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Master's Theses Graduate College

8-1985

Subsurface Stratigrapy and Sedimentologic Control on the Productive Middle Age Richfield Member of the ucasL Formation in the

Sukru Nail Apak

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Recommended Citation Apak, Sukru Nail, "Subsurface Stratigrapy and Sedimentologic Control on the Productive Middle Devonian Age Richfield Member of the ucasL Formation in the Michigan Basin" (1985). Master's Theses. 1365. https://scholarworks.wmich.edu/masters_theses/1365

This Masters Thesis-Open Access is brought to you for free and open access by the Graduate College at ScholarWorks at WMU. It has been accepted for inclusion in Master's Theses by an authorized administrator of ScholarWorks at WMU. For more information, please contact [email protected]. SUBSURFACE STRATIGRAPY AND SEDIMENTOLOGIC CONTROL ON THE PRODUCTIVE MIDDLE DEVONIAN AGE RICHFIELD MEMBER OF THE IN THE MICHIGAN BASIN

By

Sukru Nail Apak

A Thesis Submitted to the Faculty of The Graduate College in partial fullfilment of the requirements for the Degree of Master of Science Department of Geology

Western Michigan University Kalamazoo, Michigan August 1985

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. SUBSURFACE STRATIGRAPHY AND SEDIMENTOLOGIC CONTROL ON THE PRODUCTIVE MIDDLE DEVONIAN AGE RICHFIELD MEMBER OF THE LUCAS FORMATION IN THE MICHIGAN BASIN

Sukru Nail Apak, M.S.

Western Michigan University, 1985

The depositional system of the Middle Devonian

Richfield Member of Lucas Formation in the Michigan Basin

was delineated using well logs, cores, drillers' records,

and the literature. The Richfield Member was deposited

in Sabkha and lagoonal environments characterized by

cycles of anhydrite, dolomite, and limestone. Seven

significant productive dolomitic zones, interbedded with

anhydrite and limestone can be correlated throughout the

study area. These zones change laterally to anhydrite

towards the west flank and to dense limestone towards the

east flank of the basin. Post-depositional diagenetic

history of the Richfield was established with the aid of

scanning electron microscopy and electron probe analysis.

SEM and electron probe analysis revealed two stages

of dolomitization that were formed in the Richfield

particularly in central part of basin. This study

represents detailed regional research of the Richfield

Member in the Michigan Basin and it is hoped that it will

provide some information for further investigation of the

Richfield Member in Michigan Basin.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. ACKNOWLEDGEMENTS

This paper is a master thesis submitted by the

author to the graduate faculty of Western Michigan

University. Gratitude is expressed to Dr. W. B. Harrison

who supervised this work with endless help and his great

friendship, Dr. W. T. Straw and Dr. J. Grace who also

contributed to my study with their advise and support, and

the Department of Geology that allowed me to use

department facilities.

Appreciation is also expressed to Dr. A. U. Dogan who

helped me with numerous SEM analyses at the University of

Iowa.

I would like to thank The Graduate College for

supporting my research through Graduate Student Research

Fund. I would like to thank Hunt Energy Company and

Summit Petroleum Company for contributing cores for my

research.

I must also thank the Turkish Government and Turkish

Petroleum Company for allowing and supporting me in

completing my degree in the U.S.A. This study is also

dedicated to my family for their continuing moral support.

I also hope that this study will generate some ideas for

further investigation of Richfield in the Michigan Basin.

Sukru Nail Apak

ii

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Apak, Sukru Nail

SUBSURFACE STRATIGRAPHY AND SEDIMENTOLOGIC CONTROL ON THE PRODUCTIVE MIDDLE DEVONIAN AGE RICHFIELD MEMBER OF THE LUCAS FORMATION IN THE MICHIGAN BASIN

Western Michigan University M.S. 1985

University Microfilms International 300 N. Zeeb Road, Ann Arbor, Ml 48106

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Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. TABLE OP CONTENTS

ACKNOWLEDGEMENTS ...... ii

LIST OF FIGURES ...... iv

INTRODUCTION ...... 1

Previous Work ...... 1

Area of Study ...... 3

Purpose of Study ...... 3

Methods of Study ...... 5

STRUCTURE ...... 10

STRATIGRAPHY ...... 13

RICHFIELD DEPOSITIONAL ENVIRONMENT ...... 16

Sabkha Environment ...... 23

Subtidal Environment ...... 29

POROSITY TYPE AND DEVELOPMENTIN RICHFIELD ...... 33

DOLOMITIZATION ...... 35

Sabkha Type Dolomitization ...... 38

Seepage Reflux Dolomitization ...... 40

SUBSURFACE CORRELATION AND FACIES INTERPRETATION .....43

CORRELATION OF THE MAJOR ZONESWITHIN THE BASIN .....55

SEM ANALYSIS ...... 62

Anderson 1-31,Isabella ...... 63

Me Guire 1-22,Oscoda ...... 79

CONCLUSION ...... 90

APPENDIX .... 92

BIBLIOGRAPHY ...... 95

i i i

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. LIST OF FIGURES

1. Study Area Location within Michigan...... 4

2. Location of Wells within Study Area...... 7

3. Illustration of Type Section in Study Area...... 8

4. Tectonic Features Surrounding Michigan Basin...... 11

5. Structure Map of Richfield Member in the Study Area..12

6. Middle Devonian Showing Position of Richfield Member...... 14

7. Late Devonian Paleogeography Illustration of Michigan Basin as Subtropical...... 17

8. Generalized Depositional Cycle of Carbonates and Evaporites in the Sabkha Cycle...... 18

9. Isopach Map of Richfield Member in the Study Area....20

10. Block Diagram Schematically Showing Facies and Interpreted Depositional Environments in the Michigan Basin During Richfield Depositional Period...... 21

11. Southwest - Northeast Cross-Section Across the Study Area, Showing Facies Relationship within the Richfield Member...... 22

12. Laminated Dolomitic Algal Mats ...... 24

13. Decussate Algal Dolomicrite ...... 25

14. Anhydrite Laths Along Algal Mats Bedding Planes 26

15. Dolomitic Algal Mats...... 27

16. Dolomitic Algal Mats and Vertical Growth of Anhydrite Nodules...... 28

17. Vertical Growing Anhydrite Nodules ...... 31

18. Vertical Growing Anhydrite Nodules...... 32

iv

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 19. Dolomitization Map of the Richfield Member in the study area...... 37

20. Schematic Diagram Showing Sabkha and Seepage Reflux Type of Dolomitization...... 39

21. Correlation of Major Zones within the Richfield Member...... 45

22. Illustration of Type Section in Newaygo County...... 47

23. Illustration of Type Section in Clare County...... 49

24. Illustration of Type Section in Missaukee County...... 50

25. Illustration of Type Section in Roscommon County...... 51

26. Illustration of Type Section in Crawford County...... 52

27. Illustration of Type Section in Oscoda County...... 54

28. Porosity Map of zone-1...... 56

29. Porosity Map of zone-2...... 57

30. Porosity Map of zone-3...... 58

31. Porosity Map of zone-4...... 59

32. Porosity Map of zone-5...... 60

33. Porosity Map of zone-6...... 61

34. Type Log and Core Description of Anderson 1-31, Isabella County...... 64

35. Dolomite Crystals and Secondary Porosity Relationship...... 65

36. Dolomite Crystals, Secondary Porosity, and Pyrite Pramboids ...... 66

37. Pyrite Framboids and Dolomite Crystals...... 67

38. Micro-Calcite Cement, Dolomite Crystals, and Secondary Porosity Relationships...... 68

39. Dolomite Dissolution and Micro-Calcite Crystals...... 69

40. Dolomite Dissolution and Micro-calcite Crystals...... 70

v

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 41. Dolomite Rhombs and High IntercrystallinePorosity..71

