1 Orbital Evidence for Clay and Acidic Sulfate Assemblages on Mars Based on 2 Mineralogical Analogs from Rio Tinto, Spain 3 4 Hannah H. Kaplan1*, Ralph E. Milliken1, David Fernández-Remolar2, Ricardo Amils3, 5 Kevin Robertson1, and Andrew H. Knoll4 6 7 Authors: 8 9 1 Department of Earth, Environmental and Planetary Sciences, Brown University, 10 Providence, RI, 02912 USA. 11 12 2British Geological Survey, Nicker Hill, Keyworth, NG12 5GG, UK. 13 14 3 Centro de Astrobiologia (INTA-CSIC), Ctra Ajalvir km 4, Torrejon de Ardoz, 28850, 15 Spain. 16 17 4 Department of Organismic and Evolutionary Biology, Harvard University, 18 Çambridge, MA, USA. 19 20 *Corresponding author:
[email protected] 1 21 Abstract 22 23 Outcrops of hydrated minerals are widespread across the surface of Mars, 24 with clay minerals and sulfates being commonly identified phases. Orbitally-based 25 reflectance spectra are often used to classify these hydrated components in terms of 26 a single mineralogy, although most surfaces likely contain multiple minerals that 27 have the potential to record local geochemical conditions and processes. 28 Reflectance spectra for previously identified deposits in Ius and Melas Chasma 29 within the Valles Marineris, Mars, exhibit an enigmatic feature with two distinct 30 absorptions between 2.2 – 2.3 µm. This spectral ‘doublet’ feature is proposed to 31 result from a mixture of hydrated minerals, although the identity of the minerals has 32 remained ambiguous. Here we demonstrate that similar spectral doublet features 33 are observed in airborne, field, and laboratory reflectance spectra of rock and 34 sediment samples from Rio Tinto, Spain.