Gopper Mineralization in the Footwall Gomplex, Strathcona Mine, Sudburv, Ontario

Total Page:16

File Type:pdf, Size:1020Kb

Gopper Mineralization in the Footwall Gomplex, Strathcona Mine, Sudburv, Ontario Canadian Mineralogist Vol. 17, W.275-?A5 Q%9) GOPPERMINERALIZATION IN THE FOOTWALLGOMPLEX, STRATHCONAMINE, SUDBURV, ONTARIO M.K. ABELI, R. BUCHAN2, C.J.A. @ATS8 AND M.E. PENSTONE1 tFalconbrige Nickel Mines Ltd., Falconbridge, Ontario POM 150 sFalconbridgeMetallurgical Laboratories, Thornhill, Ontario L3T 4A8 sFalconbridgeNickel Mines Ltd,, Winniryg, Manitoba R3l AMI Arsrnecr suivantes: galdne, violarite, pyrite, bornitg chalco- cite, mill6rite, altaite, empressite,bismuth et atrgent High-grade copper mineralization has been fouud natifs et hauchecornite.Ia plupart des filons mon- in the footwall feldspathic gneiss complex at trent une zonation en sulfures, avec utr enrichis- Stathcona -ine, on the North Range of the sement en pentlandite et pyrrhotine du c6t6 de Sudbury Basin. The mineralization occupies a sys- f6ponte inf6rieure. L'alt6ration de la roche encais- tem of fractures that strike N68oW and dip to sante le long des filons s€ limfue e une lisi0re, the southwest at 45". This zone, containing an large de quelques mm, d€ hornblende, 6pidote, estimated 910,000 metric tons with a grade of chlorite, magn6tite et erenat. La min6ralisation 9.O9Vo C\t, 0.52% Ni and 34.3e/t Ag, is located r6sulte probablement de I'introduction, i tem.p€ra- from 150 to 350 m beneath the Imrptive contact, ture 6lev6e, dans un systdme de cassuresb6antes The fracture-filled veins range in tlicknes$ from a d'une zone en dilatation, d'un liquide cuprifdre few mm to 6 m and are essentially massive sulfides charg6 de pyrrhotine nickelifdre. composed of chalcopyrite and cubanite with lesser (Traduit par la R6daction) amounts of pentlandite and pyrrhotite. Minor com- ponents are magnetite and sphalerite; more rarely encountered galena, in the ore are violarite, pyrite, INTRODUCTION bomite, chalcocite, millqrils, altaite, empressite, native bismuth, native silver and hauchecornite. Sulfide zonation is evident in most veins, with The Strathcona mine, o\ryned and operated pentlandite and pyrrhotite concentrated on the foot- by Falconbridge Nickel Mines Limited, is lo- waU side. Wall-rock alteration adjacent to veins is cated in Levack Township on the northwest rim restricted to selvages a few mm wide composed of the Sudbury basin (Fig. 1). It is one of a of hornblende, epidote, chlorite, maguetite and group of nickel-copper sulfide ore deposits garnet. The introduction of a high-temperature, present alqng an 8.2 km section of the North copper-rich liquid containing a crystallizing nickel- Range of the Sudbury Irnrptive. In the mines rich pymhotite phase into a system of open fractures of the North Range, subunits of the Imrptive, in a dilatant zone is considered tle most likelv going from hangtng wall. to footwall, includb mode of genesis. felsic norite, dark norite and dark norite breccia, The footwall complex at Strath- Sonruernn cona includes the late granite breccia, which hosts a large proportion of the nickel- On a d6couvertune min6ralisationriche en copper ores, and a compositionally variable cuivre dans le complexe de gneissfeldspathique qui group of brecciated and migmatized rocks, herein constitue l'Qnnte inf6rieure i, la mine Strathcona, referred to as the feldspathic gneiss complex. au flanc septentrionaldu bassin de Sudbury. La It is within this latter group of rocks that the min6ralisation est localis6e dans un systdme de vein system of the Copper Zone occurs. cassuresorient6es N68oW, b pendagede 45o vers The Copper Zone was discoveredby diamond lo sud-ouest.Cette zone se trouve 150 