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Rhode Island Hazardous Substance List
Rhode Island Hazardous Substance List Source: T - ACGIH F - NFPA49 C - IARC Alphabetical Order C.A.S. ACGIH NFPA IARC CHEMICAL NAME 13010-47-4 C 1,-(2-Chloroethyl)-3-cyclohexyl-1-Nitrosourea 76-11-9 T 1,1,1,2-tetrachloro-2,2-difluoroethane 76-12-0 T 1,1,2,2-tetrachloro-1,2-difluoroethane 79-34-5 T 1,1,2,2-tetrachloroethane - skin 76-13-1 T 1,1,2-trichloro-1,2,2-trifluoroethane 79-00-5 T F C 1,1,2-trichloroethane - skin 594-72-9 T 1,1-Dichloro-1-nitroethane 74-34-3 T 1,1-dichloroethane 57-14-7 T 1,1-dimethylhydrazine (udmh) 96-18-4 T 1,2,3-trichloropropane 120-82-1 T 1,2,4-Trichlorobenzene 106-88-7 F 1,2-Butylene oxide 107-15-3 T F 1,2-Diaminoethane 96-12-8 C 1,2-Dibromo-3-chloropropane 106-93-4 T F C 1,2-Dibromoethane - skin 107-06-2 T F 1,2-Dichlorethane 540-59-0 T F 1,2-Dichloroethene 540-59-0 T F 1,2-Dichloroetylene 1615-80-1 C 1,2-Diethylhydrazine C 1,2-Dimethyl hydrazine - skin 106-99-0 T F 1,3-Butadiene 118-52-5 T 1,3-Dichloro-5,5-dimethylhydantoin 542-75-6 T F 1,3-Dichloropropene (cis and trans) 542-75-6 T F 1,3-Dichloropropylene 110-56-5 F 1,4-Dichlorobutane 123-91-1 T F C 1,4-Dioxane 1120-71-4 1-3-Propane sultone 110-53-2 F 1-Bromopentane 106-89-8 T F C 1-Chloro,2,3-epoxy-propane 600-25-9 T 1-Chloro-1-nitropropane 97-00-7 F 1-chloro-2,4-dinitrobenzene 543-59-9 F 1-Chloropentane 112-30-1 F 1-Decanol 111-27-3 F 1-Hexanol 141-79-7 T F 1-Isobutenyl methyl ketone 108-03-2 T F 1-Nitropropane 71-41-0 F 1-Pentanol 110-58-7 F 1-Pentylamine 111-40-0 T F 2,2'-Diaminodiethylamine 111-44-4 F 2,2'Dichlorodiethyl ether 75-99-0 T 2,2-dichloropropionic acid 556-52-5 T 2,3-Epoxy-1-propanol 93-76-5 T 2,4,5-T 95-95-4 F 2,4,5-trichlorophenol 88-06-2 F C 2,4,6-trichlorophenol 118-96-7 T F 2,4,6-Trinitro Toluene 479-95-8 T 2,4,6-Trinitrophenyl-methylnitramine 94-75-7 T 2,4-d (2,4-dichlorophenoxyacetic acid) 97-02-9 F 2,4-dinitroaniline 584-84-9 T F 2,4-Tolylene diisocyanate 108-83-8 T 2,6-Dimethyl-4-heptanone 108-83-8 T 2,6-Dimethyl-4-heptanone 128-37-0 T 2,6-Ditert. -
Explosion of Lithium-Thionyl-Chloride Battery Due to Presence of Lithium Nitride
Downloaded from orbit.dtu.dk on: Sep 25, 2021 Explosion of lithium-thionyl-chloride battery due to presence of lithium nitride Hennesø, E.; Hedlund, Frank Huess Published in: Journal of Failure Analysis and Prevention Link to article, DOI: 10.1007/s11668-015-0004-y Publication date: 2015 Document Version Early version, also known as pre-print Link back to DTU Orbit Citation (APA): Hennesø, E., & Hedlund, F. H. (2015). Explosion of lithium-thionyl-chloride battery due to presence of lithium nitride. Journal of Failure Analysis and Prevention, 15(5), 600-603. https://doi.org/10.1007/s11668-015-0004-y General rights Copyright and moral rights for the publications made accessible in the public portal are retained by the authors and/or other copyright owners and it is a condition of accessing publications that users recognise and abide by the legal requirements associated with these rights. Users may download and print one copy of any publication from the public portal for the purpose of private study or research. You may not further distribute the material or use it for any profit-making activity or commercial gain You may freely distribute the URL identifying the publication in the public portal If you believe that this document breaches copyright please contact us providing details, and we will remove access to the work immediately and investigate your claim. This article appeared in Journal of Failure Analysis and Prevention, ISSN 1547-7029 http://dx.doi.org/10.1007/s11668-015-0004-y Explosion of lithium-thionyl- chloride battery due to presence of lithium nitride Document no. -
