact fluorescent lamp). -
Shining Light Through the Higgs Portal with $\Gamma\Gamma $ Colliders
IFT-UAM-CSIC-20-154 FTUAM-20-24 Shining light through the Higgs portal with γγ colliders A. Garcia-Abenza1 and J. M. No2, 3 1Instituto de F´ısica Fundamental, CSIC, Serrano 121, 28006, Madrid, Spain 2Instituto de F´ısica Te´orica, IFT-UAM/CSIC, Cantoblanco, 28049, Madrid, Spain 3Departamento de F´ısica Te´orica, Universidad Aut´onomade Madrid, Cantoblanco, 28049, Madrid, Spain (Dated: November 10, 2020) High-energy γγ colliders constitute a potential running mode of future e+e− colliders such as the ILC and CLIC. We study the sensitivity of a high-energy γγ collider to the Higgs portal scenario to a hidden sector above the invisible Higgs decay threshold. We show that such γγ collisions could allow to probe the existence of dark sectors through the Higgs portal comparatively more precisely than any other planned collider facility, from the unique combination of sizable cross-section with clean final state and collider environment. In addition, this search could cover the singlet Higgs portal parameter space yielding a first-order electroweak phase transition in the early Universe. + − p I. Introduction. The existence of dark sectors in Na- Future high-energy e e colliders like the ps = 1 TeV ture, uncharged under the gauge symmetries of the Stan- International Lineal Collider (ILC) or the s = 1:5=3 dard Model (SM), and interacting with the SM through TeV Compact Linear Collider (CLIC) could provide the the Higgs boson h is a well-motivated possibility: both ideal setup to probe the Higgs portal above the mh=2 theoretically, since the operator HyH is the only super- threshold due to a combination of reach in energy and renormalizable SM Lorentz invariant operator singlet un- clean collision environment.