DOCSLIB.ORG

Introduction on Flame Ionization Detector and Thermal Conductivity Detector

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
Introduction on Flame Ionization Detector and Thermal Conductivity Detector Bioa al & na ic ly t ti ly c a a l n T Mishra, J Anal Bioanal Tech 2021, 12:S14 A e f c Journal of Analytical & Bioanalytical o h l n a i q n r u e u s o J Techniques:Open Access ISSN: 2155-9872 Editorial Open Access Introduction on Flame Ionization Detector and Thermal Conductivity Detector Anudev Mishra* Department of Bio-Chemistry, Mahamana Pandit Madan Mohan Malviya Cancer centre and Tata Memorial Centre, Uttar Pradesh, India *Corresponding author: Dr. Anudev Mishra, Department of Bio-Chemistry, Uttar Pradesh, India, E-mail: [email protected] Received date: July 09, 2021; Accepted date: July 22, 2021; Published date: July 29, 2021 Citation: Mishra A (2021) Introduction on Flame Ionization Detector and Thermal Conductivity Detector. J Anal Bioanal Tech 12: 002. Copyright: © 2021 Mishra A. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited. Description and hydrogen. Discharge ionization detector (DID) makes use of a excessive-voltage electric powered discharge to provide ions. The Commonly used detectors are the flame ionization detector (FID) polyarc reactor is an add-directly to new or present GC-FID units that and the thermal conductivity detector (TCD). While TCDs are useful converts all natural compounds to methane molecules previous to their in that they're non-destructive, its low detection restrict for maximum detection by means of the FID. This approach may be used to enhance analytes inhibits enormous use. FIDs are touchy in general to the reaction of the FID and permit for the detection of many greater hydrocarbons, and are greater touchy to them than TCD.FIDs can't carbon-containing compounds. The entire conversion of compounds to come across water or carbon dioxide which lead them to best for methane and the now equal reaction withinside the detector environmental natural analyte evaluation.FID is to 3 instances greater additionally removes the want for calibrations and requirements due to touchy to analyte detection than TCD. The TCD is predicated at the the fact reaction elements are all equal to the ones of methane. This thermal conductivity of rely passing round a skinny twine of tungsten- lets in for the fast evaluation of complicated combos that include rhenium with a modern visiting via it. In this installation helium or molecules wherein requirements aren't available. Flame photometric nitrogen function the provider fueloline due to their noticeably detector (FPD) makes use of a photomultiplier tube to come across excessive thermal conductivity which preserve the filament cool and spectral traces of the compounds as they're burned in a flame. The preserve uniform resistivity and electric performance of the filament. emitted mild is filtered and detected by means of a photomultiplier When analyte molecules elute from the column, blended with provider tube. In particular, phosphorus emission is round 510–536 nm and fueloline, the thermal conductivity decreases whilst there may be an sulfur emission is at 394 nm. With an atomic emission detector boom in filament temperature and resistivity ensuing in fluctuations in (AED), a pattern eluting from a column enters a chamber that's voltage in the end inflicting a detector reaction. Detector sensitivity is energized by means of microwaves that set off a plasma. The plasma proportional to filament modern whilst it's far inversely proportional reasons the analyte pattern to decompose and positive factors generate to the instant environmental temperature of that detector in addition to an atomic emission spectra. The atomic emission spectra is diffracted glide charge of the provider fueloline. In a flame ionization detector by means of a diffraction grating and detected by means of a chain of (FID), electrodes are positioned adjoining to a flame fueled by means photomultiplier tubes or picturegraph diodes. Electron seize detector of hydrogen / air close to the go out of the column, and while carbon (ECD) makes use of a radioactive beta particle (electron) supply to containing compounds go out the column they're pyrolyzed by means degree the diploma of electron seize. ECD are used for the detection of the flame. This detector works handiest for natural / hydrocarbon of molecules containing electronegative / chickening out factors and containing compounds because of the capacity of the carbons to shape useful companies like halogens, carbonyl, nitriles, nitro companies, cations and electrons upon pyrolysis which generates a modern among and organometalics. In this sort of detector both nitrogen or 5% the electrodes. The boom in modern is translated and looks as a top in a methane in argon is used because the cellular segment provider chromatogram. FIDs have low detection limits (some picograms fueloline. The provider fueloline passes among electrodes positioned consistent with second) however they're not able to generate ions from on the quit of the column, and adjoining to the cathode (bad electrode) carbonyl containing carbons. FID well matched provider gasses is living a radioactive foil along with 63Ni. The radioactive foil emits a encompass helium, hydrogen, nitrogen, and argon. Alkali flame beta particle (electron) which collides with and ionizes the provider detector (AFD) or alkali flame ionization detector (AFID) has fueloline to generate greater ions ensuing in a modern. When analyte excessive sensitivity to nitrogen and phosphorus, much like NPD. molecules with electronegative / chickening out factors or useful However, the alkaline steel ions are furnished with the hydrogen companies electrons are captured which ends up in a lower in modern fueloline, instead of a bead above the flame. For this cause AFD does producing a detector reaction? Nitrogen–phosphorus detector (NPD), a now no longer go through the "fatigue" of the NPD, however gives a shape of thermionic detector wherein nitrogen and phosphorus regular sensitivity over lengthy length of time. In addition, while alkali regulate the paintings feature on a in particular lined bead and a ions aren't delivered to the flame, AFD operates like a trendy FID. A ensuing modern is measured. catalytic combustion detector (CCD) measures flamable hydrocarbons J Anal Bioanal Tech, an open access journal Volume 12 • Issue S14 • 1000002 ISSN: 2155-9872.
