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(Ar) Fact Sheet

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(Ar) Fact Sheet . Attachment 5: OHMTADS File 2; Entry 1; Accession No. 8300235 (CAS) CAS Registry Number: QSOOOOO1-O5Q8-O9 (MAT) Material Name: $$$ COAL TAR CREOSOTE $$$ (SYN) Synonyms: CREOSOTE (SEE ALSO WOOD CREOSOTE, ACCESSION NUMBER 8400350); CREOSOTE FROM COAL TAR; CREOSOTE OIL (CHEMICAL ABSTRACTS SERVICE, " HOWEVER, HAS GIVEN THIS SUBSTANCE A SEPARATE REGISTRY NUMBER—61789-28- 4); DEAD OIL; LIQUID PITCH OIL; TAR OIL; BRICK OIL; COAL TAR CREOSOTE OIL; COAL TAR OIL; CREOSOTE, COAL TAR; CREOSOTE, FROM COAL TAR; CREOSOTUM; RTECS NO. GF8615000. (TRN) Tradename (Company): PRESERV-O-SOTE (CREOSOTE OIL) (CROWLEY TAR PRODUCTS COMPANY, INC.). (CHMCY* 0001) .(FML) Chemical Formula: (UNSPECIFIED FORMULA) (SPC) Species in Mixture: COAL TAR CREOSOTE IS A DISTILLATE OF COAL TAR PRODUCED BY HIGH-TEMPERATURE CARBONIZATION OF BITUMINOUS COAL. (MEIEDD 0001) PROPERTIES VARY DEPENDING ON THE SOURCE OF THE TAR. AN IN-DEPTH REVIEW OF THE CHARACTERIZATION OF WOOD-PRESERVING COAL-TAR CREOSOTE IS GIVEN IN (XAFLA7 0001) . COAL TAR CREOSOTE COMPRISES LIQUID AND SOLID AROMATIC HYDROCARBONS, UP TO 3% TAR ACIDS, AND TAR BASES. (MEIEDD 0001) MAJOR COMPONENTS OF CREOSOTE ARE POLYCYCLIC AROMATIC HYDROCARBONS, MOST WITH THREE OR MORE RINGS: NAPHTHALENE, 3.0%; 2-METHYLNAPHTHALENE, 1.2%; 1- METHYLNAPHTHALENE, 0.9%; BIPHENYL, 0.8%; DIMETHYLNAPHTHALENES, 2.0%; ACENAPHTHENE, 9.0%; DIBENZOFURAN, 5.0%; FLUORENE, 10.0%; METHYLFLUORENES, 3.0%; PHENANTHRENE, 21.0%; ANTHRACENE, 2.0%; CARBAZOLE, 2.0%; METHYLPHENANTHRENES, 3.0%; METHYLANTHRACENES, 4.0%; FLUORANTHENE, 10.0%; PYRENE, 8.5%; BENZOFLUORENES, 2.0%; CHRYSENE, 3.0%. TIMBER-TREATING COAL- TAR CREOSOTE IS PREPARED TO CONFORM TO THE DISTILLATION RANGE OF THE AMERICAN WOOD PRESERVERS SPECIFICATION Pl-78. (THIS STANDARD SPECIFIES THAT NO MORE THAN 2.0% OF NEW OR USED CREOSOTE SHOULD DISTILL BELOW 210 DEGREES CELSIUS, THAT NO MORE THAN 12.0% SHOULD DISTILL BELOW 235 DEGREES CELSIUS, THAT 10.0 TO 35.0 PERCENT SHOULD DISTILL BELOW 270 DEGREES CELSIUS, THAT 40.0 TO 65.0 PERCENT SHOULD DISTILL BELOW 315 DEGREES CELSIUS, AND THAT 60.0 TO 77.0 PERCENT SHOULD DISTILL BELOW 355 DEGREES CELSIUS. ) IN ADDITION TO THE HYDROCARBONS LISTED ABOVE, CREOSOTE CONTAINS THE HETEROCYCLIC COMPOUNDS QUINOLINE, CARBAZOLE, AND DIBENZOFURAN. THE NITROGENOUS COMPOUNDS ARE THE "TAR BASES". COMPOUNDS BOILING FROM 200 TO 270 DEGREES CELSIUS ARE PRIMARILY NAPHTHALENES. THOSE BOILING BETWEEN 270 AND 355 DEGREES CELSIUS ARE A MIXTURE OF