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Impact of High Temperatures on Aluminoceladonite Studied by Mössbauer, Raman, X-Ray Diffraction and X-Ray Photoelectron Spectroscopy
Title: Impact of high temperatures on aluminoceladonite studied by Mössbauer, Raman, X-ray diffraction and X-ray photoelectron spectroscopy Author: Mariola Kądziołka-Gaweł, Maria Czaja, Mateusz Dulski, Tomasz Krzykawski, Magdalena Szubka Citation style: Kądziołka-Gaweł Mariola, Czaja Maria, Dulski Mateusz, Krzykawski Tomasz, Szubka Magdalena. (2021). Impact of high temperatures on aluminoceladonite studied by Mössbauer, Raman, X-ray diffraction and X-ray photoelectron spectroscopy. “Mineralogy and Petrology” (Vol. 115, iss. 0, 2021, s. 1- 14), DOI: 10.1007/s00710-021-00753-z Mineralogy and Petrology (2021) 115:431–444 https://doi.org/10.1007/s00710-021-00753-z ORIGINAL PAPER Impact of high temperatures on aluminoceladonite studied by Mössbauer, Raman, X-ray diffraction and X-ray photoelectron spectroscopy Mariola Kądziołka-Gaweł1 & Maria Czaja2 & Mateusz Dulski3,4 & Tomasz Krzykawski2 & Magdalena Szubka1 Received: 9 March 2020 /Accepted: 28 April 2021 / Published online: 18 May 2021 # The Author(s) 2021 Abstract Mössbauer, Raman, X-ray diffraction and X-ray photoelectron spectroscopies were used to examine the effects of temperature on the structure of two aluminoceladonite samples. The process of oxidation of Fe2+ to Fe3+ ions started at about 350 °C for the sample richer in Al and at 300 °C for the sample somewhat lower Al-content. Mössbauer results show that this process may be associated with dehydroxylation or even initiate it. The first stage of dehydroxylation takes place at a temperature > 350 °C when the adjacent OH groups are replaced with a single residual oxygen atom. Up to ~500 °C, Fe ions do not migrate from cis- octahedra to trans-octahedra sites, but the coordination number of polyhedra changes from six to five. -
Mineral Processing
Mineral Processing Foundations of theory and practice of minerallurgy 1st English edition JAN DRZYMALA, C. Eng., Ph.D., D.Sc. Member of the Polish Mineral Processing Society Wroclaw University of Technology 2007 Translation: J. Drzymala, A. Swatek Reviewer: A. Luszczkiewicz Published as supplied by the author ©Copyright by Jan Drzymala, Wroclaw 2007 Computer typesetting: Danuta Szyszka Cover design: Danuta Szyszka Cover photo: Sebastian Bożek Oficyna Wydawnicza Politechniki Wrocławskiej Wybrzeze Wyspianskiego 27 50-370 Wroclaw Any part of this publication can be used in any form by any means provided that the usage is acknowledged by the citation: Drzymala, J., Mineral Processing, Foundations of theory and practice of minerallurgy, Oficyna Wydawnicza PWr., 2007, www.ig.pwr.wroc.pl/minproc ISBN 978-83-7493-362-9 Contents Introduction ....................................................................................................................9 Part I Introduction to mineral processing .....................................................................13 1. From the Big Bang to mineral processing................................................................14 1.1. The formation of matter ...................................................................................14 1.2. Elementary particles.........................................................................................16 1.3. Molecules .........................................................................................................18 1.4. Solids................................................................................................................19 -
A 1 Case-PR/ }*Rciofft.;Is Report
