Mercury Spill Fact Sheet
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Manganese and Its Compounds: Environmental Aspects
This report contains the collective views of an international group of experts and does not necessarily represent the decisions or the stated policy of the United Nations Environment Programme, the International Labour Organization, or the World Health Organization. Concise International Chemical Assessment Document 63 MANGANESE AND ITS COMPOUNDS: ENVIRONMENTAL ASPECTS First draft prepared by Mr P.D. Howe, Mr H.M. Malcolm, and Dr S. Dobson, Centre for Ecology & Hydrology, Monks Wood, United Kingdom The layout and pagination of this pdf file are not identical to the document in print Corrigenda published by 12 April 2005 have been incorporated in this file Published under the joint sponsorship of the United Nations Environment Programme, the International Labour Organization, and the World Health Organization, and produced within the framework of the Inter-Organization Programme for the Sound Management of Chemicals. World Health Organization Geneva, 2004 The International Programme on Chemical Safety (IPCS), established in 1980, is a joint venture of the United Nations Environment Programme (UNEP), the International Labour Organization (ILO), and the World Health Organization (WHO). The overall objectives of the IPCS are to establish the scientific basis for assessment of the risk to human health and the environment from expos ure to chemicals, through international peer review processes, as a prerequisite for the promotion of chemical safety, and to provide technical assistance in strengthening national capacities for the sound management -
HISTORY of LEAD POISONING in the WORLD Dr. Herbert L. Needleman Introduction the Center for Disease Control Classified the Cause
HISTORY OF LEAD POISONING IN THE WORLD Dr. Herbert L. Needleman Introduction The Center for Disease Control classified the causes of disease and death as follows: 50 % due to unhealthy life styles 25 % due to environment 25% due to innate biology and 25% due to inadequate health care. Lead poisoning is an environmental disease, but it is also a disease of life style. Lead is one of the best-studied toxic substances, and as a result we know more about the adverse health effects of lead than virtually any other chemical. The health problems caused by lead have been well documented over a wide range of exposures on every continent. The advancements in technology have made it possible to research lead exposure down to very low levels approaching the limits of detection. We clearly know how it gets into the body and the harm it causes once it is ingested, and most importantly, how to prevent it! Using advanced technology, we can trace the evolution of lead into our environment and discover the health damage resulting from its exposure. Early History Lead is a normal constituent of the earth’s crust, with trace amounts found naturally in soil, plants, and water. If left undisturbed, lead is practically immobile. However, once mined and transformed into man-made products, which are dispersed throughout the environment, lead becomes highly toxic. Solely as a result of man’s actions, lead has become the most widely scattered toxic metal in the world. Unfortunately for people, lead has a long environmental persistence and never looses its toxic potential, if ingested. -
ESTIMATION of FISSION-PRODUCT GAS PRESSURE in URANIUM DIOXIDE CERAMIC FUEL ELEMENTS by Wuzter A
NASA TECHNICAL NOTE NASA TN D-4823 - - .- j (2. -1 "-0 -5 M 0-- N t+=$j oo w- P LOAN COPY: RET rm 3 d z c 4 c/) 4 z ESTIMATION OF FISSION-PRODUCT GAS PRESSURE IN URANIUM DIOXIDE CERAMIC FUEL ELEMENTS by WuZter A. PuuZson una Roy H. Springborn Lewis Reseurcb Center Clevelund, Ohio NATIONAL AERONAUTICS AND SPACE ADMINISTRATION WASHINGTON, D. C. NOVEMBER 1968 i 1 TECH LIBRARY KAFB, NM I 111111 lllll IllH llll lilll1111111111111 Ill1 01317Lb NASA TN D-4823 ESTIMATION OF FISSION-PRODUCT GAS PRESSURE IN URANIUM DIOXIDE CERAMIC FUEL ELEMENTS By Walter A. Paulson and Roy H. Springborn Lewis Research Center Cleveland, Ohio NATIONAL AERONAUTICS AND SPACE ADMINISTRATION For sale by the Clearinghouse for Federal Scientific and Technical Information