UNIVERSITY of CALIFORNIA Los Angeles Analyses of Polluted White

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UNIVERSITY of CALIFORNIA Los Angeles Analyses of Polluted White UNIVERSITY OF CALIFORNIA Los Angeles Analyses of Polluted White Dwarf Stars with Applications to the Geochemistry of Rocky Exoplanets A dissertation submitted in partial satisfaction of the requirements for the degree Doctor of Philosophy in Geochemistry by Alexandra Elyse Doyle 2021 © Copyright by Alexandra Elyse Doyle 2021 ABSTRACT OF THE DISSERTATION Analyses of Polluted White Dwarf Stars with Applications to the Geochemistry of Rocky Exoplanets by Alexandra Elyse Doyle Doctor of Philosophy in Geochemistry University of California, Los Angeles, 2021 Professor Edward Donald Young, Chair In this work, exoplanet-research is combined with the study of the solar system in order to assess differences and similarities between rocky bodies in the Milky Way. To evaluate rocky bodies outside of the solar system, I utilize optical spectroscopy to study polluted white dwarf stars, dense stars that show accretion of planetary material. By observing polluted white dwarfs, we can measure elemental abundances from the rocky and icy bodies that previously orbited the star. Specifically, I conduct observations using the KAST Spectro- graph on the Shane 3-meter telescope at Lick Observatory and the High-Resolution Echelle Spectrometer (HIRES) on the Keck I Telescope, as well as evaluate compiled literature data. Generally, the elemental compositions of extrasolar planetesimals closely resemble those of rocky bodies in the solar system. In this work, a more detailed comparison with solar sys- tem meteorites and planets shows that oxidation of planetesimals prior to planet formation is common among extrasolar rocks. Overall, the processes that lead to the geochemistry and much of the geophysics of Earth is normal compared to the current sample of extrasolar planetesimals. Additionally, the origin of excesses in spallogenic nuclides in polluted white dwarfs is investigated. The MeV proton fluence required to form the high Be/O ratio in the accreted parent bodies of two polluted white dwarfs (GALEX J2339-0424 and GD 378) is consistent with irradiation of ice in the rings of a giant planet within its radiation belt, followed by accretion of the ices to form a moon that is later accreted by the WD. ii The dissertation of Alexandra Elyse Doyle is approved. Kevin D. McKeegan Hilke Elisabet Schlichting Benjamin M. Zuckerman Edward Donald Young, Committee Chair University of California, Los Angeles 2021 iii TABLE OF CONTENTS Abstract of the Dissertation :::::::::::::::::::::::::::::::: ii Committee Page :::::::::::::::::::::::::::::::::::::: iii Table of Contents :::::::::::::::::::::::::::::::::::::: iv List of Figures ::::::::::::::::::::::::::::::::::::::: vi List of Tables :::::::::::::::::::::::::::::::::::::::: viii Acknowledgements ::::::::::::::::::::::::::::::::::::: ix Vita ::::::::::::::::::::::::::::::::::::::::::::: xi Chapter 1: Introduction :::::::::::::::::::::::::::::::::: 1 Chapter 1 References :::::::::::::::::::::::::::::::::::: 5 Chapter 2: Oxygen Fugacities of Extrasolar Rocks: Evidence for an Earth-like Geochem- istry of Exoplanets ::::::::::::::::::::::::::::::::::::: 6 Appendix A ::::::::::::::::::::::::::::::::::::::::: 17 Appendix B ::::::::::::::::::::::::::::::::::::::::: 40 Appendix C ::::::::::::::::::::::::::::::::::::::::: 52 Chapter 2 References :::::::::::::::::::::::::::::::::::: 58 Chapter 3: Where are the Extrasolar Mercuries? :::::::::::::::::::: 65 Appendix D ::::::::::::::::::::::::::::::::::::::::: 104 Chapter 3 References :::::::::::::::::::::::::::::::::::: 106 iv Chapter 4: Discovery of Beryllium in White Dwarfs Polluted by Planetesimal Accretion115 Appendix E ::::::::::::::::::::::::::::::::::::::::: 156 Chapter 4 References :::::::::::::::::::::::::::::::::::: 160 Chapter 5: Icy Exomoons Evidenced by Spallogenic Nuclides in Polluted White Dwarfs 173 Chapter 5 References :::::::::::::::::::::::::::::::::::: 195 Chapter 6: Future Work :::::::::::::::::::::::::::::::::: 203 Chapter 6 References :::::::::::::::::::::::::::::::::::: 207 v LIST OF FIGURES 2.1 Bulk compositions of solar system bodies and 6 WDs . 13 2.2 ∆IW at core formation vs today . 14 2.3 Calculated ∆IW for 6 rocky extrasolar bodies . 15 2.4 Summary diagram of bootstrap method . 31 2.5 Comparison of analytical and bootstrap methods . 32 2.6 Frequency distributions from bootstrap analysis for WDs . 33 2.7 Frequency distributions from bootstrap analysis for solar system rocks . 34 2.8 Variations in calculated ∆IW for WD GD 40 . 35 2.9 Logarithm of oxygen fugacity vs temperature . 36 3.1 Bulk compositions of solar system bodies and 16 WDs . 90 rock 3.2 Cumulative frequency distributions for xFeO for 2 WDs . 91 rock 3.3 Comparison of parent body xFeO describing origin of upper limits . 92 3.4 Comparison of parent body ∆IW from our 2 methods . 93 rock 3.5 Cumulative frequency distributions for xFeO for 16 WDs . 94 3.6 ∆IW versus Oxs/Fe.................................. 95 3.7 Model for accretion histories of example DA and DB WDs . 