Applying Pesticides Correctly DATE
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Propoxur United States Environmental Protection Agency
United States Prevention, Pesticides EPA738-R-97-009 Environmental Protection And Toxic Substances August 1997 Agency (7508W) Reregistration Eligibility Decision (RED) PROPOXUR UNITED STATES ENVIRONMENTAL PROTECTION AGENCY WASHINGTON, D.C. 20460 OFFICE OF PREVENTION, PESTICIDES AND TOXIC SUBSTANCES CERTIFIED MAIL Dear Registrant: I am pleased to announce that the Environmental Protection Agency has completed its reregistration eligibility review and decisions on the pesticide chemical case propoxur. The enclosed Reregistration Eligibility Decision (RED) contains the Agency's evaluation of the data base of this chemical, its conclusions of the potential human health and environmental risks of the current product uses, and its decisions and conditions under which these uses and products will be eligible for reregistration. The RED includes the data and labeling requirements for products for reregistration. It may also include requirements for additional data (generic) on the active ingredient to confirm the risk assessments. To assist you with a proper response, read the enclosed document entitled "Summary of Instructions for Responding to the RED." This summary also refers to other enclosed documents which include further instructions. You must follow all instructions and submit complete and timely responses. The first set of required responses is due 90 days from the receipt of this letter. The second set of required responses is due 8 months from the date of receipt of this letter. Complete and timely responses will avoid the Agency taking the enforcement action of suspension against your products. If you have questions on the product specific data requirements or wish to meet with the Agency, please contact the Special Review and Reregistration Division representative Bonnie Adler (703) 308-8523. -
2,4-Dichlorophenoxyacetic Acid
2,4-Dichlorophenoxyacetic acid 2,4-Dichlorophenoxyacetic acid IUPAC (2,4-dichlorophenoxy)acetic acid name 2,4-D Other hedonal names trinoxol Identifiers CAS [94-75-7] number SMILES OC(COC1=CC=C(Cl)C=C1Cl)=O ChemSpider 1441 ID Properties Molecular C H Cl O formula 8 6 2 3 Molar mass 221.04 g mol−1 Appearance white to yellow powder Melting point 140.5 °C (413.5 K) Boiling 160 °C (0.4 mm Hg) point Solubility in 900 mg/L (25 °C) water Related compounds Related 2,4,5-T, Dichlorprop compounds Except where noted otherwise, data are given for materials in their standard state (at 25 °C, 100 kPa) 2,4-Dichlorophenoxyacetic acid (2,4-D) is a common systemic herbicide used in the control of broadleaf weeds. It is the most widely used herbicide in the world, and the third most commonly used in North America.[1] 2,4-D is also an important synthetic auxin, often used in laboratories for plant research and as a supplement in plant cell culture media such as MS medium. History 2,4-D was developed during World War II by a British team at Rothamsted Experimental Station, under the leadership of Judah Hirsch Quastel, aiming to increase crop yields for a nation at war.[citation needed] When it was commercially released in 1946, it became the first successful selective herbicide and allowed for greatly enhanced weed control in wheat, maize (corn), rice, and similar cereal grass crop, because it only kills dicots, leaving behind monocots. Mechanism of herbicide action 2,4-D is a synthetic auxin, which is a class of plant growth regulators. -
Common and Chemical Names of Herbicides Approved by the WSSA
