DOCSLIB.ORG

CBS Reimbursable User Guide Transaction Screens Table of Contents

Total Page：16

File Type：pdf, Size：1020Kb

Download full-text PDF Read full-text
CBS Reimbursable User Guide Transaction Screens Table of Contents Reimbursable Agreements Transactions CBS Reimbursable User Guide Transaction Screens Table of Contents 5.0 Reimbursable Agreement Transaction Screens ............................................................... 5-3 5.1 Reimbursable Agreement Screen (RADG002).................................................... 5-3 5.1.1 Reimbursable Agreement Control Block (RADG002)............................ 5-4 5.1.2 Reimbursable Agreement - Document Tab (RADG002) ........................ 5-6 5.1.3 Reimbursable Agreement - Customer Tab (RADG002) ....................... 5-11 5.1.4 Reimbursable Agreement - Note Tab (RADG002) ............................... 5-13 5.1.5 Reimbursable Agreement - FY Funding Tab (RADG002).................... 5-14 5.1.6 Reimbursable Agreement - Print Tab (RADG002) ............................... 5-15 5.1.7 Reimbursable Agreement - Orders Tab (RADG002) ............................ 5-16 5.1.8 Reimbursable Agreement - Projects Tab (RADG002) .......................... 5-18 5.1.9 Reimbursable Agreement - Mod/Admin Tab (RADG002) ................... 5-19 5.1.10 Create Temporary Work Authority or Reimbursable Agreement Record (RADG002)............................................................................................ 5-21 5.1.11 Modify a Reimbursable Agreement (RADG002).................................. 5-27 5.1.12 Enter an Administrative Change to a Reimbursable Agreement or Temporary Work Authority (RADG002) .............................................. 5-28 5.1.13 Change a Temporary Work Authority to a Reimbursable Agreement (RADG002)............................................................................................ 5-30 5.1.14 Void a Reimbursable Agreement (RADG002)...................................... 5-32 5.1.15 Terminate a Reimbursable Agreement (RADG002) ............................. 5-33 5.1.16 View the Reimbursable Agreement Summary Fields (RADG002)....... 5-34 5.1.17 Access the Unfilled Customer Orders via the Reimbursable Agreement Screen (RADG002)................................................................................ 5-35 5.1.18 Systems Edits and Business Rules......................................................... 5-36 5.2 Unfilled Customer Order Screen (RADG003) .................................................. 5-38 5.2.1 Unfilled Customer Order - Control Block (RADG003) ........................ 5-38 5.2.2 Unfilled Customer Order - Document Tab (RADG003) ....................... 5-41 5.2.3 Unfilled Customer Order - Project Distribution Tab (RADG003) ........ 5-43 5.2.4 Unfilled Customer Order - Modification History Tab (RADG003)...... 5-45 5.2.5 Create Unfilled Customer Order Transactions (RADG003) ................. 5-46 5.2.6 Modify an Unfilled Customer Order...................................................... 5-49 5.2.7 View Information on the Unfilled Customer Order Modification History Tab (RADG003) .................................................................................... 5-50 5.2.8 System Edits and Business Rules .......................................................... 5-51 5.3 WIP Allocation Modification and Release Screen (RADG005) ....................... 5-52 5.3.1 WIP Allocation and Modification Release Screen - Control Block (RADG005)............................................................................................ 5-53 October 2005 1 Reimbursable Agreements Transactions 5.3.2 WIP Allocation and Modification Release Screen - WIP Results Tab (RADG005)............................................................................................ 5-55 5.3.3 WIP Allocation and Modification Release Screen - Customer List Button ……….................................................................................................... 5-56 5.3.4 WIP Allocation & Modification Release Screen - Customer WIP Results Drill Down ............................................................................................. 5-57 5.3.5 WIP Allocation and Modification Release Screen - Modify Results Tab (RADG005)............................................................................................ 5-59 5.3.6 WIP Allocation and Modification Release Screen - Cost/Order Detail Tab (RADG005)............................................................................................ 5-60 5.3.7 Review WIP Transactions (RADG005)................................................. 5-61 5.3.8 Modify WIP Transactions (RADG005)................................................. 5-62 5.3.9 Adjust the Amount of Costs Allocated Between Unfilled Customer Orders on WIP Transactions (RADG005)......................................................... 5-63 5.3.10 Modify Amount of Released Costs on WIP Transactions (RADG005).5-63 5.3.11 Change Released Costs to Unreleased Costs on WIP Transactions (RADG005)............................................................................................ 5-64 5.3.12 System Edits and Business Rules .......................................................... 5-64 5.4 Receivable Screen (AR001)............................................................................... 5-65 5.4.1 Receivables - Control Block (AR001)................................................... 5-66 5.4.2 Receivables - Document Tab (AR001).................................................. 5-67 5.4.3 Receivables - Reference Tab (AR001) .................................................. 5-69 5.4.4. Receivables - Items Tab (AR001).......................................................... 