Pesticide Standards Reference Guide
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Techlab - Matériaux de référence certifiés et Equipements de laboratoire - www.techlab.fr Pesticide Standards Reference Guide AccuStandard® TECHLAB www.techlab.fr Tél. (33) 03 87 75 54 29 Techlab - Matériaux de référence certifiés et Equipements de laboratoire - www.techlab.fr Over 6,000 Standards from Abamectin to Ziram Welcome to AccuStandard's Pesticide Desk Reference Guide This guide includes the following for each individual Pesticide: ■ Chemical name ■ Structure ■ CAS number ■ Molecular formula ■ Molecular weight ■ Physical state Included for most: ■ Solvent solubility ■ Specific gravity ■ Melting or Boiling point ■ Flash point ■ Common Synonyms A CAS number index is included for easy reference on page 75. 700 pesticides are available as single component solutions and neats. Also included are standards for over 50 EPA and international methods. AccuStandard is recognized for the widest range of Reference Standards. Organics Inorganics ■ QC Standards ■ Explosives ■ ICP ■ PCBs ■ Fuels & Hydrocarbons ■ ICP/MS ■ PBDEs ■ Plastic Additives ■ AA ■ Dioxins ■ Allergens ■ Ion Chrom ■ PAHs ■ Dyes ■ EPA Methods ■ Pesticides ■ EPA Methods ■ Wet Chemistry ■ VOCs ■ Petrochemicals ■ OrganoMetallics ■ Phthalates (including 100 ASTM methods) ■ Custom Formulations and much more. Master Catalog © AccuStandard, Inc. 2010 TECHLAB www.techlab.fr Tél. (33) 03 87 75 54 29 Techlab - Matériaux de référence certifiés et Equipements de laboratoire - www.techlab.fr Table of Contents Individual Neats and Solutions 1-74 CAS Number Index 75 Triazines and Metabolites 76 Pesticide & Herbicide Kits 77 EPA Pesticide Method - Table of Content 78 CLPs 79 EPA Method 500 Series 79-88 EPA Method 600 Series 89-92 EPA Method 1300 Series 93 EPA Method 1600 Series 94-97 EPA Method 8000 Series 98-104 EU Methods and other Methodologies 105-108 ISO Guide 34 with Scope of Accredition 109-110 Contact us for Synthesis of rare Pesticides and Metabolites Visit our website to search for additional pesticide formulations or contact our Technical Service Department TECHLAB www.techlab.fr Tél. (33) 03 87 75 54 29 Techlab - Matériaux de référence certifiés et Equipements de laboratoire - www.techlab.fr Purchasing Pesticide Standards Buying an Analytical Reference Standard in Solution Rather than Making it from Neats Good scientific operations, and also many auditors, urge analytical chemists to purchase analytical reference standards from a manufacturer of standards that is accredited to ISO 17025. There are three reasons for this: 1. Safety - Using solutions rather than neats reduces the laboratory personnel’s intensity and frequency of exposure to chemicals. The less time a person is exposed to chemicals, the less risk for accidents. Further, neats are usually not fully consumed in a single use, rather, they are partially used, then stored, and then used again. This increases the potential for exposure from the chemical (as well as the risk of contamination, cost of expired dates and disposal and other risks). 2. Certification - AccuStandard is accredited to quality certifications including ISO 9001:2008, ISO/IEC 17025 and ISO Guide 34 for producing and certifying chemical reference standards. In addition, the customer’s ISO certification and laboratory procedures often require that an independent party manufacture calibration standards (rather than being manufactured by the customer’s laboratory). This promotes sound scientific conclusions and true independence of standards. 3. Savings - Even if a larger amount of a neat is the same price as the same chemical in solution, using the neat compound is not cheaper than using solutions. Dilution and sample preparation time is required. Purchasing Neat Pesticides There are two ways to purchase neat standards: 1) exact weight and 2) nominal weight. With exact weight, the standards will ship with the exact weight (to 3 significant figures) taped on the label over the nominal weight. For example, the label on a vial of 5 milligrams of a neat will have the nominal weight (5 mg) printed on the label. Over it will be taped the printout from the balance indicating the exact weight (for example, 0.005 g). There is a small additional charge for this service. To order, indicate on the order “X-WT” as a separate line item under the catalog number of the neat you wish to purchase. If “X-WT” is not specified on the order, the neat standards ship with a nominal weight shown on the label. AccuStandard routinely overfills each vial by up to 10%. Tranfering Small Amounts of Neats, the procedure is as follows: 1. Wipe the outside of the vial (containing the Standard) clean and dry (including the cap). 