42. Dolomite Crystals with probable Fluid Inclusion 72

43. Dolomite Rhombs and Fluid Inclusions...... 73

44. Dolomite Rhombs and Secondary Porosity Relationship.74

45. Dolomite Rhombs in the Pore Spaces...... 75

46. Dolomite Rhombs in the Pore Spaces...... 76

47. Two Sizes of Dolomite Crystals...... 77

48. Small Dolomite Crystal on Large Dolomite Crystal...... 78

49. Core Description of Me Guire 1-22, Oscoda County...... 79

50. Micritic Limestone and Salt Crystals...... 80

51. Micro-Calcite and Salt Crystals...... 81

52. Anhydrite Crystals in Micritic Limestone...... 82

53. Salt Crystals and Partly Dolomitic Limestone...... 83

54. Dolomite Crystals and Micritic Limestone...... 84

55. Star-Shaped Salt Crystals (KC1)...... 85

56. Dolomite Crystals...... 86

57. Micritic Limestone ...... 87

58. Secondary Single Calcite Crystal in the Pore Space...... 88

vi

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. INTRODUCTION

Previous Work

Due to poor outcrops in the Michigan Basin

investigation of the Middle Devonian strata have been done

based on subsurface strata by some authors. The main

purpose of this studies is to define the depositional

environment, facies relationships, and age determinations,

of the Middle Devonian rocks in the basin. However,

relatively little work has been published on the

depositional system of the Richfield Member of Lucas

Formation of the Detroit River Group in the Michigan Basin.

Landes (1951) correlated the outcropping rocks of

the Detroit River Group from the type locality sections.

He has also used well logs and cores to define the

formations' depositional environment, their contacts,

diagenesis and economically important future.

Ehrnann (1964) studied stratigraphic analysis of the

Detroit River Group in the Michigan Basin. He had

subdivided the Detroit River Group into the characteristic

zones in the center of the basin andcorrelated them

in the entire basin.

1

with permission of the copyright owner. Further reproduction prohibited without permission. 2

Gardner (1974) worked on the Middle Devonian

evaporite-carbonate complex to determine the depositional

environment and diagenetic history of the rocks. He tried

to establish the paleogeographic reconstruction of strata

and the relationships of the environmental complex and

its distribution in the basin.

Matthews (1977) studied the correlation of

evaporite cycles and lithofacies of Lucas Formation

in Midland County, Michigan. This study was based

on the description of the cores which were used to

correlate the cycles and salinity of the depositional

environment in Midland county.

Briggs and Haney (1964) determined the cyclicity of

textures in evaporite rocks of the Lucas Formation in the

Michigan Basin. He pointed out that the texture could be

related to the physiochemical conditions of mineral

precipitation and specific conditions of brine

concentration at that time.

Fagerstrom (1983) researched the Lucas Formation' s

carbonate and evaporite complex and their petrological and

regional significance in the eastern Michigan Basin. He

petrologically studied the interreef rocks, transition

rocks and reefs and their type of diagenetic evolution .

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 3

Melvin (1984) has studied the Richfield Member of

the Lucas Formation in Gladwin and Clare Counties

in the Michigan Basin in order to establish the

depositional model and facies analyses of the Richfield

Member. She has also defined types of hydrocarbon traps

that were formed either structurally or stratigraphically.

Area of Study

The research area includes the following counties :

Crawford, Oscoda, Missaukee, Roscommon, Ogemaw, Lake,

Osceola, Clare, Gladwin, Arenac, Bay, Newaygo, Mecosta,

Isabella, and Midland . (Figure 1).

Purpose of Study

The Middle Devonian Richfield Member of the Lucas

Formation contains oil and gas reservoirs within

structures in the central portion of the Michigan Basin.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. STUDY AREA

Figure 1. Study area location within Michigan.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 5

However, productive units in some structures are non

productive on similar structures in the eastern and

western part of the basin. The purpose of this study was

to determine which parameters limit production to

structures in the central portion of the basin. Using

available subsurface materials (well logs and core

samples), objectives of this study were:

1. To divide the Richfield Member into several

distinctive, usually productive zones which can be

correlated throughout the basin.

2. To delineate lateral facies changes of the

productive zones towards the eastern and western flank of

the basin.

3. To determine the geological factors which

controlled the reservoir properties and limit production

to the central portion of the basin.

Methods of Study

Well logs, drillers' logs, cores, core analysis

reports, and literature were used as data to prepare

subsurface maps. One hundred and eighty-one well logs

(formation density, neutron, gamma ray, resistivity, and

sonic logs) were obtained from Michigan Department of

Natural Resources in Lansing, Michigan. Drillers' logs were

used for lithologic descriptions of the Richfield where the

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 6

wire-line electric well logs were not available for

this data. Well locations were chosen from nearly every

township within the study area (Figure 2.). Producing and

non producing wells from each county, in the same geologic

interval, were used to define lateral facies and

lithological changes throughout Richfield. The upper

(just below the massive anhydrite) and the lower (below

the last dolomite zones of Richfield) contacts of the

Richfield were picked from each log in the study area

(Figure 3.).

The samples from Anderson 1-31, Isabella Co., and 1-22

McGuire, Oscoda Co. were examined and sampled in detail

to construct the depositional model and determine post-

depositional diagenesis of the sediment. Petrographic

analysis were made by 1. standard petrographic

microscope, 2. scanning electron microscope , and

3. electron probe analysis. Fifty-one core samples

were examined (27 of them from Anderson 1-31, Isabella

Co. and 24 of them from 1-22 McGuire, Oscoda Co.) using

the scanning electron microscope. All of the core samples

were coated with either 1. gold and platinium, 2. gold

and palladium, or 3. carbon.

The Jeol-35C scanning electron microscope was used to

determine rock properties such as cementation,

compaction, replacement, pore geometries, sizes

and shapes of microcrystaline authigenic minerals

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 7

Osama t 11-41 ai.Ntf«a«

1-MMffin QuuMmkE. S Nm MI'i k U.T* 11 UHff„•j*a

m rm c M M i

Figure 2. Location o£ wells within study area.

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3 HAMILTON UNIT 18 SEC.? T1IN- R1W SE NE NC CLARE CO.,MICHIGAN1

u lULK OCNIITT M

MtUTNON POIIOtlTV

MMIIVC ANNVOHITt . 8 1 0 0 0 0 /0

SOM f 1 0 3

t O N l 2 1 8

ZONK a 22.5

IO N C 4 .

IO N I 3

8201

SONS •

IO N C 7

CLACK UMCSTONC

Figure 3. Illustration of type section in study area.

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(halite, quartz etc. ). Grain or crystal surface texture

and textural relationship of diagenetic minerals was

determined by using freeze fracture method (Dogan,

Personel comm. 1984).

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. STRUCTURE

The Michigan Basin is an almost circular, intracratonic

basin located in the central interior platform.

The basin covers southern Ontario, part of the upper

peninsula of Michigan, eastern Wisconsin, the northern

portion of Illinois, northern Indiana, northwestern Ohio,

and the southern peninsula of Michigan. The Michigan Basin

is bounded by ^Wisconsin arch on the west, Kankakee platform

on the southwest, Findlay arch on the east, and Canadian

shield on the north (Figure 4.). Deposition and erosion

were controlled by these tectonic features.

Many models have been proposed to define the formation

and structure of Michigan Basin. The basin was present

during time in an embryonic form

(Fisher, 1979). Clastics and carbonates were deposited on

pre-Cambrian basement rock. The basin' s current shape

was developed in Middle time.