5-70 5.4.5 Receivables - ACCS/MDL (AR001) ..................................................... 5-71 5.4.6 Receivables - Schedule Tab (AR001).................................................... 5-72 5.4.7 Create Receivable Transactions (AR001).............................................. 5-73 5.4.8 Modify Receivable Transactions (AR001) ............................................ 5-74 5.4.9 Receivable Transactions Generated by the WIP Process (AR001) ....... 5-74 5.4.10 System Edits and Business Rules .......................................................... 5-75 5.5 Collections Screen (AR008).............................................................................. 5-75 5.5.1 Receivable Block................................................................................... 5-76 5.5.2 Collection Block.................................................................................... 5-77 5.5.3 Collection Bill Items Block ................................................................... 5-77 5.5.4 Apply a Collection ................................................................................. 5-77 5.5.5 Modify a Collection ............................................................................... 5-80 5.5.6 System Edits and Business Rules .......................................................... 5-81 5.6 AR Unbilled Collection Screen (AR009) .......................................................... 5-82 5.6.1 Control Block......................................................................................... 5-83 5.6.2 Collection Items Tab (AR009)............................................................... 5-84 5.6.3 Establish an Unbilled Collection (AR009) ............................................ 5-85 October 2005 2 Reimbursable Agreements Transactions 5.0 Reimbursable Agreement Transaction Screens Federal government agencies are authorized by legislation to undertake reimbursable activities related to the mission of the agency. The requesting party provides the main source of funding for the work to be performed. Other federal agencies or private sector businesses request goods or services from the servicing agency via a reimbursable agreement document. The customers are then billed as the work is performed or advance funding is provided. Transaction screens are used for processing transactions in the CBS Reimbursable Agreement (RA) Module. Transactions include getting authority to incur costs, billing customers, and collecting funds from customers. Three transaction screens that record, process and track the reimbursable agreement from the start to finish are part of the implemented module. These transaction screens are the RADG002 - Reimbursable Agreement Screen, the RADG003 - Unfilled Customer Orders Screen and the RADG005 - WIP Allocation Modification and Release Screen. Transaction screens rely on the information contained in the maintenance screens for system defined and bureau defined values. When transactions are processed, the system uses information from the maintenance screen and information from the specific order to create a transaction. The system displays applicable error messages if users attempt to create transactions where maintenance values have not been established. Upon receipt of error messages, users are prohibited from proceeding until relevant maintenance data has been established. 5.1 Reimbursable Agreement Screen (RADG002) The purpose of the Reimbursable Agreement (RADG002) screen is to establish the reimbursable agreement or temporary work authority (TWA) information in the system. A separate record is stored for each TWA, corresponding formal reimbursable agreement, and subsequent modifications. Some of the information recorded on RADG002 will carry forward either directly or as a List of Values (LOV) to other reimbursable screens and relevant Accounts Receivable screens. The RADG002 screen is divided into two parts. The first part is the control block where required information for the reimbursable agreement or TWA is entered
Load more

Recommended publications
  • A Combinatorial Game Theoretic Analysis of Chess Endgames
    A COMBINATORIAL GAME THEORETIC ANALYSIS OF CHESS ENDGAMES QINGYUN WU, FRANK YU,¨ MICHAEL LANDRY 1. Abstract In this paper, we attempt to analyze Chess endgames using combinatorial game theory. This is a challenge, because much of combinatorial game theory applies only to games under normal play, in which players move according to a set of rules that define the game, and the last player to move wins. A game of Chess ends either in a draw (as in the game above) or when one of the players achieves checkmate. As such, the game of chess does not immediately lend itself to this type of analysis. However, we found that when we redefined certain aspects of chess, there were useful applications of the theory. (Note: We assume the reader has a knowledge of the rules of Chess prior to reading. Also, we will associate Left with white and Right with black). We first look at positions of chess involving only pawns and no kings. We treat these as combinatorial games under normal play, but with the modification that creating a passed pawn is also a win; the assumption is that promoting a pawn will ultimately lead to checkmate. Just using pawns, we have found chess positions that are equal to the games 0, 1, 2, ?, ", #, and Tiny 1. Next, we bring kings onto the chessboard and construct positions that act as game sums of the numbers and infinitesimals we found. The point is that these carefully constructed positions are games of chess played according to the rules of chess that act like sums of combinatorial games under normal play.