Weed Science 2010 58:511–518 Common and Chemical Names of Herbicides Approved by the Weed Science Society of America Below is the complete list of all common and chemical of herbicides as approved by the International Organization names of herbicides approved by the Weed Science Society of for Standardization (ISO). A sponsor may submit a proposal America (WSSA) and updated as of September 1, 2010. for a common name directly to the WSSA Terminology Beginning in 1996, it has been published yearly in the last Committee. issue of Weed Science with Directions for Contributors to A herbicide common name is not synonymous with Weed Science. This list is published in lieu of the selections a commercial formulation of the same herbicide, and in printed previously on the back cover of Weed Science. Only many instances, is not synonymous with the active ingredient common and chemical names included in this complete of a commercial formulation as identified on the product list should be used in WSSA publications. In the absence of label. If the herbicide is a salt or simple ester of a parent a WSSA-approved common name, the industry code number compound, the WSSA common name applies to the parent as compiled by the Chemical Abstracts Service (CAS) with compound only. CAS systematic chemical name or the systematic chemical The chemical name used in this list is that preferred by the name alone may be used. The current approved list is also Chemical Abstracts Service (CAS) according to their system of available at our web site (www.wssa.net). -
WO 2012/125779 Al 20 September 2012 (20.09.2012) P O P C T
(12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (10) International Publication Number (43) International Publication Date WO 2012/125779 Al 20 September 2012 (20.09.2012) P O P C T (51) International Patent Classification: CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, DO, A01N 43/90 (2006.01) DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IS, JP, KE, KG, KM, KN, KP, KR, (21) International Application Number: KZ, LA, LC, LK, LR, LS, LT, LU, LY, MA, MD, ME, PCT/US20 12/029 153 MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, (22) International Filing Date: OM, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SC, SD, 15 March 2012 (15.03.2012) SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (25) Filing Language: English (84) Designated States (unless otherwise indicated, for every (26) Publication Language: English kind of regional protection available): ARIPO (BW, GH, (30) Priority Data: GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, SZ, TZ, 61/453,202 16 March 201 1 (16.03.201 1) US UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, MD, RU, TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, (71) Applicant (for all designated States except US) : DOW DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, AGROSCIENCES LLC [US/US]; 9330 Zionsville Road, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, Indianapolis, IN 46268 (US). -
488 Subpart A—Organic Pesticide Chemicals Manufacturing
§ 455.11 40 CFR Ch. I (7–1–12 Edition) chemical products and be considered a this subpart are applicable to dis- ‘‘stand-alone’’ PFPR facility. charges resulting from the manufac- ture of the following organic active in- [43 FR 17776, Apr. 25, 1978, as amended at 50 FR 40701, Oct. 4, 1985; 51 FR 44911, Dec. 15, gredients: Aldrin, BHC, Captan, 1986; 58 FR 50689, Sept. 28, 1993; 61 FR 57548, Chlordane, DDD, DDE, DDT, Dichloran, Nov. 6, 1996] Dieldrin, Endosulfan, Endrin, Hepta- chlor, Lindane, Methoxychlor, Mirex, Subpart A—Organic Pesticide PCNB, Toxaphene, Trifluralin, Chemicals Manufacturing Azinphos Methyl, Demeton-O, Demeton-S, Diazinon, Disulfoton, Mal- Subcategory athion, Parathion Methyl, Parathion Ethyl, Aminocarb, Carbaryl, SOURCE: 43 FR 44846, Sept. 29, 1978, unless Methiocarb, Mexacarbate, Propoxur, otherwise noted. Barban, Chlorpropham, Diuron, Fenuron, Fenuron-TCA, Linuron, § 455.11 Compliance date for pretreatment standards for existing Monuron, Monuron-TCA, Neubron, sources (PSES). Propham, Swep, 2,4-D, Dicamba, Silvex, 2,4,5-T, Siduron, Perthane, and All discharges subject to Dicofol. pretreatment standards for existing (c) The intermediates used to manu- sources (PSES) in subparts A and B of facture the active ingredients and ac- this part must comply with the stand- tive ingredients used solely in experi- ards no later than September 28, 1993. mental pesticides are excluded from [61 FR 57549, Nov. 6, 1996] coverage in this subpart. Insecticidal pathogenic organisms such as Bacillus § 455.20 Applicability; description of thuringiensis, insect growth hormones, the organic pesticide chemicals plant extracts such as pyrethrins; sex manufacturing subcategory. attractants and botanicals such as Ro- (a) For the purpose of calculating and tenone are also excluded from BPT applying effluent limitations for COD, coverage in this subpart. -
