In Situ Leach Mining Proceedings
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In Situ Leach (ISL) Mining of Uranium
In Situ Leach (ISL) Mining of Uranium (June 2009) l Most uranium mining in the USA and Kazakhstan is now by in situ leach methods, also known as in situ recovery (ISR). l In USA ISL is seen as the most cost effective and environmentally acceptable method of mining, and Australian experience supports this. l Australia's first ISL uranium mine is Beverley, which started operation late in 2000. The proposal for Honeymoon has government approval and it is expected to be operating in 2008. Conventional mining involves removing mineralised rock (ore) from the ground, breaking it up and treating it to remove the minerals being sought. In situ leaching (ISL), also known as solution mining, or in situ recovery (ISR) in North America, involves leaving the ore where it is in the ground, and recovering the minerals from it by dissolving them and pumping the pregnant solution to the surface where the minerals can be recovered. Consequently there is little surface disturbance and no tailings or waste rock generated. However, the orebody needs to be permeable to the liquids used, and located so that they do not contaminate ground water away from the orebody. Uranium ISL uses the native groundwater in the orebody which is fortified with a complexing agent and in most cases an oxidant. It is then pumped through the underground orebody to recover the minerals in it by leaching. Once the pregnant solution is returned to the surface, the uranium is recovered in much the same way as in any other uranium plant (mill). In Australian ISL mines (Beverley and the soon to be opened Honeymoon Mine) the oxidant used is hydrogen peroxide and the complexing agent sulfuric acid. -
Understanding Fluid–Rock Interactions and Lixiviant/Oxidant Behaviour for the In-Situ Recovery of Metals from Deep Ore Bodies
School of Earth and Planetary Science Department of Applied Geology Understanding Fluid–Rock Interactions and Lixiviant/Oxidant Behaviour for the In-situ Recovery of Metals from Deep Ore Bodies Tania Marcela Hidalgo Rosero This thesis is presented for the degree of Doctor of Philosophy of Curtin University February 2020 1 Declaration __________________________________________________________________________ Declaration To the best of my knowledge and belief, I declare that this work of thesis contains no material published by any other person, except where due acknowledgements have been made. This thesis contains no material which has been accepted for the award of any other degree or diploma in any university. Tania Marcela Hidalgo Rosero Date: 28/01/2020 2 Abstract __________________________________________________________________________ Abstract In-situ recovery (ISR) processing has been recognised as a possible alternative to open- pit mining, especially for low-grade resources. In ISR, the fluid–rock interaction between the target ore and the lixiviant results in valuable- (and gangue-) metal dissolution. This interaction is achieved by the injection and recovery of fluid by means of strategically positioned wells. Although the application of ISR has become more common (ISR remains the preferential processing technique for uranium and has been applied in pilot programs for treating oxide zones in copper deposits), its application to hard-rock refractory and low-grade copper-sulfide deposits is still under development. This research is focused on the possible application of ISR to primary copper sulfides usually found as deep ores. Lixiviant/oxidant selection is an important aspect to consider during planning and operation in the ISR of copper-sulfide ores. -
Uranium in Situ Leaching