During Early time , shales and carbonates

filled the basin and by Middle Silurian time

reefs were developed around the basin margin. Maximum

subsidence of the basin occurred in Paleozoic time. The

central part of the basin received 8000 feet of sediments

in Silurian and Devonian times. These sediments were

mostly limestone, evaporite, and shale (Fisher, 1979). By

Mississippian time, movement occurred along the basement

10

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 11

[study area )

CANADA \ SHIELD

UNITED STATES ' V / S - ^ - 1 - '- f ? \. v v v v si- v

CHIGAf* BASIN

ILLINOIS > BASIN'-.

DOME

MISSISSIPPI EMBAYMENT

CRETACEOUS AND TERTIARY F T ] MISSISSIPPI** AND I I PALEOZOIC ROCKS OP PRE-MISSISSIPMAN AGE '

E 3 PRINCIPALLY c r t s t a l in e r o c ks

.JO O gO MILES GULF OF MEXICO 0 ISO 320 KILOMETERS

Figure 4. Tectonic features surrounding Michigan Basin. Source: Hager, 1949, 1198-1205.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 12

ma«

mar

>4030. >3140* U 4 I II*

>3270)

Figure 5. Structure map of Richfield Member in the study area.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. faults. According to Fisher (1979) vertical movements

caused NW trending folds-in the central part of the basin.

A structure map (Figure, 5.) shows the current shape of

basin. As it is seen on the map, the central part which is

main producing area is the deepest part of the basin.

STRATIGRAPHY

Middle Devonian age strata of the Michigan Basin

include from oldest to youngest, the Detroit River Group,

Dundee Formation, and Traverse Group. The Detroit River

Group (Figure 6.) is composed of ,

Amherstburg Formation, and Lucas Formation (Gardner,1974).

Sylvania Sandstone is the basal part of Amherstburg

Formation and can be correlated in most parts of the basin

(Landes, 1951). , which is often

called " Black Limestone " by well-site geologists is

present throughout the basin. Its lithology is dark-colored

limestone and generally fosilliferous. It is underlying

the Richfield Member. The boundary between them can be

recognized by a difference in their colors. The Upper part

of Amherstburg is a black-colored limestone, whereas, the

basal part of the Richfield is lighter and dolomitic. The

contact between them appears just below the last dolomitic

zone of Richfield member. In some areas this zone is not

13

with permission of the copyright owner. Further reproduction prohibited without permission. FORMATION MEMBERS INFORMAL GROUP NOMENCLATURE

o 5 HORNER MEMBER UPPER SPUR ZONE a o r- H a C a o < m > m w a LOWER SOUR ZONE -n CO 3J O O 3 c IUTZI MEMBER O s a H 5 • 33 • £ MASSIVE ANHYDRITE RICHFIELD < m ! 31 / RICHFIELD MEMBER Q S. 3) FREER SANDSTONE O > FILER SANDSTONE C . -n 2 OX MELDRUM ■o t a m MEMBER 3 a BLACKLIME ’

i c SYLVANIA Z a SANDSTONE O

Figure 6. Middle Devonian Detroit River Group, showing position of Richfield Member.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 15

as dolomitic and also is black color, so this may suggest

a gradational boundary between them. The Lucas Formation

lies below the Dundee Formation. The upper part of Lucas

Formation is dolomite and the basal part of Dundee Fm. is

limestone. However, the basal part of Dundee Fm. may be

dolomitic and anhydritic especially in the western part of

the basin. In the central basin Lucas Formation contains

limestone, salt, and anhydrite beds. Therefore, contact

between them is not clear in the western part of basin. It

may also suggest a gradational boundary between the two

formations.

The basal part of Lucas Formation is called the

Richfield Member which is an important oil and gas

reservoir in the central Michigan Basin. It is characterized

by several cycles of anhydrite, limestone, and dolomite

with its distinctively developed secondary porosity. These

dolomitic zones have porosities range up to 30% especially

in the central part of the basin. Towards the east and

west this porosity decreases where the dolomitic

lithology turns to anhydrite at the west flank

and to dense limestone at the east flank. The upper part of

the Richfield Member is characterized by a thick anhydrite

bed which is informally called the "Big Anhydrite" . This

anhydrite is continuous in the whole basin, but it is much

thicker in the central and northern part of the basin.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. RICHFIELD DEPOSITIONAL ENVIRONMENT

During Devonian time the basin was affected by

several marine transgressions and regressions. Multiple

cycles of limestone, anhydrite, and dolomite suggest a

restricted marine environment in an arid and hot climate

(Dott and Batten, 1981) during the Richfield depositional

period (Figure 7.). Repeated sea level fluctuations

caused vertical repetition of similar rock sequences,

local unconformities, and thickness variations within the

Richfield Member. These sea level changes were caused

by: 1. marine water flowing through the Saginaw inlet,

2. basin subsidence, and 3. changes of evaporation rates.

In a Sabkha environment sediments are deposited under

very shallow water (Figure 8 .) and they are very sensitive

to sea-level fluctuations (Schreiber, pers. comm.,1985).

Slight rises of sea level cause dissolution of

evaporites and create pore places. These pore places were

filled either by hydrocarbon or cement at the later

stage. In the lower stage of sea level evaporation rates

increased, dolomitization occurred, and sea water entered

the basin. The Richfield deposition shows a similar

environment and it is considered to be deposited under the

Sabkha and lagoonal environment. Anhydrite beds are the key

marker zones within the Richfield deposition. Laterally

continuous vertically thick anhydrite beds deposited in the

16

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 17

ITUDY AHI

Figure 7. Late Devonian Paleogeography illustration of Michigan Basin as Subtropical. Source: Dott and Batten, 1981.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 18

«

GENERALIZED DEPOSITIONAL CYCLE]

EVAPORITE STRUCTURES CARBONATE FACIE

Si

- I 3

5 ^ • • •• s g B'csa y ' •= s? u

cea ■C^

• T z z < >

i 7 5 z .= r*

l r \ r v

?U9 riDAL. May oocorne stmacrinlly exposure.! during ionq oeriocs of evaporation. l

F ig u r e 8 . Generalized depositional cycle of carbonates and evaporites in the sabkha cycle, source: Loucks and Longman, 1982.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 19

shallow water lagoon environment. Laterally discontinuous

anhydrite beds and subaerial deposits indicate a sabkha

environment. In the Richfield Member each facies is

characterized by these rocks:

Subtidal Environment: It is mainly a limestone facies; however, salinity of water caused either limestone or anhydrite deposition in this facies.

Sabkha Environment: 1. Intertidal Facies; Limestone and dolomitic limestone are the main lithologies. Dolomitization rate increases towards the upper intertidal zone. Ripple-marks, oolites, algal laminated limestone are common. This facies may be good reservoir rocks. 2. Supratidal Facies: This facies is characterized by nodular anhydrite. It is an important facies because it seals the reservoir rocks as a cap rock.

Based on an Isopach map, the Richfield Member

gradually thins eastward and northeastward (Figure 9).

According to Gardner (1974) the maximum thickness

of the Richfield Member was deposited in

Missaukee and Wexford Counties. In the study area the

maximum thickness is seen in Osceola (291 feet),

Missaukee (198 feet), Clare (254 feet), and Roscommon

(221 feet) Counties. Anhydrite, which was the dominant

lithology in these counties controlled the maximum

thickness of the Richfield Member in this part of basin.

It shows that during Richfield deposition, the west flank

of the basin was under supratidal conditions (Figure 10-11)

while other parts of basin were receiving intertidal and

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174

T96i 184 1B2

|t84 231 104

180

181

181 1980 • r .107 2 00

►254

.220 108 2 5 0

161 06

Figure 9. Isopach map of Richfield Member in the study area.

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j

i

Figure 10. Block diagram schematically showing facies and interpreted depositional environments in the Michigan Basin during the Richfield depositional period.

