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Old Puzzle of Incommensurate Crystal Structure of Calaverite Aute2 And
Old puzzle of incommensurate crystal structure of calaverite AuTe2 and predicted stability of novel AuTe compound Sergey V. Streltsova,b,1, Valerii V. Roizenc, Alexey V. Ushakova, Artem R. Oganovc,d, and Daniel I. Khomskiie aDepartment of Theory of Low-Dimensional Spin Systems, Institute of Metal Physics, 620990 Yekaterinburg, Russia; bDepartment of Theoretical Physics and Applied Mathematics, Ural Federal University, 620002 Yekaterinburg, Russia; cComputational Materials Discovery Laboratory, Moscow Institute of Physics and Technology, 141701 Dolgoprudny, Moscow Region, Russian Federation; dMaterials Discovery Laboratory, Skolkovo Institute of Science and Technology, 143026 Skolkovo, Russian Federation; and eII. Physikalisches Institut, Universitat¨ zu Koln,¨ D-50937 Cologne, Germany Edited by James R. Chelikowsky, The University of Texas at Austin, Austin, Texas, and accepted by Editorial Board Member John D. Weeks August 14, 2018 (received for review February 15, 2018) Gold is a very inert element, which forms relatively few com- Old Puzzle of Calaverite’s Crystal Structure pounds. Among them is a unique material—mineral calaverite, AuTe2 has a distorted layered CdI2-type structure [the aver- AuTe2. Besides being the only compound in nature from which age structure has space group C 2=m (6)], with triangular layers one can extract gold on an industrial scale, it is a rare exam- of Au with Te atoms in between. However, there is a periodic ple of a natural mineral with incommensurate crystal structure. displacive modulation along the [010] direction, which makes Moreover, it is one of few systems based on Au, which become overall crystal structure incommensurate (7). The mechanism superconducting (at elevated pressure or doped by Pd and Pt). -
Inferred Phase Relations in Part of the System Au–Ag–Te: an Integrated Analytical Study of Gold Ore from the Golden Mile, Kalgoorlie, Australia
Mineralogy and Petrology (2005) 83: 283–293 DOI 10.1007/s00710-004-0065-1 Inferred phase relations in part of the system Au–Ag–Te: an integrated analytical study of gold ore from the Golden Mile, Kalgoorlie, Australia L. Bindi1, M. D. Rossell2, G. Van Tendeloo2, P. G. Spry3, and C. Cipriani1 1 Museo di Storia Naturale, Sezione di Mineralogia, Universita degli Studi di Firenze, Italy 2 Electron Microscopy for Materials Research (EMAT), University of Antwerp, Belgium 3 Department of Geological and Atmospheric Sciences, Iowa State University, Ames, IA, USA Received May 24, 2004; revised version accepted October 7, 2004 Published online December 7, 2004; # Springer-Verlag 2004 Editorial handling: J. G. Raith Summary Integrated X-ray powder diffraction, scanning electron microscopy, electron probe, and transmission electron microscopy studies have identified the rare contact assemblage calaverite–sylvanite–hessite in a sample of gold ore from the Golden Mile deposit, Kalgoorlie, Australia. The presence of coexisting calaverite–hessite at Kalgoorlie is a non-equilibrium assemblage whereby the stable hessite-bearing assemblage is hessite– sylvanite, which formed from the breakdown of the -phase or -phase below 120 C, stuutzite€ þ -phase, or sylvanite þ stuutzite€ þ -phase, as predicted by Cabri (1965). Introduction Epizonal and mesozonal gold and gold–silver telluride deposits spatially asso- ciated with calc-alkaline, alkaline, and mafic igneous rocks are among the largest resources of gold in the world. They include Golden Mile, Kalgoorlie, Australia (e.g., Clout et al., 1990; Shackleton et al., 2003), Emperor, Fiji (e.g., Ahmad et al., 1987; Pals and Spry, 2003), Cripple Creek, Colorado (e.g. -
Symposium on Agate and Cryptocrystalline Quartz