ACENAPHTHENE, FLUORENE, PHENANTHRENE, ANTHRACENE, AND OTHER HYDROCARBONS. THE FRACTION BOILING ABOVE 355 DEGREES CELSIUS CONTAINS PYRENE, FLUORANTHENE, AND CHRYSENE. (15SWA8 0002) (IDCDD* 0001) "CREOSOTES" OR "CREOSOTE OILS" ARE BLENDS OF A NUMBER OF RESIDUAL OILS FROM TAR DISTILLATION, SUCH AS NAPHTHALENE DRAIN OIL, WASH OIL, DRAINED ANTHRACENE OIL, AND HEAVY OIL. TIMBER PRESERVATION CREOSOTE IS A BLEND OF PRIMARILY WASH OIL, DRAINED ANTHRACENE OIL, AND HEAVY OIL. IF THE CREOSOTE IS TO BE USED FOR PARTIAL COMBUSTION TO CARBON BLACK, IT IS CHIEFLY A MIXTURE OF ANTHRACENE OIL AND HEAVY OIL. WINTER WASH OILS FOR DORMANT FRUIT TREES ARE CREOSOTES COMPRISING A MIXTURE OF DRAINED NAPHTHALENE OIL, WASH OIL, AND ANTHRACENE OIL CONTAINING RESIDUAL TAR ACIDS. CREOSOTE OILS CONTAIN MAINLY NAPHTHALENE, PHENOL, AND CRESOLS. PHENOLIC COMPOUNDS, INCLUDING NAPKTHOLS AND XYLENOLS, ARE THE "TAR ACIDS". (15SWA8 0002) (USS) Common Uses: COAL TAR CREOSOTE IS USED FOR IMPREGNATING WOOD (SUCH AS RAILROAD TIES, TELEPHONE POLES, AND MARINE PILINGS) TO PROTECT FROM ROT AND WORMS. (MEIEDD 0001) (CCDCDS 0002) OTHER USES INCLUDE WATERPROOFING AGENT, CONSTITUENT IN FUEL OIL, LUBRICANT FOR DIE MOLDS, PITCH FOR ROOFING, MANUFACTURE OF CHEMICALS AND LAMPBLACK. (85FFA3 0001) (PRD) Production Sites: U.S. STEEL CORPORATION, CLAIRTON WORKS, 400 STATE ST., P.O. BOX 270, CLAIRTON, ALLEGHENY COUNTY, PA, 15025, MID NO. 3293, EPA REGION 03; ALLIED CHEMICAL CORPORATION, P.O. BOX 1087R, MORRISTOWN, OOG003 NJ; CROWLEY TAR PRODUCTS COMPANY (CREOSOTE OIL), 261 MADISON AVE., NEW YORK, NY, NY 10016, (212)682-1200. (CHMCY* 0001) (BIN) Binary Reactants: COAL TAR CREOSOTE REACTS VIOLENTLY WITH CHLOROSULFONIC ACID. (DPMADX 0001) (LDL) Detection Limit (Lab.; Techniques, Ref) (ppm): CHEMICAL AND PHYSICAL METHODS FOR CHARACTERIZING WOOD-PRESERVING COAL TAR CREOSOTE ARE DESCRIBED IN (XAFLA7 195,1,174/NES). GAS CHROMATOGRAPHIC METHODS AND SPECTROPHOTOMETRIC METHODS REPORTED BEFORE 1974 ARE REVIEWED. A GC/MS METHOD FOR ANALYSIS OF CREOSOTE OIL HAS BEEN DESCRIBED IN A RUSSIAN PAPER BY DOLANSKY AND KOMORA IN SB. VYS. SK. CHEM.-TECHNOL. PRAZE, TECHNOL. PALIV, D30, 329-334 (1974). (CKABA8 0015) A VAPOR-PHASE ULTRAVIOLET ABSORPTION SPECTROSCOPIC METHOD AFTER EXTRACTION WITH HEXANE OR CHLOROFORM IS SAID TO BE SUITABLE FOR CREOSOTE IN WATER, BUT EXAMPLES ARE NOT GIVEN FOR THIS SUBSTANCE. (ANALAO 0006) ZITKO (1975) DEVELOPED A RAPID METHOD FOR SCREENING AQUATIC FAUNA FOR POLYCYCLIC AROMATIC HYDROCARBONS (PAH) TO DETECT CONTAMINATION BY CREOSOTE OIL. THE , CONTAMINANTS WERE SEPARATED FROM LIPIDS OF AQUATIC SPECIES BY COLUMN CHROMATOGRAPHY ON