.A 1 case-PR/ }*rciofft.;is Report (a) This eruption site on Mauna Loa Volcano was the main source of the voluminous lavas that flowed two- thirds of the distance to the town of Hilo (20 km). In the interior of the lava fountains, the white-orange color indicates maximum temperatures of about 1120°C; deeper orange in both the fountains and flows reflects decreasing temperatures (<1100°C) at edges and the surface. (b) High winds swept the exposed ridges, and the filter cannister was changed in the shelter of a p^hoehoc (lava) ridge to protect the sample from gas contamination. (c) Because of the high temperatures and acid gases, special clothing and equipment was necessary to protect the eyes. nose, lungs, and skin. Safety features included military flight suits of nonflammable fabric, fuil-face respirators that are equipped with dual acidic gas filters (purple attachments), hard hats, heavy, thick-soled boots, and protective gloves. We used portable radios to keep in touch with the Hawaii Volcano Observatory, where the area's seismic activity was monitored continuously. (d) Spatter activity in the Pu'u O Vent during the January 1984 eruption of Kilauea Volcano. Magma visible in the circular conduit oscillated in a piston-like fashion; spatter was ejected to heights of 1 to 10 m. During this activity, we sampled gases continuously for 5 hours at the west edge. Cover photo: This aerial view of Kilauea Volcano was taken in April 1984 during overflights to collect gas samples from the plume. The bluish portion of the gas plume contained a far higher density of fine-grained scoria (ash). -
New Lunar Impact Melt Flows As Revealed by Mini-Rf on Lro
43rd Lunar and Planetary Science Conference (2012) 2388.pdf NEW LUNAR IMPACT MELT FLOWS AS REVEALED BY MINI-RF ON LRO. C. D. Neish1, N. Glines2, L. M. Carter3, V. J. Bray4, B. R. Hawke5, D. B. J. Bussey1, and the Mini-RF Science Team, 1The Johns Hopkins University Applied Physics Laboratory, Laurel, MD, 20723 ([email protected]), 2Mount Holyoke College, South Hadley, MA, 01075, 3NASA Goddard Spaceflight Center, Greenbelt, MD, 20770, 4The University of Ari- zona, Tucson, AZ, 85721, 5The University of Hawai’i at Manoa, Honolulu, HI, 96822. Introduction: Flow-like deposits of impact melt fying impact melts. After a candidate melt is identified, are commonly observed on the Moon, typically around data from the LRO Camera (LROC) was used to iden- young fresh craters. These flows are thought to be mix- tify additional features associated with impact melt tures of clasts and melted material that are emplaced deposits, such as cooling cracks in ponds and tension during the late stages of impact crater formation [1]. cracks in veneers, confirming these features as impact Lunar impact melts have been primarily studied at op- melts. tical wavelengths, but complementary information can be obtained by observing impact melts at radar wave- lengths. Radar data is sensitive to surface and sub- surface roughness, and thus can highlight these rough surface features, even when they not easily seen in optical data due to burial or imperfect lighting condi- tions (Fig. 1). Impact melts have been identified in radar data on the lunar near side [2], but they have yet to be studied in depth on the lunar far side, given the lack of global radar data prior to the launch of NASA’s Mini-RF instrument on the Lunar Reconnaissance Or- biter (LRO) in 2009. -
Hectorite: Synthesis, Modification, Assembly and Applications Jing Zhang, Chun Hui Zhou, Sabine Petit, Hao Zhang
Hectorite: Synthesis, modification, assembly and applications Jing Zhang, Chun Hui Zhou, Sabine Petit, Hao Zhang To cite this version: Jing Zhang, Chun Hui Zhou, Sabine Petit, Hao Zhang. Hectorite: Synthesis, modification, assembly and applications. Applied Clay Science, Elsevier, 2019, 177, pp.114-138. 10.1016/j.clay.2019.05.001. hal-02363196 HAL Id: hal-02363196 https://hal-cnrs.archives-ouvertes.fr/hal-02363196 Submitted on 2 Dec 2020 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. 1 Hectorite:Synthesis, Modification, Assembly and Applications 2 3 Jing Zhanga, Chun Hui Zhoua,b,c*, Sabine Petitd, Hao Zhanga 4 5 a Research Group for Advanced Materials & Sustainable Catalysis (AMSC), State Key Laboratory 6 Breeding Base of Green Chemistry-Synthesis Technology, College of Chemical Engineering, Zhejiang 7 University of Technology, Hangzhou 310032, China 8 b Key Laboratory of Clay Minerals of Ministry of Land and Resources of the People's Republic of 9 China, Engineering Research Center of Non-metallic Minerals of Zhejiang Province, Zhejiang Institute 10 of Geology and Mineral Resource, Hangzhou 310007, China 11 c Qing Yang Institute for Industrial Minerals, You Hua, Qing Yang, Chi Zhou 242804, China 12 d Institut de Chimie des Milieux et Matériaux de Poitiers (IC2MP), UMR 7285 CNRS, Université de 13 Poitiers, Poitiers Cedex 9, France 14 15 Correspondence to: Prof. -