Symposium on Agate and Cryptocrystalline Quartz September 10 – 13, 2005 Golden, Colorado Sponsored by Friends of Mineralogy, Colorado Chapter; Colorado School of Mines Geology Museum; and U.S. Geological Survey 2 Cover Photos {top left} Fortification agate, Hinsdale County, Colorado, collection of the Geology Museum, Colorado School of Mines. Coloration of alternating concentric bands is due to infiltration of Fe with groundwater into the porous chalcedony layers, leaving the impermeable chalcedony bands uncolored (white): ground water was introduced via the symmetric fractures, evidenced by darker brown hues along the orthogonal lines. Specimen about 4 inches across; photo Dan Kile. {lower left} Photomicrograph showing, in crossed-polarized light, a rhyolite thunder egg shell (lower left) a fibrous phase of silica, opal-CTLS (appearing as a layer of tan fibers bordering the rhyolite cavity wall), and spherulitic and radiating fibrous forms of chalcedony. Field of view approximately 4.8 mm high; photo Dan Kile. {center right} Photomicrograph of the same field of view, but with a 1 λ (first-order red) waveplate inserted to illustrate the length-fast nature of the chalcedony (yellow-orange) and the length-slow character of the opal CTLS (blue). Field of view about 4.8 mm high; photo Dan Kile. Copyright of articles and photographs is retained by authors and Friends of Mineralogy, Colorado Chapter; reproduction by electronic or other means without permission is prohibited 3 Symposium on Agate and Cryptocrystalline Quartz Program and Abstracts September 10 – 13, 2005 Editors Daniel Kile Thomas Michalski Peter Modreski Held at Green Center, Colorado School of Mines Golden, Colorado Sponsored by Friends of Mineralogy, Colorado Chapter Colorado School of Mines Geology Museum U.S. -
Minerals of the San Luis Valley and Adjacent Areas of Colorado Charles F
New Mexico Geological Society Downloaded from: http://nmgs.nmt.edu/publications/guidebooks/22 Minerals of the San Luis Valley and adjacent areas of Colorado Charles F. Bauer, 1971, pp. 231-234 in: San Luis Basin (Colorado), James, H. L.; [ed.], New Mexico Geological Society 22nd Annual Fall Field Conference Guidebook, 340 p. This is one of many related papers that were included in the 1971 NMGS Fall Field Conference Guidebook. Annual NMGS Fall Field Conference Guidebooks Every fall since 1950, the New Mexico Geological Society (NMGS) has held an annual Fall Field Conference that explores some region of New Mexico (or surrounding states). Always well attended, these conferences provide a guidebook to participants. Besides detailed road logs, the guidebooks contain many well written, edited, and peer-reviewed geoscience papers. These books have set the national standard for geologic guidebooks and are an essential geologic reference for anyone working in or around New Mexico. Free Downloads NMGS has decided to make peer-reviewed papers from our Fall Field Conference guidebooks available for free download. Non-members will have access to guidebook papers two years after publication. Members have access to all papers. This is in keeping with our mission of promoting interest, research, and cooperation regarding geology in New Mexico. However, guidebook sales represent a significant proportion of our operating budget. Therefore, only research papers are available for download. Road logs, mini-papers, maps, stratigraphic charts, and other selected content are available only in the printed guidebooks. Copyright Information Publications of the New Mexico Geological Society, printed and electronic, are protected by the copyright laws of the United States. -
About Our Mineral World
About Our Mineral World Compiled from series of Articles titled "TRIVIAL PURSUITS" from News Nuggets by Paul F. Hlava "The study of the natural sciences ought to expand the mind and enlarge the ability to grasp intellectual problems." Source?? "Mineral collecting can lead the interested and inquisitive person into the broader fields of geology and chemistry. This progression should be the proper outcome. Collecting for its own sake adds nothing to a person's understanding of the world about him. Learning to recognize minerals is only a beginning. The real satisfaction in mineralogy is in gaining knowledge of the ways in which minerals are formed in the earth, of the chemistry of the minerals and of the ways atoms are packed together to form crystals. Only by grouping minerals into definite categories is is possible to study, describe, and discuss them in a systematic and intelligent manner." Rock and Minerals, 1869, p. 260. Table of Contents: AGATE, JASPER, CHERT AND .............................................................................................................................2 GARNETS..................................................................................................................................................................2 GOLD.........................................................................................................................................................................3 "The Mystery of the Magnetic Dinosaur Bones" .......................................................................................................4 -
Toward the Crystal Structure of Nagyagite, [Pb(Pb,Sb)S2][(Au,Te)]
American Mineralogist, Volume 84, pages 669–676, 1999 Toward the crystal structure of nagyagite, [Pb(Pb,Sb)S2][(Au,Te)] HERTA EFFENBERGER,1,* WERNER H. PAAR,2 DAN TOPA,2 FRANZ J. CULETTO,3 AND GERALD GIESTER1 1Institut für Mineralogie und Kristallographie, Universität Wien, Althanstrasse 14, A-1090 Vienna, Austria 2Institut für Mineralogie, Universität Salzburg, Hellbrunnerstrasse 34, A-5020 Salzburg 3Kärntner Elektrizitäts AG, Arnulfplatz 2, A-9021 Klagenfurt, Austria ABSTRACT Synthetic nagyagite was grown from a melt as part of a search for materials with high-tempera- ture superconductivity. Electron microprobe analyses of synthetic nagyagite and of nagyagite from the type locality Nagyág, Transylvania (now S˘ac˘arîmb, Romania) agree with data from literature. The crystal chemical formula [Pb(Pb,Sb)S2][(Au,Te)] was derived from crystal structure investi- gations. Nagyagite is monoclinic pseudotetragonal. The average crystal structure was determined from both synthetic and natural samples and was refined from the synthetic material to R = 0.045 for 657 single-crystal X-ray data: space group P21/m, a = 4.220(1) Å, b = 4.176(1) Å, c = 15.119(3) Å, β = 95.42(3)°, and Z = 2. Nagyagite features a pronounced layer structure: slices of a two slabs thick SnS-archetype with formula Pb(Pb,Sb)S2 parallel to (001) have a thickness of 9.15 Å. Te and Au form a planar pseudo-square net that is sandwiched between the SnS-archetype layers; it is [4Te] assumed that planar Au Te4 configurations are edge connected to chains and that Te atoms are in a zigzag arrangement. -
Intergrowth Texture in Au-Ag-Te Minerals from Sandaowanzi Gold Deposit, Heilongjiang Province: Implications for Ore-Forming Environment
Article Geology July 2012 Vol.57 No.21: 27782786 doi: 10.1007/s11434-012-5170-7 SPECIAL TOPICS: Intergrowth texture in Au-Ag-Te minerals from Sandaowanzi gold deposit, Heilongjiang Province: Implications for ore-forming environment XU Hong*, YU YuXing, WU XiangKe, YANG LiJun, TIAN Zhu, GAO Shen & WANG QiuShu School of Earth Sciences and Resources, China University of Geosciences, Beijing 100083, China Received January 16, 2012; accepted March 16, 2012; published online May 6, 2012 Sandaowanzi gold deposit, Heilongjiang Province, is the only single telluride type gold deposit so far documented in the world, in which 90% of gold is hosted in gold-silver telluride minerals. Optical microscope observation, scanning electron microscope, electron probe and X-ray diffraction analysis identified abundant intergrowth textures in the Au-Ag-Te minerals, typified by sylvanite-hosting hessite crystals and hessite-hosting petzite crystals. The intergrown minerals and their chemistry are consistent, and the hosted minerals are mostly worm-like or as oriented stripes, evenly distributed in the hosting minerals, with clear and smooth interfaces. These suggest an exsolution origin for the intergrowth texture. With reference to the phase-transformation temperature derived from synthesis experiments of tellurides, the exsolution texture of Au-Ag-Te minerals implies that the veined tellurides formed at 150–220°C. The early stage disseminated tellurides formed at log f(Te2) from 13.6 to 7.8, log f(S2) from 11.7 to 7.6, whereas the late stage veined tellurides formed at log f(Te2) ranging from 11.2 to 9.7 and log f(S2) from 16.8 to 12.2. -
Tungsten Minerals and Deposits
