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Polycyclic Aromatic Hydrocarbons (Pahs) in Fired Clay Bricks Incorporating Cigarette Butts

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Polycyclic Aromatic Hydrocarbons (Pahs) in Fired Clay Bricks Incorporating Cigarette Butts materials Article Polycyclic Aromatic Hydrocarbons (PAHs) in Fired Clay Bricks Incorporating Cigarette Butts Halenur Kurmus 1,*, Abbas Mohajerani 1 and Stephen Grist 2 1 School of Engineering, RMIT University, Melbourne, VIC 3000, Australia; [email protected] 2 School of Applied Sciences, RMIT University, Melbourne, VIC 3000, Australia; [email protected] * Correspondence: [email protected] Abstract: Cigarette butts (CBs) are the most common littered waste in the world and may contain polycyclic aromatic hydrocarbons (PAHs) from the incomplete combustion of tobacco during burning. Therefore, to investigate the potential PAH residual remaining in fired clay bricks (FCBs) incorpo- rating CBs and examine the environmental impact of utilizing toxic waste in the production of FCBs, a comprehensive PAH extraction analysis was conducted. The Soxhlet extraction method was utilized to conduct a qualitative and quantitative analysis of sixteen toxic Environmental Protection Authority (EPA) Polycyclic Aromatic Hydrocarbons (PAHs) in FCB samples incorporating CBs using gas chromatography–mass spectrometry (GC–MS). The concentrations of the mean total (S)PAHs for FCBs incorporating 0%, 0.5%, 1%, 1.5%, and 2% CBs by weight (wt) were found to be 0.183, 0.180, 0.242, 0.234, and 0.463 µg/mL. As expected, PAHs with higher water solubility and volatil- ity, naphthalene, fluorene, anthracene, pyrene, fluoranthene, and chrysene were found at higher concentrations compared to lipophilic PAHs. The SPAH concentrations for all five FCB–CB mixes were well below the EPA Victoria solid waste hazard categorization threshold for industrial waste. Moreover, the samples were studied for their carbon content using the carbon, hydrogen, nitrogen, and sulfur (CHNS) analyzer and thermogravimetric analysis (TGA). The results confirm an almost Citation: Kurmus, H.; Mohajerani, 100% combustion process of CBs during the firing process. A content less than 0.3% suggests that all A.; Grist, S. Polycyclic Aromatic carbon within the FCB–CB mixture relatively disappeared during the firing process up to 1050 ◦C. Hydrocarbons (PAHs) in Fired Clay However, further research regarding the emission of volatile organic compounds (VOCs) during the Bricks Incorporating Cigarette Butts. Materials 2021, 14, 2032. https:// production of FCBs incorporating CBs should be conducted. doi.org/10.3390/ma14082032 Keywords: polycyclic aromatic hydrocarbons (PAHs); cigarette butts; recycling; fired clay bricks; Academic Editor: Antonio Caggiano environmental sustainability Received: 22 March 2021 Accepted: 15 April 2021 Published: 18 April 2021 1. Introduction Globally, over 5.4 trillion cigarettes are produced, and approximately one-third of Publisher’s Note: MDPI stays neutral cigarette butts (CBs) are littered into the nearby environment [1–3]. In Australia, CBs are with regard to jurisdictional claims in the most common littered waste under the miscellaneous category, representing 91.5% [3,4]. published maps and institutional affil- When littered, CBs persist in the environment for up to 10 years due to the composition iations. of the filter. The filter of a CB is made from cellulose acetate, and, although cellulose is biodegradable, the acetate content prevents the cellulose from biological decomposition in an open environment [3,5]. A study conducted in a controlled laboratory condition found that it took up to 720 days for a CB to lose 30% to 35% of its total weight while Copyright: © 2021 by the authors. decomposing [6]. Licensee MDPI, Basel, Switzerland. In cigarette smoke, it is possible to classify more than 4000 chemical components This article is an open access article generated during burning or distilled from the tobacco [3]. Essentially, the role of the distributed under the terms and filter of the CB is to trap and absorb the particulate smoke components, consisting of more conditions of the Creative Commons than 3500 non-volatile and semi-volatile chemical compounds. The main toxic compounds Attribution (CC BY) license (https:// include polycyclic aromatic hydrocarbons (PAHs), nicotine, metals, catechols, carbonyls, creativecommons.org/licenses/by/ alcohols, nicotine alkaloids, and compounds specific to Solanaceae [7,8]. Therefore, when 4.0/). Materials 2021, 14, 2032. https://doi.org/10.3390/ma14082032 https://www.mdpi.com/journal/materials Materials 2021, 14, 2032 2 of 12 CBs are improperly disposed of, they pose a toxicant risk to the global environment and urban and aquatic life, whereby harmful chemicals are leached [9,10]. The leachate of the toxic compounds may eventually contaminate surface water and groundwater [11,12], and