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sw NE

i

I SUBTIDAL SUPRATIDAL INTEITI i

e*

B L A c

Figure 11. Southwest-Northeast cross section across the study area, showing facies relationship within the Richfield Member.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 23

subtidal deposits.

Sabkha Environment

Environmental factors such as temperature, sea level

fluctuations, high salinity, and high evaporation rate may

limit the distribution of organisms and sediments in the

Sabkha environment. The supratidal and intertidal zone,

collectively is defined as the Sabkha environment.

The supratidal environment of the Richfield Member,

on the west flank of the basin, is characterized by thick

anhydrite bed deposition interbedded with thin carbonate

beds that were completely dolomitized .

In the upper and middle supratidal zone, nodular

anhydrite is abundant. These nodules are mostly lenticular

or discoidal gypsum that were later altered to

nodular anhydrite (Schreiber, 1981). In the lower

supratidal and upper intertidal zone anhydrite laths are

generated within the algal mats (Figure 12, 13, and 14).

Sedimentary structures such as ripple marks, cross

bedding, oolites, and algal mats are associated with the

Sabkha environment. The most common plants found in the

intertidal zone are blue-green algae which are deposited

as algal mats within the lime mud (Figure 12, 15, and 16).

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 24

Figure 12. Laminated dolomitic algal mats. Dark anhydrite laths developed along wavy bedding planes, but oriented high angle to the bedding. The nodules appear to have formed low relief on the lagoon floor, but growth continued after deposition by revealing draping of.laminae.' Core: Anderson 1-31, depth: 4759.5 feet.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. Figure 13. Decussate algal dolomicrite. Dark anhydrite laths randomly oriented along bedding. Core: Anderson 1-31, depth: 4771.5 feet.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. Figure 14. Anhydrite laths along algal mats bedding planes. Intertidal environment. CoretAnderson 1-31, depth: 4789 feet.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. Figure 15. Dolomitic algal mats. Shallow and hypersaline environment. Core: Anderson 1-31, depth:4726 feet.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 28

Figure 16. Dolomitic algal mats and vertical growth of anhydrite nodules. These nodules grew under very shallow water (maximum depth of water is 15 cm.). Core: Anderson 1-31, depth: 4707 feet.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 29

Environmental factors explained above control the

marine organism distribution in the Sabkha environment.

In the restricted character of most Richfield lithologies

macrofossils are not common, because the environment would

not support those kind of organisms. Only the lower part

of Richfield, deposited during a transgressive cycle of

the Lucas sea contains such as brachiopods and

marine plankton (Melvin, 1983). The organic-rich "black

Limestone" and the dark-colored lower part of Richfield

may be possible source rocks for the hydrocarbon that later

accumulated in the porous dolomitic zones. In the study

area, especially in central part of basin which was

mostly intertidal zone during Richfield deposition,

dolomitization occurred resulting in high secondary

porosity. Then oil and gas migrated into this area where

reservoir properties allowed for hydrocarbon trapping.

Subtidal Environment

During Richfield deposition, the eastern flank of the

basin was under subtidal condition, because of the entrance

of water from the ocean into the restricted basin. In the

study area, this facies is represented by limestone

interbedded with subaqueous anhydrite deposits. There is

almost no dolomitization in this facies (10%-0%). Different

salinity of the water, which was caused by sea-level

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. fluctuations and high evaporation, caused limestone

and anhydrite deposition in the area. At the lower stage

Of sea level, Subaqueous anhydrite was deposited due to

high evaporation and hypersaline water. This anhydrite is

characterized by vertically growing crystals (Figure 17-18).

These type of anhydrite crystals indicate that they formed

in very shallow water of about 10-15 cm. (Schreiber, 1984).

During this period, no influx of water from the ocean

occurred and high evaporation yielded laterally expansive

anhydrite deposition in the area. SEM analysis of the

McGuire 1-22, Oscoda Co. core, indicates that secondary

salt crystals were precipitated in the intercrystallini

porosity of the limestone. These salt (NaCl) crystals are

most probably secondary because they filled the

intercrystalline porosity and were precipitated on the

calcite crystals (Figure 50, 53, and 54).

In the upper part of Richfield, thick anhydrite beds

called the "Big Anhydrite" were deposited due to a high rate

evaporation and hypersaline water. Laterally it can be

correlated, particularly in the central and northern part

of basin. This vast expansion of the anhydrite beds indicate

that the area remained under subtidal conditions for

a long time. During this time the basin was mostly covered

by lakes or ponds like those found in the present day

Persian Gulf lagoon environment (Kendall, 1968). This

evaporite bed covered all previous carbonate depositions,

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 31

Figure 17. Vertical growing anhydrite nodules. Core: Anderson 1-31, depth: 4697.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 32

A

Figure 18. Vertical growing anhydrite nodules. Very shallow depositional environment, Core: Anderson 1-31, depth: 4705m.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. so most of oil and gas production in Richfield carbonates

is found beneath the "Big Anhydrite" bed. At the upper last

zone of the Richfield deposition, the area was affected by

a transgressive cycle and was covered by water which was

less saline than the previous inudations. This last

Richfield carbonate sequence was deposited mostly

in the central part of the basin. Even though the sequence

has high porosity it contains no economical hydrocarbon

accumulation. "Big Anhydrite" beds apparently blocked the

hydrocarbons from migrating up into the last carbonate bed.

After the deposition of the last carbonate unit of the

Richfield Member, the basin again became a restricted

environment and the Richfield was covered by the another

thick anhydrite bed which is called "Massive Anhydrite".

POROSITY TYPE AND DEVELOPMENT IN THE RICHFIELD

Two types of porosity are present in the carbonate

sequences of the Richfield Member, 1) primary porosity

related to the depositional environment, and 2 ) secondary

porosity related to rock diagenesis occurring after

deposition.

Primary porosity forms as a result of events which

occur during the depositional process. Certain environments

have good primary porosity while others have almost none.

33

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 34

For instance, oolites deposited in a high energetic

environment have good porosity because the fine size

materials which can fill in the pores and decrease porosity

are winnowed away by currents. However, some porosity may

be associated with chemical processes instead of physical

depositional processes. Primary porosity is modified by

compaction, solution, and cementation, which may cause

a secondary decrease or increase the porosity (Choquette

and Pray, 1970).

Secondary porosity is the result of diagenetic

alteration. Textural characteristics (grain size, shape,

and packing) also help to create and increase the

secondary porosity. All these features are controlled by

the rock's facies.

In the Richfield Member of the Lucas Formation

good to poor porosity developed in the carbonate

sequences. In the central part of basin, which is

the most productive region in the Michigan Basin,

dolomitization caused the high secondary porosity.

However, the eastern and western flank of the basin show

an entirely different picture from the central part. The

western flank, which was mostly a supratidal environment

during the Richfield deposition period, is characterized

by thick anhydrite beds. Because of this lateral

facies changes in the Richfield no porosity developed

on the west flank of the basin. On the east flank

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. of the basin, the Richfield is characterized mainly by

limestone interbedded with subaqueous anhydrite. A low

energy environment, poor water circulation, and poor

dolomitization of the limestone yielded the low porosity

in this region. The samples from Anderson 1-31, Isabella

Co. in the central part of the basin, and McGuire 1-22,

Oscoda Co. in the northeastern part of the basin were

studied to determine how the facies change laterally from

the central part to the eastern flank. In the study area,

high secondary porosity developed in the Sabkha

environment. It seems that the dolomitization which occurs

throughout the Sabkha environment, is the most important

process involved in creating secondary porosity.

DOLOMITIZATION

Certain conditions are necessary for the formation of

dolomite in carbonate sequences. The first and the most

important one is that a source of Mg ion must be present

in the environment. Other factors include the Mg:Ca ratio

sulfate concentration, organic material, iron content, and

bacterial activity in the environment (Longman, 1981).

