PTR-MS (Protonenaffinit鋞en)
Total Page:16
File Type:pdf, Size:1020Kb
Proton Affinity Protonated Substance Formula [kcal/mol] Mass [amu] 1 Hydrogen (H2) 100,9 3 2 Helium (He) 42,5 5 3 Lithium hydride (HLi) 244,2 9 4 Nitrogen atom (N) 81,8 15 5 Lithium dimer (Li2) 277,7 15 6 Oxygen, atomic (O) 116,0 17 7 Methane (CH4) 129,9 17 8 NH2 (H2N) 184,8 17 9 Ammonia (H3N) 204,1 18 10 Water (H2O) 165,2 19 11 Fluorine atom (F) 81,3 20 12 Neon (Ne) 48,6 21 13 Hydrogen fluoride (HF) 115,7 21 14 Magnesium (Mg) 195,9 25 15 LiOH (HLiO) 241,0 25 16 Sodium hydride (HNa) 261,7 25 17 Ethynyl radical (C2H) 183,3 26 18 Acetylene (C2H2) 153,3 27 19 Hydrogen cyanide (CHN) 170,4 28 20 Vinyl radical (C2H3) 180,5 28 21 Hydrogen isocyanide (CHN) 184,6 28 22 Nitrogen (N2) 118,0 29 23 Carbon monoxide (CO) 141,7 29 24 Diborane(6) (H6B2) 147,0 29 25 Ethylene (C2H4) 162,6 29 26 Silicon (Si) 200,0 29 27 Ethyl radical (C2H5) 147,2 30 28 Formyl radical (CHO) 152,0 30 29 Methanimine (CH3N) 203,8 30 30 Nitric oxide (NO) 109,0 31 31 Ethane (C2H6) 142,5 31 32 Formaldehyde (CH2O) 170,4 31 33 Diimide (H2N2) 191,9 31 34 Silylene (H2Si) 200,2 31 35 CH2NH2 (CH4N) 203,0 31 36 HCOH (hydroxymethylene) (CH2O) 230,9 31 37 Dilithium monoxide (Li2O) 288,2 31 38 Phosphorus atom (P) 149,8 32 39 Hydroxymethyl radical (CH3O) 166,1 32 40 Methylamine (CH5N) 214,9 32 41 Oxygen (O2) 100,6 33 42 Silane (H4Si) 152,9 33 43 Sulfur atom (S) 158,8 33 44 Phosphinidene (HP) 160,2 33 45 Methyl alcohol (CH4O) 180,3 33 46 Fluoromethylene (CHF) 190,4 33 47 Hydrazine (H4N2) 203,9 33 48 Hydroperoxy radical (HO2) 157,7 34 49 Phosphino radical (H2P) 169,5 34 50 Methyl fluoride (CH3F) 143,0 35 51 Hydrogen peroxide (H2O2) 161,4 35 52 Hydrogen sulfide (H2S) 168,5 35 53 Phosphine (H3P) 187,6 35 54 Oxygen monofluoride (FO) 121,6 36 55 Chlorine atom (Cl) 122,8 36 56 Hydrogen chloride (HCl) 133,1 37 57 Carbon trimer (C3) 183,3 37 58 Cyclopropenylidene (C3H2) 227,4 39 59 Cyclopropenyl radical (C3H3) 175,7 40 60 Propargyl radical (C3H3) 177,1 40 61 Argon (Ar) 88,2 41 62 Propyne (C3H4) 178,8 41 63 Dicarbon monoxide (C2O) 185,2 41 64 1,2-Propadiene (C3H4) 185,3 41 65 (CD3)2O (C2D6O) 186,9 41 66 Cyclopropene (C3H4) 197,3 41 67 Magnesium monoxide (MgO) 236,1 41 68 Sodium hydroxide (HNaO) 248,0 41 69 Cyclopropyl radical (C3H5) 175,8 42 70 Allyl radical (C3H5) 175,9 42 71 Acetonitrile (C2H3N) 186,2 42 72 Methane, isocyano- (C2H3N) 199,0 42 73 Cyclopropane (C3H6) 179,3 