i 350 m drilling in 1976, by tracing the upward extension audessous du contact avec les eabbros du massif of narrow, subeconomic stringers of chalcopy- .tonnes irnrptif; elle contient environ 910,000 m6tri- rite and millerite" which had been intersected quesde minerai A"9.09Vo Ca, 0,52VoNi et 34.3 e/t in mine openings on the 305O level. Diamond Ag. Les filons, d0s au remplissage des cassures, drilling to date indicates probable ore reserves varient de quelquesmm i 6 m de largeur, consis- teot surtout en sulfures massifs, chalcopyrite et of 910,000 t grading 9.O97o Cu, 0.527o Ni cubanite, mais aussi en pentlandite, pyrrhotine et, and almost 34.3 g/t Ag. The Copper Zone is accessoirement,magn6tite et sphal6rite. Le minerai presently being developed for production, contient aussi, en quantit6s minimes, les espbces scheduled to commence late in 1978. n5 276 TIIE CANADIAN 1VTINERALOGIST l.EEEilD S Olivin diobd |rrupfir. rr++t+t K illil*tt'" >Nict.r r t t + a a + a t+ El Clnln ftd roddo|r g orolln tbi. El Oiofan! torrEtlon E oioii. od gmhr g Arftito - 6.arrach. cid A Ll u6votolomrr ' -.Folt! o.tu'lnc Fro. 1. Geological map of the Sudbury basin, showing the location of Strathsona mine. Gsolocy oF THE STRATHcoNAMr.rE The major sulfide minerals in these ore zones are pyrrhotite, pentlandite, chalcopyrite and pyrite. Magnetite is an important acces- The geology of the Strathcona ore deposit lesser sory mineral. Differences in quantities of sul' has been documented by Cowan (1968). Prin- fide minerals and variations in metal ratios cipal geological features of the mine are illus- are important features of the ore zones. There trated on cross-section 222.0OE (Fig. 2). The is a pronounced zoning in the ratio of pent- orebody, associated with an embayment in the landite to pyrrhotite. The Ni content in Fe-Ni footwall of the Sudbury Imrptive, has a strike sulfides is loqrest in the Hangrng Wall Zone length of about 800 m and a dip of 20-60" and highest in the Deep Zone. The average south. Some mineralization occurs as irregular Cu:Ni ratio in the orebodies also changes zones in dark norite and dark norite breccia steadily:Hangrng Wall Zane l:3,Main7.one l:2, and constitutes ,what is termed the Hanging Deep Zone 1:1. The Cu-Ni ratio increases Wall Ore Zones. Most of the Strathcona miner- markedly at the base of both the Main and alization is present in the Main Zone, Ore which Deep Zones, where stringers consisting almost occurs in a zone of late granite breccia, between wholly of chalcopyrite are common. the knrptive and the underlying feldspathic gneiss complex. This breccia varies from 10 to Feldspathic gneiss complex 60 m in thickness and is composed of fragments The footwall rocks of the mines on the North derived from both the Imrptive and gneiss Range consist of a brecciated volcanic and complex in a quartz-rich breccia matrix (Cowan sedimentary sequence intruded by tonalite dur' 1968, Hewins 1971). Mineralization of the ing regional metamorphism (I-angford 196O, Main Ore Zone consists of sulfide stringers and Greenman 197U. Commonly referred to as the disseminations in the breccia matrix. Lenses Levack complex, this 3-5 km wide z'ote of and stringers of massive sulfides form the Deep brecciated rocks has a highly variable content Ore Zone, Iocated up to 200 m below the base of fragments in tonalite matrfi ranging between of the Imrptive in a system of dilation fractures 2-O and 8OVo. An increase in the content of in the footwall gneissic rocks. fra8rnents is evident towards the contact with CU IN FOOTWALL COMPLEX, SUDBI'RY n7 . -: J.ECE!!