Ozone: Good up High, Bad Nearby

Total Page:16

File Type:pdf, Size:1020Kb

Ozone: Good up High, Bad Nearby actions you can take High-Altitude “Good” Ozone Ground-Level “Bad” Ozone •Protect yourself against sunburn. When the UV Index is •Check the air quality forecast in your area. At times when the Air “high” or “very high”: Limit outdoor activities between 10 Quality Index (AQI) is forecast to be unhealthy, limit physical exertion am and 4 pm, when the sun is most intense. Twenty minutes outdoors. In many places, ozone peaks in mid-afternoon to early before going outside, liberally apply a broad-spectrum evening. Change the time of day of strenuous outdoor activity to avoid sunscreen with a Sun Protection Factor (SPF) of at least 15. these hours, or reduce the intensity of the activity. For AQI forecasts, Reapply every two hours or after swimming or sweating. For check your local media reports or visit: www.epa.gov/airnow UV Index forecasts, check local media reports or visit: www.epa.gov/sunwise/uvindex.html •Help your local electric utilities reduce ozone air pollution by conserving energy at home and the office. Consider setting your •Use approved refrigerants in air conditioning and thermostat a little higher in the summer. Participate in your local refrigeration equipment. Make sure technicians that work on utilities’ load-sharing and energy conservation programs. your car or home air conditioners or refrigerator are certified to recover the refrigerant. Repair leaky air conditioning units •Reduce air pollution from cars, trucks, gas-powered lawn and garden before refilling them. equipment, boats and other engines by keeping equipment properly tuned and maintained. During the summer, fill your gas tank during the cooler evening hours and be careful not to spill gasoline. Reduce driving, carpool, use public transportation, walk, or bicycle to reduce ozone pollution, especially on hot summer days. •Use household and garden chemicals wisely. Use low VOC paints and solvents. And be sure to read labels for proper use and disposal. Region 8 - (800) 227-8917 Region 2 www.epa.gov/region8/ - (212) 637-4249 For air program www.epa.gov/region2/ 10 1 information, 8 Region 5 - (312) 353-2211 contact www.epa.gov/region5/ 2 Region 10 - (206) 553-1505 www.epa.gov/region10/ Region 1 - (617) 918-1660 your Regional www.epa.gov/region1/ EPA Office: 5 EPA Headquarters 7 3 (202) 564-7400 9 http://www.ephttp://www.epa.gov/air ...or visit EPA’s website at Region 7 - (913) 551-7020 www.epa.gov/region7/ Region 3 - (215) 814-2100 http://www.epa.gov/air Region 9 - (415) 947-8715 www.epa.gov/region3/ www.epa.gov/region9/ 4 6 Region 4 - (404) 562-9077 www.epa.gov/region4/ Region 6 - (214) 665-7229 www.epa.gov/region6/ 2 about the cover... TOP: The “good” ozone layer in the stratosphere protects life on Earth from the Sun’s harmful ultraviolet (UV) rays. MIDDLE: Antarctic Ozone Thinning–shown in blue and purple, extended out over 16 million square miles or about the same size as North America (2001 NASA satellite image). BOTTOM: “Bad” ozone at ground-level is harmful to breathe and damages crops, trees, and other vegetation. United States Office of Air and Radiation EPA-451/K-03-001 Environmental MC6101A June 2003 Protection Agency 1200 Pennsylvania Avenue, NW Washington, DC 20460 PRINTED ON RECYCLED PAPER good up high bad nearby What is Ozone? What is Happening to the protective ozone layer. Research indicates What Causes “Bad” Ozone? breathe. Many urban and suburban emphysema, and asthma. “Bad” ozone also “Good” Ozone Layer? that depletion of the “good” ozone layer is areas throughout the United States have can reduce lung function and inflame the Ozone is a gas that occurs both in the being reduced worldwide. Thinning of the Ground-level or “bad” ozone is not high levels of “bad” ozone. But many linings of the lungs. Repeated exposure Earth’s upper atmosphere and at ground Ozone is produced naturally in the protective ozone layer can be observed emitted directly into the air, but is created rural areas of the country are also subject may permanently scar lung tissue. level. Ozone can be “good” or “bad” for stratosphere. But this “good” ozone is using satellite measurements, particularly by chemical reactions between oxides of to high ozone levels as winds carry Healthy people also experience difficulty your health and the environment, gradually being destroyed by man-made over the Polar Regions. nitrogen (NOx) and volatile organic emissions hundreds of miles away from depending on its location in the chemicals referred to as ozone-depleting compounds (VOC) in the presence of their original sources. breathing when exposed to ozone atmosphere. substances (ODS), including sunlight. Emissions from industrial pollution. Because ozone forms in hot weather, anyone who spends time outdoors chlorofluorocarbons (CFCs), How Does the Depletion of facilities and electric utilities, motor hydrochlorofluorocarbons (HCFCs), “Good” Ozone Affect Human vehicle exhaust, gasoline vapors, and How Does “Bad” Ozone Affect in the summer may be affected, How Can Ozone Be Both Good halons, methyl bromide, carbon chemical solvents are some of the major particularly children, outdoor workers and Health and the Environment? Human Health and the people exercising. Millions of Americans and Bad? tetrachloride, and methyl chloroform. sources of NOx and VOC. Environment? These substances were formerly used and Ozone depletion can cause increased live in areas where the national ozone Ozone occurs in two layers of the sometimes still are used in coolants, amounts of UV radiation to reach the Earth At ground level, ozone is a harmful health standards are exceeded. atmosphere. The layer closest to the Earth’s pollutant. Ozone pollution is a concern Breathing ozone can trigger a variety of foaming agents, fire extinguishers, which can lead to more cases of skin cancer, Ground-level or “bad” ozone also damages surface is the troposphere. Here, ground- during the summer months because strong health problems including chest pain, solvents, pesticides, and aerosol cataracts, and impaired immune systems. vegetation and ecosystems. It leads to level or “bad” ozone is an air pollutant that propellants. Once released into the air Overexposure to UV is believed to be sunlight and hot weather result in harmful coughing, throat irritation, and is harmful to breathe and it damages ozone concentrations in the air we congestion. It can worsen bronchitis, reduced agricultural crop and commercial these ozone-depleting substances degrade contributing to the increase in melanoma, forest yields, reduced growth and crops, trees and other vegetation. It is a very slowly. In fact, they can remain the most fatal of all skin cancers. Since survivability of tree seedlings, and main ingredient of urban smog. The intact for years as they move through the 1990, the risk of developing melanoma has troposphere generally extends to a level All other sources increased susceptibility to diseases, pests troposphere until they reach the more than doubled. and other stresses such as harsh weather. about 6 miles up, where it meets the stratosphere. There they are broken Industrial/ In the United States alone, ground-level second layer, the stratosphere. The down by the intensity of the sun’s UV UV can also damage sensitive crops, such stratosphere or “good” ozone layer extends as soybeans, and reduce crop yields. Some Commercial/ ozone is responsible for an estimated $500 rays and release chlorine and bromine Residential million in reduced crop production each upward from about 6 to 30 miles and scientists suggest that marine Motor molecules, which destroy the “good” Fuel Combustion protects life on Earth from the sun’s phytoplankton, which are the base of the Vehicles year. Ground-level ozone also damages the ozone. Scientists estimate that one foliage of trees and other plants, affecting harmful ultraviolet (UV) rays. chlorine atom can destroy 100,000 ocean food chain, are already under stress from UV radiation. This stress could have the landscape of cities, national parks and “good” ozone molecules. forests, and recreation areas. Too little there… Many popular consumer adverse consequences for human food products like air conditioners and Even though we have reduced or supplies from the oceans. refrigerators involve CFCs or halons eliminated the use of many ODSs, their What is Being Done About use in the past can still affect the during either manufacture or use. Over What is Being Done About the “Bad” Ozone? time, these chemicals damage the earth’s Utilities protective ozone layer. Depletion of “Good” Ozone? Under the Clean Air Act, EPA has set protective health-based standards for ozone The United States, along with over 180 other countries, recognized the threats in the air we breathe. EPA, states, and cities posed by ozone depletion and in 1987 have instituted a variety of multi-faceted Sources of NOx programs to meet these health-based adopted a treaty called the Montreal Protocol to phase out the production and standards. Throughout the country, use of ozone-depleting substances. additional programs are being put into place Consumer Solvents to cut NOx and VOC emissions from EPA has established regulations to phase vehicles, industrial facilities, and electric out ozone-depleting chemicals in the utilities. Programs are also aimed at reducing United States. Warning labels must be Motor pollution by reformulating fuels and placed on all products containing CFCs or Vehicles consumer/commercial products, such as similar substances and nonessential uses of paints and chemical solvents, that contain ozone-depleting products are prohibited. VOC. Voluntary programs also encourage Releases into the air of refrigerants used in communities to adopt practices, such as car and home air conditioning units and carpooling, to reduce harmful emissions. appliances are also prohibited. Some substitutes to ozone-depleting products Industrial/ have been produced and others are being Commercial We live with ozone every day.