43 74 Propene (C3H6) 179,6 43 75 Cyanamide (CH2N2) 192,6 43 76 Ketene (C2H2O) 197,3 43 77 Lithium chloride (ClLi) 197,7 43 78 Methane, diazo- (CH2N2) 205,4 43 79 Acetyl radical (C2H3O) 156,1 44 80 Isopropyl radical (C3H7) 160,5 44 81 Isocyanic acid (CHNO) 180,0 44 82 Hydrogen azide (HN3) 180,5 44 83 Fulminic acid (CHNO) 181,2 44 84 CH2CHO (C2H3O) 185,0 44 85 SiNH (HNSi) 203,2 44 86 N-Methyl methanimine (C2H5N) 211,5 44 87 Acetaldimine (C2H5N) 211,7 44 88 Ethenamine (C2H5N) 214,9 44 89 Ethylenimine (C2H5N) 216,7 44 90 Carbon dioxide (CO2) 129,2 45 91 Nitrous oxide (N2O) 137,5 45 92 Propane (C3H8) 150,5 45 Proton Affinity Protonated Substance Formula [kcal/mol] Mass [amu] 93 Ethyne, fluoro- (C2HF) 164,0 45 94 Methinophosphide (CHP) 167,1 45 95 Boron oxide hydroxide (HBO2) 182,4 45 96 Acetaldehyde (C2H4O) 183,8 45 97 Ethylene oxide (C2H4O) 184,9 45 98 Silicon monoxide (OSi) 185,7 45 99 Carbon monosulfide (CS) 189,2 45 100 Methyl diazene (CH4N2) 202,0 45 101 Hydrocarboxyl radical (CHO2) 149,0 46 102 Cyanogen fluoride (CFN) 151,1 46 103 CH2CH2OH (C2H5O) 178,1 46 104 SiOH (HOSi) 185,3 46 105 Phosphorus mononitride (NP) 188,6 46 106 HSiO (HOSi) 193,6 46 107 Formamide (CH3NO) 196,5 46 108 Ethylamine (C2H7N) 217,9 46 109 Scandium (Sc) 218,5 46 110 Methanamine, N-methyl- (C2H7N) 222,2 46 111 Nitrogen dioxide (NO2) 141,1 47 112 Ethene, fluoro- (C2H3F) 174,2 47 113 Formic acid (CH2O2) 177,3 47 114 Thioformaldehyde (CH2S) 181,6 47 115 Ethanol (C2H6O) 185,6 47 116 Dimethyl ether (C2H6O) 189,3 47 117 HSiOH (H2OSi) 200,8 47 118 H2SiO (H2OSi) 201,0 47 119 Hydrazine, methyl- (CH6N2) 214,1 47 120 Disodium (Na2) 274,1 47 121 Phosphorus monoxide (OP) 163,0 48 122 H3SiO (H3OSi) 167,3 48 123 H2SiOH (H3OSi) 176,4 48 124 Hydroxylamine, o-methyl- (CH5NO) 202,0 48 125 Ozone (O3) 149,5 49 126 Ethane, fluoro- (C2H5F) 163,5 49 127 H3SiOH (H4OSi) 178,4 49 128 Methanethiol (CH4S) 184,8 49 129 Phosphine, methyl- (CH5P) 203,6 49 130 Chloromethylene (CHCl) 208,6 49 131 Titanium (Ti) 209,4 49 132 Magnesium dimer (Mg2) 219,6 49 133 Methyl chloride (CH3Cl) 154,9 51 134 1,3-Butadiyne (C4H2) 175,8 51 135 Difluoromethylene (CF2) 182,8 51 136 Propiolonitrile (C3HN) 179,6 52 137 Vanadium (V) 205,4 52 138 Methane, difluoro- (CH2F2) 148,2 53 139 Cyanogen (C2N2) 162,0 53 140 Tetraborane(8) (H8B4) 187,6 53 141 Chromium (Cr) 189,1 53 142 CCCO (C3O) 210,4 53 143 2-Propenenitrile (C3H3N) 187,5 54 144 Tetraborane(10) (H10B4) 