- " El LAIEoRANIE rREccra Nl FEL8rcxoRrrE mo^* ro fiE ff, rrlmnrrmc etEnc cqPLEl I cu- ir lulFto! otr! Frc. 2. Geological cross-section 22200E,,Strathcona miue 0ooking E). Line of section is located in Figure 5. the Irruptive. At Strathcona, the principal rock Occasionally the titaniferous mapetite is partly types in tle complex are feldspathic gneiss of or wholly replaced by chlorite, leaving only toualitic composition, equigranular pyroxene the exsolved blades of ilmenite unaltered. hornfels, mafic pyroxene hornfels and Levack Equigranular pyroxene hornfels occurs asr breccia. As tle main component of this hetero- large blocks, bancis or small inchrsions in tte geneous footwall assemblage is a medium- feldspathic gneiss. In drill-core intersections grained grey feldspathic gneiss, the preferred it is quite distinctive, appearing as a medium- to term for the whole unit is feldspathic gneiss fine-grained equigranular gabbroic 1esft. In thin complex. Modal compositions (in vol. Vo) for TASLEI. IIIIIIEM! ASSEI,IBLAGESIN ROCK TYPES OF TlE FELDSPAIHICEilEISS OIiIPLTX each rock tytrle within the complex are given Equigtanular l'hflc LevockBrelia. in Table 1. Feldspatilc Pyroxene Pyroxene - ktrlx. lncluslons Hbrnfels Hornfels (varlable) (vflablei Feldspathic p.eiss has a welldeveloped llineral Greiss 3{)-50 Pldoiocllse-(An) 55-60 35-45 4s-50 50-60 goeissosity that commonly is intricately folded An:s toqo-s4 An4o togo-qo brecciation (Fig. 3). and disnrpted by local Al bl te Aggregates of subhedral to euhedral andesine quartz m-25 5-10 25-40 laths about 0.1H.15 mm long are predominant ortiopyrcrene 6-10 4-6 2-5 0-10 10-20 in this leucosratic rock. Gneissosity is defined Cllnopyrcrene l-4 15-25 40-45 Anphlbole Tt to-m 1-2 0-2 0-2 by coarser-grained mosaic qruartz and blocky Blotlte l-z 6-10 5-8 2-10 2-5 subhedral grains of or'thopyroxene for'ming light ilagnetlte l-2 3-6 8-10 0-3 0-3 Tr and dark layers wifh plagioclase. Other primary Ilmnlte l-2 <l <l 0-l Chlorlte Tf Tr . Tr 0-10 l'2 'I'2 tninerals include clinopyroxene, euhedral apa- Carlonat€ Tr tr <1 0-4 tite, traces of zircon, blocky subhedral grains Apatlte Tr - of titaniferous magnetite and ilmenite. The rock Zlr@n Tr tr Talc Tr Ir - is very fresh, with only minor alteration of Epldote the ferromagnesian minerals to for,m traces of sulfldes (Tr) Cp,PY cp,polpnt,py cp,;o,Py Po,cp:Pnt,8n,sp;;l biotitg amphibole, chlorite, talc and oarbonate. 278 THE CANADIAN MINERALOCIST Fro.
Recommended publications
  • Paolovite Pd2sn C 2001-2005 Mineral Data Publishing, Version 1
    Paolovite Pd2Sn c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Orthorhombic. Point Group: 2/m 2/m 2/m. As irregular grains embedded in other minerals. Twinning: Polysynthetic. Physical Properties: Hardness = n.d. VHN = 329–378 (10 g load). D(meas.) = n.d. D(calc.) = 11.08 Optical Properties: Opaque. Color: Lilac-rose. Luster: Metallic. Pleochroism: Dark lilac-rose to pale rose. R1–R2: (400) — , (420) 44.4–46.5, (440) 44.6–47.2, (460) 45.0–48.2, (480) 45.5–49.1, (500) 45.9–50.3, (520) 46.7–51.6, (540) 47.7–52.8, (560) 49.0–54.1, (580) 50.9–55.4, (600) 52.9–56.7, (620) 55.3–57.7, (640) 57.7–59.2, (660) 59.8–59.5, (680) 61.5–60.3, (700) 62.7–60.6 Cell Data: Space Group: P bnm. a = 8.11(1) b = 5.662(6) c = 4.324(2) Z = 4 X-ray Powder Pattern: Oktyabr deposit, Russia. 2.28 (100), 2.16 (70), 1.955 (50), 2.36 (40), 1.397 (40), 1.315 (40), 1.120 (40) Chemistry: (1) (2) (3) Pd 64.8 64.3 64.19 Pt 2.5 Sn 35.5 35.0 35.81 Sb 0.3 Bi 0.2 Total 103.3 99.3 100.00 (1) Oktyabr deposit, Russia; by electron microprobe, corresponding to (Pd1.98Pt0.04)Σ=2.02Sn0.98. (2) Western Platinum mine, South Africa; by electron microprobe, corresponding to Pd2.02Sn0.98. (3) Pd2Sn. Occurrence: In Cu–Ni sulfide ores; in cubanite–chalcopyrite, cubanite–talnakhite, and cubanite–mooihoekite assemblages (Oktyabr deposit, Russia).
