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Safety Data Sheet Acc Page: 1/11 Safety Data Sheet acc. to OSHA HCS (29CFR 1910.1200) and WHMIS 2015 Regulations Printing date: September 18, 2018 Revision: September 18, 2018 1 Identification · Product identifier · Trade name: Lithium Thionyl Chloride Metal Batteries with Gallium Electrolyte · Article number: No other identifiers · Recommended use and restriction on use · Recommended use: Lithium-based battery product. · Restrictions on use: Contact manufacturer/supplier · Details of the supplier of the Safety Data Sheet · Manufacturer/Supplier: Engineered Power 20, 3103 - 14th Avenue N.E. Calgary, Alberta, Canada T2A 7N6 Telephone (403) 235-2584 · Emergency telephone number: ChemTel Inc. (800)255-3924 (North America) +1 (813)248-0585 (International) 2 Hazard(s) identification · Classification of the substance or mixture Acute Tox. 4 H302 Harmful if swallowed. Acute Tox. 3 H331 Toxic if inhaled. Skin Corr. 1A H314 Causes severe skin burns and eye damage. Eye Dam. 1 H318 Causes serious eye damage. STOT SE 3 H335 May cause respiratory irritation. · Additional information: Note: Leaking cells pose health hazards: see Sections 4 and 11. Intentional abuse of cells or batteries increases the risk of harm or damage to the product, to the user, and to surrounding materials and personnel. Do not attempt to open sealed cells or batteries. Do not intentionally short-circuit cells or batteries. Do not expose these products to temperatures exceeding the maximum manufacturers rating. Do not dispose of cells/batteries in landfills. Please follow all manufacturer guidelines in the use, storage, and disposal of these products. Consult manufacturer in cases of questions involving specific product usage. There are no other hazards not otherwise classified that have been identified. · Label elements · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms: GHS05 GHS06 GHS07 · Signal word: Danger · Hazard statements: H302 Harmful if swallowed. (Cont'd. on page 2) 47.0.13 Page: 2/11 Safety Data Sheet acc. to OSHA HCS (29CFR 1910.1200) and WHMIS 2015 Regulations Printing date: September 18, 2018 Revision: September 18, 2018 Trade name: Lithium Thionyl Chloride Metal Batteries with Gallium Electrolyte (Cont'd. of page 1) H331 Toxic if inhaled. H314 Causes severe skin burns and eye damage. H335 May cause respiratory irritation. · Precautionary statements: P260 Do not breathe dusts or mists. P264 Wash thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/face protection. P301+P312 If swallowed: Call a poison center/doctor if you feel unwell. P301+P330+P331 If swallowed: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P310 Immediately call a poison center/doctor. P321 Specific treatment (see on this label). P363 Wash contaminated clothing before reuse. P403+P233 Store in a well-ventilated place. Keep container tightly closed. P405 Store locked up. P501 Dispose of contents/container in accordance with local/regional/national/international regulations. · NFPA ratings (scale 0 - 4) Health = 3 1 Fire = 1 3 0 Instability = 0 The substance demonstrates unusual reactivity with water. · HMIS-ratings (scale 0 - 4) HEALTH *3 Health = *3 FIRE 1 Fire = 1 REACTIVITY 0 Reactivity = 0 * - Indicates a long term health hazard from repeated or prolonged exposures. 3 Composition/information on ingredients · Chemical characterization: Mixtures · Components: 7719-09-7 thionyl chloride 40-60% Acute Tox. 3, H331 Skin Corr. 1A, H314 Acute Tox. 4, H302; STOT SE 3, H335 13450-90-3 gallium trichloride 10-20% Met. Corr.1, H290; Skin Corr. 1B, H314; Eye Dam. 1, H318 7447-41-8 lithium chloride ≥5-<10% Acute Tox. 4, H302; Skin Irrit. 2, H315; Eye Irrit. 2A, H319 (Cont'd. on page 3) 47.0.13 Page: 3/11 Safety Data Sheet acc. to OSHA HCS (29CFR 1910.1200) and WHMIS 2015 Regulations Printing date: September 18, 2018 Revision: September 18, 2018 Trade name: Lithium Thionyl Chloride Metal Batteries with Gallium Electrolyte (Cont'd. of page 2) 7439-93-2 Lithium ≥2.5-<5% Water-react. 1, H260 Skin Corr. 1B, H314 · Additional information: For the listed ingredient(s), the identity and/or exact percentage(s) are being withheld as a trade secret. For the wording of the listed Hazard Statements, refer to section 16. 4 First-aid measures · Description of first aid measures · General information: Information references exposures to battery contents, and not exposures to whole units. Exposures to whole units are unlikely to produce health hazards. Immediately remove any clothing soiled by the product. Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. Take affected persons out into the fresh air. · After inhalation: Unlikely route of exposure. Supply fresh air. Seek immediate medical advice. Provide oxygen treatment if affected person has difficulty breathing. In case of unconsciousness place patient stably in side position for transportation. · After skin contact: Unlikely route of exposure. Immediately rinse with water. Seek immediate medical advice. Immediate medical treatment necessary. Failure to treat burns can prevent wounds from healing. · After eye contact: Unlikely route of exposure. Remove contact lenses if worn, if possible. Rinse opened eye for several minutes under running water. Then consult a doctor. · After swallowing: Unlikely route of exposure. Rinse out mouth and then drink plenty of water. Do not induce vomiting; immediately call for medical help. · Most important symptoms and effects, both acute and delayed: Adverse health effects are not reasonably expected from normal use of product. Coughing May cause respiratory irritation. Breathing difficulty Caustic effect on skin and mucous membranes. Eye damage. · Danger: Danger of gastric perforation. Harmful if swallowed. Danger of pulmonary edema. Danger of impaired breathing. Toxic if inhaled. (Cont'd. on page 4) 47.0.13 Page: 4/11 Safety Data Sheet acc. to OSHA HCS (29CFR 1910.1200) and WHMIS 2015 Regulations Printing date: September 18, 2018 Revision: September 18, 2018 Trade name: Lithium Thionyl Chloride Metal Batteries with Gallium Electrolyte (Cont'd. of page 3) Causes serious eye damage. Causes burns. · Indication of any immediate medical attention and special treatment needed: Decontaminate patient thoroughly with sodium bicarbonate solution; assume that some skin contact has taken place. Treat other symptoms symptomatically, with emphasis on maintaining electrolyte balance. Medical supervision for at least 48 hours. If necessary oxygen respiration treatment. 5 Fire-fighting measures · Extinguishing media · Suitable extinguishing agents: Dry sand. Graphite powder such as Lith-X. Use only the agents indicated above. · For safety reasons unsuitable extinguishing agents: Water or Halons. · Special hazards arising from the substance or mixture Information references exposures to battery contents, and not exposures to whole units. In contact with water releases flammable gases, which may ignite spontaneously. During heating or in case of fire poisonous gases are produced. Reacts violently with water. · Advice for firefighters · Protective equipment: Wear self-contained respiratory protective device. Do not inhale explosion gases or combustion gases. Wear fully protective suit. · Additional information: Evacuate area and fight fire from from the upwind side. 6 Accidental release measures · Personal precautions, protective equipment and emergency procedures Use respiratory protective device against the effects of fumes/dust/aerosol. Wear protective equipment. Keep unprotected persons away. Ensure adequate ventilation. [In case of inadequate ventilation] wear respiratory protection. Keep people at a distance and stay upwind. Do not allow contact with water. · Environmental precautions Do not allow to enter sewers/ surface or ground water. · Methods and material for containment and cleaning up If a spill is small, a trained person may attempt to stop or contain the leak by carefully neutralizing spill with calcium carbonate or sodium bicarbonate. Seal leaking container and neutralized product in a plastic bag and transfer to a lidded container for disposal or recovery. Consult an accredited waste disposal contractor or the local authority for additional advice. Large spills should only be handled by specially trained hazardous materials personnel. Do not flush with water or aqueous cleansing agents Send for recovery or disposal in suitable receptacles. · Reference to other sections See Section 7 for information on safe handling. (Cont'd. on page 5) 47.0.13 Page: 5/11 Safety Data Sheet acc. to OSHA HCS (29CFR 1910.1200) and WHMIS 2015 Regulations Printing date: September 18, 2018 Revision: September 18, 2018 Trade name: Lithium Thionyl Chloride Metal Batteries with Gallium Electrolyte (Cont'd. of page 4) See Section 8 for information on personal protection equipment. See Section 13 for disposal information. 7 Handling and storage · Handling · Precautions for safe handling: Information is only applicable to product contents, and
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