Recommended publications
  • Ozonedisinfection.Pdf
    ETI - Environmental Technology Initiative Project funded by the U.S. Environmental Protection Agency under Assistance Agreement No. CX824652 What is disinfection? Human exposure to wastewater discharged into the environment has increased in the last 15 to 20 years with the rise in population and the greater demand for water resources for recreation and other purposes. Disinfection of wastewater is done to prevent infectious diseases from being spread and to ensure that water is safe for human contact and the environment. There is no perfect disinfectant. However, there are certain characteristics to look for when choosing the most suitable disinfectant: • Ability to penetrate and destroy infectious agents under normal operating conditions; • Lack of characteristics that could be harmful to people and the environment; • Safe and easy handling, shipping, and storage; • Absence of toxic residuals, such as cancer-causing compounds, after disinfection; and • Affordable capital and operation and maintenance (O&M) costs. What is ozone disinfection? One common method of disinfecting wastewater is ozonation (also known as ozone disinfection). Ozone is an unstable gas that can destroy bacteria and viruses. It is formed when oxygen molecules (O2) collide with oxygen atoms to produce ozone (O3). Ozone is generated by an electrical discharge through dry air or pure oxygen and is generated onsite because it decomposes to elemental oxygen in a short amount of time. After generation, ozone is fed into a down-flow contact chamber containing the wastewater to be disinfected. From the bottom of the contact chamber, ozone is diffused into fine bubbles that mix with the downward flowing wastewater. See Figure 1 on page 2 for a schematic of the ozonation process.
    [Show full text]
  • Ozone Layer Depletion (PDF)
    United States Air and Radiation EPA 430-F-10-027 Environmental Protection 6205J August 2010 Agency www.epa.gov/ozone/strathome.html Ozone Layer Depletion The stratospheric ozone layer forms a thin shield in the upper atmosphere, protecting life on Earth from the sun’s ultraviolet (UV) rays. It has been called the Earth’s sunscreen. In the 1980s, scientists found evidence that the ozone layer was being depleted. Depletion of the ozone layer results in increased UV radiation reaching the Earth’s surface, which in turn leads to a greater chance of overexposure to UV radiation and the related health effects of skin cancer, cataracts, and immune suppression. This fact sheet explains the importance of protecting the stratospheric ozone layer. What is Stratospheric Ozone? Ozone is a naturally-occurring gas that can be good or bad for your health and the environment depending on its location in the atmosphere. In the layer near the Earth’s surface—the troposphere— ground-level or “bad” ozone is an air pollutant that is a key ingredient of urban smog. But higher up, in the stratosphere, “good” ozone protects life on Earth by absorbing some of the sun’s UV rays. An easy way to remember this is the phrase “good up high, bad nearby.” Ozone Layer Depletion Compounds that contain chlorine and bromine molecules, such as methyl chloroform, halons, and chlorofluorocarbons (CFCs), are stable and have atmospheric lifetimes long enough to be transported by winds into Ozone “up high” in the stratosphere protects the Earth, while ozone close to the Earth’s surface is harmful.
