Idrialite C22H14

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Idrialite C22H14 Crystal Data: Orthorhombic. Point Group: n.d. Small irregular square or six-sided crystals; tabular crystals are precipitated from a chloroform extraction of cinnabar ore. Physical Properties: Cleavage: {001}, perfect; {100}, poor. Fracture: Conchoidal. Hardness = 1-1.5 D(meas.) = 1.22-1.236 D(calc.) = 1.286 M.P. 319 °C; fluoresces pale blue or bright green under UV. Optical Properties: Semitransparent. Color: Pale brown to pale greenish yellow. Luster: Vitreous to adamantine. Optical Class: Biaxial (+). α = 1.557 β = 1.734 γ = 2.07 2V(meas.) = 84° Pleochroism: X = pale yellow; Y = Z = yellow. Orientation: X = b; Y = a, Z = c. Dispersion: r > v, weak. Cell Data: Space Group: n.d. a = 8.07 b = 6.42 c = 27.75 Z = 4 X-ray Powder Pattern: Idrija mine, Slovenia. 4.94 (100), 3.40 (80), 4.04 (60), 2.48 (30), 7.08 (20), 4.43 (20), 2.06 (20) Chemistry: (1) Identification depends on correspondence of X-ray powder patterns and other data with that of synthetic material (dimethylbenzphenanthrene). Occurrence: Probably formed by pyrolysis of organic material near hot springs or by hydrothermal fluids. Association: Cinnabar, pyrite, gypsum, quartz, “clay” (Idrija mine, Slovenia); metacinnabar, realgar, “opal” (Skaggs Springs, California, USA). Distribution: From the Idrija (Idria) mercury mine, 38 km west of Ljubljana, northwestern Slovenia. In the USA, in California, at Skaggs Springs, Sonoma Co.; from the Great Western, Mirabel, Helen, and Research mines, Lake Co.; in the Knoxville mine, Napa Co. Name: For the Idrija (Idria) mine, Slovenia, from which the first specimens were collected. Type Material: n.d. References: (1) Dana, E.S. (1892) Dana’s system of mineralogy, (6th edition), 1013. (2) Strunz, H. and B. Contag (1965) Evenkit, Flagstaffit, Idrialin und Reficit. Neues Jahrb. Mineral., Monatsh., 19- 25 (in German). (3) Blumer, M. (1975) Curtisite, idrialite, and pendletonite, polycyclic aromatic hydrocarbon minerals: their composition and origin. Chem. Geol., 16, 245-256. (4) Echigo, T., M. Kimata, T. Maruoka, M. Shimizu, and N. Nishida (2009) The crystal structure, origin, and formation of idrialite (C22H14): Inferences from the microbeam and bulk analyses. Amer. Mineral., 94, 1325-1332. Mineralogical Society of America Handbook of Mineralogy Revised 6/10/2021 .

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Karpatite C24H12 C 2001-2005 Mineral Data Publishing, Version 1
Karpatite C24H12 c 2001-2005 Mineral Data Publishing, version 1 Crystal Data: Monoclinic. Point Group: 2/m. Crystals are acicular, thin tabular parallel to [001], showing {001}, {100}, {201}, many other forms, to 1 cm; typically in bladed groups and ﬁbrous radiating aggregates. Physical Properties: Cleavage: On {001}, {100}, {201}, perfect. Fracture: Splintery. Tenacity: Flexible, nearly plastic. Hardness = ∼1 D(meas.) = 1.35–1.40 D(calc.) = 1.29–1.42 Flammable; ﬂuoresces sky-blue under LW and SW UV. Optical Properties: Subtranslucent. Color: Yellow, yellowish brown on exposure. Luster: Vitreous. Optical Class: Biaxial (–) or (+). Orientation: X = b; Z ∧ c =21◦. Dispersion: rv, extreme. α = 1.780(2) β = 1.977–1.982 γ = 2.05–2.15 2V(meas.) = 96◦–115◦ Cell Data: Space Group: P 21/c or P 2/c (synthetic). a = 10.035 b = 4.695 c = 16.014 β = 112◦ Z=2 X-ray Powder Pattern: Olenevo, Ukraine. 9.40 (10), 3.52 (9), 7.52 (8), 3.97 (7), 3.05 (6), 7.25 (5), 3.43 (4) Chemistry: (1) (2) C 96.04 95.97 H 4.04 4.03 O Total 100.08 100.00 (1) Olenevo, Ukraine. (2) C24H12 (coronene). Occurrence: In cavities at the contact of diorite porphyry with argillites (Olenevo, Ukraine); a low-temperature hydrothermal mineral (California, USA). Association: Idrialite, amorphous organic material, calcite, barite, quartz, cinnabar, metacinnabar (Olenevo, Ukraine); cinnabar, quartz (California, USA). Distribution: From near Olenevo, Transcarpathian region, western Ukraine. At Tamvotney, Kamchatka Peninsula, Russia. From the Picacho mercury mine, south of New Idria, San Benito Co., California, USA.
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