Several models have been proposed for the formation of

dolomite. These models are: 1. primary precipitation, 2.

seepage refluxion 3. solution cannibalization, 4.

capillary concentration, 5. mixing of fresh and marine

35

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 36

waters, and 6 . subsurface brines (Longman, 1981).

Dolomite can be either primary or secondary in the

carbonate sequences as suggested by Zenger, 1972. Primary

dolomites are associated with evaporite and they are

mostly found in the Sabkha environment. Secondary

dolomitization occurs by replacement of pre-existing

carbonate materials. A number of factors control the

dolomitic replacement of carbonate. Composition and grain

size are significant controlling factors. Aragonite, high

Mg-calcite, and fine-grained size materials such as

micrite become dolomitic faster than coarser-grained sizes.

During Richfield deposition, the Michigan Basin was a

restricted basin which was characterized by several cycles

of regressions and transgressions. High evaporation, dry

climate, and high salinity of the water resulted in thick

anhydrite bed deposition in the Sabkha environment. There

is also abundant dolomitization in this area (Figure 19).

Complete dolomitization of the carbonate beds in the

supratidal environment can be explained by Sabkha-type of

dolomitization (Figure 20).

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 37

0|ti

HI

Clin •tl

Figure 19. Dolomitization map of the Richfield Member in the study area. f

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 38

SUPRATIDAL intertidal SUBTIOAL

ANHYDRITE , AAAaONITE+MgCALCITE

EEEPAQE .HEFLUXION ZONe

'!

Figure 20. Schematic diagram showing sabkha and seepage reflux type of dolomitization.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 39

Sabkha Type Dolomitization

Normal marine water contains more sulfate ions than

Ca++ and Mg++ ions . When the sea is allowed to

evaporate, gypsum is precipitated until all Ca++ ions

have been used up, and the rest of sulfate remains in

residual brines. Major seawater ions and this sulfate

reaction are listed below.

Na+

Mg++

K+

Ca++

(Eg. 1) Ca + SO4 = CaS0 4 + residual SO4

Cl”

SO4

Precipitation of gypsum increases the Ca:Mg ratio

which promotes dolomitization of the carbonate host rocks.

For example, in Newaygo, Mecosta, and Osceola Counties

the thin carbonate beds are all dolomitic.

(Eg. 2) Mg + 2CaC03 = CaC03 MgC0 3 + Ca++

As a result of these reactions additional SO4 ions

combine with Ca++ ions to make more CaS0 4 , shown below

(Shearman, 1978).

(Eg. 3) Ca + SO4 = CaS0 4 + residual SO4

(Eg. 4) Mg + 2CaC03 = CaC03 MgC0 3 + Ca++

(Eg. 5) Ca + residual SO4 = CaS0 4 (Gypsum)

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 40

The reaction explained above, allows for, more calcium

sulfate to be produced in the carbonate Sabkha. That is

why the thickest part of the Richfield is deposited in the

supratidal environment.

Seepage Reflux Model Dolomitization

In the central part of basin, similar thick anhydrite

and dolomite beds are preserved. During Richfield

deposition, the restricted Lucas sea had a different

salinity than the adjacent open sea. Sea level fluctuations

were caused by the difference salinity of each transgressive

and regressive cycles. This resulted in anhydrite and

limestone deposition in the central part of basin. Loss

of water by evaporation caused lowering of sea level and

increased the concentration of the remaining brine. Then

waters entered from the adjacent open ocean. This

remaining brine sank and while incoming water from the ocean

flowed along the surface and maintained water circulation

across the shelf. At this time the Ca++ ions reacted with

with the hypersaline brine to make CaSC>4 . Than, Mg-rich

sea water seeped towards the sea and the Mg++ reacted with

the CaC0 3 , which caused the limestone to turn to dolomite

in this zone. This circulation is called seepage reflux by

Adams and Rhodes (1960), (Figure 20). It seems that Sabkha

and seepage reflux models are the appropriate model for

the widespread dolomitization in the Sabkha environment.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 41

The important question is why the dolomitization did

not occur or, was only slightly formed in subtidal

environment. According to Kastner, (1983) the important

condition for the dolomitization is not the high Ca:Mg

ratio as it was previously thought. She states that a low

dissolved sulfate (S0 4 ) content is very important for

dolomitization. High dissolved sulfate in the sea water

inhibits dolomite formation in the environment. The eastern

flank of the basin was a subtidal depositional environment

at this time. The lithology is mainly micritic limestone

and subaqueous anhydrite. A low energy environment and

poor dolomitization created little porosity in the

limestone. Due to low water circulation in the subtidal

environment, removal of sulfate ions from Sabkha

environment, either by the seeping of the sulfate-rich sea

water from intertidal to subtidal or by being washed by

water circulation, increases the amount of free sulfate

ion concentrations. This excess of sulfate ions inhibits

the dolomitization in the subtidal environment.

SEM analysis which was done in two wells, revealed

that two types of dolomite crystals formed within the

Richfield. They were formed at a slightly different

time during Richfield diagenesis. At the first stage, the

limestone beds were dolomitized (Seepage Reflux Method)

and big dolomite crystals were formed. They are not rich

in Mg content. A loss of volume due to dolomitization

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 42

created secondary porosity of the limestone (see in the

SEM section). At the second stage small dolomite crystals

were formed on the big dolomite crystals and in the pore

spaces. The second type of crystals are very small in size

and have a high Mg content. SEM result are given about the

two types of dolomitization in the SEM analysis section.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. SUBSURFACE CORRELATION AND FACIES INTERPRETATION

The Richfield Member of Lucas Formation is

characterized by Sabkha and lagoonal facies type

deposits. It is underlain by a dark-colored coralline

rich "Black Limestone". The differences in lithologies

between the "Black Limestone" and the Richfield

Member indicates normal marine conditions in the

basin during the "Black Limestone" depositional period.

These conditions changed to a widespread shallow

lagoonal and Sabkha-type depositional environment

during Richfield deposition. On the west flank and central

portion of the basin, a thick Sabkha-type deposit occurs,

whereas, on the eastern side of basin lagoonal carbonates

were deposited. In the upper part of the Richfield, the

"Big Anhydrite" covers all previous Richfield deposits

as a cap rock.

The top contact of Richfield is located between the

"Massive Anhydrite" and the carbonate bed deposited

during the last influx of sea water from the Saginaw

inlet, after "Big Anhydrite" accumulated. As mentioned

before the Richfield is composed of anhydrite, dolomite,

and limestone beds. Sabkha deposits occur in the

supratidal and intertidal environments. These lithologies

can be correlated in the basin (Figure 21). Anhydrite beds

43

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. are mainly laminar, vertical growth crystals, and

nodular type of deposits. In the supratidal zone nodular

anhydrite beds are mostly discontinuous as many of them

were deposited subaqueously in ponds on the upper intertidal

or lower supratidal zones. Most were not deeper than 15cm.

The Richfield Member is herein subdivided into seven

zones which are generally dolomitized in the central part,

change laterally to anhydrite towards the west flank,

and change to limestone towards the east flank of the basin

(Figure 21).

On the west flank, the Richfield Member is composed

of thick anhydrite beds interbedded with thin dolomitized

carbonate beds. These deposits are found in Newaygo,

Mecosta, and Osceola counties and formed in the supratidal

environment. Therefore, none of the seven carbonate zones

can be identified in this area (Figure 22). Lutz 1-27/A

(Newaygo Co.), Schwalm 1-15, Leach 1-4, and R.Quart 1-30

from Osceola Co.,and R.Thelma 1-12 from Mecosta Co. are

typical wells in the western flank.

