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Safety Data Sheet SAFETY DATA SHEET Issue Date 22-Nov-2019 Revision Date Version 5.3 Page 1 / 16 22-Nov-2019 1. IDENTIFICATION Product identifier Product Name FerroZineÒ Iron Reagent Other means of identification Product Code(s) 230149 Safety data sheet number M00186 UN/ID no UN2922 Recommended use of the chemical and restrictions on use Recommended Use Indicator for iron. Uses advised against Consumer use. Restrictions on use For Laboratory Use Only. Details of the supplier of the safety data sheet Manufacturer Address Hach Company P.O.Box 389 Loveland, CO 80539 USA +1(970) 669-3050 Emergency telephone number +1(303) 623-5716 - 24 Hour Service 2. HAZARDS IDENTIFICATION Classification Regulatory Status This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Acute toxicity - Oral Category 3 Acute toxicity - Inhalation (Vapors) Category 4 Acute toxicity - Inhalation (Dusts/Mists) Category 4 Skin corrosion/irritation Category 1 Sub-category B Serious eye damage/eye irritation Category 1 Respiratory sensitization Category 1 Skin sensitization Category 1 Chronic aquatic toxicity Category 3 Hazards not otherwise classified (HNOC) Not applicable Label elements Signal word Danger EN / AGHS Page 1 / 16 Product Code(s) 230149 Product Name FerroZineÒ Iron Reagent Issue Date 22-Nov-2019 Revision Date 22-Nov-2019 Version 5.3 Page 2 / 16 Hazard statements H301 - Toxic if swallowed H314 - Causes severe skin burns and eye damage H317 - May cause an allergic skin reaction H332 - Harmful if inhaled H334 - May cause allergy or asthma symptoms or breathing difficulties if inhaled H412 - Harmful to aquatic life with long lasting effects Precautionary statements P271 - Use only outdoors or in a well-ventilated area P304 + P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P260 - Do not breathe dust/fume/gas/mist/vapors/spray P280 - Wear protective gloves/protective clothing/eye protection/face protection P301 + P330 + P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting P303 + P361 + P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 - Immediately call a POISON CENTER or doctor/physician P363 - Wash contaminated clothing before reuse P405 - Store locked up P501 - Dispose of contents/ container to an approved waste disposal plant P285 - In case of inadequate ventilation wear respiratory protection P304 + P341 - IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing P342 + P311 - If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician P272 - Contaminated work clothing should not be allowed out of the workplace P273 - Avoid release to the environment P270 - Do not eat, drink or smoke when using this product P301 + P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician Other Hazards Known May be harmful in contact with skin Harmful to aquatic life 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance Not applicable Mixture Chemical Family Mixture. Chemical nature Mixture of organic compounds. Percent ranges are used where confidential product information is applicable. Chemical name CAS No. Percent HMRIC # Range Acetic acid, mercapto-, monoammonium salt 5421-46-5 40 - 50% - Thioglycolic acid 68-11-1 20 - 30% - EN / AGHS Page 2 / 16 Product Code(s) 230149 Product Name FerroZineÒ Iron Reagent Issue Date 22-Nov-2019 Revision Date 22-Nov-2019 Version 5.3 Page 3 / 16 Benzenesulfonic acid, 4,4-[3-(2-pyridinyl)-1,2,4-triazine-5,6-diyl]bis-, 69898-45-9 <1% - monosodium salt 4. FIRST AID MEASURES Description of first aid measures General advice Show this safety data sheet to the doctor in attendance. Immediate medical attention is required. Inhalation Remove to fresh air. If breathing has stopped, give artificial respiration. Get medical attention immediately. Do not use mouth-to-mouth method if victim ingested or inhaled the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. If breathing is difficult, (trained personnel should) give oxygen. Delayed pulmonary edema may occur. Get immediate medical advice/attention. May cause allergic respiratory reaction. Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. Do not rub affected area. Remove contact lenses, if present and easy to do. Continue rinsing. Get immediate medical advice/attention. Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Get immediate medical advice/attention. May cause an allergic skin reaction. Ingestion Do NOT induce vomiting. Clean mouth with water and drink afterwards plenty of water. Never give anything by mouth to an unconscious person. Get immediate medical advice/attention. May produce an allergic reaction. Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination. Avoid contact with skin, eyes or clothing. Avoid direct contact with skin. Use barrier to give mouth-to-mouth resuscitation. Avoid breathing vapors or mists. Most important symptoms and effects, both acute and delayed Symptoms Burning sensation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. Coughing and/ or wheezing. Itching. Rashes. Hives. Difficulty in breathing. Indication of any immediate medical attention and special treatment needed Note to physicians Product is a corrosive material. Use of gastric lavage or emesis is contraindicated. Possible perforation of stomach or esophagus should be investigated. Do not give chemical antidotes. Asphyxia from glottal edema may occur. Marked decrease in blood pressure may occur with moist rales, frothy sputum, and high pulse pressure. May cause sensitization in susceptible persons. Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Caution: Use of water spray when fighting fire may be inefficient. Specific hazards arising from the The product causes burns of eyes, skin and mucous membranes. Thermal decomposition chemical can lead to release of irritating gases and vapors. Product is or contains a sensitizer. May cause sensitization by inhalation and skin contact. May cause sensitization by skin contact. EN / AGHS Page 3 / 16 Product Code(s) 230149 Product Name FerroZineÒ Iron Reagent Issue Date 22-Nov-2019 Revision Date 22-Nov-2019 Version 5.3 Page 4 / 16 Hazardous combustion products Carbon monoxide, Carbon dioxide. Nitrogen oxides. Sulfur oxides. Ammonia. Special protective equipment for Firefighters should wear self-contained breathing apparatus and full firefighting turnout fire-fighters gear. Use personal protection equipment. 6. ACCIDENTAL RELEASE MEASURES U.S. Notice Only persons properly qualified to respond to an emergency involving hazardous substances may respond to a spill according to federal regulations (OSHA 29 CFR 1910.120(a)(v)) and per your company's emergency response plan and guidelines/procedures. See Section 13, Special Instructions for disposal assistance. Outside of the US, only persons properly qualified according to state or local regulations should respond to a spill involving chemicals. Personal precautions, protective equipment and emergency procedures Personal precautions Attention! Corrosive material. Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Use personal protective equipment as required. Evacuate personnel to safe areas. Keep people away from and upwind of spill/leak. Avoid breathing vapors or mists. Other Information Refer to protective measures listed in Sections 7 and 8. Environmental precautions Environmental precautions Prevent further leakage or spillage if safe to do so. Should not be released into the environment. Do not allow to enter into soil/subsoil. Prevent product from entering drains. Methods and material for containment and cleaning up Methods for containment Prevent further leakage or spillage if safe to do so. Methods for cleaning up Pick up and transfer to properly labeled containers. Prevention of secondary hazards Clean contaminated objects and areas thoroughly observing environmental regulations. Reference to other sections See section 8 for more information. See section 13 for more information. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. In case of insufficient ventilation, wear suitable respiratory equipment. Handle product only in closed system or provide appropriate exhaust ventilation. Do not eat, drink or smoke when using this product. Take off contaminated clothing and wash before reuse. Provide extract ventilation to points where emissions occur. Remove contaminated clothing and shoes. Avoid breathing vapors or mists. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly
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