Reactions of Lithium Nitride with Some Unsaturated Organic Compounds. Perry S
Louisiana State University LSU Digital Commons LSU Historical Dissertations and Theses Graduate School 1963 Reactions of Lithium Nitride With Some Unsaturated Organic Compounds. Perry S. Mason Jr Louisiana State University and Agricultural & Mechanical College Follow this and additional works at: https://digitalcommons.lsu.edu/gradschool_disstheses Recommended Citation Mason, Perry S. Jr, "Reactions of Lithium Nitride With Some Unsaturated Organic Compounds." (1963). LSU Historical Dissertations and Theses. 898. https://digitalcommons.lsu.edu/gradschool_disstheses/898 This Dissertation is brought to you for free and open access by the Graduate School at LSU Digital Commons. It has been accepted for inclusion in LSU Historical Dissertations and Theses by an authorized administrator of LSU Digital Commons. For more information, please contact [email protected]. This dissertation has been 64—5058 microfilmed exactly as received MASON, Jr., Perry S., 1938- REACTIONS OF LITHIUM NITRIDE WITH SOME UNSATURATED ORGANIC COMPOUNDS. Louisiana State University, Ph.D., 1963 Chemistry, organic University Microfilms, Inc., Ann Arbor, Michigan Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. REACTIONS OF LITHIUM NITRIDE WITH SOME UNSATURATED ORGANIC COMPOUNDS A Dissertation Submitted to the Graduate Faculty of the Louisiana State University and Agricultural and Mechanical College in partial fulfillment of the requireiaents for the degree of Doctor of Philosophy in The Department of Chemistry by Perry S. Mason, Jr. B. S., Harding College, 1959 August, 1963 Reproduced with permission of the copyright owner. Further reproduction prohibited without permission. -
1 Understanding Continuous Lithium-Mediated Electrochemical Nitrogen Reduction Nikifar Lazouski,1 Zachary J Schiffer,1 Kindle Wi
© 2019 This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ doi: 10.1016/j.joule.2019.02.003 Understanding Continuous Lithium-Mediated Electrochemical Nitrogen Reduction Nikifar Lazouski,1 Zachary J Schiffer,1 Kindle Williams,1 and Karthish Manthiram1* 1Department of Chemical Engineering; Massachusetts Institute of Technology; Cambridge, MA 02139, USA *Corresponding Author: [email protected] 1 © 2019 This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/ doi: 10.1016/j.joule.2019.02.003 Summary Ammonia is a large-scale commodity chemical that is crucial for producing nitrogen- containing fertilizers. Electrochemical methods have been proposed as renewable and distributed alternatives to the incumbent Haber-Bosch process, which utilizes fossils for ammonia production. Herein, we report a mechanistic study of lithium-mediated electrochemical nitrogen reduction to ammonia in a non-aqueous system. The rate laws of the main reactions in the system were determined. At high current densities, nitrogen transport limitations begin to affect the nitrogen reduction process. Based on these observations, we developed a coupled kinetic-transport model of the process, which we used to optimize operating conditions for ammonia production. The highest Faradaic efficiency observed was 18.5 ± 2.9%, while the highest production rate obtained was (7.9 ± 1.6) × 10-9 mol cm-2 s-1. Our understanding of the reaction network and the influence of transport provides foundational knowledge for future improvements in continuous lithium- mediated ammonia synthesis. -