    [Show full text]
  • Cu-Fe-S Phases in Lunar Rocks
    American Mineralogist, Volume 58, pages 952-954, 1973 Cu-Fe-SPhases in LunarRocks LawnnNcn A. Tevronl Departmentol Geosciences,Purdue Uniuersity, Lalaye t te, I ndiana47 907 KBNNrrn L. Wnrrnus Departmentof Applied Earth Sciences,Stanlord Uniaersity, Stanford, Calilornia 943 0 5 Abstract The sulfide minerals reported to be present in lunar rocks include troilite, mackinawite, the discredited mineral "chalcopyrrhotite", sphalerite, chalcopyrite, and cubanite. Apollo 12 sam- ple l2D2l,l34 contains these last two minerals, and the first chemical analyses of the Cu-Fe-S phases are presented. These minerals occur along cracks and grain boundaries within troilite and are probably exsolution products formed at low temperatures (i.e, 100"-300'C) from a cupriferous troilite. Introduction Cu-Fe-S Minerals The opaqueminerals, although constituting only a "Chalcopyrrhotite", a discreditedmineral (Yund minor amount of a given sample,have proven useful and Kullerud, 1966; Cabri, 7967) , hasbeen reported as indicators of the genesisand cooling histories of from Apollo 12, 14, and 15 rocks (El Goresyet al, the lunar rocks (e.9., Reid, 1971; Taylor and Mc- l97la,b; 1972a,b). It wasdescribed as a yellowish, Callister, 19721,Taylor et al, I973b). The most chalcopyrite-coloredphase which appearsisotropic abundant opaque mineral is ilmenite, and many of and is alwaysfound within troilite. It is probablethat the oxide phasesin lunar rocks are unique (e.6'., this phase is either talnakhite, a mineral originally armalcolite as per Anderson et al, l97A). In addi- describedby Cabri (1967) andhaving a composition tion to native Fe metal, native Cu, and schreibersite, of CusFesSro(Cabri and Harris, 1971) near chal- the remaining opaqueminerals consistof sulfides.
    [Show full text]
  • MACKINAWITE from SOUTH AFRICA W. C J. Van RDNSBU*.O, Geological Surtey Oj Soulh Africa, Preloria, Soulh A.[Ri Co, L. Lrbnunsbyc
    TI.IE AMERICAN MINERALOGIST, VOL 52, JULY AUGUST, 1967 MACKINAWITE FROM SOUTH AFRICA W. C J. vAN RDNSBU*.o,Geological Surtey oJ Soulh Africa, Preloria,Soulh A.[rico, AND L. LrBnuNsByc, Deparlment of Geology,Llnit:ersity of Pretoria, Pre!oria,Soul h Africa. ABSTRAcT Mackinawite has been identified in mafic and ultramafic rocks of the Bushveld igneous complex and Insizwa and also in the carbonatite and pegmatoid of Loolekop, Phalaborrva complex in South Africa. The mineral occurs predominantly as somewhat irregular to oriented intergrowths in pentlandite in all these occurrences and less commonly as regular oriented lamellae in chalcopyrite and rarely in cubanite. The textural evidence suggests that mackinawite may represent an exsolution product of pentlandite, chalcopyrite and cubanite. INrnonucrroN The iron sulphide, mackinawite was recently named in a paper by Evans, et al, (1964). Natural occurrencesof this mineral f rom Finland were describedby- Kouvo et al (1963)and from the Muskox intrusion in Canada by Chamberlain and Delabio (1965). During the presentinvestigation mackinawite was distinguishedfrom valleriite in the carbonatite and pegmatoid of Loolekop, Phalaborwa complex, in the Bushveld igneous complex, and from Insizwa, Cape Province.The mode of occurrenceof the mackinawite in the carbonatite difiers somewhatfrom that in the mafic rocks of Insizwa and the Bush- veld complex. MrNnn.q.rocv The physicaland optical propertiesof mackinawitefrom the Bushveid complex,Insizwa and Loolekop are very similar and are in closeagree- ment with the propertiesgiven for the same mineral from the Muskox intrusion by Chamberlain and Delabio (1965). The mineral takes a fairly good polish,particularly after buffing with a chromic oxide slurry.