In the central part of basin, Richfield was deposited

in an intertidal environment. In the regression cycle, the

lower stage of sea level, influx of water from the sea

affected the environment. Dolomitization occurred and

progressed towards the central area and decreased towards

the eastward edge of the basin. This dolomitization caused

high secondary porosity in the central part of basin.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. CRAWFOftB

OSCEOLA

MECOSTA

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 47

1 -2 7 A LUTZ SEC.1T T18H-R11W BW MW SC NEWAYGO CO., MICHIGAN

3.0 GAMMA «AV 2.0 BUU D1N1ITT 2.3 NVUINON R0AQI1TV 400 4.5 3 0 13

i V 4264 I

SWWWl .4300« \ \ v

ftmwv 2

-4400

Figure 22. Illustration of type section in Newaygo County.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 48

Wells used in this study which represent deposition in

the central basin, include the Hamilton Unit 3-18 (Clare

C o.), Molhoek 9-31 (Missaukee Co.), Helveston 4-25 (Crawford

Co.), and Porter Hogan 1-8 (Roscommon Co.). It is seen in

these wells that the Richfield lithology can be correlated

from well to well. In the Hamilton Unit 3-18 (Clare Co.)

seven carbonate zones and anhydrite beds are seen.

The porosity range in this well from 9% (zone-6) to

22.5% (zone-3 ), (Figure 23).

In the Molhoek 9-31 (Missaukee Co.) similar

carbonate zones and depositional cycles are seen. The only

difference between them is that the anhydrite beds are

much thicker than in the Hamilton Unit 3-18. It seems

reasonable because the Molhoek 9-31 is much closer to the

west flank of the basin. The porosity range is 8% (zone-4)

to 16% (zone-2), (Figure 24).

The Porter Hogan 1-8 (Roscommon Co.) is located in

the central part of study area. The porosity range is from

7% (zone-2) to 18.5% (zone-6), (Figure 25).

The Helveston 4-25 (Crawford Co.) is in the northern

part of study area. It is very similar to the Porter Hogan

1-8. Its porosity range is from 6.5% (zone-4) to 15%

(zone-2), (Figure 26).

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 3 HAMILTON UNIT 18 »eC.T TUN-MW SENENI CLARE CO.,MICHIGAN•

M ______»um BIHIIft,,

Figure 23. Illustration of type section in Clare County.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 50

9 r 31. MOLHOEK SEC 31 T22N - ROW NW NWSW

MISSAUKE CO., MICHIGAN

NIUM09 POROIIVV u ______ac______is

Ispi-l II

i d i i i _ 4 . . 1 .

■lac* umiioMi__

Figure 24. Illustration .of type section in Missaukee County.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. PORTER HOGAN 1-8 8IC.I N-II'W NE BE tW ROSCOMMON CO., MICHIGAN flmm iit miLi.nmiiii

JOMB t •

4 0 N t | F

IDMI S IJ

....CJU*

Figure 25. Illustration of type section in Roscommon County.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 52

HELVESTON 4-25

SEC >1 TilN • R 1 W NE S W NE CRAWFORD CO., MICHIGAN

Figure 26. Illustration of type section in Crawford County.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 53

The cycles of regressions and transgressions

caused many unconformities within the Richfield

Member. That is why individual dolomite or anhydrite beds

would disappear from one field to another one.

The McGuire 1-22 well is located, Oscoda Co., in the

northeastern portion of study area. It was completed as a

dry well. The depositional environment is subtidal and

has poor dolomitization and low porosity within this

portion of the Richfield Member. The porosity range is

0% (zone-1) to 14% (zone-7), (Figure 27).

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 54

1-22 MC GUIRE SEC.23 T25N - R2E SW NE SW OSCODA C0„ MICHIGAN

b«mm« ■» _iUt« 91

-011- _14-

UAttW I AMHU1MTI - o & - t o u t

IO N I I

I O N I I 10

IO N I I

IO N I I 9

icmi r u

•LACK UMKIfONI

T

Figure 27. Illustration of type section in Oscoda County.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. CORRELATION OF THE MAJOR ZONES WITHIN THE BASIN

Major zones followed throughout the basin are well

developed especially in the central part of basin. For

zone-1 (top of Richfield) to zone-6 porosity maps were

made to establish porosity patterns in each different

zone. The highest porosity developed in the central part

of basin, and each zone's porosity decreased and approached

zero towards the east and west flank of the basin.

Although the precise pattern and actual value of the

porosity changes from zone-1 to zone-6, the similarily is

enough to allow some general statements about the origin

and the relationships of the porosity in different zones.

The similar pattern of the porosity maps from these

six zones indicates that the same depositional environment

was dominant during the deposition of these major carbonate

zones. Because of the dolomitization, porosity is much

better developed in the central part of the basin. In the

supratidal zone (west flank), porosity becomes very low

and zero in Mecosta and Newaygo Counties. Because of the

high concentration of anhydrite in the eastern flank of

the basin, dolomitic carbonate zones turn into impermeable

limestone and porosity drops down to zero. The limestones

are deposited seaward of the environments affected by the

dolomitizing fluids.

55

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 56

* r

i it *12

i

*S| • I t

Qiiull t i 1U • s

n s

17

I I

••r

Figure 28. Porosity map of zone-1.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 57

18.7

0 | i m 1.1 IS*

•IS

Figure 29. Porosity map of zone-2.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 58

t2J

O a iu li

aa1

127

Figure 30. Porosity map of zone-3.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 59

Oicodt

> • ?

Figure 31. Porosity map of zone-4.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 60

it* •«

Oo

• 0 •Iu

00

»•»

Figure 32. Porosity map of zone-5

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 61

>u

UJ

•11

• 0 • 0 •t

° !DO ’*0 #

'•IT

•14(

•r

*•1

lia b a ltt

Figure 33. Porosity map of zone-6. ,

I

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. SEM ANALYSIS

The Middle Devonian Richfield Member of the Lucas

Formation in the Michigan Basin, consists of alternated

anhydrite, limestone and dolomite. The post-depositional

history of the Richfield Member was determined by using

Scanning Electrone Microscope (SEM) and Transmission

Electron Probe (TEP) as well as the standard

petrographic microscope. Study samples were taken from

subsurface cores of the Anderson 1-31; Isabella Co., and

McGuire 1-22; Oscoda co. The resolution of the light

microscope is not sufficiant to resolve fine details less

than 30 microns in diameter, however SEM with its maximum

resolution of about 100a, is adequate to study the grain to

grain relations, grain to cement relations, and the pores

of the rocks. Samples cut to about 2 by 1 inches and

dipped in liquid nitrogen for a couple of minutes, than

applying pressure breaks it into two pieces. One of them

is dried and coated with either C or Au+Pd to make it

conductive then analysed under SEM .

Scanning electron microscopy (Jeol Jsm-35c) and

Energy Dispersive X-Ray micro analysis (Kevex 7000)

revealed that the Richfield Member has complex diagenetic

history. Analysis result from two wells are as follows.

62

with permission of the copyright owner. Further reproduction prohibited without permission. 63

1) Anderson 1-31 Rosebush field T16N R3W Isabella Co.,Michigan

The Anderson 1-31 was completed as a dry hole. It was

off structure and was about 30 feet deeper than the closest

producing well in the area. According to cores of the

Anderson 1-31 the Richfield was deposited in mostly

upper intertidal environment ( Figure 34 ). SEM analysis

shows that these authegenic minerals observed in the

Richfield Member's carbonate sequences .

Dolomite : Two types of dolomite crystals are

present in the samples. SEM and X-Ray analysis show

the large dolomite crystals have less Mg content than

small dolomite crystals(see photos). In the first stage of

dolomitization, calcite altered to large dolomite crystals.

