Orbital evidence for clay and acidic sulfate assemblages on Mars based on mineralogical analogs from Rio Tinto, Spain
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Citation Kaplan, Hannah H., Ralph E. Milliken, David Fernández-Remolar, Ricardo Amils, Kevin Robertson, and Andrew H. Knoll. 2016. “Orbital Evidence for Clay and Acidic Sulfate Assemblages on Mars Based on Mineralogical Analogs from Rio Tinto, Spain.” Icarus 275 (September): 45–64. doi:10.1016/j.icarus.2016.03.019.
Published Version doi:10.1016/j.icarus.2016.03.019
Citable link http://nrs.harvard.edu/urn-3:HUL.InstRepos:34391777
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RRTS - *- *0/,0 *0./$1$/49+- . -1/$*)+*/ )/$'9) 2/ -=-*&=/(*.+# - RRTT $)/ -/$*)*)-.< RRTU VQ RRTV %"! RRTW # 0/#*-.2*0' '$& /*&)*2' " /# .0++*-/*!/# ./-*$*'*"4 RRTX )./$/0/ E / (92- RTZQF!*-!0) $)"/#$.2*-&< '.*/#)& RRTY *#)0./- !*-+-*1$ $)"/# 4+ /) /# !' /) 3+ -$( )/ RRTZ *-/*-4E F!$'$/4!*-+-*1$ $)".*( *!/# .+ /-' /0. $)/#$. RRUQ ./0 4<*(( )/.!-*())*)4(*0.- 1$ 2 -) $5(+ # '+ /*$(+-*1 RRUR /#$.()0.-$+/) /# $- !!*-/.- "-$*0.'4&)*2' " <'' /0. $)/#$. RRUS ++ -- 1$'' 0+*)- ,0 .//#-*0"#/# *-- .+*) $)"0/#*- RRUT E ))#M +')N-*2)< 0F< RRUU RRUV ! RRUW RRUX Altheide, T.S., Chevrier, V.F., Noe Dobrea, E., 2010. Mineralogical characterization of acid weathered RRUY phyllosilicates with implications for secondary martian deposits. 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USGS spectrum: Jarosite (GDS98K) RTVU RTVV # ,( !' /) .+ /-*!($) -'.2$/#.*-+/$*). /2 )S VV & ' ( ) ! * " + " , " - " . " &% " && " &' &( &) &* &+ " & &, ! " ' &- ! " ' &. " ' '% ! " ' '& " ' '' " ' '( " ' ') '* '+ ', ! '- '. (% (& (' (( RTWS () RTWT RTWU ,(!0'''$./*!.(+' .*'' / //# (* -)./- ( 9'*2 -) 0++ - RTWV / -- ./$*$)/*<''.(+' .- -*&.0)' ..*/# -2$. )*/ <#.(+' $. RTWW ( .0- 2$/#/# 9 9) $)/# '*-/*-4<(+' .2$/#.+ /-' RTWX *0' /) /#*. /#/#1 ))'45 2$/#$ /1 ' - !$) ( )/- )*/ < RTWY VW RTWZ RTXQ # -( -- .*!/# $*$)/*$)/# .# (/$ $"-(!-*( -)) 5= RTXR (*'- /'<ESQQVF- (/# 2$/#'*/$*).$)/# 4+ -$'#4+ -.+ /-' RTXS $(" *!/# - "$*)/#/2 - .(+' $)/#$../0 4< RTXT VX RTXU RTXV RTXW # .(+-$)$+'*(+*) )/.)'4.$.#. )--$ *0/*)/# .( 4+ RTXX $(" .. )$)$"0- S9) '$& *'*-.$)/# $(" *-- .+*) /*- "$*).*! RTXY .+ /-'.$($'-$/4E^) X9^) T9^) VF<# .+ /-' *0' /$. RTXZ ..*$/ 2$/#0)$/./#/++ -$) -&- *'*-$)/#$.!'. =*'*-$(" 92#$# RTYQ $.+-/$0'-'4 1$ )//) '@.- )E$). /F2# - )0( -*!/# *0' /= RTYR -$)".(+' .2 - *'' / <-$/$*)$)/# .+ /-' *0' /!-*(S VY RTYW -((+' .) *-$"$)*!.(+' ./#/2 - )'45 0.$)") RTYX - !' /) .+ /-*.*+4<# %-*.$/ ) '='4E(0.*1$/ C$''$/ F*)/ )/*! # RTYY .(+' 2. ./$(/ 0.$)"$ /1 ' - !$) ( )/*)/# +// -).< RTYZ RTZQ Band Centers 2000 1500 1000 Noise Counts 0.015 500 0 2.1 2.2 2.3 0.01 Wavelength of Band Center Noise 0.005 2500 2000 0 1500 Counts 1000 500 1 km 0 0 0.005 0.01 0.015 Standard Deviation (from 1.7 - 1.85 +m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arosite (%)/Al-clay (%) = 0.17 Sample Fit Error Jarosite (%)/Al-clay (%) = 0.74 Jarosite (%)/Al-clay (%) = 3.15 Goethite Muscovite/ Jarosite Quartz Illite RUSQ RUSR # 1(+// -).2$/#*-- .