Chemical Name Federal P Code CAS Registry Number Acutely
Acutely / Extremely Hazardous Waste List Federal P CAS Registry Acutely / Extremely Chemical Name Code Number Hazardous 4,7-Methano-1H-indene, 1,4,5,6,7,8,8-heptachloro-3a,4,7,7a-tetrahydro- P059 76-44-8 Acutely Hazardous 6,9-Methano-2,4,3-benzodioxathiepin, 6,7,8,9,10,10- hexachloro-1,5,5a,6,9,9a-hexahydro-, 3-oxide P050 115-29-7 Acutely Hazardous Methanimidamide, N,N-dimethyl-N'-[2-methyl-4-[[(methylamino)carbonyl]oxy]phenyl]- P197 17702-57-7 Acutely Hazardous 1-(o-Chlorophenyl)thiourea P026 5344-82-1 Acutely Hazardous 1-(o-Chlorophenyl)thiourea 5344-82-1 Extremely Hazardous 1,1,1-Trichloro-2, -bis(p-methoxyphenyl)ethane Extremely Hazardous 1,1a,2,2,3,3a,4,5,5,5a,5b,6-Dodecachlorooctahydro-1,3,4-metheno-1H-cyclobuta (cd) pentalene, Dechlorane Extremely Hazardous 1,1a,3,3a,4,5,5,5a,5b,6-Decachloro--octahydro-1,2,4-metheno-2H-cyclobuta (cd) pentalen-2- one, chlorecone Extremely Hazardous 1,1-Dimethylhydrazine 57-14-7 Extremely Hazardous 1,2,3,4,10,10-Hexachloro-6,7-epoxy-1,4,4,4a,5,6,7,8,8a-octahydro-1,4-endo-endo-5,8- dimethanonaph-thalene Extremely Hazardous 1,2,3-Propanetriol, trinitrate P081 55-63-0 Acutely Hazardous 1,2,3-Propanetriol, trinitrate 55-63-0 Extremely Hazardous 1,2,4,5,6,7,8,8-Octachloro-4,7-methano-3a,4,7,7a-tetra- hydro- indane Extremely Hazardous 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]- 51-43-4 Extremely Hazardous 1,2-Benzenediol, 4-[1-hydroxy-2-(methylamino)ethyl]-, P042 51-43-4 Acutely Hazardous 1,2-Dibromo-3-chloropropane 96-12-8 Extremely Hazardous 1,2-Propylenimine P067 75-55-8 Acutely Hazardous 1,2-Propylenimine 75-55-8 Extremely Hazardous 1,3,4,5,6,7,8,8-Octachloro-1,3,3a,4,7,7a-hexahydro-4,7-methanoisobenzofuran Extremely Hazardous 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O- [(methylamino)-carbonyl]oxime 26419-73-8 Extremely Hazardous 1,3-Dithiolane-2-carboxaldehyde, 2,4-dimethyl-, O- [(methylamino)-carbonyl]oxime. -
SDS SOB SAF SAW 2015-07-10.Xlsx
SAFETY DATA SHEET Issuing Date: 28-Mar-2014 Revision Date: 10-July-2015 Revision No.: 1 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Product Name Strike Anywhere Matches Other means of identification UN-No. UN1331 Synonyms SAW Recommended use of the chemical and restrictions on use Recommended use Matches Uses advised against No information available Details of the supplier of the safety data sheet Supplier Name Jarden Home Brands Supplier Address 1800 Cloquet Ave. Cloquet MN 55720 US Supplier Phone Number Phone:1-800-392-2575 Supplier Email [email protected] Emergency telephone number CHEMTREC 1-800-424-9300 2. HAZARDS IDENTIFICATION Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Flammable solids Category 2 GHS Label elements, including precautionary statements Emergency Overview Signal Word Warning Hazard Statements Flammable solids Appearance: wooden match Physical State: Solid Odor: none Precautionary Statements - Prevention Keep away from heat/sparks/open flames/hot surfaces - KEEP AWAY FROM CHILDREN - No smoking Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response