IAEA-TECDOC-720 Uranium in situ leaching Proceedings Technicala of Committee Meeting held in Vienna, 5-8 October 1992 INTERNATIONAL ATOMIC ENERGY AGENC\ /A Y The IAEA doe t normallsno y maintain stock f reportso thin si s series. However, microfiche copies of these reports can be obtained from IIMIS Clearinghouse International Atomic Energy Agency Wagramerstrasse5 P.O. Box 100 A-1400 Vienna, Austria Orders shoul accompaniee db prepaymeny db f Austriao t n Schillings 100,- in the form of a cheque or in the form of IAEA microfiche service coupons which may be ordered separately from the INIS Clearinghouse. Copies of this IAEA-TECDOC may be obtained from: Nuclear Material Fued san l Cycle Technology Section International Atomic Energy Agency Wagramerstrasse 5 P.O. Box 100 A-1400 Vienna, Austria URANIU SITMN I U LEACHING IAEA, VIENNA, 1993 IAEA-TECDOC-720 ISSN 1011-4289 Printe IAEe th AustriAn y i d b a September 1993 FOREWORD The IAEA's latest published estimates show that nuclear power production worldwide will maintain modest growth well into the next century. These estimates indicate that nuclear energy production will gro averagn wo 1.5y eb % 2.5o t year %pe r worldwide ove nex e decadeso rth tw t s i t I . for this reason that despite the continuing depressed uranium market, the question of uranium supply demand an d remain issun sa e that needaddressee b o st monitoredd dan developmentsw Ne . e du , to the recent entry of the Commonwealth of Independent States and China into the uranium market, increase such a need. -
Sell-1559, Leaching
CONTACT INFORMATION Mining Records Curator Arizona Geological Survey 416 W. Congress St., Suite 100 Tucson, Arizona 85701 520-770-3500 http://www.azgs.az.gov [email protected] The following file is part of the James Doyle Sell Mining Collection ACCESS STATEMENT These digitized collections are accessible for purposes of education and research. We have indicated what we know about copyright and rights of privacy, publicity, or trademark. Due to the nature of archival collections, we are not always able to identify this information. We are eager to hear from any rights owners, so that we may obtain accurate information. Upon request, we will remove material from public view while we address a rights issue. CONSTRAINTS STATEMENT The Arizona Geological Survey does not claim to control all rights for all materials in its collection. These rights include, but are not limited to: copyright, privacy rights, and cultural protection rights. The User hereby assumes all responsibility for obtaining any rights to use the material in excess of “fair use.” The Survey makes no intellectual property claims to the products created by individual authors in the manuscript collections, except when the author deeded those rights to the Survey or when those authors were employed by the State of Arizona and created intellectual products as a function of their official duties. The Survey does maintain property rights to the physical and digital representations of the works. QUALITY STATEMENT The Arizona Geological Survey is not responsible for the accuracy of the records, information, or opinions that may be contained in the files. The Survey collects, catalogs, and archives data on mineral properties regardless of its views of the veracity or accuracy of those data. -
Changes in Bornite (Cu5fes4) After Heating in Air: Mössbauer Effect
Vol. 134 (2018) ACTA PHYSICA POLONICA A No. 5 Proceedings of the All-Polish Seminar on Mössbauer Spectroscopy, Goniądz, Poland, June 17–20, 2018 Changes in Bornite (Cu5FeS4) after Heating in Air: Mössbauer Effect Study M. Kądziołka-Gaweła;∗ and Z. Adamczykb aInstitute of Physics, University of Silesia in Katowice, 75 Pułku Piechoty 1a, 41-500 Chorzów, Poland bInstitute of Applied Geology, Silesian University of Technology, Akademicka 2, 44-100 Gliwice, Poland The phase transitions and structural behaviour in natural bornite sample were investigated after heat treatment in air in a temperature range of (180÷500) ◦C using high-resolution Faraday, X-ray diffraction and 57Fe Mössbauer spectroscopy studies. X-ray diffraction and the Mössbauer spectroscopy results show that polymorph phases can exist only at high temperatures, and at a temperature of 220 ◦C a process of decomposition of bornite structure starts. Hematite is a main Fe-bearing phase and Cu is located mainly in cooper oxides present in the sample after annealing at 500 ◦C. DOI: 10.12693/APhysPolA.134.1044 PACS/topics: 76.80.+y, 91.60.–x, 88.10.jn 1. Introduction 2. Experimental procedure Bornite (Cu5FeS4), also known as peacock ore, is a The natural sample of bornite was chosen for detailed widespread natural mineral that is composed of non- analyses. The bornite sample was taken from the Per- toxic and earth-abundant elements. Natural bornite mian copper-silver deposit from the Fore-Sudetic Mon- (L-bornite) crystallizes in the orthorhombic structure ocline and was collected in a Lubin mine located about with space group P bca. -
