Materials 2014, 7, 2833-2881; doi:10.3390/ma7042833 OPEN ACCESS materials ISSN 1996-1944 www.mdpi.com/journal/materials Review Zinc Oxide—From Synthesis to Application: A Review Agnieszka Kołodziejczak-Radzimska * and Teofil Jesionowski Institute of Chemical Technology and Engineering, Faculty of Chemical Technology, Poznan University of Technology, M. Sklodowskiej-Curie 2, PL-60965 Poznan, Poland; E-Mail:
[email protected] * Author to whom correspondence should be addressed; E-Mail:
[email protected]; Tel.: +48-61-665-3626; Fax: +48-61-665-3649. Received: 17 December 2013; in revised form; 25 March 2014 / Accepted: 27 March 2014 / Published: 9 April 2014 Abstract: Zinc oxide can be called a multifunctional material thanks to its unique physical and chemical properties. The first part of this paper presents the most important methods of preparation of ZnO divided into metallurgical and chemical methods. The mechanochemical process, controlled precipitation, sol-gel method, solvothermal and hydrothermal method, method using emulsion and microemulsion enviroment and other methods of obtaining zinc oxide were classified as chemical methods. In the next part of this review, the modification methods of ZnO were characterized. The modification with organic (carboxylic acid, silanes) and inroganic (metal oxides) compounds, and polymer matrices were mainly described. Finally, we present possible applications in various branches of industry: rubber, pharmaceutical, cosmetics, textile, electronic and electrotechnology, photocatalysis were introduced. This review provides useful information for specialist dealings with zinc oxide. Keywords: zinc oxide; synthesis; modification; application 1. Introduction Zinc oxide, with its unique physical and chemical properties, such as high chemical stability, high electrochemical coupling coefficient, broad range of radiation absorption and high photostability, is a multifunctional material [1,2].