COMBINED LIST of Particularly Hazardous Substances
COMBINED LIST of Particularly Hazardous Substances revised 2/4/2021 IARC list 1 are Carcinogenic to humans list compiled by Hector Acuna, UCSB IARC list Group 2A Probably carcinogenic to humans IARC list Group 2B Possibly carcinogenic to humans If any of the chemicals listed below are used in your research then complete a Standard Operating Procedure (SOP) for the product as described in the Chemical Hygiene Plan. Prop 65 known to cause cancer or reproductive toxicity Material(s) not on the list does not preclude one from completing an SOP. Other extremely toxic chemicals KNOWN Carcinogens from National Toxicology Program (NTP) or other high hazards will require the development of an SOP. Red= added in 2020 or status change Reasonably Anticipated NTP EPA Haz list COMBINED LIST of Particularly Hazardous Substances CAS Source from where the material is listed. 6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10- hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide Acutely Toxic Methanimidamide, N,N-dimethyl-N'-[2-methyl-4-[[(methylamino)carbonyl]oxy]phenyl]- Acutely Toxic 1-(2-Chloroethyl)-3-(4-methylcyclohexyl)-1-nitrosourea (Methyl-CCNU) Prop 65 KNOWN Carcinogens NTP 1-(2-Chloroethyl)-3-cyclohexyl-1-nitrosourea (CCNU) IARC list Group 2A Reasonably Anticipated NTP 1-(2-Chloroethyl)-3-cyclohexyl-1-nitrosourea (CCNU) (Lomustine) Prop 65 1-(o-Chlorophenyl)thiourea Acutely Toxic 1,1,1,2-Tetrachloroethane IARC list Group 2B 1,1,2,2-Tetrachloroethane Prop 65 IARC list Group 2B 1,1-Dichloro-2,2-bis(p -chloropheny)ethylene (DDE) Prop 65 1,1-Dichloroethane -
Solventless Formulation of Triclopyr Butoxyethyl
(19) & (11) EP 1 983 829 B1 (12) EUROPEAN PATENT SPECIFICATION (45) Date of publication and mention (51) Int Cl.: of the grant of the patent: A01N 43/40 (2006.01) A01N 25/30 (2006.01) 13.01.2010 Bulletin 2010/02 A01N 25/04 (2006.01) A01P 13/00 (2006.01) (21) Application number: 06837962.7 (86) International application number: PCT/US2006/044751 (22) Date of filing: 17.11.2006 (87) International publication number: WO 2007/094836 (23.08.2007 Gazette 2007/34) (54) SOLVENTLESS FORMULATION OF TRICLOPYR BUTOXYETHYL ESTER LÖSUNGSMITTELFREIE FORMULIERUNG VON TRICLOPYR-BUTOXYETHYLESTER FORMULE SANS SOLVANT D’ESTER DE BUTOXYETHYLE DU TRICYCLOPYR (84) Designated Contracting States: • POMPEO, Michael, P. DE ES FR GB IT Sumter, SC 29150 (US) (30) Priority: 15.02.2006 US 773417 P (74) Representative: Weiss, Wolfgang Weickmann & Weickmann (43) Date of publication of application: Patentanwälte 29.10.2008 Bulletin 2008/44 Postfach 86 08 20 81635 München (DE) (73) Proprietors: • Dow AgroSciences LLC (56) References cited: Indianapolis, WO-A-96/28027 WO-A-2004/093546 Indiana 46268-1054 (US) US-A1- 5 466 659 • Jensen, Jeffrey, Lee Brownsburg IN 46112 (US) • BOVEY RODNEY W ET AL: "Honey mesquite (Prosopis glandulosa) control by synergistic (72) Inventors: action of clopyralid: Triclopyr mixtures" WEED • JENSEN, Jeffrey, Lee SCIENCE, vol. 40, no. 4, 1992, pages 563-567, Brownsburg, IN 46112 (US) XP009080681 ISSN: 0043-1745 • KLINE, William, N., III • BEBAWI F F ET AL: "Impact of foliar herbicides Duluth, GA 30096 (US) on pod and seed behaviour of rust-infected • BURCH, Patrick, L. rubber vine (Cryptostegia grandiflora) plants" Christiansburg, VA 24073 (US) PLANT PROTECTION QUARTERLY, vol. -
Herbicide Mode of Action Table High Resistance Risk