Precautionary Statements - Storage Store in a cool, dry location, away from heat, open flames or sparks, or flammable materials. Page 1 Diamond Strike Anywhere Matches Revision Date: 10-Jul-2015 Precautionary Statements - Disposal None Hazards not otherwise classified (HNOC) Smoke from fire may be irritating to lungs and eyes. Unknown Toxicity 11% of the mixture consists of ingredient(s) of unknown toxicity Other Information None Interactions with Other Chemicals No information available 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No. -
WO 2016/074683 Al 19 May 2016 (19.05.2016) W P O P C T
(12) INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property Organization International Bureau (10) International Publication Number (43) International Publication Date WO 2016/074683 Al 19 May 2016 (19.05.2016) W P O P C T (51) International Patent Classification: (81) Designated States (unless otherwise indicated, for every C12N 15/10 (2006.01) kind of national protection available): AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, (21) International Application Number: BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, PCT/DK20 15/050343 DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, (22) International Filing Date: HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KN, KP, KR, 11 November 2015 ( 11. 1 1.2015) KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, (25) Filing Language: English PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, (26) Publication Language: English SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. (30) Priority Data: PA 2014 00655 11 November 2014 ( 11. 1 1.2014) DK (84) Designated States (unless otherwise indicated, for every 62/077,933 11 November 2014 ( 11. 11.2014) US kind of regional protection available): ARIPO (BW, GH, 62/202,3 18 7 August 2015 (07.08.2015) US GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, (71) Applicant: LUNDORF PEDERSEN MATERIALS APS TJ, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, [DK/DK]; Nordvej 16 B, Himmelev, DK-4000 Roskilde DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, (DK). -
Lithium Nitride
TECHNICAL DATA SHEET Date of Issue: 2016/12/12 Lithium Nitride CAS-No. 26134-62-3 EC-No. 247-475-2 Molecular Formula Li3N Product Number 401121 SPECIFICATION Lithium Nitride: min. 94% METHOD OF ANALYSIS Assay by determination of nitrogen by the method of Kjeldahl. A detailed laboratory instruction is available on request. PHYSICAL PROPERTIES Appearance fine powder Color red brown Melting point/ range ca. 840 - 845 °C Density ca. 1.38 g/cm3 at 20 °C Water solubility (Not applicable) Molecular weight 34.82 g/mol Additional Physical Theoretical lithium weight: 59.8 % Properties The information presented herein is believed to be accurate and reliable, but is presented without guarantee or responsibility on the part of Albemarle Corporation and its subsidiaries and affiliates. It is the responsibility of the user to comply with all applicable laws and regulations and to provide for a safe workplace. The user should consider any health or safety hazards or information contained herein only as a guide, and should take those precautions which are necessary or prudent to instruct employees and to develop work practice procedures in order to promote a safe work environment. Further, nothing contained herein shall be taken as an inducement or recommendation to manufacture or use any of the herein materials or processes in violation of existing or future patent. Technical data sheets may change frequently. You can download the latest version from our website www.albemarle-lithium.com. Please contact us at www.albemarle-lithium.com/contact with questions. Lithium Nitride Page 2 / 3 Product Number: 401121 Date of Issue: 2016/12/12 HANDLING & STORAGE Handling Lithium Nitride should be handled under inert gas atmosphere. -
