Oxygen Isotopic Composition of Ferric Oxides from Recent Soil, Hydrologic, and Marine Environments
Geochimica et Cosmochimica Acta, Vol. 64, No. 13, pp. 2221–2231, 2000 Copyright © 2000 Elsevier Science Ltd Pergamon Printed in the USA. All rights reserved 0016-7037/00 $20.00 ϩ .00 PII S0016-7037(00)00351-3 Oxygen isotopic composition of ferric oxides from recent soil, hydrologic, and marine environments 1, 2 3 HUIMING BAO, *PAUL L. KOCH, and MARK H. THIEMENS 1Department of Chemistry and Biochemistry, Mail Code 0356, 9500 Gilman Drive, University of California San Diego, La Jolla, CA 92093, USA 2Department of Earth Sciences, University of California, Santa Cruz, CA 95064, USA 3Department of Chemistry and Biochemistry, Mail Code 0356, University of California San Diego, La Jolla, CA 92093, USA (Received September 27, 1999; accepted in revised form January 24, 2000) Abstract—Low-temperature synthesis experiments on ferric oxide–water systems have resulted in disparate oxygen isotope fractionation–temperature (␣-T) curves. In this study, recent ferric oxides, mostly goethites of Holocene age, were collected and analyzed from a variety of modern soil, stream, and marine environments, where formation temperature and the oxygen isotopic composition (␦18O) of the water from which ferric oxides precipitated can be independently measured or estimated. This allows comparison of experimental ␣-T relationships with data from natural systems. Selective dissolution methods were refined for the pretreatment of fine-grained minerals in order to obtain reliable ␦18O values for pure and crystalline ferric oxides. The difference (⌬␦18O) between the ␦18O value of goethite and that of local mean meteoric water ranges from Ϫ1.5 to ϩ6.3‰ for soil goethites from New Jersey, Indiana, Michigan, Iowa, South Dakota, and Taiwan.
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