    [Show full text]
  • High-Pressure Crystal Chemistry of Cubanite, Cufers
    American Mineralogist, Volume 77, pages 937-944, 1992 High-pressure crystal chemistry of cubanite,CuFerS, CarnnnrNr McClvrmoNr* JrNvrrN ZruNG, RonBnr M. HlznNo Llnnv W. FrNcBn GeophysicalLaboratory and Centerfor High-PressureResearch, Carnegie Institution of Washington, 5251Broad Branch Road NW, Washington,DC 20015-1305,U.S.A. ABSTRACT We have studied cubanite, CuFerS, (orthorhombic, space gtoup Pcmn, a: 6.46, b : 11.10, c : 6.22 A), using single-crystalX-ray diffraction in a diamond-anvil cell at room temperature from 0 to 3.68 GPa. Refinementswere performed aI 0, 1.76, and 3.59 GPa, and cell parameterswere measuredat 20 pressuresup to 3.68 GPa. The linear compress- ibilities of the a, b, and c crystalaxes are 0.00513(5),0.00479(5),and 0.00575(4)GPa ', respectively.Compressibility data were fitted to a Birch-Murnaghan equation of statewith parametersKo : 55.3 + 1.7 GPa with Ko' constrained to be 4. High-pressurerefinement data indicate that the principal responseof the crystal structure to compression is a re- duction in Cu-S bond lengths, whereasFe-S bond lengths remain essentiallyunchanged. Results are compared to bulk moduli and polyhedral bulk moduli of other sulfides. INrnonucrroN lography provides an excellent means for examining the effect of pressure on individual atomic configurations. The crystal structure of cubanite, CuFerSr, is ortho- Cubanite is a worthy candidate becauseof the interest in rhombic with ordered tetrahedral cation sites and S at- the effect ofpressure on intervalence transitions (see,for oms in approximately hexagonal closest packing. The example,Burns, I 98 l) and becausevery few sulfideshave structure was first determined by Buerger (1945, 1947) beenexamined with this technique.We undertook a crys- and described as slices of wurtzite structure parallel to tallographic study of cubanite at high pressurewith the (010) with widthb/2,joined such that every other slab is following goals: (l) to determine the relative axial com- inverted, resulting in edge-sharedpairs oftetrahedra.
    [Show full text]
  • Covellite) Probed by NQR
    Phase transition and anomalous electronic behavior in layered dichalcogenide CuS (covellite) probed by NQR R.R. Gainov 1*, A.V. Dooglav 1, I.N. Pen’kov 2, I.R. Mukhamedshin 1,3, N.N. Mozgova 4, A.V. Evlampiev 1, and I.A. Bryzgalov 5 1 Department of Physics, Magnetic RadioSpectroscopy Laboratory, Kazan State University, Kazan, Kremlevskaya str. 18, 420008, Russian Federation 2 Department of Geology, Kazan State University, Kazan, Kremlevskaya str. 4/5, 420111, Russian Federation 3 Laboratoire de Physique des Solides, UMR 8502, Universite Paris-Sud, 91405 Orsay, France 4 Institute of geology of ore deposits, petrography, mineralogy and geochemistry (Russian Academy of Science), Staromonetny per. 35, Moscow 109017, Russian Federation 5 Department of Geology, Moscow State University, Moscow, Vorob’evy gory, 119991, Russian Federation * Corresponding author: tel.: 7-843-2315175; fax.: 7-843-2387201. Electronic address: [email protected] (R.R. Gainov). Nuclear quadrupole resonance (NQR) on copper nuclei has been applied for studies of the electronic properties of quasi-two-dimensional low-temperature superconductor CuS (covellite) in the temperature region between 1.47 and 290 K. Two NQR signals corresponding to two non- equivalent sites of copper in the structure, Cu(1) and Cu(2), has been found. The temperature dependences of copper quadrupole frequencies, line-widths and spin-lattice relaxation rates, which so far had never been investigated so precisely for this material, altogether demonstrate the structural phase transition near 55 K, which accompanies transformations of electronic spectrum not typical for simple metals. The analysis of NQR results and their comparison with literature data show that the valence of copper ions at both sites is intermediate in character between monovalent and divalent states with the dominant of the former.