Study of Corrosion Potential Measurements As a Means to Monitor the Storage and Stabilisation Processes of Archaeological Copper Artefacts
Proceedings of Metal 2004 National Museum of Australia Canberra ACT 4-8 October 2004 ABN 70 592 297 967 Study of corrosion potential measurements as a means to monitor the storage and stabilisation processes of archaeological copper artefacts K. Leyssensa, A. Adriaensa, E. Pantosb and C. Degrignyc a Ghent University, Department of Analytical Chemistry, Krijgslaan 281 – S12, B-9000 Ghent, Belgium b CCLRC, Synchrotron Radiation Department, Daresbury Laboratory, Warrington, UK WA4 4AD c Malta Centre for Restoration, East Wing, Royal Naval Hospital, Bighi, Kalkara, Malta __________________________________________________________________________________________ Abstract Archaeological copper artefacts recovered from wet saline environments are often stored in tap water and stabilized in sodium sesquicarbonate solutions. Modification of the natural patina and development of active corrosion can occur during these processes. This implies that monitoring of storage/stabilisation processes is necessary. The focus of the study consists of examining how corrosion potential (Ecorr) measurements can contribute in providing information on the effectiveness of storage and stabilisation treatments. This paper reports on the Ecorr versus time plots of artificially prepared copper coupons (covered or not with corrosion layers) immersed in tap water and a sodium sesquicarbonate solution. Synchrotron radiation XRD was performed in parallel to understand the reactions that take place during the immersion processes. Keywords: corrosion potential measurements, XRD, copper, saline environments, storage, stabilisation, sodium sesquicarbonate, tap water 1. Introduction Archaeological copper artefacts recovered from wet saline environments should not be exposed directly to the atmosphere, especially when they contain aggressive chloride species, as the metal will then corrode at an accelerated rate in the oxygen-rich air (Scott 2002, p125). -
Minerals Found in Michigan Listed by County
Michigan Minerals Listed by Mineral Name Based on MI DEQ GSD Bulletin 6 “Mineralogy of Michigan” Actinolite, Dickinson, Gogebic, Gratiot, and Anthonyite, Houghton County Marquette counties Anthophyllite, Dickinson, and Marquette counties Aegirinaugite, Marquette County Antigorite, Dickinson, and Marquette counties Aegirine, Marquette County Apatite, Baraga, Dickinson, Houghton, Iron, Albite, Dickinson, Gratiot, Houghton, Keweenaw, Kalkaska, Keweenaw, Marquette, and Monroe and Marquette counties counties Algodonite, Baraga, Houghton, Keweenaw, and Aphrosiderite, Gogebic, Iron, and Marquette Ontonagon counties counties Allanite, Gogebic, Iron, and Marquette counties Apophyllite, Houghton, and Keweenaw counties Almandite, Dickinson, Keweenaw, and Marquette Aragonite, Gogebic, Iron, Jackson, Marquette, and counties Monroe counties Alunite, Iron County Arsenopyrite, Marquette, and Menominee counties Analcite, Houghton, Keweenaw, and Ontonagon counties Atacamite, Houghton, Keweenaw, and Ontonagon counties Anatase, Gratiot, Houghton, Keweenaw, Marquette, and Ontonagon counties Augite, Dickinson, Genesee, Gratiot, Houghton, Iron, Keweenaw, Marquette, and Ontonagon counties Andalusite, Iron, and Marquette counties Awarurite, Marquette County Andesine, Keweenaw County Axinite, Gogebic, and Marquette counties Andradite, Dickinson County Azurite, Dickinson, Keweenaw, Marquette, and Anglesite, Marquette County Ontonagon counties Anhydrite, Bay, Berrien, Gratiot, Houghton, Babingtonite, Keweenaw County Isabella, Kalamazoo, Kent, Keweenaw, Macomb, Manistee, -
Literature Review on the Properties of Cuprous Oxide Cu2o and the Process of Copper Oxidation