    [Show full text]
  • Stratosphere-Troposphere Coupling: a Method to Diagnose Sources of Annular Mode Timescales
    STRATOSPHERE-TROPOSPHERE COUPLING: A METHOD TO DIAGNOSE SOURCES OF ANNULAR MODE TIMESCALES Lawrence Mudryklevel, Paul Kushner p R ! ! SPARC DynVar level, Z(x,p,t)=− T (x,p,t)d ln p , (4) g !ps x,t p ( ) R ! ! Z(x,p,t)=− T (x,p,t)d ln p , (4) where p is the pressure at the surface, R is the specific gas constant and g is the gravitational acceleration s g !ps(x,t) where p is the pressure at theat surface, the surface.R is the specific gas constant and g is the gravitational acceleration Abstract s Geopotentiallevel, Height Decomposition Separation of AM Timescales p R ! ! at the surface. This time-varying geopotentialZ( canx,p,t be)= decomposed− T into(x,p a,t cli)dmatologyln p , and anomalies from the(4) climatology AM timescales track seasonal variations in the AM index’s decorrelation time6,7. For a hydrostatic fluid, geopotential height may be describedg !p sas(x ,ta) function of time, pressure level Timescales derived from Annular Mode (AM) variability provide dynamical and ashorizontalZ(x,p,t position)=Z (asx,p a )+temperatureδZ(x,p,t integral). Decomposing from the Earth’s the temperature surface to a andgiven surface pressure pressure fields inananalogous insight into stratosphere-troposphere coupling and are linked to the strengthThis of time-varying level, geopotentialwhere can beps is decomposed the pressure at into the a surface, climatologyR is the and specific anomalies gas constant from and theg is climatology the gravitational acceleration NCEP, 1958-2007 level: ^ a) o (yL ) d) o AM responses to climate forcings.
    [Show full text]
  • Frequently Asked Questions
    FACT SHEET Frequently Asked Questions How can I find out today's air quality? Citizens can call a smog recording at (858) 586-2800 which gives the day's maximum pollution levels listed by monitoring stations and the forecasted pollution levels for the next day. The recording is updated at 4:30 p.m. each weekday. The recording also provides advance notice if there is the potential for unhealthful air quality. Air quality information can also be obtained through this web site (www.sdapcd.org) under Current Air Quality. Why do we need to regulate air quality? Because it involves the health of our community. All of us face some health risk from polluted air. Short-term exposure to smog (ozone) for an hour or two can add stress to the body. It is a strong irritant that can cause constriction of the airways, forcing the respiratory system to work harder in order to provide oxygen. Chronic exposure to smog can reduce lung capacity, lower stamina, and leave people more vulnerable to long-term respiratory problems. Smog is especially harmful for children whose lungs are still developing, senior citizens whose immune systems are breaking down, and those who suffer from heart or lung disease. Another pollutant, inhalable particles, can increase the number and severity of asthma attacks and cause or aggravate bronchitis and other lung diseases. Tiny particles, 2.5 microns or less in diameter, are so small they can penetrate deep into the lungs and damage lung tissue. Safeguarding our air quality is the primary focus of our regulatory system.
    [Show full text]
  • Regional Influence of Wildfires on Aerosol Chemistry in the Western US
    Atmos. Chem. Phys., 17, 2477–2493, 2017 www.atmos-chem-phys.net/17/2477/2017/ doi:10.5194/acp-17-2477-2017 © Author(s) 2017. CC Attribution 3.0 License. Regional influence of wildfires on aerosol chemistry in the western US and insights into atmospheric aging of biomass burning organic aerosol Shan Zhou1, Sonya Collier1, Daniel A. Jaffe2,3, Nicole L. Briggs2,3,4, Jonathan Hee2,3, Arthur J. Sedlacek III5, Lawrence Kleinman5, Timothy B. Onasch6, and Qi Zhang1 1Department of Environmental Toxicology, University of California, Davis, CA 95616, USA 2School of Science, Technology, Engineering, and Mathematics, University of Washington Bothell, Bothell, WA 98011, USA 3Department of Atmospheric Sciences, University of Washington, Seattle, WA 98195, USA 4Gradient, Seattle, WA 98101, USA 5Environmental and Climate Sciences Department, Brookhaven National Laboratory, Upton, NY 11973, USA 6Aerodyne Research Inc., Billerica, MA 01821, USA Correspondence to: Qi Zhang ([email protected]) Received: 19 September 2016 – Discussion started: 23 September 2016 Revised: 2 January 2017 – Accepted: 19 January 2017 – Published: 16 February 2017 Abstract. Biomass burning (BB) is one of the most im- OA mass); and a highly oxidized BBOA-3 (O = C D 1.06; portant contributors to atmospheric aerosols on a global 31 % of OA mass) that showed very low volatility with only scale, and wildfires are a large source of emissions that im- ∼ 40 % mass loss at 200 ◦C. The remaining 32 % of the OA pact regional air quality and global climate. As part of the mass was attributed to a boundary layer (BL) oxygenated Biomass Burning Observation Project (BBOP) field cam- OA (BL-OOA; O = C D 0.69) representing OA influenced by paign in summer 2013, we deployed a high-resolution time- BL dynamics and a low-volatility oxygenated OA (LV-OOA; of-flight aerosol mass spectrometer (HR-AMS) coupled with O = C D 1.09) representing regional aerosols in the free tro- a thermodenuder at the Mt.