    [Show full text]
  • EXPERIMENTAL STUDY of CRYSTALLIZATION PRODUCTS of CНALCOPYRITE SOLID SOLUTION Tatyana A
    86 New Data on Minerals. 2011. Vol. 46 EXPERIMENTAL STUDY OF CRYSTALLIZATION PRODUCTS OF CНALCOPYRITE SOLID SOLUTION Tatyana A. Kravchenko Institute of Mineralogy and Petrography Siberian Branch RAS, Novosibirsk, [email protected] In order to understand the conditions of formation of cubanite СuFe2S3, talnakhite Cu9Fe8S16, mooihoekite Cu9Fe9S16 and haycockite Cu4Fe5S8 in magmatic Cu-Fe ores of the Norilsk type the method of melt cooling from 1150–1100°C up to room temperature and subsequent annealing at 600 and 800°C phase associations of the cen- tral part of Cu-Fe-S system have been synthesized: 50 at.% of S, Cu/Fe = 1.22–0.25, 47 at.% S, Cu/Fe = 1.12–0.63 and 45 at.% S, Cu/Fe = 1.44–0.69. According to the received results, cubic cubanite enriched in cop- per (Cu/Fe і 0.5) crystallizes in associations with tetragonal chalcopyrite Cu1xFe1+xS2 and cubic talnakhite. The new data concerning steady phase equillibriums of mooihoekite with bornite Cu5FeS4 and cubic pc phase of the haycockite composition with cubic cubanite enriched in iron (Cu/Fe Ј 0.5) bornite and pyrrhotite Fe1xS are received. 1 figure, 1 table, 20 references. Key words: Cu-Fe-S system, chalcopyrite solid solution, crystallization of melt. Introduction system for determination of phase composi- tions and phase equillibriums in the sphere of Cubic talnakhite Cu9Fe8S16 (Bud`ko, Kula - chalcopyrite solid solution. gov, 1963; Cabri, 1967), tetragonal mooihoekite Cu9Fe9S16 (Cabri, Hall, 1972; Muraviova et al., Methodics 1972), rhombic haycockite Cu4Fe5S8(Cabri, Hall, 1972) and cubic cubanite CuFe2S3 (Cabri, 1973) Up to now the most complete experimental are attributed to the products of crystallization of research of phases from the sphere of chalcopy- chalcopyrite (Yund, Kullerud, 1966) intermedi- rite solid solution is the work by L.J.
    [Show full text]
  • Troilite Fes C 2001-2005 Mineral Data Publishing, Version 1
    Troilite FeS c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Hexagonal. Point Group: 6/m 2/m 2/m. Massive, granular; nodular. Physical Properties: Hardness = 3.5–4.5 VHN = 250(3) D(meas.) = 4.67–4.79 D(calc.) = 4.85 Optical Properties: Opaque. Color: Pale grayish brown, tarnishes rapidly on exposure. Streak: Dark grayish brown. Luster: Metallic. Anisotropism: Strong. R1–R2: (400) 24.3–28.4, (420) 24.9–29.6, (440) 25.8–30.9, (460) 27.1–32.6, (480) 28.4–34.0, (500) 29.9–35.5, (520) 31.3–36.7, (540) 32.7–37.9, (560) 34.2–39.0, (580) 35.5–40.0, (600) 36.9–41.0, (620) 38.1–41.7, (640) 39.2–42.4, (660) 40.2–43.1, (680) 41.1–43.5, (700) 42.0–44.0 Cell Data: Space Group: P 63/mmc. a = 5.958 c = 11.74 Z = 12 X-ray Powder Pattern: Del Norte Co., California, USA. 2.09 (100), 2.66 (60), 1.719 (50), 2.98 (40), 1.331 (40), 1.119 (40), 1.923 (30) Chemistry: (1) (2) (3) Fe 62.70 63.0 63.53 S 35.40 35.0 36.47 Total 98.10 98.0 100.00 (1) Del Norte Co., California, USA. (2) Cranbourne meteorite. (3) FeS. Occurrence: In serpentine (Del Norte Co., California, USA); with Fe–Cu–Ni sulfides in a layered ultramafic intrusive (Sally Malay deposit, Australia); and as nodules in meteorites. Association: Pyrrhotite, pentlandite, mackinawite, cubanite, valleriite, chalcopyrite, pyrite (Wannaway deposit, Australia); daubr´eelite,chromite, sphalerite, graphite, various phosphates and silicates (meteorites).
    [Show full text]
  • Metals from Ores: an Introduction
    CRIMSONpublishers http://www.crimsonpublishers.com Mini Review Aspects Min Miner Sci ISSN 2578-0255 Metals from Ores: An Introduction Fathi Habashi* Department of Mining, Laval University, Canada *Corresponding author: Fathi Habashi, Department of Mining, Metallurgical and Materials Engineering, Laval University, Quebec City, Canada Submission: October 09, 2017; Published: December 11, 2017 Introduction of metallic lustre. Of these about 300 are used industrially in the chemical industry, in building materials, in fertilizers, as fuels, etc., chemical composition, constant physical properties, and a A mineral is a naturally occurring substance having a definite characteristic crystalline form. Ores are a mixture of minerals: they are processed to yield an industrial mineral or treated chemically and are known as the industrial minerals Figure 3. to yield a single or several metals. Ores that are generally processed for only a single metal are those of iron, aluminium, chromium, tin, mercury, manganese, tungsten, and some ores of copper. Gold ores may yield only gold, but silver is a common associate. Nickel ores are always associated with cobalt, while lead and zinc always occur together in ores. All other ores are complex yielding a number of metals. before being treated by chemical methods to recover the metals. Ores undergo a beneficiation process by physical methods and grinding then separation of the individual mineral by physical Figure 2: Metals and metalloids obtained from ores. Beneficiation processes involve liberation of minerals by crushing methods (gravity, magnetic, etc.) or physicochemical methods pyrometallurgical, and electrochemical methods. Metals and (flotation) Figure 1. Chemical methods involve hydrometallurgical, metalloids obtained from ores are shown in Figure 2.
