Cr3+ in Phyllosilicates
Mineral Spectroscopy: A Tribute to Roger G. Bums © The Geochemical Society, Special Publication No.5, ]996 Editors: M. D. Dyar, C. McCammon and M. W. Schaefer 3 Cr + in phyllosilicates: Influence of the nature of coordinating ligands and their next cationic neighbors on the crystal field parameters I 2 2 A. N. PLATONOV , K. LANGER , M. ANDRUT .3, G. CALAS4 'Institute of Geochemistry, Mineralogy and Ore Formation, Academy of Science of Ukraine, 252680 Kiev, Ukraine 2Institute of Mineralogy and Crystallography, Technical University, D-10623 Berlin, Germany 3GeoForschungszentrum Potsdam, D-14473 Potsdam, Deutschland "Laboratoire de Mineralogie et de Cristallographie, Universite de Paris 6 et 7, F-7525l Paris, France 3 Abstract- The electronic absorption spectra of Cr + -bearing clinochlore (I, kammererite), amesite (II), muscovite (III, fuchsite), dickite (IV), and montmorillonite (V, volkonskite) analysed by electron microprobe were obtained on single crystals. Microscope-spectrometric techniques and polarized radiation in the spectral range 10000-38000 cm " (I, II, III) or (on fine grained material) diffuse reflectance spectrometry in the spectral range 8000-50000 cm-I (IV, V) were used. The ligand field theoretical evaluation of the spectra showed the following: (i) The fl.o = 10Dq = f(1/R5) relation, wherein fl.o is the octahedral crystal field parameter and R the mean cation ligand distance, is valid within each series of layer silicates containing octahedral Cr3+ either in a trioctahedral layer (I, II and phlogopite) or in a dioctahedral layer (III, IV, V). Between the two functions, fl.o.trioct = f(1lR~ioct) and fl.o.di=t = f(1/R~ioct), there exists an energy difference of about 2200 em -I.
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