+*) $)"- !' /) .+ /-!-*(/#- RUSS +*2 - .(+' .2$/# $!! - )/+-*+*-/$*).*!%-*.$/ ) '='4ERR9RV9 RUST RWF<%*-+#. .- ' ' !*-/# +// -).) .*-+/$*). RUSU *-- .+*) $)"/*/# *0' /! /0- - (-& 4- --*2.$)/# - !' /) RUSV .+ /-+'*/.< RUSW WR RT19 RT10 RUSX RUSY # 2(3(+' - !' /) .+ /-,0$- $)/# !$ ' ) !*-#) .(+' 9 RUSZ #$+9) +*2 -1 -.$*).*!/2*.(+' .!-*( $!! - )/'*/$*).2$/#$)/# ./0 4 RUTQ - "$*)<#$+.- _Z(($) $( / -) +*2 -.2 - .$ 1 /*_UVc(<+ /-*! RUTR /# . .(+' .#$"#'$"#//# 1-$/$*)$).*'0/ - !' /) ) ) +/#*!/# RUTS /2*.*-+/$*).$)/# *0' /! /0- 2# )( .0- / $!! - )/.+/$'.' .< RUTT ) .(+' RQ#.1-)$.# .0-! !*-2#$#/# - !' /) .+ /- 3#$$/ RUTU ' - *0' /! /0- 92# - ..+ /-!-*(/# $)/ -$*-+*-/$*). 3#$$/(0# RUTV 2 & -'*)"=21 ' )"/#E%-*.$/ F.*-+/$*)< RUTW Relative Band Depth vs. Al-Clay vs. Band Depth 1 1 XRD Peak Area 100 RT10 2 2 0.8 R 80 R RT11 0.6 60 RT9 0.4 40 $OFOD\ ZW 0.2 20 0 0 0 0.2 0.4 0.6 0.8 1 0 0.02 0.04 0.06 0.08 RT26 $OïFOD\ $OïFOD\-DURVLWH %DQG'HSWKDWPLFURQV Relative Band Depth vs. XRD Reitveld Refinement Jarosite vs. Band Depth 2 RT16 1 100 R2 0.8 2 RT19 80 R RT12 0.6 60 RT15 0.4 40 0.2 -DURVLWH ZW 20 0 0 0 0.2 0.4 0.6 0.8 1 0 0.02 0.04 0.06 0.08 $OïFOD\ $OïFOD\-DURVLWH %DQG'HSWKDWPLFURQV %DQG'HSWK %DQG'HSWK RUTX WS RUTY # 3(*(+-$.*)*!- .0'/.2$/#- !' /) .+ /-E) +/#.F/* RUTZ .#*2- '/$*).#$+ /2 )($) -'0) ) .) /# .*-+/$*)! /0- RUUQ ./- )"/#< $- /- '/$*).#$+ /2 )- '/$1 (*0)/.*!%-*.$/ ) '='4) RUUR /# ./- )"/#.*!/# .*-+/$*)! /0- .$) $/ ./# .#*-/ -21 ' )"/# RUUS .*-+/$*)E) R:LS WT RUVT A 50 km FRT00009B27 FRT0000A396 FRT0000AD3D 5 km 5 km 5 km B 4 4 x10 Band Centers x10 Band Centers 4 Band Centers C 6 8 9x10 5 7 8 6 7 4 5 6 3 4 5 Counts 4 Counts Counts 3 2 3 2 1 2 1 1 0 0 0 2.15 2.2 2.25 2. 3 2.15 2.2 2.25 2. 3 2.15 2.2 2.25 2.3 Wavelength of Band Center Wavelength of Band Center Wavelength of Band Center Relative Amplitude Relative Amplitude Relative Amplitude 4 4 x104 of Absorptions x10 of Absorptions x10 of Absorptions D 2 2.5 2.5 Jarosite Al-Clay 2 Rich Rich 1 Counts 1 Counts 1 Counts 0 0 0 1 2 3 4 5 0 1 2 3 4 5 0 1 2 3 4 5 Band 1 Amp./ Band 2 Amp. Band 1 Amp./ Band 2 Amp. Band 1 Amp./ Band 2 Amp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RVRT $)"(*- %-*.$/ -$#$)$"0- Y) ++ -./* ./-/$"-+#$''4'*2 -/#) RVRU /# '$"#/=/*) 0)$/< /$.)*/+*..$' /* / -($) /# 3/- '/$*).#$+ /2 ) RVRV /#$.-$"#/(/ -$') /# -&9./-/$!$ '4 +*.$/$)/#$.'*/$*)90/$)*/# - RVRW - "$*).$/++ -..$!/# -$"#/ ./E%-*.$/ =-$#F(/ -$'$../-/$"-+#$''4 RVRX *1 /# '4= -$)"./-/<# - !*- 9/# $)- .$)"./-/$"-+#$*- -++ -. RVRY /* ; -&E'4= -$)"F./-/`-$"#/ ./0)$/`'$"#/=/*) 0)$/`(* -/ = RVRZ /*) 0)$/<# *-- .+*) $)"($) -'*"4$.*).$./ )/2$/#;'4=-$#`(*- RVSQ %-*.$/ =-$#` ,0''=+#4''*.$'$/ ) %-*.$/ `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a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b0/) ,0$++ 2$/# $!! - )/ RVXY !*- *+/$./*- 0 /# /*..(''.Rb<$ ' .