Load more

Recommended publications
  • Low Level Formaldehyde Detection with the Polyarc System
    Low Level Formaldehyde Detection with the Polyarc System Application Note Sub 1 mg/kg (ppm) formaldehyde, or multiple detectors to detect formaldehyde along with other common organics1. Author Jonathan McIntyre Activated Research Company Eden Prairie, MN [email protected] Abstract Method development for the analysis of formaldehyde has been historically tricky to derive in a simplistic and easily available way for all laboratories to perform. The detector of choice when using gas chromatography (GC) is the flame ionization detector (FID) because of Figure 1. Polyarc System on an Agilent 7890 GC. its large linear dynamic range and robustness. Formaldehyde, however, has a low response in the In this application note, a Polyarc is used with a FID due to its lack of C-H bonds. Incorporation of the GC/FID to and accurately detect formaldehyde down Polyarc reactor into the GC/FID system allowed for to the single mg/kg (ppm) level. Previously, an FID sub-ppm detection of formaldehyde by converting it to was not able to accurately detect formaldehyde due to methane prior to FID detection. the small amount of C-H bonds available for ionization in the flame. This is a known issue with heteroatom- containing organic compounds, which has historically Introduction been resolved with lengthy calibration and verification steps to estimate the FID response per unit of concentration for each compound. The Polyarc Methanal, commonly known as formaldehyde, is one converts organic compounds to methane after of the most common Volatile Organic Compounds chromatographic separation via a two-stage (VOCs) that is present in numerous products including combustion-reduction reaction sequence.
    [Show full text]
  • High Resolution Mass Spectrometry to Explore Molecular-Level Understanding of Biomass Pyrolysis Carolyn P
    Iowa State University Capstones, Theses and Graduate Theses and Dissertations Dissertations 2017 High resolution mass spectrometry to explore molecular-level understanding of biomass pyrolysis Carolyn P. Hutchinson Iowa State University Follow this and additional works at: https://lib.dr.iastate.edu/etd Part of the Analytical Chemistry Commons Recommended Citation Hutchinson, Carolyn P., "High resolution mass spectrometry to explore molecular-level understanding of biomass pyrolysis" (2017). Graduate Theses and Dissertations. 15535. https://lib.dr.iastate.edu/etd/15535 This Dissertation is brought to you for free and open access by the Iowa State University Capstones, Theses and Dissertations at Iowa State University Digital Repository. It has been accepted for inclusion in Graduate Theses and Dissertations by an authorized administrator of Iowa State University Digital Repository. For more information, please contact [email protected]. High resolution mass spectrometry to explore molecular-level understanding of biomass pyrolysis by Carolyn P. Hutchinson A dissertation submitted to the graduate faculty in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY Major: Analytical Chemistry Program of Study Committee: Young-Jin Lee, Major Professor Robert S. Houk Emily Smith Javier Vela Wenyu Huang The student author and the program of study committee are solely responsible for the content of this dissertation. The Graduate College will ensure this dissertation is globally accessible and will not permit alterations
    [Show full text]
  • M.Sc. [Botany] 346 13