    [Show full text]
  • LNCS 7215, Pp
    ACoreCalculusforProvenance Umut A. Acar1,AmalAhmed2,JamesCheney3,andRolyPerera1 1 Max Planck Institute for Software Systems umut,rolyp @mpi-sws.org { 2 Indiana} University [email protected] 3 University of Edinburgh [email protected] Abstract. Provenance is an increasing concern due to the revolution in sharing and processing scientific data on the Web and in other computer systems. It is proposed that many computer systems will need to become provenance-aware in order to provide satisfactory accountability, reproducibility,andtrustforscien- tific or other high-value data. To date, there is not a consensus concerning ap- propriate formal models or security properties for provenance. In previous work, we introduced a formal framework for provenance security and proposed formal definitions of properties called disclosure and obfuscation. This paper develops a core calculus for provenance in programming languages. Whereas previous models of provenance have focused on special-purpose languages such as workflows and database queries, we consider a higher-order, functional language with sums, products, and recursive types and functions. We explore the ramifications of using traces based on operational derivations for the purpose of comparing other forms of provenance. We design a rich class of prove- nance views over traces. Finally, we prove relationships among provenance views and develop some solutions to the disclosure and obfuscation problems. 1Introduction Provenance, or meta-information about the origin, history, or derivation of an object, is now recognized as a central challenge in establishing trust and providing security in computer systems, particularly on the Web. Essentially, provenance management in- volves instrumenting a system with detailed monitoring or logging of auditable records that help explain how results depend on inputs or other (sometimes untrustworthy) sources.
    [Show full text]
  • 11 Practice Lesso N 4 R O U N D W H Ole Nu M Bers U N It 1
    CC04MM RPPSTG TEXT.indb 11 © Practice and Problem Solving Curriculum Associates, LLC Copying isnotpermitted. Practice Lesson 4 Round Whole Numbers Whole 4Round Lesson Practice Lesson 4 Round Whole Numbers Name: Solve. M 3 Round each number. Prerequisite: Round Three-Digit Numbers a. 689 rounded to the nearest ten is 690 . Study the example showing how to round a b. 68 rounded to the nearest hundred is 100 . three-digit number. Then solve problems 1–6. c. 945 rounded to the nearest ten is 950 . Example d. 945 rounded to the nearest hundred is 900 . Round 154 to the nearest ten. M 4 Rachel earned $164 babysitting last month. She earned $95 this month. Rachel rounded each 150 151 152 153 154 155 156 157 158 159 160 amount to the nearest $10 to estimate how much 154 is between 150 and 160. It is closer to 150. she earned. What is each amount rounded to the 154 rounded to the nearest ten is 150. nearest $10? Show your work. Round 154 to the nearest hundred. Student work will vary. Students might draw number lines, a hundreds chart, or explain in words. 100 110 120 130 140 150 160 170 180 190 200 Solution: ___________________________________$160 and $100 154 is between 100 and 200. It is closer to 200. C 5 Use the digits in the tiles to create a number that 154 rounded to the nearest hundred is 200. makes each statement true. Use each digit only once. B 1 Round 236 to the nearest ten. 1 2 3 4 5 6 7 8 9 Which tens is 236 between? Possible answer shown.
    [Show full text]
  • Sabermetrics: the Past, the Present, and the Future
    Sabermetrics: The Past, the Present, and the Future Jim Albert February 12, 2010 Abstract This article provides an overview of sabermetrics, the science of learn- ing about baseball through objective evidence. Statistics and baseball have always had a strong kinship, as many famous players are known by their famous statistical accomplishments such as Joe Dimaggio’s 56-game hitting streak and Ted Williams’ .406 batting average in the 1941 baseball season. We give an overview of how one measures performance in batting, pitching, and fielding. In baseball, the traditional measures are batting av- erage, slugging percentage, and on-base percentage, but modern measures such as OPS (on-base percentage plus slugging percentage) are better in predicting the number of runs a team will score in a game. Pitching is a harder aspect of performance to measure, since traditional measures such as winning percentage and earned run average are confounded by the abilities of the pitcher teammates. Modern measures of pitching such as DIPS (defense independent pitching statistics) are helpful in isolating the contributions of a pitcher that do not involve his teammates. It is also challenging to measure the quality of a player’s fielding ability, since the standard measure of fielding, the fielding percentage, is not helpful in understanding the range of a player in moving towards a batted ball. New measures of fielding have been developed that are useful in measuring a player’s fielding range. Major League Baseball is measuring the game in new ways, and sabermetrics is using this new data to find better mea- sures of player performance.