ALUMINA. THEN THEY WERE CHARACTERIZED AND QUANTITATED BY FLUOROMETRY WITH PYRENE AS A FLUORESCENCE STANDARD. THE DETECTION LIMIT FOR CREOSOTE WAS 100 .HU.G/G LIPID. (BECTA6 0038) AIR—BENZENE- SOLUBLE COMPOUNDS IN AIR. NIOSH METHOD NO. P&CAM 217. MATRIX: AIR PARTICIPATES TRAPPED ON SILVER MEMBRANE AND GLASS FIBER FILTERS. ULTRASONIC EXTRACTION WITH BENZENE, EVAPORATION OF ALIQUOT TO DRYNESS. WEIGH RESIDUE. DETECTION LIMIT: 20 .MU.G BENZENE-SOLUBLE MATERIAL IN A FILTER SAMPLE. WATER—A CREOSOTE-DERIVED PAH COMPLEX WAS DETERMINED BY BLACK (1982) BY HPLC WITH DETECTION BY ABSORBENCE AND FLUORESCENCE SPECTROPHOTOMETERS CONNECTED IN SERIES. (AECTCV 0013) THE AMERICAN SOCIETY FOR TESTING AND MATERIALS PROVIDES METHODS FOR ANALYZING AND TESTING CREOSOTE FOR WATER (METHOD D 370), HATTER INSOLUBLE IN BENZENE (D 367), SPECIFIC GRAVITY (D 368), DISTILLATION (D 246), SPECIFIC GRAVITY OF FRACTIONS (D 369), FLOAT TEST OR RESIDUE (D 139), AND COKE RESIDUE (D 168). (STDS** 0001) (STD) Standard Codes: SUPERFUND DESIGNATED (HAZARDOUS SUBSTANCES) LIST. HAZARDOUS WASTE NO. U051. HAZARDOUS WASTE NO. FOR THE WASTEWATER TREATMENT SLUDGES IN THE PRODUCTION OF CREOSOTE—K035. HAZARDOUS WASTE NO. FOR THE BOTTOM SEDIMENT SLUDGE FROM THE TREATMENT OF WASTEWATERS FROM WOOD PRESERVING PROCESSES THAT USE CREOSOTE AND/OR PENTACHLOROPHENOL— K001. COAL TAR CREOSOTE—STCC NO. 4915363. NFPA HAZARD CLASSIFICATION (CREOSOTE OIL) 2,2,0. NAS HAZARD RATING FOR BULK WATER TRANSPORTATION- CATEGORY (RATING): FIRE (1); HEALTH: VAPOR IRRITANT, (2); LIQUID OR SOLID IRRITANT, (3); POISONS, (2); WATER POLLUTION: HUMAN TOXICITY, (2); AQUATIC TOXICITY, (3); AESTHETIC EFFECT (4); REACTIVITY: OTHER CHEMICALS, (1); WATER, (0); SELF-REACTION, (0). U.S. COAST GUARD HAZARD ASSESSMENT CODE A-T-U-X-Y. (CGHCD* 0001) DOT—COAL TAR CREOSOTE OR CREOSOTE OIL— COMBUSTIBLE LIQUID. NA1993. NO LABEL REQUIREMENT. PACKAGING EXCEPTION 173.118A. NO SPECIFIC REQUIREMENT. NO PACKAGE LIMIT ON CARGO OR PASSENGER AIRCRAFT OR RAIL CAR. STOW ON OR UNDER DECK ON CARGO AND PASSENGER VESSELS. (FEREAC 0017) IMCO—NOT LISTED. SEE POISONOUS LIQUIDS, N.O.S. UNDER ICAO BELOW, THIS FIELD. IATA— LIQUID CREOSOTE. CLASS ORA.A. PACKING NOTE 692 FOR PASSENGER OR CARGO AIRCRAFT. NO LIMIT ON QUANTITY. (RARAD5 0002) ICAO—CREOSOTE IS SHIPPED ACCORDING TO SPECIFICATIONS FOR POISONOUS LIQUIDS NOT OTHERWISE SPECIFIED. UN NO. 2810. CLASS AND DIVISION 6.1. LABEL: "POISON" (GROUP I AND II) OR "KEEP AWAY FROM FOOD" (GROUP III). (ICAO** 0001) (FLM) Flammability: COAL TAR CREOSOTE WILL BURN. MAY BE IGNITED BY HEAT, SPARKS, AND FLAMES. FLAMMABLE VAPORS MAY SPREAD AWAY