144,6 55 145 2-Butyne (C4H6) 185,6 55 146 1,2-Butadiene (C4H6) 186,3 55 147 1,3-Butadiene (C4H6) 187,1 55 148 Cyclobutene (C4H6) 190,3 55 149 1-Methylcyclopropene (C4H6) 204,9 55 150 2-Methylallyl radical (C4H7) 185,9 56 151 Propanenitrile (C3H5N) 189,8 56 152 Manganese (Mn) 190,6 56 153 Ethane, isocyano- (C3H5N) 203,6 56 154 1-Azabicyclo[1.1.0]butane (C3H5N) 211,5 56 155 Propargylamine (C3H5N) 212,2 56 156 vinylimine (C3H5N) 218,1 56 157 2-Butene, (E)- (C4H8) 178,5 57 158 Iron (Fe) 180,2 57 159 2-Propenal (C3H4O) 190,5 57 160 1-Propene, 2-methyl- (C4H8) 191,7 57 161 NCCH2NH2 (C2H4N2) 197,2 57 162 Methylketene (C3H4O) 199,4 57 163 C2S (C2S) 207,8 57 164 Potassium hydroxide (HKO) 263,0 57 165 Calcium monoxide (CaO) 284,6 57 166 Methane, isocyanato- (C2H3NO) 182,7 58 167 CH2COCH3 (C3H5O) 196,0 58 168 Methyl azide (CH3N3) 199,1 58 169 Cyclopropylamine (C3H7N) 216,4 58 170 2-Propen-1-amine (C3H7N) 217,5 58 171 Aziridine, 2-methyl- (C3H7N) 219,2 58 172 Aziridine, 1-methyl- (C3H7N) 222,1 58 173 2-Propanimine (C3H7N) 223,2 58 174 1-Methylethenylamine (C3H7N) 225,1 58 175 Azetidine (C3H7N) 225,8 58 176 Isobutane (C4H10) 161,5 59 177 Nickel (Ni) 176,1 59 178 Propanal (C3H6O) 187,6 59 179 Oxetane (C3H6O) 191,6 59 180 Acetone (C3H6O) 194,1 59 181 Propylene oxide (C3H6O) 194,2 59 182 Thioketene (C2H2S) 197,5 59 183 Ethene, methoxy- (C3H6O) 205,2 59 184 (E)-Dimethyldiazene (C2H6N2) 207,2 59 Proton Affinity Protonated Substance Formula [kcal/mol] Mass [amu] 185 Diazene, dimethyl- (C2H6N2) 211,0 59 186 CH3C(=NH)NH2 (C2H6N2) 232,1 59 187 CH2CH2CH2OH (C3H7O) 175,9 60 188 Cobalt (Co) 177,5 60 189 Formamide, N-methyl- (C2H5NO) 203,5 60 190 Acetamide (C2H5NO) 206,5 60 191 1-Propanamine (C3H9N) 219,4 60 192 2-Propanamine (C3H9N) 220,8 60 193 Ethanamine, N-methyl- (C3H9N) 225,4 60 194 Trimethylamine (C3H9N) 226,8 60 195 Carbonyl sulfide (COS) 150,2 61 196 Silicon monosulfide (SSi) 163,2 61 197 SiS (SSi) 169,7 61 198 Acetic acid (C2H4O2) 186,9 61 199 Methyl formate (C2H4O2) 187,0 61 200 1-Propanol (C3H8O) 188,2 61 201 Isopropyl alcohol (C3H8O) 190,1 61 202 Phosphirane (C2H5P) 191,7 61 203 Ethane, methoxy- (C3H8O) 193,4 61 204 Thiirane (C2H4S) 193,4 61 205 Hydrazine, 1,1-dimethyl- (C2H8N2) 221,5 61 206 Ethylenediamine (C2H8N2) 227,2 61 207 Cyanogen chloride (CClN) 172,6 62 208 Methane, nitro- (CH3NO2) 179,9 62 209 Methyl nitrite (CH3NO2) 191,0 62 210 HCOONH2 (CH3NO2) 199,6 62 211 Ethanolamine (C2H7NO) 