Springfield, Virginia 22151 - CFSTl price $3.00 ABSTRACl Fission-product gas pressure in macroscopic voids was calculated over the tempera- ture range of 1000 to 2500 K for clad uranium dioxide fuel elements operating in a fast neutron spectrum. The calculated fission-product yields for uranium-233 and uranium- 235 used in the pressure calculations were based on experimental data compiled from various sources. The contributions of cesium, rubidium, and other condensible fission products are included with those of the gases xenon and krypton. At low temperatures, xenon and krypton are the major contributors to the total pressure. At high tempera- tures, however, cesium and rubidium can make a considerable contribution to the total pressure. ii ESTIMATION OF FISSION-PRODUCT GAS PRESSURE IN URANIUM DIOXIDE CERAMIC FUEL ELEMENTS by Walter A. Paulson and Roy H. -
Mercury Education
MERCURY The Slippery, Silent Toxin to Dispose of Carefully You may be surprised to find mercury in your home, business and places you go often. When spilled or not disposed of carefully, it poses a risk to human and ecosystem health. DID YOU KNOW? Mercury is the only metal that is liquid at room Why is Mercury Such a Problem? temperature. Mercury, or quicksilver, is an element that serves many useful 80 purposes – when contained. It conducts electricity, is used in thermometers, thermostats, barometers, blood pressure cuffs and many other everyday items such as some alarm clocks Mercury 200.59 and irons. The most common use is in today’s fluorescent light bulbs that use mercury vapor. Read the reverse The trouble comes when mercury is not disposed of properly for safe ways to or worse, when it spills. Mercury is a toxic element that can dispose of mercury. enter the body through an open wound or by inhaling or ingesting it. It can cause damage to nerves, the liver and kidneys, as well as a number of other symptoms. If mercury is poured down the drain or dumped into the sewer, it seeps into lakes and waterways, a chemical process occurs, converting it to deadly methylmercury, potentially contaminating the fish and animals we eat. When products containing mercury are placed in the trash or poured down the drain, the mercury does not disappear. It ends up in the environment via landfills and wastewater treatment facilities. Now that you know some of the items that contain mercury, you can make Never touch or vacuum up buying decisions that reduce the amount of mercury in your home or office, spilled mercury in any form, and that assure safe disposal of products that contain mercury. -
TOXICOLOGY and EXPOSURE GUIDELINES ______(For Assistance, Please Contact EHS at (402) 472-4925, Or Visit Our Web Site At
(Revised 1/03) TOXICOLOGY AND EXPOSURE GUIDELINES ______________________________________________________________________ (For assistance, please contact EHS at (402) 472-4925, or visit our web site at http://ehs.unl.edu/) "All substances are poisons; there is none which is not a poison. The right dose differentiates a poison and a remedy." This early observation concerning the toxicity of chemicals was made by Paracelsus (1493- 1541). The classic connotation of toxicology was "the science of poisons." Since that time, the science has expanded to encompass several disciplines. Toxicology is the study of the interaction between chemical agents and biological systems. While the subject of toxicology is quite complex, it is necessary to understand the basic concepts in order to make logical decisions concerning the protection of personnel from toxic injuries. Toxicity can be defined as the relative ability of a substance to cause adverse effects in living organisms. This "relative ability is dependent upon several conditions. As Paracelsus suggests, the quantity or the dose of the substance determines whether the effects of the chemical are toxic, nontoxic or beneficial. In addition to dose, other factors may also influence the toxicity of the compound such as the route of entry, duration and frequency of exposure, variations between different species (interspecies) and variations among members of the same species (intraspecies). To apply these principles to hazardous materials response, the routes by which chemicals enter the human body will be considered first. Knowledge of these routes will support the selection of personal protective equipment and the development of safety plans. The second section deals with dose-response relationships. -