ultimately bioaccumulate in the human food chain and wildlife [13,14]. Based on several years of research, Mohajerani et al. [15] proposed that the CB conun- drum can potentially be eliminated by incorporating 1% CBs into 2.5% of the world’s total FCB production. Various mechanical and physical tests were conducted to determine the practicality and competency of incorporating toxic waste in the production of FCBs, and the results were promising [16–20]. The tests included compressive strength, density, water absorption, initial rate of absorption, efflorescence, shrinkage, energy savings, thermal conductivity, and gas emissions. The research continued with the implementation phase of recycling CBs in FCBs, whereby several sterilization methods and odor elimination techniques were reviewed, CB collection systems were explored, and an implementation procedure was proposed on an industrial scale [21]. However, an environmental issue that may evolve through the addition of CBs in the construction of FCBs is the potential leachate of heavy metals and toxic chemicals during the use and disposal of the material. In 2020, Kurmus and Mohajerani [22] conducted a comprehensive leachate study of heavy metals from FCBs incorporating various percentages of CBs. The modified FCBs were found to be below the regulatory threshold limits and categorized as non-hazardous waste when compared to the EPA Victoria industrial waste guidelines. Regarding PAHs in FCBs modified with CBs, no studies have been conducted. PAHs in CBs are dangerous compounds produced through the incomplete combustion and pyrolysis of tobacco. They consist of two or more aromatic rings and are hydrophobic in nature with very low water solubility. PAHs are a concern, considering that they bioac- cumulate and linger in the environment, with carcinogenic, teratogenic, and mutagenic properties [23,24]. In 2008, 28 PAHs were identified as priority pollutants by the National Waste Minimization Program, a project which was funded by the US Environmental Protec- tion Agency [25]. In a study conducted by Dobaradaran et al. [12], it was found that PAHs, particularly fluorine, acenaphthylene, naphthalene, and acenaphthene, are released into the environment from freshly littered CBs. In addition to CBs, PAH contamination in soil is a common issue, because soil is less receptive to chemical and biological degradation and the PAHs tend to absorb tightly into the organic matter present in the soil. Moreover, the recalcitrance of PAHs towards treatment increases with prolonged aging time, promoting the sequestration of PAH molecules into micropores [26]. Thus, the aim of this study was to conduct a comprehensive evaluation of PAHs in FCBs incorporated with CBs to examine the potential environmental impact of utilizing this toxic waste in the production of FCBs. In this study, a direct Soxhlet extraction method was employed using dichloromethane as the solvent. The aim of the extraction process is to effectively remove the analyte (PAHs) from its matrix, with minimal solvent usage [27]. The extract was analyzed for sixteen US EPA priority PAH compounds using gas chromatography–mass spectrometry (GC–MS) in accordance with the US EPA Method 3540C [28]. The PAH concentrations were then compared to the Environmental Protection Authority (EPA) Victorian solid industrial waste hazard categorization and management thresholds [29] to assess the suitability of FCBs incorporating CBs. Furthermore, the FCB samples incorporating CBs were studied for their carbon content using the carbon, hydrogen, nitrogen, and sulfur (CHNS) analyzer and thermogravimetric analysis (TGA). 2. Materials and Methods 2.1. Materials and Brick Manufacturing Methodology Soil and CBs are the raw materials that were used in this study. A sieve analysis was conducted to classify the soil, and, according to unified soil classification, the soil was categorized as sandy silty clay (MC) [30]. The soil material was obtained from PGH Bricks and Pavers (Melbourne, Australia) and the CBs, of distinct brands and sizes, were provided by Butt Out Australia Pty Ltd (Melbourne, Australia). The raw materials, CBs and soil, Materials 2021, 14, x FOR PEER REVIEW 3 of 13 categorized as sandy silty clay (MC) [30]. The soil material was obtained from PGH Bricks and Pavers (Melbourne, Australia) and the CBs, of distinct brands and sizes, were pro- vided by Butt Out Australia Pty Ltd (Melbourne, Australia). The raw materials, CBs and soil, were initially oven-dried at 105 °C for 24 h. Various percentages (0%, 0.5%, 1%, 1.5%, and 2% CBs by weight (wt)) of CBs were then added and uniformly mixed with the soil for 25 min in a mechanical mixer at a moisture content of 15.5%. The fast-mixing process caused the CBs to shred and homogenously integrate into the soil mixture. Prior to being placed in the oven at 105 °C for 24 h, the samples were compacted
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