    [Show full text]
  • Molecular Symmetry
    Molecular Symmetry Symmetry helps us understand molecular structure, some chemical properties, and characteristics of physical properties (spectroscopy) – used with group theory to predict vibrational spectra for the identification of molecular shape, and as a tool for understanding electronic structure and bonding. Symmetrical : implies the species possesses a number of indistinguishable configurations. 1 Group Theory : mathematical treatment of symmetry. symmetry operation – an operation performed on an object which leaves it in a configuration that is indistinguishable from, and superimposable on, the original configuration. symmetry elements – the points, lines, or planes to which a symmetry operation is carried out. Element Operation Symbol Identity Identity E Symmetry plane Reflection in the plane σ Inversion center Inversion of a point x,y,z to -x,-y,-z i Proper axis Rotation by (360/n)° Cn 1. Rotation by (360/n)° Improper axis S 2. Reflection in plane perpendicular to rotation axis n Proper axes of rotation (C n) Rotation with respect to a line (axis of rotation). •Cn is a rotation of (360/n)°. •C2 = 180° rotation, C 3 = 120° rotation, C 4 = 90° rotation, C 5 = 72° rotation, C 6 = 60° rotation… •Each rotation brings you to an indistinguishable state from the original. However, rotation by 90° about the same axis does not give back the identical molecule. XeF 4 is square planar. Therefore H 2O does NOT possess It has four different C 2 axes. a C 4 symmetry axis. A C 4 axis out of the page is called the principle axis because it has the largest n . By convention, the principle axis is in the z-direction 2 3 Reflection through a planes of symmetry (mirror plane) If reflection of all parts of a molecule through a plane produced an indistinguishable configuration, the symmetry element is called a mirror plane or plane of symmetry .
    [Show full text]
  • Call Numbers
    Call numbers: It is our recommendation that libraries NOT put J, +, E, Ref, etc. in the call number field in front of the Dewey or other call number. Use the Home Location field to indicate the collection for the item. It is difficult if not impossible to sort lists if the call number fields aren’t entered systematically. Dewey Call Numbers for Non-Fiction Each library follows its own practice for how long a Dewey number they use and what letters are used for the author’s name. Some libraries use a number (Cutter number from a table) after the letters for the author’s name. Other just use letters for the author’s name. Call Numbers for Fiction For fiction, the call number is usually the author’s Last Name, First Name. (Use a comma between last and first name.) It is usually already in the call number field when you barcode. Call Numbers for Paperbacks Each library follows its own practice. Just be consistent for easier handling of the weeding lists. WCTS libraries should follow the format used by WCTS for the items processed by them for your library. Most call numbers are either the author’s name or just the first letters of the author’s last name. Please DO catalog your paperbacks so they can be shared with other libraries. Call Numbers for Magazines To get the call numbers to display in the correct order by date, the call number needs to begin with the date of the issue in a number format, followed by the issue in alphanumeric format.
    [Show full text]
  • Minorities and Women in Television See Little Change, While Minorities Fare Worse in Radio
    RunningRunning inin PlacePlace Minorities and women in television see little change, while minorities fare worse in radio. By Bob Papper he latest figures from the RTNDA/Ball State Uni- Minority Population vs. Minority Broadcast Workforce versity Annual Survey show lit- 2005 2004 2000 1995 1990 tle change for minorities in tel- evision news in the past year but Minority Population in U.S. 33.2% 32.8% 30.9% 27.9% 25.9% slippage in radio news. Minority TV Workforce 21.2 21.8 21.0 17.1 17.8 TIn television, the overall minority Minority Radio Workforce 7.9 11.8 10.0 14.7 10.8 workforce remained largely un- Source for U.S. numbers: U.S. Census Bureau changed at 21.2 percent, compared with last year’s 21.8 percent. At non-Hispanic stations, the the stringent Equal Employment minority workforce in TV news is up minority workforce also remained Opportunity rules were eliminated in 3.4 percent. At the same time, the largely steady at 19.5 percent, com- 1998. minority population in the U.S. has pared with 19.8 percent a year ago. News director numbers were increased 7.3 percent. Overall, the After a jump in last year’s minority mixed, with the percentage of minor- minority workforce in TV has been at radio numbers, the percentage fell this ity TV news directors down slightly to 20 percent—plus or minus 3 per- year.The minority radio news work- 12 percent (from 12.5 percent last cent—for every year in the past 15.
