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The Dependence of the Sio Bond Length on Structural Parameters in Coesite, the Silica Polymorphs, and the Clathrasils
American Mineralogist, Volume 75, pages 748-754, 1990 The dependence of the SiO bond length on structural parameters in coesite, the silica polymorphs, and the clathrasils M. B. BOISEN, JR. Department of Mathematics, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24061, U.S.A. G. V. GIBBS, R. T. DOWNS Department of Geological Sciences, Virginia Polytechnic Institute and State University, Blacksburg, Virginia 24061, U.S.A. PHILIPPE D' ARCO Laboratoire de Geologie, Ecole Normale Superieure, 75230 Paris Cedex OS, France ABSTRACT Stepwise multiple regression analyses of the apparent R(SiO) bond lengths were com- pleted for coesite and for the silica polymorphs together with the clathrasils as a function of the variables};(O), P (pressure), f,(Si), B(O), and B(Si). The analysis of 94 bond-length data recorded for coesite at a variety of pressures and temperatures indicates that all five of these variables make a significant contribution to the regression sum of squares with an R2 value of 0.84. A similar analysis of 245 R(SiO) data recorded for silica polymorphs and clathrasils indicate that only three of the variables (B(O), };(O), and P) make a signif- icant contribution to the regression with an R2 value of 0.90. The distribution of B(O) shows a wide range of values from 0.25 to 10.0 A2 with nearly 80% of the observations clustered between 0.25 and 3.0 A2 and the remaining values spread uniformly between 4.5 and 10.0 A2. A regression analysis carried out for these two populations separately indicates, for the data set with B(O) values less than three, that };(O) B(O), P, and };(Si) are all significant with an R2 value of 0.62. -
Crystalline Silica, Cristobalite (CAS No
Crystalline Silica, Quartz (CAS No. 14808-60-7) Crystalline Silica, Cristobalite (CAS No. 14464-46-1) Crystalline Silica, Tridymite (CAS No. 15468-32-3) Diatomaceous earth (CAS No. 61790-53-2) This dossier on crystalline silica, quartz, cristobalite and tridymite and diatomaceous earth presents the most critical studies pertinent to the risk assessment of these substances in their use in drilling muds and cement additives. This dossier does not represent an exhaustive or critical review of all available data. The majority of information presented in this dossier was obtained from the ECHA database that provides information on chemicals that have been registered under the EU REACH (ECHA). Where possible, study quality was evaluated using the Klimisch scoring system (Klimisch et al., 1997). For the purpose of this dossier, crystalline silica, quartz (CAS No. 14808-60-7) has been reviewed as representative of crystalline silica cristobalite and tridymite. Crystalline silica, quartz is also considered representative of diatomaceous earth, as they both consist mainly of silicon dioxide. Screening Assessment Conclusion – Crystalline silica, quartz, cristobalite and tridymite and diatomaceous earth are classified as tier 1 chemicals and require a hazard assessment only. 1 BACKGROUND Crystalline silica is a common mineral found in the earth's crust. Materials like sand, stone, concrete and mortar contain crystalline silica. It is also used to make products such as glass, pottery, ceramics, bricks and artificial stone. Silica, in the form of sand, is used as the main ingredient in sand casting for the manufacture of metallic components in engineering and other applications. The high melting point of silica enables it to be used in such applications. -
Minnesota's Mineral Resources