FROM SPILL. (85EWAF 0001) MODERATELY FLAMMABLE WHEN EXPOSED TO HEAT OR FLAME. (DPMADX 0001) (TCP) Toxic Combustion Products: NO DATA AVAILABLE ON COMBUSTION PRODUCTS. FIRE MAY PRODUCE IRRITATING OR POISONOUS GAS. (85EWAF 0001) (EXT) Extinguishing Method: COAL TAR CREOSOTE—SMALL FIRES: DRY CHEMICAL, 000004 CO2, WATER SPRAY OR ALCOHOL FOAM. LARGE FIRES: WATER SPRAY, FOG, OR ALCOHOL FOAM. MOVE CONTAINER FROM FIRE AREA IF YOU CAN DO IT WITHOUT ' RISK. STAY AWAY FROM ENDS OF TANKS. COOL CONTAINERS THAT ARE EXPOSED TO W FLAMES WITH WATER FROM THE SIDE UNTIL WELL AFTER FIRE IS OUT. FOR MASSIVE FIRE IN CARGO AREA, USE UNMANNED HOSE HOLDER OR MONITOR NOZZLES. WITHDRAW IMMEDIATELY IN CASE OF RISING SOUND FROM VENTING SAFETY DEVICE OR _ DISCOLORATION OF TANK. (85EWAF 0001) THE U.S. COAST GUARD (CGHCD* 0001) AND THE BUREAU OF EXPLOSIVES (BUXEH* 0001) STATE THAT SOLID STREAMS OF WATER MAY BE INEFFECTIVE. v (FLP) Flash Point (C.): 74 (DEGREES CELSIUS; COAL TAR CREOSOTE, CLOSED CUP *-' (CCDCDS 0002)) (AIP) Autoignition Point (C.): 336 (DEGREES CELSIUS; COAL TAR CREOSOTE l (CGHCD* 0001)) MEXP) Explosiveness: CONTAINER OF COAL TAR CREOSOTE MAY EXPLODE IN HEAT OF FIRE; VAPOR EXPLOSION HAZARD INDOORS, OUTDOORS, OR IN SEWERS. RUNOFF TO SEWER MAY CREATE FIRE OR EXPLOSION HAZARD. (85EWAF 0001) W(BLP) Boiling Point (C.): >180; 200 TO 400 (COAL TAR CREOSOTE); 200 TO 250; 200 TO 270 (CREOSOTE OILS) . (BOC) Boiling Characteristics: THE LOWER VALUE OF >180 DEGREES CELSIUS AND THE RANGE 200 TO 400 DEGREES CELSIUS ARE FOR COAL TAR CREOSOTE. (CGHCD* w 0001) CREOSOTE OILS (ALSO CAT.T.ED MIDDLE OILS) ARE GENERALLY THE FRACTION BOILING FROM APPROXIMATELY 200 TO 250 OR 270 DEGREES CELSIUS. (15SWA8 0002) w(SOL) Solubility (ppm @ 25C): 5 (SLC) Solubility Characteristics: COAL TAR CREOSOTE—5 PPM, INSOLUBLE (RCRAC* 80/EPA); VERY SLIGHTLY SOLUBLE (IDCDD* 0001); PRACTICALLY i, INSOLUBLE. (MEIEDD 0001) (SPG) Specific Gravity: 1.05 TO 1.09; 1.076 (COAL TAR CREOSOTE: 1.05 TO 1.09 AT 15 DEGREES CELSIUS (LIQUID); >=1.076 COAL TAR CREOSOTE AT 15 DEGREES CELSIUS) (CGHCD* 0001); (MEIEDD 0001) ^-(PER) Persistency: SLOWLY BIODEGRADABLE. (IDCDD* 0001) EPA ESTIMATED THAT FOR PONDS, LAKES, AND RESERVOIRS WITH AVERAGE RETENTION TIMES OF 100 OR i 365 DAYS, 98 TO 99% OF THE CREOSOTE EMITTED TO THE WATER BODY WILL BE w DEGRADED OR ELIMINATED. APPROXIMATELY 9.1% OF THE CREOSOTE EMITTED TO A RIVER WILL BE DISSOLVED AND TRANSPORTED 50 TO 250 MILES DOWNSTREAM WITH 5 DAYS* TRAVEL TIME. ABOUT 91% OF THE TOTAL AMOUNT EMITTED WILL BE DEGRADED OR OTHERWISE ELIMINATED.
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