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EP SDS Tetrachlorogate Sulfuryl Chloride

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EP SDS Tetrachlorogate Sulfuryl Chloride Page: 1/11 Safety Data Sheet acc. to OSHA HCS (29CFR 1910.1200) and WHMIS 2015 Regulations Printing date: July 16, 2018 Revision: July 16, 2018 1 Identification · Product identifier · Trade name: Lithium Tetrachlorogalate in Sulfuryl Chloride Solution · Product code: No other identifiers · Recommended use and restriction on use · Recommended use: Product Component · Restrictions on use: Contact manufacturer/supplier · Details of the supplier of the Safety Data Sheet · Manufacturer/Supplier: Engineered Power 20, 3103 - 14th Avenue N.E. Calgary, Alberta, Canada T2A 7N6 Telephone (403) 235-2584 · Emergency telephone number: ChemTel Inc. (800)255-3924 (North America) +1 (813)248-0585 (International) 2 Hazard(s) identification · Classification of the substance or mixture Acute Tox. 2 H330 Fatal if inhaled. Skin Corr. 1B H314 Causes severe skin burns and eye damage. Eye Dam. 1 H318 Causes serious eye damage. STOT SE 3 H335 May cause respiratory irritation. · Label elements · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms: GHS05 GHS06 GHS07 · Signal word: Danger · Hazard statements: H330 Fatal if inhaled. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. · Precautionary statements: P260 Do not breathe mist/vapors/spray. P264 Wash thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection. P284 [In case of inadequate ventilation] wear respiratory protection. P301+P330+P331 If swallowed: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. (Cont'd. on page 2) 47.0.2 Page: 2/11 Safety Data Sheet acc. to OSHA HCS (29CFR 1910.1200) and WHMIS 2015 Regulations Printing date: July 16, 2018 Revision: July 16, 2018 Trade name: Lithium Tetrachlorogalate in Sulfuryl Chloride Solution (Cont'd. of page 1) P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a poison center/doctor. P320 Specific treatment is urgent (see on this label). P363 Wash contaminated clothing before reuse. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · Other hazards There are no other hazards not otherwise classified that have been identified. 3 Composition/information on ingredients · Chemical characterization: Mixtures · Components: 7791-25-5 sulphuryl chloride >80% Acute Tox. 2, H330 Skin Corr. 1B, H314 STOT SE 3, H335 13450-90-3 gallium trichloride 10% Met. Corr.1, H290; Skin Corr. 1B, H314; Eye Dam. 1, H318 7447-41-8 lithium chloride 2.5-5% Acute Tox. 4, H302; Skin Irrit. 2, H315; Eye Irrit. 2A, H319 · Additional information: For the listed ingredient(s), the identity and/or exact percentage(s) are being withheld as a trade secret. For the wording of the listed Hazard Statements, refer to section 16. 4 First-aid measures · Description of first aid measures · General information: Immediately remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Take affected persons out into the fresh air. · After inhalation: Supply fresh air. Seek immediate medical advice. Provide oxygen treatment if affected person has difficulty breathing. In case of unconsciousness place patient stably in side position for transportation. · After skin contact: Immediately rinse with water. Seek immediate medical advice. Immediate medical treatment necessary. Failure to treat burns can prevent wounds from healing. · After eye contact: Remove contact lenses if worn, if possible. (Cont'd. on page 3) 47.0.2 Page: 3/11 Safety Data Sheet acc. to OSHA HCS (29CFR 1910.1200) and WHMIS 2015 Regulations Printing date: July 16, 2018 Revision: July 16, 2018 Trade name: Lithium Tetrachlorogalate in Sulfuryl Chloride Solution (Cont'd. of page 2) Rinse opened eye for several minutes under running water. Then consult a doctor. · After swallowing: Rinse out mouth and then drink plenty of water. Do not induce vomiting; immediately call for medical help. · Most important symptoms and effects, both acute and delayed: Coughing Strong caustic effect on skin and mucous membranes. May cause respiratory irritation. Breathing difficulty Caustic effect on skin and mucous membranes. Eye damage. · Danger: Danger of gastric perforation. Danger of pulmonary edema. Danger of impaired breathing. Causes serious eye damage. Fatal if inhaled. Causes burns. · Indication of any immediate medical attention and special treatment needed: Decontaminate patient thoroughly with sodium bicarbonate solution; assume that some skin contact has taken place. Treat other symptoms symptomatically, with emphasis on maintaining electrolyte balance. Medical supervision for at least 48 hours. If necessary oxygen respiration treatment. 