Technical Report TR-11-08 Literature review on the properties of cuprous oxide Cu2O and the process of copper oxidation P A Korzhavyi, B Johansson Department of Materials Science and Engineering Royal Institute of Technology October 2011 Svensk Kärnbränslehantering AB Swedish Nuclear Fuel and Waste Management Co Box 250, SE-101 24 Stockholm Phone +46 8 459 84 00 CM Gruppen AB, Bromma, 2012 CM Gruppen ISSN 1404-0344 Tänd ett lager: SKB TR-11-08 P, R eller TR. Literature review on the properties of cuprous oxide Cu2O and the process of copper oxidation P A Korzhavyi, B Johansson Department of Materials Science and Engineering Royal Institute of Technology October 2011 This report concerns a study which was conducted for SKB. The conclusions and viewpoints presented in the report are those of the author. SKB may draw modified conclusions, based on additional literature sources and/or expert opinions. A pdf version of this document can be downloaded from www.skb.se. Abstract The purpose of the present review is to provide a reference guide to the most recent data on the prop- erties of copper(I) oxide as well as on the atomic processes involved in the initial stages of oxidation of copper. The data on the structure of surfaces, as obtained from atomic-resolution microscopy studies (for example, STM) or from first-principles calculations, are reviewed. Information of this kind may be useful for understanding the atomic mechanisms of corrosion and stress-corrosion cracking of copper. SKB TR-11-08 3 Introduction The name “cuprite” of cuprous oxide Cu2O comes from the Latin “cuprum”, meaning copper. -
CUPRITE Calcite, Which Impart a Carmine Red Color to That Cu2o Mineral (Yedlin, 1974; Morris, 1983)
in interstices between conglomerate boulders. Also as variety “chalcotrichite” and as inclusions in CUPRITE calcite, which impart a carmine red color to that Cu2O mineral (Yedlin, 1974; Morris, 1983). 2. Clark A secondary copper mineral formed by supergene mine, Copper Harbor. 3. North Cliff mine: Fine alteration of native copper (q.v.) and copper micro-crystals showing gyroidal forms in nodules sulfides. Much of the native copper from the of copper (Moore and Beger, 1963). 4. Cliff mine: Keweenaw has films of cuprite, some of which With azurite as massive nodules cemented by formed after the mines were opened, but some of copper and, locally, silver. A few vugs lined with which, particularly from the higher levels, predates excellent crystals were found by Williams (1966). the mining (Butler and Burbank, 1929). Usually these crystals are faced by {001}, {011}, “Chalcotrichite” is a capillary or fibrous variety. and {111} of about equal development. Some Northern Peninsula. crystals show gyroidal symmetry with {321} left, and, if this is present, {211} is a major form. 5. Houghton County: 1. Centennial mine. 2. Delaware mine (Morris, 1983). 6. In stromatolites Laurium and La Salle mines, Osceola. 3. Quincy (calcite) in the Copper Harbor Conglomerate near mine, Hancock (2, 3 Morris, 1983). Gemmy red Copper Harbor with copper (q.v.), domeykite, and crystals up to 1 mm encrusting copper and quartz copper sulfides (Nishioka et al., 1983). crystals have been found on the 7th level of the Microscopic. 7. At the Central and Phoenix Quincy amygdaloid lode, 50 to 100 meters mines: As a red patina on native copper crystals, northeast of the No. -
CUPRITE RIDGE Porphyry Cu +/- Mo +/- Au with Epithermal Gold Potential
CUPRITE RIDGE Porphyry Cu +/- Mo +/- Au With Epithermal Gold Potential Numerous local occurrences of Malachite, Bornite and Cuprite are found in shear zones within the Triassic Mount Lytton Complex diorites and quartz diorites. Chlorite alteration of the intrusive rocks is extensive. Pegmatite dykes also cut the intrusive in places. In one locality wide zones of mineralized quartz is reported. The project area is underlain by Triassic Mount Lytton Complex intrusive rocks, comprising granodiorites, quartz diorites and amphibolites. Steeply dipping, southeast-striking shear zones and fractures are extensive and host Cu +/- Mo - Au mineralisation. Dioritic host rocks has pervasive chlorite alteration and intense oxidation and leaching are typical within shear zones. Characteristic alteration minerals are chlorite, hematite, sericite and kaolin. Oxidation minerals include limonite, cuprite and malachite. Shear zones up to 15 metres wide in drill core and traced for 200 metres host quartz veins which carry disseminated bornite and malachite. Grains of bornite were visible in samples. Pyrite, chalcopyrite and molybdenite were reported, but not defined in RC drill logs (Assessment Report 10881). The original Marion copper showings are located near one of two old (1968) percussion drill holes on the property at an elevation of about 1600 metres. This claim was explored by surface work by various owners intermittently from the turn of the century. The only known previous work was a diamond drill hole collared in 1968 on a zone of copper-enriched quartz veins by Burlington Mines Limited (Assessment Report 10881). John G. Wells had two percussion holes drilled in the area in 1982 to test a southeast-trending shear zone exposed by a road cut and an intensely altered area exposed by bulldozer work. -