Ethylene Glycol Ingestion Reviewer: Adam Pomerlau, MD Authors: Jeff Holmes, MD / Tammi Schaeffer, DO
Pediatric Ethylene Glycol Ingestion Reviewer: Adam Pomerlau, MD Authors: Jeff Holmes, MD / Tammi Schaeffer, DO Target Audience: Emergency Medicine Residents, Medical Students Primary Learning Objectives: 1. Recognize signs and symptoms of ethylene glycol toxicity 2. Order appropriate laboratory and radiology studies in ethylene glycol toxicity 3. Recognize and interpret blood gas, anion gap, and osmolal gap in setting of TA ingestion 4. Differentiate the symptoms and signs of ethylene glycol toxicity from those associated with other toxic alcohols e.g. ethanol, methanol, and isopropyl alcohol Secondary Learning Objectives: detailed technical/behavioral goals, didactic points 1. Perform a mental status evaluation of the altered patient 2. Formulate independent differential diagnosis in setting of leading information from RN 3. Describe the role of bicarbonate for severe acidosis Critical actions checklist: 1. Obtain appropriate diagnostics 2. Protect the patient’s airway 3. Start intravenous fluid resuscitation 4. Initiate serum alkalinization 5. Initiate alcohol dehydrogenase blockade 6. Consult Poison Center/Toxicology 7. Get Nephrology Consultation for hemodialysis Environment: 1. Room Set Up – ED acute care area a. Manikin Set Up – Mid or high fidelity simulator, simulated sweat if available b. Airway equipment, Sodium Bicarbonate, Nasogastric tube, Activated charcoal, IV fluid, norepinephrine, Simulated naloxone, Simulate RSI medications (etomidate, succinylcholine) 2. Distractors – ED noise For Examiner Only CASE SUMMARY SYNOPSIS OF HISTORY/ Scenario Background The setting is an urban emergency department. This is the case of a 2.5-year-old male toddler who presents to the ED with an accidental ingestion of ethylene glycol. The child was home as the father was watching him. The father was changing the oil on his car. -
Poison Hemlock G
Pasture Weed Fact Sheet W 325 Poison Hemlock G. Neil Rhodes, Jr., Professor and Extension Weed Management Specialist Trevor D. Israel, Extension Assistant Department of Plant Sciences Poison Hemlock Conium maculatum L. Classification and Description Poison hemlock, also called deadly hemlock, poison parsley, spotted hemlock, and California fern, is a highly poisonous bien- nial weed that is a member of the family Apiaceae, which is also referred to as the carrot family. It was originally introduced as a garden plant because of its attractive flowers. Other members of this family include wild carrot (Daucus carota L.), wild chervil (Anthriscus syvlestris (L.) Hoffm.), and a close relative to poison hemlock, water hemlock (Cicuta maculata L.). This native of Eurasia is found throughout Tennessee where it usually occurs in patches in cool-season grass pastures, roadsides, drainage ditches and stream banks. The cotyledons or seed leaves of seedlings are Fig. 1. Poison hemlock flowers in compound umbels. oblong-lanceolate, and the first true leaf is pinnately compound and glabrous. Flowers are small and white in large, compound umbels 1.5 to 2.4 inches wide (Fig. 1). The hollow stems of this plant are ridged, glabrous, and purple-spotted (Fig. 2). Leaves form a basal rosette; they are alternate upward, petioled, approxi- mately 8 to 16 inches long, broadly triangular-ovate, and com- pound. Leaflets are lanceolate to ovate-oblong, finely cut, less than 0.5 inch long. Crushed leaves have a mouse-like odor. Ma- ture plants can be 3 to 4 feet tall (Fig. 3) with fibrous roots branching from a turnip-like taproot (Fig. -
Poison Hemlock (Conium Maculatum)