(12) United States Patent (10) Patent No.: US 8,871,843 B2 Lee (45) Date of Patent: Oct
USOO887 1843B2 (12) United States Patent (10) Patent No.: US 8,871,843 B2 Lee (45) Date of Patent: Oct. 28, 2014 (54) HALOGEN-FREE FLAME RETARDANT 5,456,984 A 10/1995 Bishop et al. MATERAL 5,484,830 A 1/1996 Staendeke 5,648.436 A 7/1997 Janowitz et al. 5,925,700 A 7/1999 Imahashi (75) Inventor: Jean L. Lee, San Jose, CA (US) 5,955, 184 A 9, 1999 Honda et al. 5,994,429 A 11/1999 Honda et al. (73) Assignee: Apple Inc., Cupertino, CA (US) 6,140,411 A 10/2000 Schwanborn et al. 6,355,767 B1 * 3/2002 Takagi .......................... 528,196 (*) Notice: Subject to any disclaimer, the term of this 6,440,567 B1 8, 2002 Choate et al. 6,495,244 B1 12/2002 Andresakis et al. patent is extended or adjusted under 35 6,518,336 B1 2/2003 Yabuhara et al. U.S.C. 154(b) by 190 days. 6,642,288 B1 1 1/2003 Hulskotte 6,755,995 B1 6/2004 Hasegawa et al. (21) Appl. No.: 12/638,489 6,767,941 B2 7/2004 Van Der Speket al. 6,809,130 B2 10/2004 Chiou et al. 6,894, 101 B2 5, 2005 Paul et al. (22) Filed: Dec. 15, 2009 6,916,539 B2 7/2005 Cooray et al. 6,998,536 B2 2/2006 Barusseau et al. (65) Prior Publication Data 7,053,145 B1 5/2006 Tasaka et al. US 2011/O144244A1 Jun. 16, 2011 7,115,678 B2 10/2006 Ihara et al. -
Safety Data Sheet
SAFETY DATA SHEET SECTION 1: CHEMICAL PRODUCT and COMPANY IDENTIFICATION Product Name: Lithium nitride 99.5% Li -60 Mesh Product Code: L04310 Supplier: Pfaltz & Bauer, Inc. 172 E. Aurora Street Waterbury, CT 06708 USA Phone: 203-574-0075 FAX: 203-574-3181 Emergency Phone: INFOTRAC, US: 1-800-535-5053 INFOTRAC, INTERNATIONAL: +1-352-323-3500 SECTION 2: HAZARDS IDENTIFICATION Statement of Hazard: Corrosive, Dangerous when wet, Irritant, Reacts violently with water, Respiratory irritant Acute Health Hazard: Irritant to eyes, skin, mucous membranes and respiratory system. May be harmful by ingestion, skin absorption and inhalation. Chronic Health Hazard: Not Available HMIS Rating: H: 3 F: 3 P: 2 NFPA Rating: H: 3 F: 0 R: 2 To the best of our knowledge, the toxicological properties of this chemical have not been thoroughly investigated. Use appropriate procedures and precautions to prevent or minimize exposure. GHS Classification in accordance with 29 CFR 1910 (OSHA HCS): Page 1 of 7 Acute toxicity, dermal (Category 4), H312 Acute toxicity, inhalation (Category 4), H332 Acute toxicity, oral (Category 4), H302 Serious eye damage/eye irritation (Category 2A), H319 Skin corrosion/irritation (Category 1A), H314 Specific target organ toxicity, single exposure; Respiratory tract irritation (Category 3), H335 Substances and mixtures which, in contact with water, emit flammable gases (Category 1), H260 Pictogram: Signal Word: Danger Hazard Statement(s): H260 In contact with water releases flammable gases which may ignite spontaneously. H302 Harmful if swallowed. H312 Harmful in contact with skin. H314 Causes severe skin burns and eye damage. H319 Causes serious eye irritation. H332 Harmful if inhaled. -
