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Sulfurchloride Interim AEGL Document INTERIM 1: 09/2007 ACUTE EXPOSURE GUIDELINE LEVELS (AEGLs) FOR SULFUR CHLORIDE (CAS No. 10025-67-9) INTERIM 1: 09/2007 PREFACE 1 2 Under the authority of the Federal Advisory Committee Act (FACA) P. L. 92-463 of 3 1972, the National Advisory Committee for Acute Exposure Guideline Levels for Hazardous 4 Substances (NAC/AEGL Committee) has been established to identify, review and interpret 5 relevant toxicologic and other scientific data and develop AEGLs for high priority, acutely toxic 6 chemicals. 7 AEGLs represent threshold exposure limits for the general public and are applicable to 8 emergency exposure periods ranging from 10 minutes to 8 hours. Three levels — AEGL-1, 9 AEGL-2 and AEGL-3 — are developed for each of five exposure periods (10 and 30 minutes, 1 10 hour, 4 hours, and 8 hours) and are distinguished by varying degrees of severity of toxic effects. 11 The three AEGLs are defined as follows: 12 AEGL-1 is the airborne concentration (expressed as parts per million or milligrams per 13 cubic meter [ppm or mg/m3]) of a substance above which it is predicted that the general 14 population, including susceptible individuals, could experience notable discomfort, irritation, or 15 certain asymptomatic, non-sensory effects. However, the effects are not disabling and are 16 transient and reversible upon cessation of exposure. 17 AEGL-2 is the airborne concentration (expressed as ppm or mg/m3) of a substance above 18 which it is predicted that the general population, including susceptible individuals, could 19 experience irreversible or other serious, long-lasting adverse health effects or an impaired ability 20 to escape. 21 AEGL-3 is the airborne concentration (expressed as ppm or mg/m3) of a substance above 22 which it is predicted that the general population, including susceptible individuals, could 23 experience life-threatening health effects or death. 24 Airborne concentrations below the AEGL-1 represent exposure levels that could produce 25 mild and progressively increasing but transient and nondisabling odor, taste, and sensory 26 irritation or certain asymptomatic, non-sensory effects. With increasing airborne concentrations 27 above each AEGL, there is a progressive increase in the likelihood of occurrence and the 28 severity of effects described for each corresponding AEGL. Although the AEGL values 29 represent threshold levels for the general public, including susceptible subpopulations, such as 30 infants, children, the elderly, persons with asthma, and those with other illnesses, it is recognized 31 that individuals, subject to unique or idiosyncratic responses, could experience the effects 32 described at concentrations below the corresponding AEGL. 1 INTERIM 1: 09/2007 TABLE OF CONTENTS 1 2 PREFACE ...................................................................1 3 4 LIST OF TABLES.............................................................3 5 6 EXECUTIVE SUMMARY......................................................4 7 8 1. INTRODUCTION ..........................................................6 9 10 2. HUMAN TOXICITY DATA .................................................7 11 12 3. ANIMAL TOXICITY DATA.................................................7 13 3.1. Acute Lethality ......................................................7 14 3.1.1. Rat .............................................................7 15 3.1.2. Other Species .....................................................8 16 3.2. Nonlethal Toxicity ....................................................8 17 18 4. SPECIAL CONSIDERATIONS...............................................8 19 20 5. DATA ANALYSIS AND PROPOSED AEGL-1 ..................................9 21 5.1. Human Data Relevant to AEGL- .........................................9 22 5.2. Animal Data Relevant to AEGL-1 ........................................9 23 5.3. Derivation of AEGL-1 .................................................9 24 25 6. DATA ANALYSIS AND PROPOSED AEGL-2 .................................10 26 6.1. Human Data Relevant to AEGL-2 .......................................10 27 6.2. Animal Data Relevant to AEGL-2 .......................................10 28 6.3. Derivation of AEGL- .................................................10 29 30 7. DATA ANALYSIS AND PROPOSED AEGL-3 .................................10 31 7.1. Human Data Relevant to AEGL-3 .......................................10 32 7.2 Animal Data Relevant to AEGL-3.......................................10 33 7.3. Derivation of AEGL-3 ................................................11 34 35 8. SUMMARY OF PROPOSED AEGLs .........................................11 36 8.1. Proposed AEGLs ....................................................11 37 8.2. Comparison of AEGLs with Other