The Social Impact of Mine Closure in the Jiu Valley
E3S Web of Conferences 239, 00004 (2021) https://doi.org/10.1051/e3sconf/202123900004 ICREN 2020 The social impact of mine closure in the Jiu Valley Izabella Kovacs*, Sorin Simion, Alin Irimia, Ligia Ioana Tuhuţ , and Gheorghe Daniel Florea National Institute for Research and Development in Mine Safety and Protection to Explosion – INSEMEX Petrosani, 32-34 G-ral Vasile Milea Street, Petrosani 332047, Romania Abstract. The impact of transition periods is experienced by the local population and economy as a result of mining activities closure and dismissal of a large number of workers followed by diversification of employment and career reorientation opportunities. The aim of the paper is to highlight the impact generated by closure of mining operations on local society and economy as well as identifying opportunities for harmonious development of communities in the Jiu Valley. Following the assessment of the social impact of mining activities closure, we found a rising tendency of unemployment rate among the middle-aged population that did not benefit from vocational retraining and the growing tendency of young people to leave the region for strictly economic reasons leading to widespread social aging. 1 Restructuring of mi ning activity in Romania and the Jiu Valley Jiu Valley is a micro-region in Hunedoara County, located between the Retezat and Parâng Mountains (fig.1). It consists of 3 cities: Petrila, Uricani and Aninoasa and 3 municipalities - Petroșani, Lupeni and Vulcan. Officially, the micro-region has no rural areas, because it has been incorporated into municipalities or cities, being considered urban. * Corresponding author: [email protected] © The Authors, published by EDP Sciences. -
Impact Melt Emplacement on Mercury
Western University Scholarship@Western Electronic Thesis and Dissertation Repository 7-24-2018 2:00 PM Impact Melt Emplacement on Mercury Jeffrey Daniels The University of Western Ontario Supervisor Neish, Catherine D. The University of Western Ontario Graduate Program in Geology A thesis submitted in partial fulfillment of the equirr ements for the degree in Master of Science © Jeffrey Daniels 2018 Follow this and additional works at: https://ir.lib.uwo.ca/etd Part of the Geology Commons, Physical Processes Commons, and the The Sun and the Solar System Commons Recommended Citation Daniels, Jeffrey, "Impact Melt Emplacement on Mercury" (2018). Electronic Thesis and Dissertation Repository. 5657. https://ir.lib.uwo.ca/etd/5657 This Dissertation/Thesis is brought to you for free and open access by Scholarship@Western. It has been accepted for inclusion in Electronic Thesis and Dissertation Repository by an authorized administrator of Scholarship@Western. For more information, please contact [email protected]. Abstract Impact cratering is an abrupt, spectacular process that occurs on any world with a solid surface. On Earth, these craters are easily eroded or destroyed through endogenic processes. The Moon and Mercury, however, lack a significant atmosphere, meaning craters on these worlds remain intact longer, geologically. In this thesis, remote-sensing techniques were used to investigate impact melt emplacement about Mercury’s fresh, complex craters. For complex lunar craters, impact melt is preferentially ejected from the lowest rim elevation, implying topographic control. On Venus, impact melt is preferentially ejected downrange from the impact site, implying impactor-direction control. Mercury, despite its heavily-cratered surface, trends more like Venus than like the Moon. -
Arxiv:2103.07476V1 [Astro-Ph.GA] 12 Mar 2021