DEPARTMENT OF THE INTERIOR FRANKLIN K. LANE, Secretary UNITED STATES GEOLOGICAL SURVEY GEORGE OTIS SMITH, Director Bulletin 652 4"^ TUNGSTEN MINERALS AND DEPOSITS BY FRANK L. HESS WASHINGTON GOVERNMENT PRINTING OFFICE 1917 ADDITIONAL COPIES OF THIS PUBLICATION MAY BE PROCURED FROM THE SUPERINTENDENT OF DOCUMENTS GOVERNMENT PRINTING OFFICE WASHINGTON, D. C. AT 25 CENTS PER COPY CONTENTS. Page. Introduction.............................................................. , 7 Inquiries concerning tungsten......................................... 7 Survey publications on tungsten........................................ 7 Scope of this report.................................................... 9 Technical terms...................................................... 9 Tungsten................................................................. H Characteristics and properties........................................... n Uses................................................................. 15 Forms in which tungsten is found...................................... 18 Tungsten minerals........................................................ 19 Chemical and physical features......................................... 19 The wolframites...................................................... 21 Composition...................................................... 21 Ferberite......................................................... 22 Physical features.............................................. 22 Minerals of similar appearance................................. -
Bi-Se-Te Mineralization from Úhorná (Spišsko Gemerské Rudohorie Mts., Slovakia): a Preliminary Report
MINERALOGIA, 39, No. 3–4: 87–103 (2008) DOI: 10.2478/v10002-008-0007-3 www.Mineralogia.pl MINERALOGICAL SOCIETY OF POLAND POLSKIE TOWARZYSTWO MINERALOGICZNE Original paper Bi-Se-Te mineralization from Úhorná (Spišsko Gemerské Rudohorie Mts., Slovakia): A preliminary report Jaroslav PRŠEK1*, Dušan PETEREC2 1 Comenius University, Faculty of Natural Sciences, Department of Mineralogy and Petrology, Mlynská dolina 842 15, Bratislava; e-mail: [email protected] 2 Aragonit s.r.o, Rovníková 8, 040 12 Košice * Corresponding author Received: January 31, 2008 Accepted: January 07, 2009 Abstract. An unusual association of Se minerals was studied. Se enters into the structures of sulphosalts – into bournonite, jamesonite and tintinaite at concentrations up to 0.10, 0.38 and 1.11 apfu, respectively. However, Se and Te, together with Bi, also form discrete minerals such as tetradymite, laitakarite, ikunolite and hedleyite. Members of the laitakarite-ikunolite solid solution display a wide range of anion substitution from the nearly Se-free (0.10 apfu) end member to the S-poor (0.42 apfu) end member. Their contents of Te are low. Accompanying tetrahedrite does not contain Se or Te. Key-words: laitakarite-ikunolite solid solutions, sulphosalts, tetradymite, Slovakia, Úhorná 1. Introduction In Slovakia, occurrences of Se- and Te minerals are relatively rare in comparison with other sulphide minerals. Besides occurrences in Neogene volcanites (neovolcanites), they have only been identified in a few localities. Tellurides of Bi, Au and Ag occur in the neovolcanites. Tetradymite was described from upkov, Hodruša, Bukovec and Kopanice (Zepharovich 1859, 1873; Lexa et al. 1989; Kalinaj, Bebej 1992; Mao, Bebej 1994; Jeleò 2003; Sejkora et al. -
Prospecting for and Instructions on How to Finish Fire Agate Gems
Prospecting For And Instructions On How To Finish Fire Agate Gems In this booklet I will do my best to help the lapidarian who wants to start working with Fire Agates as well as those who only need a little help on just how to get started. In turn I will do all that I can to encourage the reader who is not a lapidarian to be able to start a lifetime hobby of it. I will also include as much information as I can possibly find on the subject through researching current books. It has been said that knowledge is wealth. I have found that wealth is not found in monetary means alone. To me happiness is the ultimate wealth. Even if you never do work with rocks, it is nice to learn as we go through life. Who knows it could spark that tad bit of interest that would start you on the road to being a true rock hound for life. In turn be able to share the beautiful world of lapidary with millions of rock hound people around the world, who I feel in my world are among the finest people I have ever had the pleasure of knowing. Sometimes in life it is just that little spark that sets off the interest in your mind that in some way will change your thinking for the remainder of your life. I wish that every child had the opportunity to go out with their parents hunting rocks together and finding the things that set us apart from the other animals on our planet. -