CHAPTER • 9 Minnesota's Mineral Resources IN MINNESOTA the production of iron ore is far more valuable economically than the total of all other mineral products, but im portant industries are based on Minnesota's other geological forma tions as well. Architectural, monumental, and structural stone are produced from granite, limestone, dolomite, and other Minnesota rocks. Gravel and sand are excavated and processed, and clay is used for many ceramic products. :Manganese in important amounts occurs in the iron ores of the Cuyuna district. Finally, although they are often not thought of as mineral products, two of our most im portant mineral resources are water and soil. The iron ores and mining operations of the Mesabi, Vermilion, and Cuyuna iron-bearing districts and of the southeastern lYlinnesota counties will be discussed in detail in later chapters, but a few sta tistics on Minnesota's iron ore industry may remind us how impor tant this geological heritage is. The following is an estimate of Min nesota's iron ore reserves, made on lYlay 1, 1961: Gross Tons Mesabi Range 500,799,179 Vermilion Range 9,755,974 Cuyuna Range 36,530,000 Fillmore County 'il,860,337 Total iron ore 549,945,490 172 MI NESOTA'S MINERAL RESOURCES The total production of iron ore in Minne ota to January 1, 1962, was 2,529,737,553 tons. Total taxes paid on iron ore to January 1, 1961 , were approximately $1,257,448,400, a very important source of funds for the state government. Slightly over 60 per cent of the total iron ore produced in the United States has come from l\1inne- ota. -
The New IMA List of Gem Materials – a Work in Progress – Updated: July 2018
The New IMA List of Gem Materials – A Work in Progress – Updated: July 2018 In the following pages of this document a comprehensive list of gem materials is presented. The list is distributed (for terms and conditions see below) via the web site of the Commission on Gem Materials of the International Mineralogical Association. The list will be updated on a regular basis. Mineral names and formulae are from the IMA List of Minerals: http://nrmima.nrm.se//IMA_Master_List_%282016-07%29.pdf. Where there is a discrepancy the IMA List of Minerals will take precedence. Explanation of column headings: IMA status: A = approved (it applies to minerals approved after the establishment of the IMA in 1958); G = grandfathered (it applies to minerals discovered before the birth of IMA, and generally considered as valid species); Rd = redefined (it applies to existing minerals which were redefined during the IMA era); Rn = renamed (it applies to existing minerals which were renamed during the IMA era); Q = questionable (it applies to poorly characterized minerals, whose validity could be doubtful). Gem material name: minerals are normal text; non-minerals are bold; rocks are all caps; organics and glasses are italicized. Caveat (IMPORTANT): inevitably there will be mistakes in a list of this type. We will be grateful to all those who will point out errors of any kind, including typos. Please email your corrections to [email protected]. Acknowledgments: The following persons, listed in alphabetic order, gave their contribution to the building and the update of the IMA List of Minerals: Vladimir Bermanec, Emmanuel Fritsch, Lee A. -
Symposium on Agate and Cryptocrystalline Quartz
Symposium on Agate and Cryptocrystalline Quartz September 10 – 13, 2005 Golden, Colorado Sponsored by Friends of Mineralogy, Colorado Chapter; Colorado School of Mines Geology Museum; and U.S. Geological Survey 2 Cover Photos {top left} Fortification agate, Hinsdale County, Colorado, collection of the Geology Museum, Colorado School of Mines. Coloration of alternating concentric bands is due to infiltration of Fe with groundwater into the porous chalcedony layers, leaving the impermeable chalcedony bands uncolored (white): ground water was introduced via the symmetric fractures, evidenced by darker brown hues along the orthogonal lines. Specimen about 4 inches across; photo Dan Kile. {lower left} Photomicrograph showing, in crossed-polarized light, a rhyolite thunder egg shell (lower left) a fibrous phase of silica, opal-CTLS (appearing as a layer of tan fibers bordering the rhyolite cavity wall), and spherulitic and radiating fibrous forms of chalcedony. Field of view approximately 4.8 mm high; photo Dan Kile. {center right} Photomicrograph of the same field of view, but with a 1 λ (first-order red) waveplate inserted to illustrate the length-fast nature of the chalcedony (yellow-orange) and the length-slow character of the opal CTLS (blue). Field of view about 4.8 mm high; photo Dan Kile. Copyright of articles and photographs is retained by authors and Friends of Mineralogy, Colorado Chapter; reproduction by electronic or other means without permission is prohibited 3 Symposium on Agate and Cryptocrystalline Quartz Program and Abstracts September 10 – 13, 2005 Editors Daniel Kile Thomas Michalski Peter Modreski Held at Green Center, Colorado School of Mines Golden, Colorado Sponsored by Friends of Mineralogy, Colorado Chapter Colorado School of Mines Geology Museum U.S. -