    [Show full text]
  • Download the Scanned
    Tnn AuERTcAN M rxuRAr,ocrsr JOURNAL OT'THE MINERALOGICAL SOCIETY OF AMERICA Vol. 19 JULY, 1934 No. 7 CRYSTALLOGRAPHIC RELATIONS BETWEEN CUBAN- ITE SEGREGATION PLATES, CHALCOPYRITE MATRIX, AND SECONDARY CHALCO- PYRITE TWINS N. W. Buancnn eNn M. J. Burncrn, M assachusettsInstitute of T echnology, Cambrid. ge, M ass. ABsrnncr The orientation of cubanite plates unmixed from chalcopyrite have been said to parallel | 111 | of the chalcopyrite matrix, but the best method hitherto used to determine this does not lead to a unique solution. rn this paper, the orientations of the cubanite plates as well as certain twin lamellae, occurring in the coarse grained chalcopyrite from Corinth, Vermont, are uniquely determined by a study of the traces of these features on two polished surfaces. The general method of determining the pole of a plane making traces on two datum planes is discussed with the aid of the stereographic projection. The method is then applied to the cubanite and twin lamellae traces, resulting in a composite stereographic projection of these features. The orientation of the chalcopyrite crystal containing these is determined from the symmetry of this composite pro- jection. This, in turn, permits the poles to be easily indexed. cubanite plates are found to be parallei to {1111, as previously surmised. Two new twin lamellae are discovered, the first, parallel to {1101, called grid twins, the second parallel to { 101 }, called erhelon twins, the names being desciiptive of the habit of the lamellae. Both groups of lamellae are secondary, resulting from plastic deformation. The possible causes of this include external forces, unmixing stresses) and possible in- version stresses.
    [Show full text]
  • Minerals Found in Michigan Listed by County
    Michigan Minerals Listed by Mineral Name Based on MI DEQ GSD Bulletin 6 “Mineralogy of Michigan” Actinolite, Dickinson, Gogebic, Gratiot, and Anthonyite, Houghton County Marquette counties Anthophyllite, Dickinson, and Marquette counties Aegirinaugite, Marquette County Antigorite, Dickinson, and Marquette counties Aegirine, Marquette County Apatite, Baraga, Dickinson, Houghton, Iron, Albite, Dickinson, Gratiot, Houghton, Keweenaw, Kalkaska, Keweenaw, Marquette, and Monroe and Marquette counties counties Algodonite, Baraga, Houghton, Keweenaw, and Aphrosiderite, Gogebic, Iron, and Marquette Ontonagon counties counties Allanite, Gogebic, Iron, and Marquette counties Apophyllite, Houghton, and Keweenaw counties Almandite, Dickinson, Keweenaw, and Marquette Aragonite, Gogebic, Iron, Jackson, Marquette, and counties Monroe counties Alunite, Iron County Arsenopyrite, Marquette, and Menominee counties Analcite, Houghton, Keweenaw, and Ontonagon counties Atacamite, Houghton, Keweenaw, and Ontonagon counties Anatase, Gratiot, Houghton, Keweenaw, Marquette, and Ontonagon counties Augite, Dickinson, Genesee, Gratiot, Houghton, Iron, Keweenaw, Marquette, and Ontonagon counties Andalusite, Iron, and Marquette counties Awarurite, Marquette County Andesine, Keweenaw County Axinite, Gogebic, and Marquette counties Andradite, Dickinson County Azurite, Dickinson, Keweenaw, Marquette, and Anglesite, Marquette County Ontonagon counties Anhydrite, Bay, Berrien, Gratiot, Houghton, Babingtonite, Keweenaw County Isabella, Kalamazoo, Kent, Keweenaw, Macomb, Manistee,
    [Show full text]
  • And Associated Ni-PGE Mineralization from Gondpipri Mafic-Ultramafic Complex, Bastar Craton, Central India