Figure: 30 TAC §335.521(A)(2) [Figure: 30 TAC §335.521(A)(2)]
Figure: 30 TAC §335.521(a)(2) [Figure: 30 TAC §335.521(a)(2)] Appendix 1, Table 2. Examples of Ignitable Solids. Constituents listed from Department of Transportation Regulations, 49 CFR Part 173 Subpart E, October 1, 1993. (Note: The presence of a constituent on this table in a nonhazardous [non-hazardous] waste does not automatically identify that waste as a Class 1 ignitable waste. The constituents on this table are examples of materials which could be considered Class 1 ignitable waste. The physical characteristics of the waste will be the determining factor as to whether or not a waste is ignitable. Refer to §335.505(2) of this title (relating to Class 1 Waste Determination) for the Class 1 ignitable criteria.) Compound or Material Aluminum, metallic, powder Alkali metal amalgams Alkali metal amides Aluminum alkyl halides Aluminum alkyl hydrides Aluminum alkyls Aluminum borohydrides Aluminum carbide Aluminum ferrosilicon powder Aluminum hydride Aluminum phosphide Aluminum resinate Aluminum silicon powder Ammonium picrate 2, 2'-Azodi-(2,4-dimethyl-4-methoxyvaleronitrile) 2, 2'-Azodi-(2,4-dimethylvaleronitrile) 1, 1' Azodi-(hexahydrobenzonitrile) 2,2'-Azodi (2-methyl-butryronitrile) Azodiisobutryonitrile Barium, metallic Barium alloys, pyrophoric Barium azide Benzene-1,3-disulfohydrazide Benzene sulfohydrazide 4-(Benzyl(ethyl)amino)-3-ethoxybenzenediazonium zinc chloride 4-(Benzyl(methyl)amino)-3-ethoxybenzenediazonium zinc chloride Borneol Boron trifluoride dimethyl etherate 5-tert-Butyl-2,4,6-trinitro-m-xylene Calcium, metallic Calcium -
Low Temperature and Pressure Synthesis of Lithium–Nitride
Materials Transactions, Vol. 54, No. 12 (2013) pp. 2233 to 2237 ©2013 The Japan Institute of Metals and Materials Low Temperature and Pressure Synthesis of LithiumNitride Compound with H2O Addition on Lithium Target for BNCT Shintaro Ishiyama1,+, Yuji Baba1, Ryo Fujii2, Masaru Nakamura2 and Yoshio Imahori2 1Quantum Beam Science Directorate, Japan Atomic Energy Agency, Naka-gun, Ibaraki 319-1195, Japan 2Cancer Intelligence Care Systems, Inc., Tokyo 135-0063, Japan Low temperature synthesis of lithiumnitride compound was conducted on the lithium target for BNCT by N2/H2O mixing gas squirt in the ultra high vacuum chamber, and the following results were derived. (1) Lithiumnitride compound was synthesized on the lithium target ¹8 under 101.3 Pa N2 gas squirt at room temperature and in the ultra high vacuum chamber under the pressure of 1 © 10 Pa. (2) Remarkable contamination by O and C was observed on the lithiumnitride compound synthesized under the squirt pressure of 13.380 Pa/1.334.7 Pa N2/ H2O mixing gas. (3) No contamination and synthesis of LiN compound was observed under the squirt pressure of 0.0130.027 Pa/00.005 Pa N2/H2O mixing gas. (4) Contamination by O and C was enhanced with excessive addition of H2O at the pressure of over 1.33 Pa. [doi:10.2320/matertrans.M2013242] (Received June 26, 2013; Accepted September 25, 2013; Published November 9, 2013) Keywords: boron neutron capture therapy, neutron source, lithium target, lithium nitride, nitrogen gas, contamination, H2O addition 1. Introduction Implemented deployment of accelerator-driven neutron source for Boron Neutron Capture Therapy (BNCT) is scheduled in 2013 in National Cancer Center, Japan.