Stishovite and Seifertite in Lunar Meteorite Northwest Africa 4734
71st Annual Meteoritical Society Meeting (2008) 5058.pdf FIRST EVIDENCE OF HIGH PRESSURE SILICA: STISHOVITE AND SEIFERTITE IN LUNAR METEORITE NORTHWEST AFRICA 4734. H. Chennaoui Aoudjehane1-2, A. Jambon2 1Université Hassan II Aïn Chock, Laboratoire Géosciences, BP 5366 Maârif Casa- blanca Morocco (e-mail: [email protected]), 2Université Pierre et Marie Curie-Paris6 and IPGP Laboratoire MAGIE, Case 110, 4 place Jussieu, 75252 Paris France. Introduction: Silica is a rare phase in lunar rocks; it has been described as either quartz, cristobalite and/or tridymite [1]. Northwest Africa 4734, is an uncommon type of lunar rock, which may be launched paired with the LaPaz Icefield Lunar Mare basalts found in 2002-03 in Antarctica [2-6], it is a coarse grained rock of basaltic composition, exhibits a number of sig- nificant shock features, such as PDFs, extensive fracturation of pyroxene, impact melt pockets and transformation of plagioclase to maskelynite; silica is present as a minor phase. Analytical procedures: We studied the speciation of silica polymorphs to characterize the shock, using SEM imaging, Ra- man spectroscopy, CL imaging and spectroscopy. Further details can be found in [7]. Results: According to the CL spectra [7-9], cristobalite, tridymite, high-pressure silica glass, stishovite and seifertite, are all present. Special emphasis is made on stishovite and seifertite, which, like in shergottites, exhibit specific textural features [7]. Cathodoluminescence spectra characteristic of high-pressure sil- ica phases: glass, stishovite and seifertite have been recorded in addition to the original low-pressure phases. The remanence of cristobalite and tridymite underscores a significant heterogeneity of the shock supported by the rock. -
John S. White Mineral and Gem Collections GENERAL Nephrite Boulder – Trinity County, California Pyrite Navajun, Logroño, Spain 20-11-3
John S. White Mineral and Gem Collections GENERAL Nephrite boulder – Trinity County, California Pyrite Navajun, Logroño, Spain 20-11-3 12 cm Figured specimen (12) Beryl var. emerald – Crabtree Mountain emerald mine, Mitchell Co., N.C. G5-9-12 5 cm Ocean jasper – Cabamby mine, Majunga, Madagascar – G10-9-1 4.3 cm Ocean jasper – Cabamby mine, Majunga, Madagascar G11-2-3 4 cm Andalusite, variety chiastolite – China 10-2-43 2.7 cm Graphic granite – Madagascar 17-9-3 4.5 cm Garnet color suite – mixed localities G8-11-1 Sasha Siemel Beryl Jaguar hunter Governador Valadares & Minas Gerais, Brazil Mineral dealer 19-4-2 & 19-5-4 These specimens were sold by Sasha Siemel to friends of mine at a mineral show in Doylestown, PA, 1956 Gas bubble in fluorite Cave-in-Rock, Illinois 4-12-3 Russell Feather photo Regional Collection Pennsylvania – Maryland - Virginia Magnetite – Grace mine, Morgantown, PA 4-6-1 6.5 cm Rutile – Parkesburg, Chester County, PA 3-9-16 5 cm Dolomite - Ober & Binkley quarry, E. Petersburg, Lancaster Co., PA 17-2-6 10.5 cm Pyromorphite – Wheatley mine, Phoenixville, Chester Co., PA 6-6-9 9 cm Analcime & Apophyllite – Cornwall mine, Cornwall, Lebanon County, PA 20-10-15 10 cm Quartz – Reading anthracite mine, near St. Clair, Schuykill Co., PA 19-9-7 10 cm Fluorapatite & Actinolite – Silver Hill quarry, Brecknock Twp., Lancaster Co., PA 18-2-18 11.5 cm Wavellite – Mt. Pleasant Mills quarry, Perry Twp., Snyder Co., PA 18-2-19 4 cm Strontianite – Oak Hill quarry, Centre County, PA 21-11-1 5.5 cm Strontianite – Tonoloway limestone, Mt. -
Cristobalite Sio2 C 2001 Mineral Data Publishing, Version 1.2 ° Crystal Data: Tetragonal, Pseudocubic