2. Weigh the entire unit on an analytical balance. Record the weight to the nearest 0.1 mg. 3. Carefully transfer the contents to a volumetric flask using a suitable solvent. Rinse the cap and vial several times to assure a complete transfer. 4. Dry inside and outside of the vial and cap with mild heat or inert gas. 5. Weigh the empty dry vial and cap on the same analytical balance to the nearest 0.1 mg. The difference is amount of material transferred. TECHLAB www.techlab.fr Tél. (33) 03 87 75 54 29 Techlab - Matériaux de référence certifiés et Equipements de laboratoire - www.techlab.fr Pesticide Standards P-615 - Abamectin Abamectin Acetamiprid Acifluorfen methyl ester P-820 - Acetamiprid H H3C N-((6-chloro-3-pyridinyl)methyl)-N’-cyano-N- Methyl 5-(2-Chloro-alpha,alpha,alpha-trifluoro-P-246 - Acifluorfen methyl ester H H CH3 H HO R OH O O methylethanimidamide o-tolyloxy)-2-nitrobenzoate O O O H CH3 CH3 H H H H H H CH3 O OCH3 OCH3 H3C + H H CN F3C N - O O N N O (i) R = CH(CH ) H 3 2 OH O CH3 O CH Cl N 3 C O CH Cl O (ii) R = H3C CH2CH3 H 3 H H CAS 135410-20-7 MFC10 HC1110ClNH114ClN4 MW 222.67 OH 3 C15H9ClF3NO5 PS S SOL H, D, AMol. SG Wt.: 1.33 222.67 g/cm MP 98 - 99 °C CAS 50594-67-7 MFMol. C 15Wt.:H9 ClF375.683NO5 MW 375.69 PS S SG 1.47 g/cm3 MP N/A BP 392 °C CAS 71751-41-2 MF C H O / C H O BP ~350 °C FP 167 °C 48 72 14 47 70 14 FP 191 °C MW 873.09 / 859.06 PS S SOL T, A, IPA Matrix Cat. No. Unit SG 1.18 g/cm3 MP 165 °C BP N/A FP >150 °C Matrix Cat. No. Unit 100 µg/mL in AcCN P-820S-CN 1 mL Matrix Cat. No. Unit Neat P-246N 10 mg Neat P-615N 10 mg P-465 - Acetochlor 100 µg/mL in MeOH P-246S 1 mL Acetochlor 100 µg/mL in MeOH P-615S 1 mL 2-Chloro-N-ethoxymethyl-6’-ethylacet-o-toluidide Acrinathrin CH3 Abate (S)-(alpha)-cyano-3-phenoxybenzyl (Z)-(1R,3S)-2,2- O dimethyl-3-[2-(2,2,2-trifluoro-1-trifluoromethylethoxy- O,O,O’O’-TetramethylP-101 - Abate/Temephos O,O’-thiodi-p-phenylene P-842 - Acrinathrin carbonyl)vinyl]cyclopropanecarboxylate bis(phosphorothioate) Cl N CH3 H3C CH 3 O O CH H C O CF3 H H 3 3 H3C O C C C F3C CN S P O OSP CH O O 3 CAS 34256-82-1 MF C1414HH20ClNO20ClNO2 2 MW 269.77 C O Mol. Wt.: 269.77 3 O O PS L SOL MeOH, A, EA SG 1.12 g/cm MP 11 °C O H H H CH BP 172 °C FP N/A 3 C26H21F6NO5 S Matrix Cat. No. Unit Mol. Wt.: 541.44 CAS 101007-06-1 MF C H F NO MW 541.44 CAS 3383-96-8 MF C16H20O6P2S3 MW 466.47 Neat P-465N 10 mg 26 21 6 5 3 PS S SOL H, E, A SG 1.38 g/cm3 MP 81 °C PS S SOL H SG 1.32C 16g/cmH20O6P 2 SMP3 30 °C BP 120 °C FP N/A Mol. Wt.: 466.47 100 µg/mL in MeOH P-465S 1 mL BP ~230 °C FP >230 °C Matrix Cat. No. Unit Matrix Cat. No. Unit Neat P-101N 10 mg Acifluorfen ∆ 100 µg/mL in AcCN P-842S-CN 1 mL P-245 - Acifluorfen 100 µg/mL in MeOH P-101S 1 mL 5-(2-Chloro-alpha,alpha,alpha-trifluoro-o-tolyloxy)- 2-nitrobenzoic acid Admiral see Pyriproxyfen Affirm see Abamectin Acarol see Bromopropylate O OH Agritox see Trichloronate Accent see Nicosulfuron F3C NO2 P-102 - Alachlor P-200 - Acephate Alachlor Acephate 2-Chloro-2’,6’-diethyl-N-methoxymethylacetanilide O,S-Dimethyl acetylphosphoramidothioate O O Cl CAS 50594-66-6 MF C H ClF NO MW 383.65 H3C Cl O C14H147ClF63NO53 5 O N O PS S SOL A, H SGMol. 1.47 Wt.: g/cm 361.663 MP 124 - 125 °C BP 422 °C FP 209 °C OP NH H3C CH3 Matrix Cat. No. Unit S Neat P-245N 10 mg CAS 15972-60-8 MF C H ClNO MW 269.77 C H14 ClNO20 2 100 µg/mL in MeOH P-245S 1 mL 3 14 20 2 CAS 30560-19-1 MF C4H10NO3PS MW 183.17 PS S SG 1.12 g/cmMol. MP Wt.: 39 269.77 - 42 °C BP 404 °C C34H10NO3PS PS S SG 1.35 g/cmMol. MPWt.: 88 183.17 °C BP N/A FP N/A 100 µg/mL in AcCN P-245S-CN 1 mL FP 198 °C Matrix Cat. No. Unit Matrix Cat. No. Unit Neat P-200N 10 mg Neat P-102N 10 mg 100 µg/mL in Acetone P-200S-A 1 mL 100 µg/mL in MeOH P-102S 1 mL Property Key Solubility Key (SOL) CAS Chemical Abstract A Acetone Service Number CN Acetonitrile (AcCN) MF Molecular Formula D Methlyene chloride MW Molecular Weight DMSO Dimethyl sulfoxide PS Physical State EA Ethyl acetate ∆ Pesticides containing a carboxyl group will autoesterify (Solid, Liquid) H Hexane in MeOH.