Standards and Criteria ....................12 38 8.3. Data Adequacy and Research Needs .....................................13 39 40 9. REFERENCES ...........................................................13 41 2 INTERIM 1: 09/2007 APPENDIX A: DERIVATION OF AEGLs ........................................16 1 2 APPENDIX B: DERIVATION SUMMARY FOR SULFUR CHLORIDE AEGLs .........20 3 4 APPENDIX C: CATEGORY PLOT FOR SULFUR CHLORIDE.......................24 5 6 LIST OF TABLES 7 8 Proposed AEGL Values For Sulfur Chloride ........................................5 9 1. Physical/Chemical Data ......................................................6 10 2. AEGL-1 Values for Sulfur Chloride............................................10 11 3. AEGL-2 Values for Sulfur Chloride............................................10 12 4. AEGL-3 Values for Sulfur Chloride............................................11 13 5. Proposed AEGL Values For Sulfur Chloride .....................................12 14 6. Extant Standards and Guidelines for Sulfur Chloride ..............................12 15 3 INTERIM 1: 09/2007 SUMMARY 1 2 Sulfur chloride is a fuming yellowish red oily liquid. It is used in the production of 3 vulcanized rubber, as an intermediate in synthesis of organic chemicals, as a hardening agent for 4 soft woods, for purifying sugar juices, and as a military poison. A survey conducted from 1981- 5 1983 found that about 28,180 workers were potentially exposed to sulfur chloride. Sulfur 6 chloride has an irritating, penetrating, nauseating, or suffocating odor, but the odor detection 7 threshold is not known. It decomposes primarily to sulfur, sulfur dioxide, and hydrochloric acid 8 in water or a moist environment. 9 The data on sulfur chloride was very limited. No data were found on lethal 10 concentrations. Sulfur chloride vapor causes irritation to the eyes, nose, and throat of humans. 11 The threshold for irritation to humans is 2 ppm and mild irritation was reported to occur at 2-9 3 12 ppm. The LC50 for rats exposed to sulfur chloride for 4 hours was 483 ppm (2670 mg/m ). An 13 acute inhalation study in rats was used for deriving AEGL values for all three levels. The 14 degradation products of sulfur chloride (hydrogen chloride and sulfur dioxide) should not be 15 considered surrogates for deriving AEGL values for sulfur chloride because (1) the degradation 16 level is dependent on the moisture content of the environment and under dry conditions very 17 little degradation would be expected to occur and (2) unlike hydrogen chloride and sulfur 18 dioxide, sulfur chloride is not water soluble and would not be efficiently scrubbed in the upper 19 respiratory tract, thus allowing the parent compound to reach the pulmonary region of the 20 respiratory tract. No odor data were available; therefore, a level of distinct odor awareness 21 (LOA) could not be calculated. 22 AEGL-1 values were based on the no-observed-effect level (NOEL) of 33.3 ppm (point- 23 of-departure, POD) for upper respiratory tract irritation, breathing abnormalities, and other 24 clinical signs (reduced activity, piloerection, and ungroomed fur) that suggest discomfort in rats 25 exposed to sulfur chloride for 4 hours. Very little is known about the toxicity of inhaled sulfur 26 chloride and no data were available to compare the toxicity of sulfur chloride in different species 27 or to evaluate the toxicity in sensitive individuals in the human population. Therefore, the 28 default uncertainty factors, 10 for interspecies sensitivity and 10 for intraspecies variability (total 29 uncertainty factor was 100) were applied to the exposure concentration of 33.3 ppm. The 4-hour 30 exposure duration was extrapolated to the relevant AEGL time frames using the equation: 31 Cn × t = k. Data were not available to derive n empirically; therefore, the defaults values n = 3 32 and n = 1 were used to extrapolate from the 4-hour exposure duration to the shorter and longer 33 time frames, respectively. Time scaling was applied for all exposure durations except the 10- 34 minute exposure because sulfur chloride is not water soluble and would not be scrubbed in the 35 upper respiratory tract; therefore, the potential for pulmonary effects exist for all exposure 36 concentrations. In addition, AEGL-1 value for 10 minutes is assigned the same value as the 30- 37 minute AEGL, because the data did not support extrapolating from a 4-hour exposure duration to 38 a 10-minute time frame. 39 AEGL-2 values were based on a 4-hour exposure to 242 ppm (POD) that caused upper 40 respiratory irritation (bloody and serous nasal discharge), abnormal breathing (dyspnea and 41 decelerated breathing), and reduced activity. Although piloerection and ungroomed fur were 4 INTERIM 1: 09/2007 observed, these findings are
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