FERMILAB-PUB-21-075-AE-LDRD Draft version September 3, 2021 Typeset using LATEX twocolumn style in AASTeX63 The DECam Local Volume Exploration Survey: Overview and First Data Release A. Drlica-Wagner ,1, 2, 3 J. L. Carlin ,4 D. L. Nidever ,5, 6 P. S. Ferguson ,7, 8 N. Kuropatkin ,1 M. Adamow´ ,9, 10 W. Cerny ,2, 3 Y. Choi ,11 J. H. Esteves,12 C. E. Mart´ınez-Vazquez´ ,13 S. Mau ,14, 15 A. E. Miller,16, 17 B. Mutlu-Pakdil ,2, 3 E. H. Neilsen ,1 K. A. G. Olsen ,6 A. B. Pace ,18 A. H. Riley ,7, 8 J. D. Sakowska ,19 D. J. Sand ,20 L. Santana-Silva ,21 E. J. Tollerud ,11 D. L. Tucker ,1 A. K. Vivas ,13 E. Zaborowski,2 A. Zenteno ,13 T. M. C. Abbott ,13 S. Allam ,1 K. Bechtol ,22, 23 C. P. M. Bell ,16 E. F. Bell ,24 P. Bilaji,2, 3 C. R. Bom ,25 J. A. Carballo-Bello ,26 D. Crnojevic´ ,27 M.-R. L. Cioni ,16 A. Diaz-Ocampo,28 T. J. L. de Boer ,29 D. Erkal ,19 R. A. Gruendl ,30, 31 D. Hernandez-Lang,32, 13, 33 A. K. Hughes,20 D. J. James ,34 L. C. Johnson ,35 T. S. Li ,36, 37, 38 Y.-Y. Mao ,39, 38 D. Mart´ınez-Delgado ,40 P. Massana,19, 41 M. McNanna ,22 R. Morgan ,22 E. O. Nadler ,14, 15 N. E. D. Noel¨ ,19 A. Palmese ,1, 2 A. H. G. Peter ,42 E. S. -
Reactions Accompanying Stabilization of Clay with Cement A
Reactions Accompanying Stabilization Of Clay with Cement A. HERZOG, Senior Lecturer in Civil Engineering, University of New South Wales, Newcastle, Australia, and J. K. :MITCHELL, Assistant Professor of Civil Engineering, and Assistant Research Engineer, Institute of Transportation and Traffic Engineering, University of California, Berkeley This paper reports the results of an investigation aimed at de lineating the nature of the reactions accompanying the stabili zation of clay with portland cement. Consideration of the nature of cement hydration, the physico-chemical character istics of clays and lime-clay interaction leads to the hypothesis that during the hydration of a clay-cement mixture, hydrolysis and hydration of cement could be regarded as primary reac tions which form usual cement hydration products, increase the pH, and liberate lime. The high pH and Ca(OHh concen tration could initiate attack of the clay particles and also cause breakdown of amorphous silica and alumina which then could combine with calcium to form secondary cementitious material. A clay-cement skeleton and a clay matrix are likely. Mechanical, X-ray diffraction, and chemical tests on kao linite and montmorillonite stabilized with portland cement and with pure tricalcium silicate (C3S), the major strength-producing compound in portland cement, gave results in agreement with this hypothesis. Compacted clay-cement mixtures were cured at 100 percent relative humidity and at 60 C (to accelerate hardening) and studied at different times after molding. X-ray analyses showed that calcium hydroxide was formed in hydrat ing clay-cement, but was rapidly used up in reaction with the clay. Minor alteration of the kaolinite-cement X-ray pattern and marked alteration of the montmorillonite-cement X-ray pattern were indicated after curing periods of 12 weeks, sug gesting clay mineral structure breakdown and/or interaction with cement at particle surfaces. -
Storylines in Intercalation Chemistry
Dalton Transactions Storylines in intercalation chemistry Journal: Dalton Transactions Manuscript ID: DT-ART-01-2014-000203.R2 Article Type: Perspective Date Submitted by the Author: 07-May-2014 Complete List of Authors: Lerf , Prof. Dr. Anton; Walther-Meissner-Institut,D-85748 Garching, der Bayerischen Akademie der Wissenschaften Page 1 of 33 Dalton Transactions Storylines in intercalation chemistry A. Lerf Walther-Meißner-Institut, Bayerische Akademie der Wissenschaften, D-85748 Garching Abstract Intercalation chemistry is soon hundred years old. The period of the greatest activity in this field of solid state chemistry and physics was from about 1970 to 1990. The intercalation reactions are defined as topotactic solid state reactions and the products – the intercalation compounds – clearly distinguished from inclusion and interstitial compounds. After a short historical introduction emphasizing the pioneering work of Ulrich Hofmann the central topics and concepts will be reviewed and commented. The most important ones in my view are: dichalcogenide intercalation compounds, the electrochemical intercalation and search for new battery electrodes, the physics of graphite intercalation compounds, the staging and interstratification phenomena. The relation to other fields of actual research and demands for forthcoming research will be also addressed. Introduction As far as I found the verb „to intercalate“ and the term „intercalation“ has been used for the first time by McDonnell et al. in 1951 without any explanation for using it. 1 In 1959 Rüdorff used the phrase „intercalation compounds“ in the title of a review about all chemical derivatives of graphite.2 In these compounds atoms or ions have been inserted (alternatively, intercalated, or in German „eingelagert") under expansion of the lattice perpendicular to the nearly unchanged graphite layers. -