Herbicide Mode of Action Table High resistance risk Chemical family Active constituent (first registered trade name) GROUP 1 Inhibition of acetyl co-enzyme A carboxylase (ACC’ase inhibitors) clodinafop (Topik®), cyhalofop (Agixa®*, Barnstorm®), diclofop (Cheetah® Gold* Decision®*, Hoegrass®), Aryloxyphenoxy- fenoxaprop (Cheetah®, Gold*, Wildcat®), fluazifop propionates (FOPs) (Fusilade®), haloxyfop (Verdict®), propaquizafop (Shogun®), quizalofop (Targa®) Cyclohexanediones (DIMs) butroxydim (Factor®*), clethodim (Select®), profoxydim (Aura®), sethoxydim (Cheetah® Gold*, Decision®*), tralkoxydim (Achieve®) Phenylpyrazoles (DENs) pinoxaden (Axial®) GROUP 2 Inhibition of acetolactate synthase (ALS inhibitors), acetohydroxyacid synthase (AHAS) Imidazolinones (IMIs) imazamox (Intervix®*, Raptor®), imazapic (Bobcat I-Maxx®*, Flame®, Midas®*, OnDuty®*), imazapyr (Arsenal Xpress®*, Intervix®*, Lightning®*, Midas®* OnDuty®*), imazethapyr (Lightning®*, Spinnaker®) Pyrimidinyl–thio- bispyribac (Nominee®), pyrithiobac (Staple®) benzoates Sulfonylureas (SUs) azimsulfuron (Gulliver®), bensulfuron (Londax®), chlorsulfuron (Glean®), ethoxysulfuron (Hero®), foramsulfuron (Tribute®), halosulfuron (Sempra®), iodosulfuron (Hussar®), mesosulfuron (Atlantis®), metsulfuron (Ally®, Harmony®* M, Stinger®*, Trounce®*, Ultimate Brushweed®* Herbicide), prosulfuron (Casper®*), rimsulfuron (Titus®), sulfometuron (Oust®, Eucmix Pre Plant®*, Trimac Plus®*), sulfosulfuron (Monza®), thifensulfuron (Harmony®* M), triasulfuron (Logran®, Logran® B-Power®*), tribenuron (Express®), -
40 CFR Ch. I (7–1–18 Edition) § 455.61
§ 455.61 40 CFR Ch. I (7–1–18 Edition) from: the operation of employee show- § 455.64 Effluent limitations guidelines ers and laundry facilities; the testing representing the degree of effluent of fire protection equipment; the test- reduction attainable by the applica- ing and emergency operation of safety tion of the best available tech- showers and eye washes; or storm nology economically achievable water. (BAT). (d) The provisions of this subpart do Except as provided in 40 CFR 125.30 not apply to wastewater discharges through 125.32, any existing point from the repackaging of microorga- source subject to this subpart must nisms or Group 1 Mixtures, as defined achieve effluent limitations rep- under § 455.10, or non-agricultural pes- resenting the degree of effluent reduc- ticide products. tion attainable by the application of the best available technology economi- § 455.61 Special definitions. cally achievable: There shall be no dis- Process wastewater, for this subpart, charge of process wastewater pollut- means all wastewater except for sani- ants. tary water and those wastewaters ex- § 455.65 New source performance cluded from the applicability of the standards (NSPS). rule in § 455.60. Any new source subject to this sub- § 455.62 Effluent limitations guidelines part which discharges process waste- representing the degree of effluent water pollutants must meet the fol- reduction attainable by the applica- lowing standards: There shall be no dis- tion of the best practicable pollut- charge of process wastewater pollut- ant control technology (BPT). ants. Except as provided in 40 CFR 125.30 through 125.32, any existing point § 455.66 Pretreatment standards for existing sources (PSES). -
Reduction of Nitroaromatic Pesticides with Zero-Valent Iron
Chemosphere 54 (2004) 255–263 www.elsevier.com/locate/chemosphere Reduction of nitroaromatic pesticides with zero-valent iron Young-Soo Keum, Qing X. Li * Department of Molecular Biosciences and Bioengineering, University of Hawaii, 1955 East-West Road, Ag Sci 218, Honolulu, HI 96822, USA Received 5 February 2003; received in revised form 4 June 2003; accepted 4 August 2003 Abstract Reduction of eleven nitroaromatic pesticides was studied with zero-valent iron powder. Average half-lives ranged from 2.8 to 6.3 h and the parent compounds were completely reduced after 48–96 h. The di-nitro groups of the 2,6- dinitroaniline herbicides were rapidly reduced to the corresponding diamines, with a negligible amount of partially reduced monoamino or nitroso products. Low levels of de-alkylated products were observed after 10 days. The nitro group of the organophosphorus insecticides was reduced dominantly to the monoamines but in a slower rate than the 2,6-dinitroanilines. A trace amount of oxon products was found. Reduction of nitro to amino was also the predominant reaction for the diphenyl ether herbicides. Aromatic de-chlorination and de-alkylation were minor reactions. These amine products were more stable than the parent compounds and 60% or more of the amines were detected after two weeks. Humic acid decreased the reduction rates of pendimethalin, and dichlone (a known quinone redox mediator) counteracted the effect of humic acid on the reactivity. Storage of iron powder under air decreased the reactivity very rapidly due to iron oxidation. Repeated use of iron powder also showed similar results. The reduced activity of air- oxidized iron was recovered by purging with hydrogen, but not nitrogen. -