    cover page as mentioned below: below: mentioned Youas arepage instructedcover the to updateupdate to the coverinstructed pageare asYou mentioned below: Increase the font size of the Course Name. Name. 1. IncreaseCourse the theof fontsize sizefont ofthe the CourseIncrease 1. Name. use the following as a header in the Cover Page. Page. Cover 2. the usein the followingheader a as as a headerfollowing the inuse the 2. Cover Page. ALAGAPPAUNIVERSITY UNIVERSITYALAGAPPA [Accredited with ’A+’ Grade by NAAC (CGPA:3.64) in the Third Cycle Cycle Third the in (CGPA:3.64) [AccreditedNAAC by withGrade ’A+’’A+’ Gradewith by NAAC[Accredited (CGPA:3.64) in the Third Cycle and Graded as Category–I University by MHRD-UGC] MHRD-UGC] by University and Category–I Graded as as Graded Category–I and University by MHRD-UGC] M.Sc. [Botany] 003 630 – KARAIKUDIKARAIKUDI – 630 003 346 13 EDUCATION DIRECTORATEDISTANCE OF OF DISTANCEDIRECTORATE EDUCATION BIOLOGICAL TECHNIQUES IN BOTANY I - Semester BOTANY IN TECHNIQUES BIOLOGICAL M.Sc. [Botany] 346 13 cover page as mentioned below: below: mentioned Youas arepage instructedcover the to updateupdate to the coverinstructed pageare asYou mentioned below: Increase the font size of the Course Name. Name. 1. IncreaseCourse the theof fontsize sizefont ofthe the CourseIncrease 1. Name. use the following as a header in the Cover Page. Page. Cover 2. the usein the followingheader a as as a headerfollowing the inuse the 2. Cover Page. ALAGAPPAUNIVERSITY UNIVERSITYALAGAPPA [Accredited with ’A+’ Grade by NAAC (CGPA:3.64) in the Third Cycle Cycle Third the in (CGPA:3.64) [AccreditedNAAC by withGrade ’A+’’A+’ Gradewith by NAAC[Accredited (CGPA:3.64) in the Third Cycle and Graded as Category–I University by MHRD-UGC] MHRD-UGC] by University and Category–I Graded as as Graded Category–I and University by MHRD-UGC] M.Sc.
    [Show full text]
  • Modified FID for Determination of Underivatized Formaldehyde by GC
    Modified FID for Determination of Formaldehyde in Consumer Products Application Note Sensitivity Comparison for GC/FID Introduction Formaldehyde is a hazardous compound commonly found in treated wood, caulk, hair products, and a variety of other substances (soil near burial grounds, glue, plywood, fiberboard insulation, car exhaust, etc.). OSHA established an exposure limit of 0.75 ppm on average over an 8-hour work day. Measuring Author compounds like formaldehyde and formic acid by gas chromatography is difficult due to the low response in Erick Walts the flame ionization detector. Historically, Lee N. Polite formaldehyde determination required the addition of Axion Labs & Training Institute a mass spectrometer (MS) or photo ionization detector 14 N Peoria St (PID). There are also HPLC methods, but those require Chicago, IL 60607 the use of post-column derivatization to detect the [email protected] formaldehyde. Abstract In this study, we investigate the use of the Polyarc® two-stage reactor in-line with a flame ionization detector to measure the presence of formic acid and Formaldehyde is a common, naturally occurring formaldehyde. The first stage of the reactor oxidizes chemical found in foods and added to treated wood all the carbon-containing compounds into carbon products commonly used in the construction of dioxide. The second stage employs a proprietary homes across the world. Formaldehyde has been catalyst in a hydrogen-rich environment to convert the known to be a carcinogen and health hazard to carbon dioxide into methane, which is then easily humans. The need and use of a simple and effective detected by the FID.