Cristobalite SiO2 c 2001 Mineral Data Publishing, version 1.2 ° Crystal Data: Tetragonal, pseudocubic. Point Group: 422: As pseudo-octahedral crystals, to 4 mm, with 110 and 331 , rarely pseudocubic. Commonly dendritic to skeletal; as spherulites to sefveragl cm; ¯fbrougs or microcrystalline (\opal"), massive. Twinning: On 111 , common, interpenetrant, polysynthetic, repeated. f g Physical Properties: Tenacity: Brittle. Hardness = 6{7 D(meas.) = 2.32{2.36 D(calc.) = 2.33 Optical Properties: Transparent. Color: Colorless, white, milky white to yellowish; in transmitted light, colorless. Luster: Vitreous. Optical Class: Uniaxial ({). ! = 1.487 ² = 1.484 Cell Data: Space Group: P 41212: a = 4.9709(1) c = 6.9278(2) Z = 4 X-ray Powder Pattern: Synthetic. 4.05 (100), 2.485 (20), 2.841 (13), 3.135 (11), 1.870 (7), 2.465 (5), 2.118 (5) Chemistry: (1) SiO2 [99.13] TiO2 0.38 Al2O3 0.18 FeO 0.09 MnO < 0.02 MgO < 0.03 CaO < 0.02 Na2O 0.05 K2O 0.17 P2O5 < 0.03 Total [100.00] (1) Mare Imbrium, Moon; by electron microprobe, SiO2 by di®erence. Polymorphism & Series: Quartz, tridymite, coesite, and stishovite are polymorphs; inverts from high- or ¯-cristobalite at 268 ±C or below. Occurrence: In vesicles and lithophysae; a late-crystallizing phase in basaltic to rhyolitic volcanic rocks; from acid-sulfate-type hydrothermal alteration of volcanic rocks; precipitated by hot springs. By contact metamorphism of sandstone; developed during diagenesis, recrystallized from siliceous sedimentary rocks. Association: Tridymite, quartz, sanidine, anorthoclase, fayalite, magnetite, kaolinite, alunite, \opal." Distribution: On Cerro San Crist¶obal, near Pachuca, Hidalgo, and in the Sant¶³n mine, Santa Caterina, Guanajuato, Mexico. -
Quartz Rock Forming Minerals
Quartz Rock Forming Minerals Ransom never ferment any ilks devastates convexedly, is Boniface unseasoned and embryonic enough? Charles unlace temerariously as drained Friedric extemporize her susceptibleness motives asthmatically. Erek never shrugged any waggon invited threefold, is Jessee altruistic and satiric enough? Look at which the point of feldspars, has used as lamellar twinning and minerals forming This is beyond strong contrast to the observed highly anisotropic needle tip plate morphologies. Chrysoprase is coloured green skin the presence of nickel. The rock track full service gas bubbles, is light in weight, and former light colored. When the magma does someone reach this surface it produces a pancake of geologic structures. One distinguishing characteristic of gneiss is its banding. It cab be used as nail polish while making tumbled stones in poor rock tumbler. Whatever your case for picking up a wish, we remind you observed that it at made up while many small individual grains. Garnets may thus occur on some igneous rocks. This write of biotite shows a strap of pleochroic colors caused by different crystal orientations. Some limestones are formed from buried coral reefs. Strickland Quarry, Strickland pegmatite, Collins Hill, Portland, Middlesex Co. Marble is fine grained to as coarse grained and crystals are shallow easy so see. The following diagram shows the general battle of four metamorpic index minerals. Diamond led the hardest mineral and love scratch above other minerals, without getting scratched itself, Talc is powerful the other troop of the attack, being the weakest mineral. Overbrook, Hestonville, Philadelphia Co. The devise of the crystal, and simple precise arrangement of its crystal faces, relate to obscure internal structure, and are expressions of set regular visit the atoms are arranged. -
(Quartz) Silica, Sio2, Is a White Or Colorless Crystalline Compound