    [Show full text]
  • Precise Radioactivity Measurements a Controversy
    http://cyclotron.tamu.edu Precise Radioactivity Measurements: A Controversy Settled Simultaneous measurements of x-rays and gamma rays emitted in radioactive nuclear decays probe how frequently excited nuclei release energy by ejecting an atomic electron THE SCIENCE Radioactivity takes several different forms. One is when atomic nuclei in an excited state release their excess energy (i.e., they decay) by emitting a type of electromagnetic radiation, called gamma rays. Sometimes, rather than a gamma ray being emitted, the nucleus conveys its energy electromagnetically to an atomic electron, causing it to be ejected at high speed instead. The latter process is called internal conversion and, for a particular radioactive decay, the probability of electron emission relative to that of gamma-ray emission is called the internal conversion coefficient (ICC). Theoretically, for almost all transitions, the ICC is expected to depend on the quantum numbers of the participating nuclear excited states and on the amount of energy released, but not on the sometimes obscure details of how the nucleus is structured. For the first time, scientists have been able to test the theory to percent precision, verifying its independence from nuclear structure. At the same time, the new results have guided theorists to make improvements in their ICC calculations. THE IMPACT For the decays of most known excited states in nuclei, only the gamma rays have been observed, so scientists have had to combine measured gamma-ray intensities with calculated ICCs in order to put together a complete picture known as a decay scheme, which includes the contribution of electron as well as gamma-ray emission, for every radioactive decay.
    [Show full text]
  • Multiplication As Comparison Problems
    Multiplication as Comparison Problems Draw a model and write an equation for the following: a) 3 times as many as 9 is 27 b) 40 is 4 times as many as 10 c) 21 is 3 times as many as 7 A Write equations for the following: a) three times as many as four is twelve b) twice as many as nine is eighteen c) thirty-two is four times as many as eight B Write a comparison statement for each equation: a) 3 x 7 = 21 b) 8 x 3 = 24 c) 5 x 4 = 20 ___ times as many as ___ is ___. C Write a comparison statement for each equation a) 45 = 9 x 5 b) 24 = 6 x 4 c) 18 = 2 x 9 ___ is ___ times as many as ___. ©K-5MathTeachingResources.com D Draw a model and write an equation for the following: a) 18 is 3 times as many as 6 b) 20 is 5 times as many as 4 c) 80 is 4 times as many as 20 E Write equations for the following: a) five times as many as seven is thirty-five b) twice as many as twelve is twenty-four c) four times as many as nine is thirty-six F Write a comparison statement for each equation: a) 6 x 8 = 48 b) 9 x 6 = 54 c) 8 x 7 = 56 ___ times as many as ___ is ___. G Write a comparison statement for each equation: a) 72 = 9 x 8 b) 81 = 9 x 9 c) 36 = 4 x 9 ___ is ___ times as many as ___.