222,3 62 212 H3BO3 (B(OH)3) (BH3O3) 174,5 63 213 H2N-NO2 (H2N2O2) 181,0 63 214 Ethanethiol (C2H6S) 188,6 63 215 CH2=S=O (CH2OS) 191,0 63 216 1,2-Ethanediol (C2H6O2) 195,1 63 217 Dimethyl sulfide (C2H6S) 198,6 63 218 Phosphine, dimethyl- (C2H7P) 217,2 63 219 Disodium oxide (Na2O) 328,8 63 220 Copper (Cu) 156,6 64 221 Phosphorus monosulfide (PS) 166,8 64 222 Nitric acid (HNO3) 179,6 64 223 B5H8 (B5H8) 182,5 64 224 Ethylamine, 2-fluoro- (C2H6FN) 213,4 64 225 Zinc (Zn) 145,5 65 226 Sulfur dioxide (O2S) 160,5 65 227 Osmium tetraoxide (O4Os) 161,8 65 228 Ethene, 1,2-difluoro-, (E)- (C2H2F2) 164,8 65 229 Ethyl chloride (C2H5Cl) 165,9 65 230 Pentaborane(9) (H9B5) 167,3 65 231 Ethanol, 2-fluoro- (C2H5FO) 171,0 65 232 Ethene, 1,1-difluoro- (C2H2F2) 175,4 65 233 Cyclopentadienyl radical (C5H5) 198,8 66 234 Carbonic difluoride (CF2O) 159,6 67 235 Malononitrile (C3H2N2) 173,2 67 236 Chlorofluoromethylene (CClF) 184,6 67 237 1,3-Cyclopentadiene (C5H6) 196,5 67 238 Cyanoketene (C3HNO) 187,4 68 239 Cyclopropanecarbonitrile (C4H5N) 193,5 68 240 HNCCCO (C3HNO) 205,8 68 241 Pyrrole (C4H5N) 209,2 68 242 Cyclopentene (C5H8) 183,0 69 243 Furan (C4H4O) 190,4 69 244 2-Pentyne (C5H8) 193,8 69 245 Ethenylcyclopropane (C5H8) 195,2 69 246 1-Butyne, 3-methyl- (C5H8) 196,5 69 247 1,3-Butadiene, 2-methyl- (C5H8) 198,9 69 248 1,3-Pentadiene, (E)- (C5H8) 200,5 69 249 Cyclobutene, 1-methyl- (C5H8) 202,2 69 250 Cyclopropene, 3,3-dimethyl- (C5H8) 203,3 69 251 1H-Pyrazole (C3H4N2) 213,4 69 252 C3S (C3S) 223,0 69 253 1H-Imidazole (C3H4N2) 225,2 69 254 CH3COCN propanenitrile, 2-oxo (C3H3NO) 178,5 70 255 Butanenitrile (C4H7N) 191,2 70 256 Propanenitrile, 2-methyl- (C4H7N) 192,1 70 257 Isoxazole (C3H3NO) 202,8 70 258 Propane, 1-isocyano- (C4H7N) 204,7 70 259 Oxazole (C3H3NO) 209,5 70 260 1H-1,2,3-Triazole (C2H3N3) 210,0 70 261 1H-1,2,4-Triazole (C2H3N3) 211,8 70 262 Methane, trifluoro- (CHF3) 147,9 71 263 Cyclobutanone (C4H6O) 191,8 71 264 2-Propenal, 2-methyl- (C4H6O) 193,3 71 265 2-Butene, 2-methyl- (C5H10) 193,3 71 266 Furan, 2,5-dihydro- (C4H6O) 196,8 71 267 2-Butenal (C4H6O) 198,7 71 268 Methyl vinyl ketone (C4H6O) 199,5 71 269 Cyanamide, dimethyl- (C3H6N2) 203,7 71 270 CH3NHCH2CN (C3H6N2) 206,5 71 271 H2NCH2CH2CN (C3H6N2) 207,2 71 272 Furan, 2,3-dihydro- (C4H6O) 207,3 71 273 Iron, methylene- (CH2Fe) 222,8 71 274 Nitrogen trifluoride (F3N) 135,7 72 275 Methoxyacetonitrile (C3H5NO) 181,4 72 276 2-Azetidinone