    [Show full text]
  • Impacts of Anthropogenic Aerosols on Fog in North China Plain
    BNL-209645-2018-JAAM Journal of Geophysical Research: Atmospheres RESEARCH ARTICLE Impacts of Anthropogenic Aerosols on Fog in North China Plain 10.1029/2018JD029437 Xingcan Jia1,2,3 , Jiannong Quan1 , Ziyan Zheng4, Xiange Liu5,6, Quan Liu5,6, Hui He5,6, 2 Key Points: and Yangang Liu • Aerosols strengthen and prolong fog 1 2 events in polluted environment Institute of Urban Meteorology, Chinese Meteorological Administration, Beijing, China, Brookhaven National Laboratory, • Aerosol effects are stronger on Upton, NY, USA, 3Key Laboratory of Aerosol-Cloud-Precipitation of China Meteorological Administration, Nanjing University microphysical properties than of Information Science and Technology, Nanjing, China, 4Institute of Atmospheric Physics, Chinese Academy of Sciences, macrophysical properties Beijing, China, 5Beijing Weather Modification Office, Beijing, China, 6Beijing Key Laboratory of Cloud, Precipitation and • Turbulence is enhanced by aerosols during fog formation and growth but Atmospheric Water Resources, Beijing, China suppressed during fog dissipation Abstract Fog poses a severe environmental problem in the North China Plain, China, which has been Supporting Information: witnessing increases in anthropogenic emission since the early 1980s. This work first uses the WRF/Chem • Supporting Information S1 model coupled with the local anthropogenic emissions to simulate and evaluate a severe fog event occurring Correspondence to: in North China Plain. Comparison of the simulations against observations shows that WRF/Chem well X. Jia and Y. Liu, reproduces the general features of temporal evolution of PM2.5 mass concentration, fog spatial distribution, [email protected]; visibility, and vertical profiles of temperature, water vapor content, and relative humidity in the planetary [email protected] boundary layer throughout the whole period of the fog event.
    [Show full text]
  • Controlling Biogenic Volatile Organic Compounds for Air Quality
    Indiana Law Journal Volume 94 Issue 5 The Supplement Article 5 2019 Controlling Biogenic Volatile Organic Compounds for Air Quality Brian Sawers Georgetown University, [email protected] Follow this and additional works at: https://www.repository.law.indiana.edu/ilj Part of the Agriculture Law Commons, Air and Space Law Commons, Environmental Law Commons, Health Law and Policy Commons, Law and Society Commons, and the Natural Resources Law Commons Recommended Citation Sawers, Brian (2019) "Controlling Biogenic Volatile Organic Compounds for Air Quality," Indiana Law Journal: Vol. 94 : Iss. 5 , Article 5. Available at: https://www.repository.law.indiana.edu/ilj/vol94/iss5/5 This Article is brought to you for free and open access by the Law School Journals at Digital Repository @ Maurer Law. It has been accepted for inclusion in Indiana Law Journal by an authorized editor of Digital Repository @ Maurer Law. For more information, please contact [email protected]. Controlling Biogenic Volatile Organic Compounds for Air Quality BRIAN SAWERS* This Article tells a story that is true but seems completely wrong: Trees can make air pollution worse. Smog and ground-level ozone require two chemical ingredients to form: nitrous oxides (NOx) and volatile organic compounds (VOCs). On a warm, sunny day, these two precursors combine to form smog and ground-level ozone, a pollutant. While NOx are pollutants that are largely human-created, VOCs can originate with plants. In fact, emissions of just one type of VOC from trees exceed all human-caused emissions.1 This Article presents new research on the impact of plants, especially trees, on air quality.