Due to volume loss secondary porosity created (see

photos). Subsequently, Mg rich water came into the pores and

small dolomite crystals formed. Their size is much smaller

than the first generation dolomite. The different Mg content

indicates that slightly different conditions affected the

area during its diagenetic history.

Micro-calcite is seen in the samples' photographs as

cement 3-5 microns in size.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. OEPOSITIONAL ENV

CORE NEUTRON

HIQH LOW 4678 0 % SUBTIOAL

Algal Lamlnalad M u d ilo n a

4700

Nodular Anhydrlta Cryal.

.O o lita a

4800 4797

Figure 34. Type log and core description of Anderson 1-31, Isabella County.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. Authigenic quartz: it is found as a trace element in

the samples.

NaCl ; x-ray analysis revealed that Na and Cl are

found in the samples. Salt is the reasonable assumption.

Authegenic pyrite and some zeolite like minerals are

presented in these samples. Analysis results on the

samples of Anderson 1-31, Isabella Co. are;

Figure 35. Dolomite crystals and secondary porosity relationship. Depth=4679 feet (1426,15 M.) magnification=300x, scale= 1 micron.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. Figure 36. Dolomite crystals, secondary porosity, and pyrite framboids. Notice that the sample is mostly dolomitized and has good porosity. Closer look to pyrite framboids. Perhaps indicate pressure of organism and reducing environment. Depth=4679 feet (1426,15 M.), magnification=1000x, scale= 10 ' microns.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 67

Figure 37. Pyrite framboids and dolomite crystals. Depth=4679 feet (1426.15 M.), magnification =5000x, scale= 1 micron.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. Figure 38. Micro-calcite cement, dolomite crystals, and secondary porosity relationships. Depth=4679 feet (1426.15 M.) magnification = lOOOx, scale=10 microns.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 69

Figure 39. Dolomite dissolution and micro calcite crystals Depth=4679 feet (1426.15 M.), magnification=3000x, scale= 1 micron.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 70

. Figure 40. Dolomite dissolution and micro calcite crystals. Depth=4679 feet ,(1426,15 M),magni£ication=5000x, scale =1 micron.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 71

Figure 41. Dolomite rhombs and high intercrystaline porosity. Mg=1680 and Ca=24515. Depth=4684 feet (1427.68 M . ),magnification=500x scale=10 microns.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 72

Figure 42. Dolomite crystals with probable fluid inclusions. Notice the high secondary porosity. Depth=4686 feet (1428,29 M.), magnification=1000x, scale= 10 microns.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 73

Figure 43. Dolomite rhombs and fluid inclusions. Depth=4686 feet (1428,29 M.) magnification = 5000x, scale= 1 micron.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. Figure 44. Dolomite rhombs and secondary porosity relationship. Depth=4699 feet (1432,25 M.), magnification=100x,scale=100 microns.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 75

Figure 45. Dolomite rhombs in the pore spaces. Dolomite crystals have diffferent compositions. Large crystals have low Mg content and small crystals have high Mg content. Depth=4699 feet (1432,25 M.) , magnification=200x,scale=200 microns.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. Figure 46. Dolomite rhombs in the pore spaces. Depth=4699 feet (1432,25 M.j magnification=200x, scale=200 microns.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. Figure 47. Two sizes of dolomite crystals. At the center, large and small crystals are seen. In the small crystal, Mg content is high, in the large crystal Mg content is low.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. Figure 48. Small dolomite crystal on large dolomite crystal. SEM counts and result are given below.

Figure 47-48 Large crystal Small crystal 1 2 3 1 2 3 Mg 1518 2807 2917 12815 13209 17515 Ca (L) 17450 23939 29365 37205 35150 38423 Ca (B) 2633 3482 3989 4601 4271 4465

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 79

1) McQuire 1-22 Big Creek Field T25N R2E' Oscoda Co.,Michigan

McQuire 1-22, located in the Big Creek Field (SE SE SW),

was completed as a dry hole. In this well, the Richfield

Member is characterized by micritic limestone with little

porosity and subaqueous type-anhydrite (Figure 49).

DEPOSITIONAL EIMV. DENSITY (Pb) CORE HIOH LOW 4168 4170 ; llylotltee

Snliy^rA l* cry.

Mud atone eery IhUl .laminated

C loieU packed anhydrite ety»

4250 : Thin laminated mudelenc.

4367

Figure 49. Core description of McGuire 1-22, Oscoda County.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 80

Fi,gure 50. Micritic limestone and salt crystals. In the micritic limestone these elements have been counted; Na = 9646 Cl =90012 Mg = 505 Si = 701 Ca = 7440 As it seen besides the NaCl the samples contains a few dolomite crystals and Si which was also found in the Anderson 1-31 as a trace element. Depth=4169 feet (1270,71.m),magnification=1000x scale-10 microns."

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 81

Figure 51. Micro-calcite and salt crystals. The lithology is micro-calcitic limestone and the porosity was filled by salt crystals. Depth=4173 feet (1271,93M.) magnification= 1500x, scale= 10 microns.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 82

Figure 52. Anhydrite crystals in micritic limestone . These elements have been counted. Ca = 51318 S = 47696 Si = 578 Depth=4178 feet(1273,45M.), magnificati9 n=6 0 x, scale=100 microns.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. Figure 53. Salt crystals and partly dolomitic limestone. SEM counting results are given ; Ca = 30603 Mg = 6449 Depth=4180 feet(1274 M.), magnification=2000x, scale=10 microns.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 84

Figure 54. Dolomite crystals and micritic limestone. Triangle shape dolomite crystals (Mg = 1224 and Ca=51512). Depth=4180 feet ( 1274M.) magnification=3000x, scale=10microns.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. Figure 55. Star-shaped salt crystals (KC1). Notice the poor porosity in the sample. The following elements have been counted. Ca = 75293 Mg = 950 Cl = 32203 K = 352 Star-shaped minerals seen on the photo are probably KC1. Magnification=1000x, scale=10 microns.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 86

Figure 56. Dolomite crystals. Mg=5484 and Ca=43313 have been counted. Depth=4231 feet(1289,60M.), Magnification=1000x, scale=10 microns.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. i 87

Figure 57. Micribic limestone. No Mg has been found . Notice the intercrystaline porosity in the sample. Depth=4201 feet(1280,46M.), magnification=100x,scale=100 microns.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 88

2 0 KU 8 5 0 0 0

Figure 58. Secondary single Ca crystal in the pore space. Depth=4201feet(1280,4M), magnification =5000x, scale=l micron.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. 89

According to SEM results, the Richfield Member has a

complex diagenetic history. In the central part of the

basin, which is the major oil producing area, dolomitization

resulted in high intercrystalline porosity. The oil wells

occur in the central, deep part of basin as seen on the

structure map, are mostly productive. Some are

non productive in spite of their high porosity.

The reason is that they are either off structure or

that anhydrite beds, laterally extended in a different

interval, did not let hydrocarbons migrate upward. It seems

that different producing zones in the central part of the

basin were caused by lateral extention of anhydrite beds.

As is clearly seen, porosity, structure, and anhydrite beds

are the most important factors controlling the production

in the central part of basin. On the eastern flank of the

basin, the Richfield has a different character than in the

central part of the basin as is seen in the McQuire 1-22.