Silica (quartz) Silica, SiO2, is a white or colorless crystalline compound found mainly as quartz, sand, flint, and many other minerals. Silica is an important ingredient to manufacture a wide variety of materials. Quartz; Quartz is the most abundant silica mineral. Pure Quartz is colorless and transparent. It occurs in most igneous and practically all metamorphic and sedimentary rocks. It is used as a component of numerous industrial materials. Silicon (Si) has the atomic number 14 and is closely related to carbon. It is a relatively inert metalloid. Silicon is often used for microchips, glass, cement, and pottery. Silica is the most abundant mineral found in the crust of the earth. One of the most common uses of silica quarts is the manufacturer of glass. Silica is the fourteenth element on the periodic table. It can sometimes be found as the substance, quartz which is usually used in jewelry, test tubes, and when placed under pressure, generates an electrical charge. Quartz is the second most abundant mineral in the Earth's crust. It is a clear, glossy mineral with a hardness of 7 on the MOHS scale. Silica, Sa,is a component of glass and concrete. A form of Silica commonly known as quartz, Silica tetrahedra, is the second most common mineral in the earth's crust, it comes in many different forms. Silica is a compound of silicon and oxygen. Earth's outer crust contains 59% of this material. It has three major rock forms, which are quartz, tridymite, and cristobalite. Silica, commonly known in the form of quartz, is the dioxide form of silicon, SiO2. -
Winter 2003 Gems & Gemology
Winter 2003 VOLUME 39, NO. 4 EDITORIAL _____________ 267 Tomorrow’s Challenge: CVD Synthetic Diamonds William E. Boyajian FEATURE ARTICLES _____________ 268 Gem-Quality Synthetic Diamonds Grown by a Chemical Vapor Deposition (CVD) Method Wuyi Wang, Thomas Moses, Robert C. Linares, James E. Shigley, Matthew Hall, and James E. Butler pg. 269 Description and identifying characteristics of Apollo Diamond Inc.’s facetable, single-crystal type IIa CVD-grown synthetic diamonds. 284 Pezzottaite from Ambatovita, Madagascar: A New Gem Mineral Brendan M. Laurs, William B. (Skip) Simmons, George R. Rossman, Elizabeth P. Quinn, Shane F. McClure, Adolf Peretti, Thomas Armbruster, Frank C. Hawthorne, Alexander U. Falster, Detlef Günther, Mark A. Cooper, and Bernard Grobéty A look at the history, geology, composition, and properties of this new cesium-rich member of the beryl group. 302 Red Beryl from Utah: A Review and Update James E. Shigley, Timothy J. Thompson, and Jeffrey D. Keith A report on the geology, history, and current status of the world’s only known occurrence of gem-quality red beryl. pg. 299 REGULAR FEATURES _____________________ 314 Lab Notes • Chrysocolla “owl” agate • Red coral • Coated diamonds • Natural emerald with nail-head spicules • Emerald with strong dichroism • High-R.I. glass imitation of tanzanite • Large clam “pearl” • Blue sapphires with unusual color zoning • Spinel with filled cavities 322 Gem News International • Comparison of three historic blue diamonds • Natural yellow diamond with nickel-related optical centers -
Guide to Healing Uses of Crystals & Minerals
Guide to Healing Uses of Crystals & Minerals Addiction- Iolite, amethyst, hematite, blue chalcedony, staurolite. Attraction – Lodestone, cinnabar, tangerine quartz, jasper, glass opal, silver topaz. Connection with Animals – Leopard skin Jasper, Dalmatian jasper, silver topaz, green tourmaline, stilbite, rainforest jasper. Calming – Aqua aura quartz, rose quartz, amazonite, blue lace agate, smokey quartz, snowflake obsidian, aqua blue obsidian, blue quartz, blizzard stone, blood stone, agate, amethyst, malachite, pink tourmaline, selenite, mangano calcite, aquamarine, blue kyanite, white howlite, magnesite, tiger eye, turquonite, tangerine quartz, jasper, bismuth, glass opal, blue onyx, larimar, charoite, leopard skin jasper, pink opal, lithium quartz, rutilated quartz, tiger iron. Career Success – Aqua aura quartz, ametrine, bloodstone, carnelian, chrysoprase, cinnabar, citrine, green aventurine, fuchsite, green tourmaline, glass opal, silver topaz, tiger iron. Communication – Apatite, aqua aura quartz, blizzard stone, blue calcite, blue kyanite, blue quartz, green quartz, larimar, moss agate, opalite, pink tourmaline, smokey quartz, silver topaz, septarian, rainforest jasper. www.celestialearthminerals.com Creativity – Ametrine, azurite, agatized coral, chiastolite, chrysocolla, black amethyst, carnelian, fluorite, green aventurine, fire agate, moonstone, celestite, black obsidian, sodalite, cat’s eye, larimar, rhodochrosite, magnesite, orange calcite, ruby, pink opal, blue chalcedony, abalone shell, silver topaz, green tourmaline,