    [Show full text]
  • Girls' Elite 2 0 2 0 - 2 1 S E a S O N by the Numbers
    GIRLS' ELITE 2 0 2 0 - 2 1 S E A S O N BY THE NUMBERS COMPARING NORMAL SEASON TO 2020-21 NORMAL 2020-21 SEASON SEASON SEASON LENGTH SEASON LENGTH 6.5 Months; Dec - Jun 6.5 Months, Split Season The 2020-21 Season will be split into two segments running from mid-September through mid-February, taking a break for the IHSA season, and then returning May through mid- June. The season length is virtually the exact same amount of time as previous years. TRAINING PROGRAM TRAINING PROGRAM 25 Weeks; 157 Hours 25 Weeks; 156 Hours The training hours for the 2020-21 season are nearly exact to last season's plan. The training hours do not include 16 additional in-house scrimmage hours on the weekends Sep-Dec. Courtney DeBolt-Slinko returns as our Technical Director. 4 new courts this season. STRENGTH PROGRAM STRENGTH PROGRAM 3 Days/Week; 72 Hours 3 Days/Week; 76 Hours Similar to the Training Time, the 2020-21 schedule will actually allow for a 4 additional hours at Oak Strength in our Sparta Science Strength & Conditioning program. These hours are in addition to the volleyball-specific Training Time. Oak Strength is expanding by 8,800 sq. ft. RECRUITING SUPPORT RECRUITING SUPPORT Full Season Enhanced Full Season In response to the recruiting challenges created by the pandemic, we are ADDING livestreaming/recording of scrimmages and scheduled in-person visits from Lauren, Mikaela or Peter. This is in addition to our normal support services throughout the season. TOURNAMENT DATES TOURNAMENT DATES 24-28 Dates; 10-12 Events TBD Dates; TBD Events We are preparing for 15 Dates/6 Events Dec-Feb.
    [Show full text]
  • Season 6, Episode 4: Airstream Caravan Tukufu Zuberi
    Season 6, Episode 4: Airstream Caravan Tukufu Zuberi: Our next story investigates the exotic travels of this vintage piece of Americana. In the years following World War II, Americans took to the open road in unprecedented numbers. A pioneering entrepreneur named Wally Byam seized on this wanderlust. He believed his aluminium-skinned Airstream trailers could be vehicles for change, transporting Americans to far away destinations, and to a new understanding of their place in the world. In 1959, he dreamt up an outlandish scheme: to ship 41 Airstreams half way around the globe for a 14,000-mile caravan from Cape Town to the pyramids of Egypt. Nearly 50 years later, Doug and Suzy Carr of Long Beach, California, think these fading numbers and decal may mean their vintage Airstream was part of this modern day wagon train. Suzy: We're hoping that it's one of forty-one Airstreams that went on a safari in 1959 and was photographed in front of the pyramids. Tukufu: I’m Tukufu Zuberi, and I’ve come to Long Beach to find out just how mobile this home once was. Doug: Hi, how ya doing? Tukufu: I'm fine. How are you? I’m Tukufu Zuberi. Doug: All right. I'm Doug Carr. This is my wife Suzy. Suzy: Hey, great to meet you. Welcome to Grover Beach. Tukufu: How you doing? You know, this is a real funky cool pad. Suzy: It's about as funky as it can be. Tukufu: What do you have for me? Suzy: Well, it all started with a neighbor, and he called over and said, “I believe you have a really famous trailer.” He believed that ours was one of a very few that in 1959 had gone on a safari with Wally Byam.
    [Show full text]
  • Symmetry Numbers and Chemical Reaction Rates
    Theor Chem Account (2007) 118:813–826 DOI 10.1007/s00214-007-0328-0 REGULAR ARTICLE Symmetry numbers and chemical reaction rates Antonio Fernández-Ramos · Benjamin A. Ellingson · Rubén Meana-Pañeda · Jorge M. C. Marques · Donald G. Truhlar Received: 14 February 2007 / Accepted: 25 April 2007 / Published online: 11 July 2007 © Springer-Verlag 2007 Abstract This article shows how to evaluate rotational 1 Introduction symmetry numbers for different molecular configurations and how to apply them to transition state theory. In general, Transition state theory (TST) [1–6] is the most widely used the symmetry number is given by the ratio of the reactant and method for calculating rate constants of chemical reactions. transition state rotational symmetry numbers. However, spe- The conventional TST rate expression may be written cial care is advised in the evaluation of symmetry numbers kBT QTS(T ) in the following situations: (i) if the reaction is symmetric, k (T ) = σ exp −V ‡/k T (1) TST h (T ) B (ii) if reactants and/or transition states are chiral, (iii) if the R reaction has multiple conformers for reactants and/or tran- where kB is Boltzmann’s constant; h is Planck’s constant; sition states and, (iv) if there is an internal rotation of part V ‡ is the classical barrier height; T is the temperature and σ of the molecular system. All these four situations are treated is the reaction-path symmetry number; QTS(T ) and R(T ) systematically and analyzed in detail in the present article. are the quantum mechanical transition state quasi-partition We also include a large number of examples to clarify some function and reactant partition function, respectively, without complicated situations, and in the last section we discuss an rotational symmetry numbers, and with the zeroes of energy example involving an achiral diasteroisomer.
    [Show full text]