    Cent. Eur. J. Geosci. • 6(4) • 2014 • 506-517 DOI: 10.2478/s13533-012-0185-9 Central European Journal of Geosciences Tsumoite (BiTe) and associated Ni-PGE mineralization from Gondpipri mafic-ultramafic complex, Bastar Craton, Central India: mineralogy and genetic significance Topical issue M.L. Dora1∗, H. Singh1, A .Kundu2, M.Shareef3, K.R. Randive4, S. Joshi2 1 Geological Survey of India, Shillong, 793003, India 2 Geological Survey of India, Faridabad, India 3 Geological Survey of India, Bangalore, India 4 Dept of Geology, RTM Nagpur University, Nagpur, 440001, India Received 25 March 2014; accepted 19 June 2014 Abstract: This paper reports the occurrence of Tsumoite (a bismuth telluride) in the Heti Cu-Ni-PGM prospect, Gondpipri mafic-ultramafic complex, Central India. The Gondpipri complex consists of several tectonically dismembered gabbronorite-gabbro- anorthositic gabbro - olivine gabbro -websterite disposed in ~10 km long tonalite-trondhjemite- granodiorite (TTG) and charnockite-enderbite suite of rocks. The mineralization occurs in the sulphide zone hosted by gabbro variants. The host rocks have been deformed and metamorphosed to granulite grade and subjected to various degrees of hydrothermal alteration. The mineralization comprises chalcopyrite, pentlandite, pyrrhotite, cubanite, millerite, and pyrite. In addition to these, occur (1) tsumoite (2) PGM in the form of moncheite, merenskyite, Pd-mellonite, and Pt-Pd-Te-Bi-Fe-S alloy. The present study indicates that the mineralization occurs in two stages related to: (i) magmatic and (ii) hydrothermal remobilization and transport of Cu-rich sulphides, tsumoite and PGM, and their re-deposition in hydrosilicate alteration zones. It is possible that the mineralization at Heti formed at different stages of bismuth activity under variable fS , T, and fTe conditions due to change in total concentration of Te and S and /or cooling.
    [Show full text]
  • CHEMICAL COMPOSITION, MINERAL CHEMISTRY, and SULFUR ISOTOPES1 Katsuo Kase,2 Masahiro Yamamoto,2 and Tsugio Shibata2
    Detrick, R., Honnorez, J., Bryan, W. B., Juteau, T., et al., 1990 Proceedings of the Ocean Drilling Program, Scientific Results, Vol. 106/109 13. COPPER-RICH SULFIDE DEPOSIT NEAR 23°N, MID-ATLANTIC RIDGE: CHEMICAL COMPOSITION, MINERAL CHEMISTRY, AND SULFUR ISOTOPES1 Katsuo Kase,2 Masahiro Yamamoto,2 and Tsugio Shibata2 ABSTRACT In Snake Pit massive sulfide fragments and friable, unconsolidated material recovered during ODP Leg 106, isocubanite and pyrite are generally the predominant phases, followed by marcasite, chalcopyrite, sphalerite, and pyrrhotite. Detailed analyses of paragenetic relations of minerals indicate that isocubanite first precipitated together with pyrrhotite. With decreasing temperature, chalcopyrite and sphalerite precipitated, and at the latest stage colloform sphalerite-pyrite (or colloform marcasite) formed. Isocubanite usually has exsolution lamellae of chalcopyrite and less commonly of pyrrhotite. The average bulk chemical composition of the friable, unconsolidated material indicates that it is rich in copper, reflecting the dominance of isocubanite in the specimens, and is characterized by high Co, low Pb, and Ag contents. Sulfur isotope ratios are very uniform, ranging in S34S from +1.2 to +2.8%c. The obtained values are apparently low, compared to those for the eastern Pacific sulfide samples, reflecting a smaller contribution of seawater sulfate in the Snake Pit sulfide deposit. INTRODUCTION from the Snake Pit sulfide deposit and examine its depositional conditions. During ODP Leg 106, an active high-temperature vent field was discovered on the Mid-Atlantic Ridge (MAR) rift valley ANALYTICAL PROCEDURES near 23°22'N, 44°57'W. The active vent field named the Snake Data acquisition for this study consisted of ore microscopy, Pit hydrothermal area is located on a small terrace near the microprobe analyses, bulk major and trace element analyses, and crest of the median ridge about 25 km south of the Kane sulfur isotope analyses.
    [Show full text]