Pre-Mission Insights on the Interior of Mars Suzanne E
Pre-mission InSights on the Interior of Mars Suzanne E. Smrekar, Philippe Lognonné, Tilman Spohn, W. Bruce Banerdt, Doris Breuer, Ulrich Christensen, Véronique Dehant, Mélanie Drilleau, William Folkner, Nobuaki Fuji, et al. To cite this version: Suzanne E. Smrekar, Philippe Lognonné, Tilman Spohn, W. Bruce Banerdt, Doris Breuer, et al.. Pre-mission InSights on the Interior of Mars. Space Science Reviews, Springer Verlag, 2019, 215 (1), pp.1-72. 10.1007/s11214-018-0563-9. hal-01990798 HAL Id: hal-01990798 https://hal.archives-ouvertes.fr/hal-01990798 Submitted on 23 Jan 2019 HAL is a multi-disciplinary open access L’archive ouverte pluridisciplinaire HAL, est archive for the deposit and dissemination of sci- destinée au dépôt et à la diffusion de documents entific research documents, whether they are pub- scientifiques de niveau recherche, publiés ou non, lished or not. The documents may come from émanant des établissements d’enseignement et de teaching and research institutions in France or recherche français ou étrangers, des laboratoires abroad, or from public or private research centers. publics ou privés. Open Archive Toulouse Archive Ouverte (OATAO ) OATAO is an open access repository that collects the wor of some Toulouse researchers and ma es it freely available over the web where possible. This is an author's version published in: https://oatao.univ-toulouse.fr/21690 Official URL : https://doi.org/10.1007/s11214-018-0563-9 To cite this version : Smrekar, Suzanne E. and Lognonné, Philippe and Spohn, Tilman ,... [et al.]. Pre-mission InSights on the Interior of Mars. (2019) Space Science Reviews, 215 (1). -
195 Ecotourism Trigger of Sustainable Development In
Analele Universităţii din Oradea, Fascicula Protecţia Mediului Vol. XXIV, 2015 ECOTOURISM TRIGGER OF SUSTAINABLE DEVELOPMENT IN THE JIU VALLEY Luca Sergiu*, Marchiş Diana** *University of Petroşani, 20 University St., 332006 Petroşani, Romania, e-mail: [email protected] **University of Petroşani, Faculty of Mining, 20 University St., 332006 Petroşani, Romania, e-mail: marchiş[email protected] Abstract Jiu Valley, a mono-industrial area, where mining was the main activity of the inhabitants, underwent many transformations in recent years. Restructuring the mining industry, the large number of layoffs has led to rapid increase in unemployment and decline in living standards of the inhabitants of Petrosani Depression . In these circumstances, from the local authorities have identified tourism development as a complementary activity / alternative to local economy. Key words : mountain environment, tourism, mining, unemployment INTRODUCTION In the south of Hunedoara county, in a triangle proved to be golden , on the border between Transylvania, Banat and the Romanian Country, lies an area known generically under denu - groom " Jiu Valley " and geographi- cally that " Petrosani Depression " region that has earned the reputation as the " Land of black Diamond " (fig. 1). Fig. 1. Layout and composition Jiu Valley 195 REASON Jiu Valley - a region made up of three municipalities: Petrosani,Lupeni, Vulcan and three cities : Petrila, Uricani, alder, with a total population of 120 734 inhabitants, the main economic activity was the coal mining industry in the years after 1990 suffered transformations in economic, social and demographic changes resulting from the restructuring of this activity sector. Besides mining sector restructuring , the reference faced available - saw and activities related to mining or provide services to the mining sector, which has led to diponibilizări from these activities, leading to a high rate of unemployment in the area.