Environmental Properties of Chemicals Volume 2
1 t ENVIRONMENTAL 1 PROTECTION Esa Nikunen . Riitta Leinonen Birgit Kemiläinen • Arto Kultamaa Environmental properties of chemicals Volume 2 1 O O O O O O O O OO O OOOOOO Ol OIOOO FINNISH ENVIRONMENT INSTITUTE • EDITA Esa Nikunen e Riitta Leinonen Birgit Kemiläinen • Arto Kultamaa Environmental properties of chemicals Volume 2 HELSINKI 1000 OlO 00000001 00000000000000000 Th/s is a second revfsed version of Environmental Properties of Chemica/s, published by VAPK-Pub/ishing and Ministry of Environment, Environmental Protection Department as Research Report 91, 1990. The pubiication is also available as a CD ROM version: EnviChem 2.0, a PC database runniny under Windows operating systems. ISBN 951-7-2967-2 (publisher) ISBN 952-7 1-0670-0 (co-publisher) ISSN 1238-8602 Layout: Pikseri Julkaisupalvelut Cover illustration: Jussi Hirvi Edita Ltd. Helsinki 2000 Environmental properties of chemicals Volume 2 _____ _____________________________________________________ Contents . VOLUME ONE 1 Contents of the report 2 Environmental properties of chemicals 3 Abbreviations and explanations 7 3.1 Ways of exposure 7 3.2 Exposed species 7 3.3 Fffects________________________________ 7 3.4 Length of exposure 7 3.5 Odour thresholds 8 3.6 Toxicity endpoints 9 3.7 Other abbreviations 9 4 Listofexposedspecies 10 4.1 Mammais 10 4.2 Plants 13 4.3 Birds 14 4.4 Insects 17 4.5 Fishes 1$ 4.6 Mollusca 22 4.7 Crustaceans 23 4.8 Algae 24 4.9 Others 25 5 References 27 Index 1 List of chemicals in alphabetical order - 169 Index II List of chemicals in CAS-number order -
PUBLIC WATER SUPPLY SAMPLING PLAN for Contaminants with a Vermont Health Advisory – May 2020
PROPOSED PUBLIC WATER SUPPLY SAMPLING PLAN For Contaminants with a Vermont Health Advisory – May 2020 Vermont Department of Environmental Conservation Drinking Water & Groundwater Protection Division A Plan to Sample for Chemicals with a Vermont Health Advisory As required by Act 21 (2019), Section 10(b), the Secretary of the Agency of Natural Resources, on or before January 1, 2020, must publish for public review and comment a plan to collect data for contaminants in drinking water from public community water systems and all non-transient non-community water systems, for which a health advisory has been established, but no Maximum Contaminant Level has been adopted. These health advisories are referred to as Vermont Health Advisories (VHAs) in this document. 1 | P a g e TABLE OF CONTENTS I. Executive Summary …………………………………………………………………………………………..Page 3 II. Background ……………………………………………………………………………………………………… Page 4 III. Determining the VHA contaminants for sampling at public water systems ………..Page 6 IV. Sampling Considerations …..…………………………………………………………………………….. Page 10 V. Proposed Sampling Plan ………………………………………………………………………….………..Page 12 Attachments Table 1 Complete List of Vermont Health Advisories (VHAs) …………………………………………..Page 13 Table 2 Proposed List of VHAs with Potential Concern ……………………………………………………Page 18 2 | P a g e I. Executive Summary The Secretary of the Agency of Natural Resources was tasked with developing a sampling plan for public review, for certain drinking water contaminants that have an established health advisory, also known as the Vermont Health Advisory (VHA) but have no Maximum Contaminant Level (MCL). This Sampling Plan (Plan) is targeted to public community and public non- transient non-community water systems. To provide context for public water system regulation, and standards that apply, a discussion of how VHAs and MCLs are determined is given.