KING COUNTY NOXIOUS WEED ALERT Class B Noxious Weed: Poison Hemlock Control Required on Conium maculatum Parsley Family Public Lands and Roads Identification Tips • Tall biennial, reaching 8 to 10 feet the second year • Bright green, fernlike leaves with strong musty smell • First year plants form low clumps of lacy leaves with reddish spots on stems • Second year stems are stout, hollow, hairless, ribbed, with reddish or purple spotting/streaking • Flowering plants covered with numerous small, umbrella-shaped clusters of tiny white flowers that have five petals • Seeds form in green, ridged capsules that eventually turn brown Poison-hemlock has bright green, fern- like leaves with a musty smell. Biology Reproduces by seed. First year grows into a rosette; second year, develops tall stems and flowers. Rapid growth from March to May, flowers in late spring. Up to 40,000 seeds per plant are produced. Seeds fall near the plant and are moved by erosion, animals, rain and human activity. Seeds viable up to 6 years and germinate throughout the growing season; do not require a dormant period. Impacts Acutely toxic to people, livestock, wildlife; causes death by Thick, hairless stems have reddish- respiratory paralysis after ingestion. Aggressive growth crowds out purple spots or streaks. desirable vegetation. Early spring growth makes it more likely to be eaten by animals when there is limited forage available. Can be mistaken for a carrot when small. Distribution Eurasian species, widely found in North America. Widespread in King County; found along roadsides, riparian areas, ravines, fields, ditches and un-managed yards and vacant lots. -
Elemental Mercury Emission in the Indoor Environment Due to Broken Compact Fluorescent Light (CFL) Bulbs
Elemental Mercury Emission In The Indoor Environment Due To Broken Compact Fluorescent Light (CFL) Bulbs David Marr1, Mark Mason1, Stanley Durkee2 1U.S. EPA, RTP, NC 2U.S. EPA, Washington DC Mark Mason l [email protected] l 919-541-4835 Paper control number 553 Introduction Mercury emissions from broken Broken CFL Bulb Cleanup fluorescent bulbs Compact fluorescent light (CFL) bulbs require elemental The U.S EPA, as part of its public outreach program, provides mercury for operation. Each bulb contains a few milligrams Published research on mercury emissions cleanup guidance when a CFL is broken in the indoor of mercury, a value that has been decreasing over time due to environment. As part of this guidance, it is recommended that new technologies and methodologies, driven primarily by from lighting the debris be cleaned up following 5 to 10 minutes of increased environmental and consumer concerns. If a CFL breaks, Aucott et al. (2003) generated mercury emission rate ventilation and some initial steps. Figure 3 shows indoor model some of the mercury is immediately released as elemental equations for fluorescent lamps (FLs) broken in a barrel at results that include the emission rate of Equation 1, but with mercury vapor while the remainder is available for emission three ambient air temperatures in an effort to quantify source removal occurring at 15 minutes to provide a visual of over time to air via the bulb debris and contaminated indoor mercury emissions in time. Equation 1 is their published the impact of proper cleanup on indoor mercury concentrations surfaces until properly remediated. -
Mercury Use and Loss from Gold Mining in Nineteenth-Century Victoria 45
CSIRO Publishing The Royal Society of Victoria, 127, 44 –54, 2015 www.publish.csiro.au/journals/rs 10.1071/RS15017 Me RCuRy uSe and LOSS fROM GOLd MInInG In nIneTeenTh- CenTuRy Victoria Peter Davies1, susan Lawrence2 anD JoDi turnbuLL3 1, 2, 3 department of archaeology and history, La Trobe university, Bundoora, Victoria 3086 Correspondence: Peter davies, [email protected] ABSTRACT: This paper reports on preliminary research into gold-mining-related mercury contamination in nineteenth-century Victoria. data drawn from contemporary sources, including Mineral Statistics of Victoria and Mining Surveyors Reports from 1868‒1888, are used to calculate quantities of mercury used by miners to amalgamate gold in stamp batteries and the rates of mercury lost in the process. Some of the mercury discharged from mining and ore milling flowed into nearby waterways and some remained in the waste residue, the tailings near the mills. We estimate that a minimum of 121 tons of mercury were discharged from stamp batteries in this period. although the figures fluctuate through time and space, they allow a good estimate of how much mercury was leaving the mine workings and entering Victorian creeks and rivers. Better understanding of historic mercury loss can provide the basis for improved mapping of mercury distribution in modern waterways, which can in turn inform the management of catchment systems. Keywords: mercury, gold mining, pollution, water, rivers In recent years, mercury in waterways has emerged as an et al. 1996) and new Zealand (Moreno et al. 2005), while important environmental issue in south-eastern australia extensive mercury pollution also resulted from silver and in many other areas. -