5 Fire-fighting measures · Extinguishing media · Suitable extinguishing agents: The product is not flammable. CO2, sand, extinguishing powder. Do not use water. · For safety reasons unsuitable extinguishing agents: Water · Special hazards arising from the substance or mixture During heating or in case of fire poisonous gases are produced. · Advice for firefighters · Protective equipment: Wear self-contained respiratory protective device. Do not inhale explosion gases or combustion gases. Wear fully protective suit. · Additional information: Evacuate area and fight fire from from the upwind side. 6 Accidental release measures · Personal precautions, protective equipment and emergency procedures Use respiratory protective device against the effects of fumes/dust/aerosol. Isolate area and prevent access. Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation. Keep people at a distance and stay upwind. (Cont'd. on page 4) 47.0.2 Page: 4/11 Safety Data Sheet acc. to OSHA HCS (29CFR 1910.1200) and WHMIS 2015 Regulations Printing date: July 16, 2018 Revision: July 16, 2018 Trade name: Lithium Tetrachlorogalate in Sulfuryl Chloride Solution (Cont'd. of page 3) · Environmental precautions Do not allow to enter sewers/ surface or ground water. · Methods and material for containment and cleaning up If a spill is small, a trained person may attempt to stop or contain the leak by carefully neutralizing spill with calcium carbonate or sodium bicarbonate. Seal leaking container and neutralized product in a plastic bag and transfer to a lidded container for disposal or recovery. Consult an accredited waste disposal contractor or the local authority for additional advice. Large spills should only be handled by specially trained hazardous materials personnel. Do not flush with water or aqueous cleansing agents Send for recovery or disposal in suitable receptacles. · Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage · Handling · Precautions for safe handling: Prevent formation of aerosols. Use only in well ventilated areas. Contact lenses should not be worn. · Information about protection against explosions and fires: Keep respiratory protective device available. · Conditions for safe storage, including any incompatibilities · Requirements to be met by storerooms and receptacles: Store only in approved receptacles. Provide ventilation for receptacles. Protect from humidity and water. Unsuitable material for receptacle: aluminium. · Information about storage in one common storage facility: Store away from foodstuffs. Do not store together with oxidizing and acidic materials. Do not store together with alkalis (caustic solutions). Store away from water. · Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles. Keep containers tightly sealed. Protect from humidity and water. This product is hygroscopic. · Specific end use(s) No relevant information available. 8 Exposure controls/personal protection · Control parameters · Components with limit values that require monitoring at the workplace: The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace. (Cont'd. on page 5) 47.0.2 Page: 5/11 Safety Data Sheet acc. to OSHA HCS (29CFR 1910.1200) and WHMIS 2015 Regulations Printing date: July 16, 2018 Revision: July 16, 2018 Trade name: Lithium Tetrachlorogalate in Sulfuryl Chloride Solution (Cont'd. of page 4) · Exposure controls · General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. Use adequate ventilation, to include fume hood. Safety shower / eye wash should be provided. Provide sodium bicarbonate solution for skin contact. Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing. Wash hands before breaks and at the end of work. Do not inhale gases / fumes / aerosols. Avoid contact with the eyes and skin. · Engineering controls: No relevant information available. · Breathing equipment: Respiratory protection required. · Protection of hands: Protective gloves
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