    [Show full text]
  • Increased Instrument Uptime with Improved Methanizer for Dissolved Gas Analysis
    Increased Instrument Uptime with Improved Methanizer for Dissolved Gas Analysis Application Note Dissolved gas analysis (DGA)/Transformer oil gas analysis (TOGA) Author Andrew Jones Activated Research Company 7561 Corporate Way Eden Prairie, MN 55344 [email protected] Abstract A nickel catalyst methanizer that was previously poisoned by transformer oil gas was replaced by a Polyarc methanizer on an Agilent 7890 gas chromatograph (GC) analyzer equipped for dissolved gas analysis under ASTM D3612-C. The analyzer met or exceeded the performance criteria from the ASTM Figure 1. Power Transformer method in all aspects. The Polyarc’s two-stage oxidation-reduction catalyst system eliminated The introduction and propagation of new transformer unplanned downtime due to methanizer failures. oils have led to increased performance requirements These improvements led to considerable cost and time for methanizers that convert CO and CO2 to CH4 for savings, and increased sample throughput. FID quantification. Specifically, many labs have struggled with frequent methanizer failures due to catalyst poisoning from these oils. Introduction The Polyarc reactor introduced by ARC in October Dissolved gas analysis (DGA) is an important method 2015, is the latest improvement to methanizer designs for the determination of pending or current faults and utilizes advances in nanoengineered catalysts and within a power transformer. Specifically, as a 3D metal printing to improve robustness, resist transformer ages, the oil that insulates and cools poisons, and improve performance and ease of use. components can begin to degrade. The analysis of Here, we demonstrate how the replacement of a nickel several dissolved gases (H2, N2, O2, CO, CO2, C2H2, catalyst methanizer with a Polyarc can improve DGA C2H4, C2H6, C3H8, C3H6, C4H8) can give early indicators analysis and reduce instrument downtime leading to of faults and transformer stability.
    [Show full text]
  • Formaldehyde Analysis in Water Using the Polyarc System
    Formaldehyde Analysis in Water using the Polyarc System Application Note Increased FID Response Authors Bruce Pierson, James Humpula POET Research 4615 N Lewis Ave Sioux Falls, South Dakota 57104 Abstract Formaldehyde has a poor response when run by conventional GC-FID. However, when run on a GC-FID system equipped with a Polyarc® Figure 1. Polyarc System on an Agilent 7890 GC. reactor, formaldehyde (HCHO) can be seen down to at least 100 mg/L in water. It was The response-per-carbon in the FID is equivalent for also found that to reduce apparent adsorption all molecules because the FID only ionizes methane. of HCHO onto the glass surface of the liner, it was necessary to exchange the default While the catalytic reaction of the Polyarc allows the split/splitless liner for an Ultra Inert liner. formaldehyde to be detected, interactions within the inlet and on the column can still affect the intensity Introduction and shape of the peak. These interactions can include adsorption and chemical interactions with the column’s stationary phase. This application note Formaldehyde is one of many compounds monitored describes the optimization of a method for analyzing when investigating Hazardous Air Pollutants (HAPs). formaldehyde using a GC system with a Polyarc Unfortunately, gas chromatographic (GC) analysis of reactor. During optimization, it was discovered that formaldehyde requires derivatization, which formaldehyde can adsorb to the inlet liner; an ultra- complicates real time monitoring using GC, or use of inert liner was found to resolve this issue. GC detectors, which can have limitations in sensitivity. Previous work has shown that the Polyarc System Experimental (Figure 1) can be used to detect formaldehyde in aqueous solution without the need for derivatization.1 A stock solution of 37% w/w formaldehyde in water/ The Polyarc is a catalytic microreactor that is an methanol was diluted to ~10,000 mg/L HCHO with intermediate step after the column and before deionized water.
    [Show full text]
  • International Journal of Medical Studies Print ISSN 2542-2766