Chalcocite Several Centimeters Wide Were Found (Butler and Burbank, 1929)
Veinlets of solid chalcocite several centimeters wide were found (Butler and Burbank, 1929). 2. CHALCOCITE Isle Royale mine: In fissures with “ankerite” and Cu2S “specularite.” Lane (1911) reports veins of Widespread, but historically not significant as an chalcocite, bornite, chalcopyrite, “whitneyite,” ore mineral in Michigan, except at the White Pine pyrrhotite(?), natrolite, analcime, and “adularia.” 3. deposit; in fissure veins cutting various rocks of Centennial mine: Disseminated in the Calumet and the native copper lodes and locally disseminated in Hecla Conglomerate. 4. Champion mine: In the lodes themselves; also present in a variety of veinlets with silver. Some as very fine-grained metalliferous veins. Twelve chalcocite deposits pulverulent material consisting of hexagonal have been located on the Keweenaw Peninsula, the platelets less than 0.5 mm across (Koenig, 1902). most notable being the Mount Bohemia and 5. Portage mine: In fissure veins with quartz and Gratiot Lake deposits (Robertson, 1975; Maki, orange calcite. 6. Wolverine mine. 7. Osceola 1999). Maki (1999) estimates the Gratiot Lake mine: As complex microcrystals and crusts on deposit may contain as much as 4.5 million metric prehnite from the No. 10 shaft (Falster, 1978). 8. tons of ore with an average grade of 2.3% copper. East slope Six Mile Hill, southwest of Houghton: Northern Peninsula. Networks of veins with copper, calcite, epidote, prehnite, datolite, and a considerable amount of chalcocite (Rominger, 1895). 9. Laurium mine: (Morris, 1983). Iron County: Sherwood and Buck iron mines: With other sulfides and uraninite (Vickers, 1956b; James et al., 1968). Figure 54: Chalcocite crystals from the White Pine mine, White Pine, Ontonagon County. -
Generic Environmental Impact Statement for In-Situ
GENERIC ENVIRONMENTAL IMPACT STATEMENT FOR IN-SITU LEACH URANIUM MILLING FACILITIES SCOPING SUMMARY REPORT JUNE 2008 U.S. Nuclear Regulatory Commission Rockville, Maryland 1. INTRODUCTION The U.S. Nuclear Regulatory Commission (NRC) expects to receive a number of new license applications for uranium milling at sites in the states of Nebraska, South Dakota, Wyoming and New Mexico over the next several years. NRC anticipates that most of these potential license applications will involve uranium milling facilities that would use the in-situ leach (ISL) process. Because there are environmental issues common to ISL milling facilities, NRC has prepared a Generic Environmental Impact Statement (GEIS) to evaluate the potential environmental impacts associated with the construction, operation, aquifer restoration, and decommissioning at future ISL milling facilities in specific regions of interest within these four western states, where NRC is the licensing authority for uranium milling. In the ISL process, a leaching agent, such as oxygen with sodium bicarbonate, is added to native ground water for injection through wells into the subsurface ore body to dissolve the uranium. The leach solution, containing the dissolved uranium, is pumped back to the surface and sent to a processing plant, where ion exchange is used to separate the uranium from the solution. The underground leaching of the uranium also frees other metals and minerals from the host rock. Operators of ISL facilities are required to restore the ground water affected by the leaching operations. The milling process concentrates the recovered uranium into the product known as "yellowcake" (U3O8). This yellowcake is then shipped to uranium conversion facilities for further processing in the overall uranium fuel cycle.