    [Show full text]
  • Ethanol Purification with Ozonation, Activated Carbon Adsorption, and Gas Stripping Shinnosuke Onuki Iowa State University
    Agricultural and Biosystems Engineering Agricultural and Biosystems Engineering Publications 9-4-2015 Ethanol purification with ozonation, activated carbon adsorption, and gas stripping Shinnosuke Onuki Iowa State University Jacek A. Koziel Iowa State University, [email protected] William S. Jenks Iowa State University, [email protected] Lingshuang Cai Iowa State University Somchai Rice Iowa State University SeFoe nelloxtw pa thige fors aaddndition addal aitutionhorsal works at: https://lib.dr.iastate.edu/abe_eng_pubs Part of the Agriculture Commons, Bioresource and Agricultural Engineering Commons, and the Organic Chemistry Commons The ompc lete bibliographic information for this item can be found at https://lib.dr.iastate.edu/ abe_eng_pubs/909. For information on how to cite this item, please visit http://lib.dr.iastate.edu/ howtocite.html. This Article is brought to you for free and open access by the Agricultural and Biosystems Engineering at Iowa State University Digital Repository. It has been accepted for inclusion in Agricultural and Biosystems Engineering Publications by an authorized administrator of Iowa State University Digital Repository. For more information, please contact [email protected]. Ethanol purification with ozonation, activated carbon adsorption, and gas stripping Abstract Fermentation of sugar to produce ethanol also produces volatile byproducts. This study was aimed at purifying corn-based ethanol for industrial and pharmaceutical use. The er search was on treatment for 10 impurities removal after distillation. The the anol headspace was sampled with solid-phase microextraction and analyzed with gas chromatography–mass spectrometry. A 40 mg/L ozone treatment resulted in >56% and >36% removal of styrene and 2-pentylfuran, respectively, without significant generation of byproducts.
    [Show full text]
  • Publication No. 17: Ozone Treatment of Private Drinking Water Systems
    PRIVATE DRINKING WATER IN CONNECTICUT Publication Date: April 2009 Publication No. 17: Ozone Treatment of Private Drinking Water Systems Effective Against: Pathogenic (disease-causing) organisms including bacteria and viruses, phenols (aromatic organic compounds), some color, taste and odor problems, iron, manganese, and turbidity. Not Effective Against: Large cysts and some other large organisms resulting from possible or probable sewage contamination, inorganic chemicals, and heavy metals. How Ozone (O3) Treatment Works Ozone is a chemical form of pure oxygen. Like chlorine, ozone is a strong oxidizing agent and is used in much the same way to kill disease-causing bacteria and viruses. It is effective against most amoebic cysts, and destroys bacteria and some aromatic organic compounds (such as phenols). Ozone may not kill large cysts and some other large organisms, so these should be eliminated by filtration or other procedures prior to ozone treatment. Ozone is effective in eliminating or controlling color, taste, and odor problems. It also oxidizes iron and manganese. Ozone treatment units are installed as point-of-use treatment systems. Raw water enters one opening and treated water emerges from another. Inside the treatment unit, ozone is produced by an electrical corona discharge or ultraviolet irradiation of dry air or oxygen. The ozone is mixed with the water whenever the water pump is running. Ozone generation units require a system to clean and remove the humidity from the air. For proper disinfection the water to be treated must have negligible color and turbidity levels. The system requires routine maintenance and an ozone treatment system can be very energy consumptive.
    [Show full text]
  • Interaction of Ozone and Hydrogen Peroxide in Water Implications For
    UC Irvine Faculty Publications Title Interaction of ozone and hydrogen peroxide in water: Implications for analysis of H 2 O 2 in air Permalink https://escholarship.org/uc/item/7j7454z7 Journal Geophysical Research Letters, 9(3) ISSN 00948276 Authors Zika, R. G Saltzman, E. S Publication Date 1982-03-01 DOI 10.1029/GL009i003p00231 License https://creativecommons.org/licenses/by/4.0/ 4.0 Peer reviewed eScholarship.org Powered by the California Digital Library University of California GEOPHYSICLARESEARCH LETTERS, VOL. 9, NO. 3, PAGES231-234 , MARCH1982 INTERACTION OF OZONE AND HYDROGEN PEROXIDE IN WATER: IMPLICATIONSFORANALYSIS oFH20 2 IN AIR R.G. Zika and E.S. Saltzman Division of Marine and Atmospheric Chemistry, University of Miami, Miami, Florida 331#9 Abstract. We have attempted to measure gaseous Analytical Methods H202 in air usingan aqueoustrapping method. With continuousbubbling, H 20 2 levels in the traps reacheda a. Hydrogen Peroxide. Hydrogen peroxide in aqueous plateau, indicating that a state of dynamic equilibrium solution was measured using a modified fluorescence involving H202 destrbction was established. We decay technique [Perschke and Broda, 1976; Zika and attribute this behavior to the interaction of ozone and its Zelmer, 1982]. The method involved the addition of a decompositionproducts (OH, O[) withH 20 2 inacld:•ous known amot•at of scopoletin (6-methyl-7-hydroxyl-i,2- solution. This hypothesis was investigated by replacing benzopyrone)to a pH 7.0 phosphatebuffered. sample. the air stream with a mixture of N2, 02 and 0 3. The The sample was prepared bY diluting an aliquot of the results Of this experiment show that H O was both reaction solution to 20 mls with low contaminant producedand destroyedin the traps.