Mercury and Mercury Compounds
United States Office of Air Quality EPA-454/R-97-012 Environmental Protection Planning And Standards Agency Research Triangle Park, NC 27711 December 1997 AIR EPA LOCATING AND ESTIMATING AIR EMISSIONS FROM SOURCES OF MERCURY AND MERCURY COMPOUNDS L & E EPA-454/R-97-012 Locating And Estimating Air Emissions From Sources of Mercury and Mercury Compounds Office of Air Quality Planning and Standards Office of Air and Radiation U.S. Environmental Protection Agency Research Triangle Park, NC 27711 December 1997 This report has been reviewed by the Office of Air Quality Planning and Standards, U.S. Environmental Protection Agency, and has been approved for publication. Mention of trade names and commercial products does not constitute endorsement or recommendation for use. EPA-454/R-97-012 TABLE OF CONTENTS Section Page EXECUTIVE SUMMARY ................................................ xi 1.0 PURPOSE OF DOCUMENT .............................................. 1-1 2.0 OVERVIEW OF DOCUMENT CONTENTS ................................. 2-1 3.0 BACKGROUND ........................................................ 3-1 3.1 NATURE OF THE POLLUTANT ..................................... 3-1 3.2 OVERVIEW OF PRODUCTION, USE, AND EMISSIONS ................. 3-1 3.2.1 Production .................................................. 3-1 3.2.2 End-Use .................................................... 3-3 3.2.3 Emissions ................................................... 3-6 4.0 EMISSIONS FROM MERCURY PRODUCTION ............................. 4-1 4.1 PRIMARY MERCURY -
Direct Detection of Atmospheric Atomic Bromine Leading to Mercury and Ozone Depletion
Direct detection of atmospheric atomic bromine leading to mercury and ozone depletion Siyuan Wanga,1, Stephen M. McNamaraa, Christopher W. Mooreb,2, Daniel Obristb,3, Alexandra Steffenc, Paul B. Shepsond,e,f,4, Ralf M. Staeblerc, Angela R. W. Rasod, and Kerri A. Pratta,g,5 aDepartment of Chemistry, University of Michigan, Ann Arbor, MI 48109; bDivision of Atmospheric Science, Desert Research Institute, Reno, NV 89523; cAir Quality Processes Research Section, Environment and Climate Change Canada, Toronto, ON M3H5T4, Canada; dDepartment of Chemistry, Purdue University, West Lafayette, IN 47907; eDepartment of Earth, Atmospheric, and Planetary Sciences, Purdue University, West Lafayette, IN 47907; fPurdue Climate Change Research Center, Purdue University, West Lafayette, IN 47907; and gDepartment of Earth and Environmental Sciences, University of Michigan, Ann Arbor, MI 48109 Edited by Mark H. Thiemens, University of California San Diego, La Jolla, CA, and approved May 29, 2019 (received for review January 12, 2019) Bromine atoms play a central role in atmospheric reactive halogen O3 producing BrO ([R2]), which can undergo photolysis to chemistry, depleting ozone and elemental mercury, thereby reform Br ([R3]). Br is also regenerated by BrO reaction with enhancing deposition of toxic mercury, particularly in the Arctic NO ([R4]), or a halogen monoxide (XO = BrO, ClO, or IO; near-surface troposphere. However, direct bromine atom mea- [R5]) (19). surements have been missing to date, due to the lack of analytical capability with sufficient sensitivity for ambient measurements. Br2 + hv → Br + Br, [R1] Here we present direct atmospheric bromine atom measurements, conducted in the springtime Arctic. Measured bromine atom levels − Br + O → BrO + O , [R2] reached 14 parts per trillion (ppt, pmol mol 1;4.2× 108 atoms 3 2 − per cm 3) and were up to 3–10 times higher than estimates using + + → + [R3] previous indirect measurements not considering the critical role of BrO hv O2 Br O3, molecular bromine.