    Available at www.ijmsonline.in Available online 30 july 2019 International Journal of Medical Studies Print ISSN 2542-2766 Original Article IJMS JULY 2019/Vol 4/Issue 7 A REVIEW ON MODERN TECHNIQUES OF PHARMACEUTICAL ANALYSIS 1Karan Gupta 1Department of Pharmaceutical Analysis, BRNCOP, Mandsaur, Madhya Pradesh Corresponding author: [email protected] ABSTRACT Traditionally, pharmaceutical analysis referred to the chemical analysis of drug molecules. However, over the years, modern pharmaceutical analysis has evolved beyond this to encompass combination techniques, high- throughput technologies, chemo metrics, micro dosing studies, miniaturization and nanotechnology. These analytical advances are now being employed in all stages of drug discovery and the focus of this review will be on how these technologies are being employed within this process. With new, improved and evolving technologies, as well as new applications for existing technology, the search for new drugs for the prevention and treatment of human diseases continues Keywords: Chromatography, Pharmaceutical Analysis, Constructive Technologies. INTRODUCTION Traditionally, pharmaceutical analysis referred to the chemical analysis of drug molecules. However, over the years, modern pharmaceutical analysis has evolved beyond this to encompass combination techniques, high-throughput technologies, chemo metrics, micro dosing studies, miniaturization and nanotechnology. These analytical advances are now being employed in all stages of drug discovery and the focus of this review
    [Show full text]
  • New GC and Sample Preparation Products for 2016
    297–372 5, 34 Number Volume Volume 34 Number 5 May 2016 www.chromatographyonline.com LCGC NORTH AMERICA NORTH LCGC New GC and Sample Preparation Products for 2016 How to Tackle an Unknown Extracting Peptides from Whole Blood What You Need May 2016 May to Know about LC Pumps WHOSE GC SOURCE CAN BE SERVICED IN LESS THAN 3 MINUTES? Th roughput and uptime are crucial in any environmental monitoring laboratory. is a registered trademark of PerkinElmer, Inc. Which is why PerkinElmer engineered the ® Clarus® SQ 8 GC/MS with a revolutionary SMARTsource™ that can be removed, cleaned, and reassembled in a matt er of minutes. Streamline and simplify your routine applications with the Clarus SQ 8 GC/MS. And enjoy a source of unparalleled precision and productivity. www.perkinelmer.com/gcms ©2016 PerkinElmer,©2016 Inc. 400344_01. All rights reserved. PerkinElmer Wine should ONLY be wine. People trust their wine to be exactly as they expect. Unadulterated, safe, consistent. And not coincidentally, each of the world’s top ten beverage companies trust us to help keep it that way. They know how long it takes to build a brand’s reputation and how quickly one can disappear. So they come to us and our widest instrumentation portfolio on the planet — ion, liquid and gas chromatography, metal analysis, mass spectrometry, discrete analyzers to data management — for accurate, reliable answers no matter where they are in the beverage analysis process. They trust us to help keep their product their product. And equally important, their brand their brand. YOUR BRAND IS EVERYTHING. ThermoFisher.com/BeverageTesting ©2016 Thermo FisherrS Sciecentint ficfi Inc.
    [Show full text]
  • Innovation Awakens
    DECEMBER 2015 # 35 Upfront In My View Feature Sitting Down With Introducing NASA’s How to teach computers Exploring chirality and Deirdre Cabooter – chemical laptop plasma physics the origins of life going far, but not alone 10 – 11 18 36 – 41 50 – 51 Innovation Awakens The Analytical Scientist Innovation Awards return for 2015! 25 – 33 www.theanalyticalscientist.com WHEN STUDYING TISSUE IMAGES, THE MORE YOU SEE THE BETTER YOU UNDERSTAND. Waters Full Spectrum Molecular Imaging system is mass spectrometry-based, it’s true. What mass spectrometry brings to imaging is truly amazing. FULL SPECTRUM Just imagine label-free, multiplexed and objective molecular information at MOLECULAR IMAGING your fingertips. With a fraction of the time and effort you put into traditional imaging techniques, you can now uncover more information than ever before. To see for yourself, visit waters.com/SEEMORE PHARMACEUTICAL ■ HEALTH SCIENCES ■ FOOD ■ ENVIRONMENTAL ■ CHEMICAL MATERIALS ©2015 Waters Corporation. Waters and The Science of What’s Possible are registered trademarks of Waters Corporation. Online this Month WHEN STUDYING TISSUE IMAGES, THE MORE YOU SEE Tea With Monika The delightful Monika Dittman joins Rich Whitworth for tea in Geneva and THE BETTER YOU UNDERSTAND. once again “surfs” the limits of liquid chromatography. Monika considers a future where multidimensional separations are a necessity – after all, she says, instrument companies have already offered the ability to perform routine 2D-LC analyses. Looking further ahead, Monika believes Peter Schoenmakers’ work on the potential of three-dimensional LC offers a glimpse of the future: seriously powerful separations. Watch the video now: tas.txp.to/1215/teawithmonika Waters Full Spectrum Molecular Imaging system is mass spectrometry-based, it’s true.