    [Show full text]
  • The Impact of Aerosols on the Color and Brightness of the Sun and Sky
    The Impact of Aerosols on the Color and Brightness of the Sun and Sky Stanley David Gedzelman * Department of Earth and Atmospheric Sciences and NOAA CREST Center, City College of New York 1. INTRODUCTION and brightness that capture the main aspects of scattering behavior. SKYCOLOR is such a model. Long before the climatic impact of aerosols was It is available at www.sci.ccny.cuny.edu/~stan recognized, their impact on the appearance of the (then click on Atmospheric Optics). In §2, sky was considered obvious (Minnaert, 1954). SKYCOLOR is briefly described and in §3 it is The sky is deepest blue when air is clean and dry, applied to situations that indicate how sky color but it always whitens toward the horizon when the and brightness provide information about the sun is high in the sky and reddens at the horizon aerosol and ozone content of the atmosphere. during twilight. Hazy skies are typically brighter, This shows its relevance to climate problems. particularly near the sun, but less blue, and may even take on pastel or earth tones. At twilight, 2. SKYCOLOR: THE MODEL aerosol laden skies can exhibit rich red colors near the horizon, and volcanic aerosol particles SKYCOLOR is a simplified model of sky color and may even turn the twilight sky crimson far above brightness in the vertical plane including the sun the horizon. and the observer (Gedzelman, 2005). Model Sky colors result from a combination of factors skylight consists of sunbeams that are scattered including the solar spectrum and zenith angle, the toward the observer, but depleted by scattering scattering properties of air molecules and aerosol and absorption in the Chappuis bands of ozone.
    [Show full text]
  • WHO Guidelines for Indoor Air Quality : Selected Pollutants
    WHO GUIDELINES FOR INDOOR AIR QUALITY WHO GUIDELINES FOR INDOOR AIR QUALITY: WHO GUIDELINES FOR INDOOR AIR QUALITY: This book presents WHO guidelines for the protection of pub- lic health from risks due to a number of chemicals commonly present in indoor air. The substances considered in this review, i.e. benzene, carbon monoxide, formaldehyde, naphthalene, nitrogen dioxide, polycyclic aromatic hydrocarbons (especially benzo[a]pyrene), radon, trichloroethylene and tetrachloroethyl- ene, have indoor sources, are known in respect of their hazard- ousness to health and are often found indoors in concentrations of health concern. The guidelines are targeted at public health professionals involved in preventing health risks of environmen- SELECTED CHEMICALS SELECTED tal exposures, as well as specialists and authorities involved in the design and use of buildings, indoor materials and products. POLLUTANTS They provide a scientific basis for legally enforceable standards. World Health Organization Regional Offi ce for Europe Scherfi gsvej 8, DK-2100 Copenhagen Ø, Denmark Tel.: +45 39 17 17 17. Fax: +45 39 17 18 18 E-mail: [email protected] Web site: www.euro.who.int WHO guidelines for indoor air quality: selected pollutants The WHO European Centre for Environment and Health, Bonn Office, WHO Regional Office for Europe coordinated the development of these WHO guidelines. Keywords AIR POLLUTION, INDOOR - prevention and control AIR POLLUTANTS - adverse effects ORGANIC CHEMICALS ENVIRONMENTAL EXPOSURE - adverse effects GUIDELINES ISBN 978 92 890 0213 4 Address requests for publications of the WHO Regional Office for Europe to: Publications WHO Regional Office for Europe Scherfigsvej 8 DK-2100 Copenhagen Ø, Denmark Alternatively, complete an online request form for documentation, health information, or for per- mission to quote or translate, on the Regional Office web site (http://www.euro.who.int/pubrequest).
    [Show full text]