In comparing production, the eastern flank has a lower

potential of hydrocarbon accumulation. Micritic limestone

was deposited in this part of basin, which was mostly a

subtidal environment during the Richfield depositional

period. According to SEM results, poor dolomitization was

the reason for low porosity development on the east flank

of the basin. The conditions of a low energy environment of

deposition, poor dolomitization, and low porosity make the

area less important in hydrocarbon production.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. CONCLUSION

The Richfield Member of Lucas Formation was deposited

in a coastal, shallow marine setting which included sabkha

and lagonal facies. It overlies the "Black Limestone"which

represents an open marine shelf facies. Early Richfield

deposition contains some fossils such as brachiopods,

ostracods, and marine plankton. This organic-rich

lower part of Richfield could, along with the "Black

Limestone", have been the source of the hydrocarbons in

the Richfield. After the basal part of the Richfield was

deposited, the area became a restricted environment and the

salinity of water increased. In this depositional period

several cycles of emergence and submergence affected the

basin. As a result of this cyclicity, basin-wide

depositional conditions on the west flank and central part

of basin produced interbedded sabkha type sediments of

mixed carbonate and anhydrite. On the east flank of the

basin, subtidal types of limestone beds were deposited.

Sabkha-type deposits are characterized by nodular and

subaqueous-type anhydrite, algal-laminated and micritic

limestone, and dolomite beds.

Sabkha and seepage reflux-type of dolomitization

occurred by replacement of carbonate in the sabkha

environment and two types of dolomite crystals were

90

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. formed during two separate stages. High concentration of

sulfate ions inhibited the dolomitization in the eastern

flank of the basin. In the upper part of the Richfield,

a thick accumulation of "Big Anhydrite" indicates that

a hypersaline lagoon depositional environment covered the

basin. This anhydrite bed sealed the previous Richfield

deposits as a cap rock. Above the "Big Anhydrite" the

Richfield is characterized by a carbonate bed. It was

deposited in less saline water that again flooded the

basin.

Hydrocarbon production mostly comes from the porous

dolomitic carbonate zones. Trapping by various anhydrite

beds on structurally high positions yield the production

from the different dolomitic zones. More detail mapping of

local facies distribution and geologic or geophysical

mapping of structures should help to increase oil and gas

production in the near future in the Michigan basin.

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. APPENDIX

List of Wells

Name County T rR,S. Q.Sec Permit No

1-35 Morley Arenac 19N,3Ef 35 NE NW SW 35969

1-33 A.Edwin Arenac 19Nr5E,33 SWNW NW SW 32397

1-30 Maday Arenac 19N,4E,30 NW NE NW 35566

1-29 Magyar Arenac 19N,4E,29 NW SW NW 34313

1-30 K.Ronald Arenac 19N,4E,30 NWNENE 34679

1 B.Peter Arenac 19N,4E,30 NW NW NE 33868

1-29 Ackerman Arenac 19N,4E,29 NW NW NW 34163

1-31 Greniuk Arenac 18N,4E,31 CNW SE 36495

1- 1. C ,Adams Bay 18N,3E, 1 (IE NW NW 33618

1-21 Hugo Bay 14N,6E,21 NW NE NE 33753

2- 2 Kryszak Bay 14N,6E,22 NW NE NE 34500

1 - 7 Gallagher Clare 17N,4W, 7 NW NW NE 33097

3-18 Hamilton Clare 19N,3W, 7 SE NE NE 34330

1-20 Prackelton Clare 18N,5W,20 SE NW NE 32858

1- 8 Harrington Clare 17N,3W, 8 SWNW NW SW 32546

5-7 Summerfield Clare ’ 20N,5W, 7 NE SW NW 34706

2-7 Summerfield Clare 20N,5W, 7 NWNW NW 34698

4-7 Summerfield Clare 20N,5W/ 7 NW SE NW 34700

1-30 Dale L.Bray Clare 20N,6W,30 NE SW NE 32385

5-29 Beulah June Clare 20N,6W,29 NE SW NE 32384

4-29 Blackledge Clare 20N,6W,29 SENE NW 32296

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13 St.Bea.Cr. Crawford 25N,4W, 7 SWNE SE 33710

1-33 St.Lovells Crawford 27N, 1W, 33 CSWNW 35726

4-25 Helveston Crawford 25N,2W,25 NE SW NE 34905

1-17 S.Branch Crawford 25N,2W,17 SE NENW 35072

1- 3 Mc.Crandell Gladwin 17N,1E, 3 SE SE NE 34374

1-12 W. Butman Gladvin 20N,1W,12 NE SE SW 35746

1/A Smith Vera Isabella 14N,3w, 2 NE SW NW 35540

1-31 Anderson Isabella

1-12 R.Thelma Mecosta 16N,8W 12 NW NW NE 35426

9-31 Milhoek Missaukee 22N/6W/31 NW NW SW 33819

11-31 Milhoek Missaukee 22N,6W,31 NW SWSW 34981

4-140 N.Unit TR. Missaukee 24N,5W,13 NW SE NW 36100

4-109 N.Unit TR. Missaukee 24N,5W,13 NW NW NW 33506

4-89 N.Unit Tr. Missaukee 24N,5W,14 33592

1-36 R.Edwards Missaukee 22n,7W,36 NWNENE 32139

2-36 F.powers Missaukee 22N,7Wf 36 NW SE NE 32223

9-36 W.Muellen Missaukee 22N,7Wf36 NW SE NW 34005

8-36 P.school Missaukee 22N,7Wf 36 NW NW SE 34000

3-36 AN.Tacoma Missaukee 22N,7Wf 36 NW NW NE 32421

1-31 Fritsch,B. Montcalm 9N,5W,31 NE SE SE 35474

1-27/A Lutz Nevaygo 16N,11W,27 SW NW SE 34906

1-15 B.Ronald Ogemaw 22N,IE,15 SE NE NW 34701

1-30 M.Norman Osceola 17N,8Wr 30 NW NE SW 33466

1- 4 Leach Osceola 17N,9W, 4 SW SE SE 35025

1-30 R.Quart Osceola 20N,7W,30 SE SE SE 35089

1-27 Mc.Cormick Osceola 18N,8W,27 SWNE NW 33813

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1-19 Gerber Osceola 17N,10W,19 SW SE SW 35997

1-15 Schalm Osceola 17N,10W,15 SE SE SE 33505

1-23 USA Big.Cr. Oscoda 25N,2E,23 SWNESW 34748

1-22 USA Big Cr. Oscoda 25n,2E,22 SW SW SE 35131

7-23 USA Big Cr. Oscoda 25N,2E,23 SE NE SE 35765

2-23 USA Big Cr. Oscoda 25N,2E,23 NE SW SE 34749

1-22 Me.Quire Oscoda 25N,2E,22 SE SESW 35069

48-15 Helen Unit Roscommon 24N,1W,30 SW NE NE 35443

50-15 Helen Unit Roscommon 24N,1W,28 SW NW NW 35385

1-28 St.Backus Roscommon 22N,2W,28 NW NE SE 36310

2-27 St.Backus Roscommon 22N,2W,27 NE SW NW 36269

6 Enterp.Unit Roscommon 23N,4W,18 SE SW NW 35767

16-6 Norwich U. Roscommon 24N,4W, 7 S2 SW NE 33683

F-l St.Lyons Roscommon 24N,4W, 6 S2 S2 NW 30978

17-6 Norwich U. Roscommon 24N,4W,18 S2 NW NE 34061

1-20 St.Lyons Roscommon 24N,4W,20 SE SE SE 36166

13-6 Norwich U. Roscommon 24N,4W, 7 33339

15-6 Norwich U. Roscommon 24N,4W,18 SW SW NW 33681

1-17 Ida Hogan Roscommon 22N,4W,17 NE NE NW 32356

1- 8 Ida Hogan Roscommon 22N,4W, 8 NE SE SW 32355

Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. BIBLIOGRAPHY

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American Association of Petroleum Geologists Bulletin, 67, 2156.

Kendall,C. and E.Skipwith (1968). Recent Algal Mats of a Persian Gulf Lagoon. Journal of Sedimentary Petrology, 38, 1040-1058.

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Reproduced with permission of the copyright owner. Further reproduction prohibited without permission.