96 3.8 Evolution of ∆IW for CI chondrite material in WDs with various Teff . 97 3.9 Evolution of bulk composition and ∆IW for a reduced body . 98 3.10 Evolution of molar abundances in WD atmosphere for a reduced body . 99 3.11 Evolution of ∆IW for a reduced body in WDs with various Teff . 100 3.12 Evolution of ∆IW for a reduced body with <4% Fe core in WDs with various Teff 101 3.13 Comparison of ∆IW in steady-state vs build-up assumption . 102 4.1 Be II detection in spectrum of GALEX J2339-0424 . 137 vi 4.2 Be II detection in spectrum of GD 378 . 138 4.3 Distribution of radial velocities for GALEX J2339-0424 . 139 4.4 Distribution of radial velocities for GD 378 . 140 4.5 SED for GALEX J2339-0424 . 141 4.6 SED for GD 378 . 142 4.7 Element detections in spectrum for GALEX J2339-0424 . 143 4.8 Lighter element detections in spectra for GD 378 . 144 4.9 Heavier element detections in spectra for GD 378 . 145 4.10 Be II region in spectrum of GD 362 . 146 4.11 Various abundance ratios by number for WDs and solar system objects . 147 5.1 Element/Fe ratios for GALEX J2339-0424 parent body relative to various rocks 190 5.2 Reduced chi-squared for fits of GALEX J2339-0424 parent body to various rocks 191 5.3 Optimal accretion durations vs τdisk . 192 5.4 Diagram of proposed formation environment for ices enriched in Be . 193 6.1 Log abundance by number for Mg and Na normalized to Ca . 206 vii LIST OF TABLES 2.1 Parameters for WDs in Chapter 2 . 16 2.2 Elemental compositions of solar system rocks and WDs . 37 2.3 Input values for solar system rocks and WDs into ∆IW calculation . 38 3.1 Parameters and ∆IW values for WDs in Chapter 3 . 103 4.1 Historical element discoveries in cool polluted WDs . 148 4.2 Absorption Lines in GALEX J2339−0424 . 149 4.3 Absorption Lines in GD 378 . 150 4.4 Parameters for GALEX J2339-0424 and GD 378 . 151 4.5 Be ratios relative to CI chondrite for various astronomical objects . 152 4.6 Elemental abundances for GALEX J2339−0424 . 153 4.7 Elemental abundances for GD 378 . 154 4.8 Be upper limits in polluted WDs . 155 4.9 UV-Optical abundance comparison for GD 378 . 159 5.1 Elemental abundances for GALEX J2339-0424 . 194 viii ACKNOWLEDGMENTS Chapter 2 is a version of Doyle, A. E., Young, E. D., Klein, B., Zuckerman, B., and Schlicht- ing, H. E. (2019) Oxygen fugacities of extrasolar rocks: evidence for an Earth-like geochem- istry of exoplanets. Science, 366, 356-359. DOI: 10.1126/science.aax3901. A.E.D. performed the calculations and co-wrote the manuscript. E.D.Y. conceived of the project, supervised the calculations, and co-wrote the manuscript. B.Z. and B.K. analyzed the WD data. H.E.S. contributed to the statistical analysis. All authors contributed to the interpretation of the data and the preparation of the paper. E.D.Y. acknowledges support from the NASA Exo- planets program grant NNX16AB53G. A.E.D. acknowledges financial support from NASA Space Grant. H.E.S. gratefully acknowledges support from the National Aeronautics and Space Administration under grant 17 NAI18 2-0029 issued through the NExSS Program. Chapter 3 is a version of Doyle, A. E., Klein, B., Schlichting, H. E., and Young, E. D. (2020) Where are the Extrasolar Mercuries? Ap.J., 901, 10. DOI: 10.3847/1538- 4357/abad9a. A.E.D. performed the calculations and analyzed the WD data. B.K. assisted in analysis of WD data. H.E.S. provided the statistical framework for the treatment of WD data. E.D.Y. supervised the calculations. A.E.D. and E.D.Y. co-wrote the manuscript. This work was supported by NASA 2XRP grant No. 80NSSC20K0270 to E.D.Y.. H.E.S. grate- fully acknowledges support from the National Aeronautics and Space Administration under grant No. 17 NAI18 2-0029 issued through the NExSS Program. Chapter 4 is a version of Klein, B., Doyle, A. E., Zuckerman, B., Dufour, P., Blouin, S., Melis, C., Weinberger, A., and Young, E. D. Discovery of Beryllium in White Dwarfs Pol- luted by Accreted Planetesimals. Ap.J., accepted. A.E.D. was involved in observations using the KAST spectrograph, combining and normalizing spectra, iterations of the model atmo- spheres, creating the SED for GALEX J2339-0424 (Figure 4.5), making preliminary line lists (versions of those in Tables 4.2 and 4.3), and co-identifying the Be spectral lines. B.K. was supported by the A.P.S. M. Hildred Blewett Fellowship. A.E.D. and B.K. acknowledge sup- port from the NASA Exoplanets program award number 80NSSC20K0270 to E.D.Y.. Partial support was also provided by other NASA grants to UCLA. S.B. acknowledges support from ix the Laboratory Directed Research and Development program of Los Alamos National Lab- oratory under project number 20190624PRD2. C.M. and B.Z. acknowledge support from NSF grants SPG-1826583 and SPG-1826550. Chapter 5 is a version of Doyle, A. E., Desch, S. J., and Young, E. D. (2021) Icy Ex- omoons Evidenced by Spallogenic Nuclides in Polluted White Dwarfs. Ap.J.L., 907, L35. DOI: 10.3847/2041-8213/abd9ba. A.E.D. performed the composition calculations. S.J.D. suggested the formation environment for the parent body.
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