+ /-( .0- /$*$)/* RVXZ 0.$)".*'-- $/$*)2 - ,0$- 0.$)"Vb!*- *+/$2$/#/4+$'./) *!! RVYQ $./) *!LR(!-*(/# /-" /*!$)/ - ./<# *)//+-* 0. .)$)/ -)' RVYR ,0-/5=/0)"./ )=#'*" )E F0'!*-$''0($)/$*)) ( .0- ..+*/.$5 *! RVYS LRQ((<# *)//+-* #./# 1)/" /#/1$ 2$)"C$''0($)/$*)" *( /-4 RVYT $.!$3 ) /#0.$ )/$'!*-''( .0- ( )/.< RVYU RVYV ,(. ! % ! " ! RVYW # '$"#/.*0- !*-/# '*-/*-4- !' /) ( .0- ( )/.2$/#/# RVYX $ ' + *).$./ *!) )'*. 0'$)*($)/$*)2$/#!$ -*+/$' RVYY /#/#.SVb<# .*0- !$ -2.+*.$/$*) /*#1 )/-'$)$ ) )"' RVYZ *!TQbE!-*()*-('F) /# - $1$)"!$ -E//# /*/# .+ /-*( / -F2. RVZQ +*.$/$*) /*#1 )/-' ( -" ) )"' *!Qb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asciano, L.C., Peterson, R.C., 2008. Crystal chemistry of the natrojarosite-jarosite and natrojarosite- RWRQ hydronium jarosite solid-solution series: A synthetic study with full Fe site occupancy. American RWRR Mineralogist 93, 853–862. doi:10.2138/am.2008.2731 RWRS Basciano, L.C., Peterson, R.C., 2007. Jarosite hydronium jarosite solid-solution series with full iron site RWRT occupancy: Mineralogy and crystal chemistry. American Mineralogist 92, 1464–1473. RWRU doi:10.2138/am.2007.2432 RWRV Bayliss, P., 1977. Crystal structure refinement of a weakly anisotropic pyrite. American Mineralogist 62, RWRW 1168–1172. RWRX Birle, J.D., 1968. Refined Muscovite Structure. Mineralogical Magazine 36, 883–886. RWRY doi:10.1180/minmag.1968.036.282.24 RWRZ Boeyens, J.C.A., Ichharam, V.V.H., 2002. Redetermination of the crystal structure of calcium sulphate RWSQ dihydrate, CaSO4 · 2H2O. Zeitschrift für Kristallographie - New Crystal Structures 217. RWSR doi:10.1524/ncrs.2002.217.jg.9 RWSS Brigatti, M.F., Frigieri, P., Luciano, P., 1998. Crystal chemistry of Mg-, Fe-bearing muscovites 2M1. RWST American Mineralogist 83, 775–785. RWSU Gualtieri, A.F., 2000. Accuracy of XRPD QPA using the combined Rietveld–RIR method. Journal of RWSV Applied Crystallography 33, 267–278. doi:10.1107/S002188989901643X RWSW Levien, L., Prewitt, C.T., Weidner, D.J., 1980. Structure and elastic properties of quartz at pressure. RWSX American Mineralogist 65, 920–930. XR RWSY Ransom, B., Bennett, R.H., Baerwald, R., Shea, K., 1997. TEM study of in situ organic matter on RWSZ continental margins: occurrence and the “monolayer” hypothesis. Marine Geology 138, 1–9. RWTQ doi:10.1016/S0025-3227(97)00012-1 RWTR Scarlett, N.V.Y., Grey, I.E., Brand, H.E.A., 2010. Ordering of iron vacancies in monoclinic jarosites. RWTS American Mineralogist 95, 1590–1593. doi:10.2138/am.2010.3591 RWTT Yang, H., Lu, R., Downs, R.T., Costin, G., 2006. Goethite, α-FeO(OH), from single-crystal data. Acta RWTU Crystallographica Section E Structure Reports Online 62, i250–i252. RWTV doi:10.1107/S1600536806047258 RWTW Zanazzi, P.F., Montagnoli, M., Nazzareni, S., Comodi, P., 2007. Structural effects of pressure on RWTX monoclinic chlorite: A single-crystal study. American Mineralogist 92, 655–661. RWTY doi:10.2138/am.2007.2341 RWTZ XS