Mineral of the Month Club October 2016
Mineral of the Month Club October 2016 QUARTZ var. AGATE (NODULE) Distinctive multicoloration and banding make this month’s mineral—the agate subvariety of microcrystalline quartz (chalcedony)—one of the world’s most recognizable gemstones. Our agate-nodule specimens were collected, cut, and polished in Soledade, Brazil, the world’s leading source of gem-quality agate. OVERVIEW PHYSICAL PROPERTIES: Chemistry: SiO2 Silicon Dioxide, often containing small amounts of iron and manganese. Class: Silicates Subclass: Tectosilicates (Framework Silicates) Group: Quartz Subgroup: Microcrystalline Quartz (Chalcedony) Crystal System: Hexagonal Crystal Habits: The agate subvariety of microcrystalline quartz occurs in massive form as nodules, veinlets, and geode linings. Color: Red, pink, orange, yellow, green, blue, bluish-gray, gray, white, brown, and black; agate bands, layers, and inclusions are usually multicolored. Luster: Vitreous and waxy to dull Transparency: Translucent Streak: White Refractive Index: 1.544-1.553 Cleavage: None Fracture and Tenacity: Conchoidal to subconchoidal and irregular; brittle to tough. Hardness: Quartz has a Mohs hardness of 7.0; agate is slightly softer at Mohs 6.5-7.0. Specific Gravity: 2.62-2.65 Luminescence: Agate often fluoresces yellow or bluish-white; fluorescence color and intensity vary among individual layers. Distinctive Features and Tests: Agate is difficult to confuse with other minerals or mineral varieties. Best field marks are translucency; microcrystalline structure; multicolored banding, layers, or inclusions; wide range of colors; hardness; relatively low specific gravity; and occurrence in volcanic environments. Dana Classification Number: 75.1.3.1 NAME: The word “agate,” pronounced AAH-get (rhymes with “tag it”), stems from Achatēs, the ancient Greek name for the Dirillo River on Italy’s island of Sicily, a former source of the stone. -
Mineral of the Month Club June 2017
Mineral of the Month Club June 2017 OPAL subvar. FIRE This month our featured mineral is the fire subvariety of common opal from Mexico. Our write- up discusses the mineralogy of fire opal, the origin of its yellow-orange-red coloration, and its classification as a mineraloid. OVERVIEW PHYSICAL PROPERTIES Chemistry: SiO2·nH20 Hydrous Silicon Dioxide, containing varying amounts of water. The fire subvariety of common opal contains traces of hematite and hydrous iron oxides. Class: Silicates Subclass: Tectosilicates (Framework Silicates) Group: Hydrated Tectosilicates Subgroup: Opal Crystal System: None; opal has a noncrystalline structure. Crystal Habits: None; occurs as amorphous fillings or botryoidal coatings in vugs and fissures. Color: Fire opal is always a shade of yellow, orange, or red, or a mix of these colors; color intensity varies from pale to saturated; color zoning and multicoloration is common. Fire opal occasionally exhibits an internal play of green color. Luster: Vitreous to dull Transparency: Transparent to translucent Streak: White Cleavage: None Fracture/Tenacity: Conchoidal; tough. Brittleness increases with level of hydration. Hardness: 5.5-6.0 Specific Gravity: Varies with water content from 1.9 to 2.3; the average specific gravity of all opal varieties is 2.09. The specific gravity of fire opal is about 2.2. Luminescence: Most opal fluoresces pale greenish-yellow in shortwave ultraviolet light and white in long-wave ultraviolet light. Refractive Index: 1.44-1.46 Distinctive Features and Tests: The best field identification marks for fire opal are low density; conchoidal fracture; lack of crystal faces and cleavage planes; yellow- orange-red coloration; and occurrence in rhyolite formations.