    [Show full text]
  • Digital Method Development Principles, Benefits, and Potential Pitfalls
    March 2018 Volume 31 Number 3 www.chromatographyonline.com Digital Method Development Principles, benefits, and potential pitfalls LC TROUBLESHOOTING GC CONNECTIONS BIOPHARMACEUTICAL Eluent preparation for HILIC The past and present of GC PERSPECTIVES detection Peptide mapping using micro-pillar array columns All other trademarks are the property of their respective owners. WHOSE TRIPLE QUAD CAN GIVE YOU 15% MORE TIME? Copyright © 2016 PerkinElmer, Inc. 400358A_03. All rights reserved. PerkinElmer® is a registered trademark of SIMPLE: PERKINELMER. Whether you’re performing environmental, food, or industrial testing, your lab needs to analyze more and increasingly complex samples under tighter regulatory standards. Because our new QSight™ triple-quad LC/MS/MS needs no routine cleaning and maintenance, you get up to 15% more uptime (that’s up to 35 more days per year) to take on your increased testing workload. Plus, our patented technology delivers exceptional sensitivity and reliability along with all that productivity. QSight: A triple quad that simply knows the value of time. Learn more at www.perkinelmer.com/QSight Put Our Insight to Work For You Imagine how productive you could be if you had access to a global team of Real Stories from the Lab experts who strive to deliver insight in every interaction with your lab. With True Story 44: Agilent CrossLab, that’s exactly what you get. Lab-Wide Data Analytics Consider us for compliance services, complete lab relocations, lab analytics System data insight leads to to optimize performance, on-site and on-demand training, as well as complete improved lab performance. service coverage for your Agilent and non-Agilent instruments.
    [Show full text]
  • Gas Chromatography a Mini Review
    Research and Reviews Journal of Pharmaceutical Analysis e-ISSN: 2320-0812 p-ISSN: 2347-2340 Gas Chromatography a Mini Review S. Pravallika* Department of Pharmaceutical Analysis, Srinivasa Pharmaceutical Institute and Center for Research SPICR, JNTUH, Telangana, India Review Article Received: 20/08/2016 ABSTRACT Revised: 29/08/2016 Accepted: 31/08/2016 Gas Chromatography (GC or GLC) is a normally utilized analytic *For Correspondence technique as a part of numerous research and industrial research facilities for quality control and in addition identification and quantitation of S. Pravallika, Department of components in a mixture. GC is likewise utilized technique as a part of Pharmaceutical Analysis, numerous environmental and forensic labs since it takes into consideration Srinivasa Pharmaceutical the detection of very little quantities. An expansive variety of tests can be Institute and Center for research analysed the until the compounds are adequately thermally steady and (SPICR), JNTUH, Telangana, India reasonably volatile. In gas chromatography (GC), the mobile phase is a inert gas (eg E-mail: [email protected] helium). The stationary stage is a thin layer of a inert fluid on an inert solid support -, for example, beads of silica pressed into a long thin tube (this Keywords: Gas chromatograph, adaptable tube is curled ordinarily inside a thermostatically-controlled oven Autosamplers, Inlets, Detectors, to keep it at a consistent temperature). Photo-ionization detector GAS CHROMATOGRAPHY A gas chromatograph (GC) is an analytical instrument that is utilized to gauge the substance of various segments in a sample [1,2]. The investigation performed by a gas chromatograph is gas chromatography. Gas chromatography (GC) is a common kind of chromatography used as a piece of analytical science for segregating and investigating exacerbates that can be vaporized without disintegration.
    [Show full text]
  • Tjwilke 1.Pdf
    Catalysis with Dispersed Cation-Exchanged Polyoxometalates by Trenton J. Wilke A dissertation submitted in partial fulfillment of the requirements for the degree of Doctor of Philosophy (Chemical Engineering) in the University of Michigan 2018 Doctoral Committee: Adjunct Professor Mark A. Barteau, Co-Chair Professor Levi T. Thompson, Co-Chair Professor Bart Bartlett Professor Suljo Linic Trenton J. Wilke [email protected] ORCID iD: 0000-0001-9444-7820 © Trenton J. Wilke 2018 Acknowledgements I would like to thank my advisor, Professor Mark Barteau, for the opportunity to join his research group and for his mentorship and guidance throughout this journey. I could not ask for a better advisor; supportive, available, brilliant, and a critical eye would begin a list longer than I have vocabulary to construct. I cannot adequately portray his knowledge and wit which I found invaluable time and time again. The challenge and opportunity of setting up the lab from scratch is something that I will cherish and benefit from throughout my career. I would also like to acknowledge Professor Barteau and the University of Michigan Energy Institute for providing funding throughout my PhD. Thank you to Professor Levi Thompson, for serving as an unofficial co-advisor since my early days in the Barteau lab and as a co-chair on my dissertation committee. The support and experience I gained through your mentorship, the mentorship of your students, and by honing my presentation skills through Thompson group meetings was essential to my success as a PhD student. I also want to gratefully acknowledge your generosity for allowing me to use equipment in your lab throughout my PhD, including the equipment necessary for many of the characterization techniques discussed in this work, including BET, NH3 TPD, TGA, the catalyst press, and the like.
    [Show full text]