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A Practical Guide: Reducing Mercury Use in Artisanal and Small-Scale Gold Mining

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A Practical Guide: Reducing Mercury Use in Artisanal and Small-Scale Gold Mining A PRACTICAL GUIDE REDUCING MERCURY USE IN ARTISANAL AND SMALL-SCALE GOLD MINING CommissionIUGS-GEM on Geoscience for Environmental Management Copyright © United Nations Environment Programme, 2012 A UNEP Global Mercury Partnership document produced in conjunction with the Artisanal Gold Council and with assistance from UNIDO, University of Victoria, and the International Union of Geosciences Commission on geosciences for Environmental Management (IUGS-GEM); 2012. The primary authors of this document are Kevin Telmer and Daniel Stapper of the Artisanal Gold Council (AGC). All of the photographs and images in the document with the exception of those specifically indicated are property of the Artisanal Gold Council and can not be used without permission. This publication may be reproduced in whole or in part and in any form for educational or non- profit purposes with special permission from the copyright holder, provided acknowledgement of the source is made. UNEP would appreciate receiving a copy of any publication that uses this publication as a source. No use of this publication may be made for resale or for any other commercial purpose whatsoever without prior permission in writing from the United Nations Environment Programme. Disclaimer The designations employed and the presentation of the material in this publication do not imply the expression of any opinion whatsoever on the part of the United Nations Environment Programme concerning the legal status of any country, territory, city or area or of its authorities, or concerning delimitation of its frontiers or boundaries. Moreover, the views expressed do not necessarily represent the decision or the stated policy of the United Nations Environment Programme, nor does citing of trade names or commercial processes constitute endorsement. Reducing Mercury Use in Artisanal and Small-scale Gold Mining A Practical Guide A UNEP Global Mercury Partnership document produced in conjunction with Artisanal Gold Council. www.artisanalgoldcouncil.org Table of Contents The Basics Perspective . .page 7 Who can use this document? .....................page 7 Why worry about mercury? .......................page 8 Worldwide mercury consumption and emissions ......page 9 How is mercury used to capture gold? .............page 10 Health risk to miners and families .................page 12 CHAPTER 1 - Mercury use in detail 1.1 Whole ore amalgamation ....................page 16 1.2 Concentrate amalgamation ...................page 18 CHAPTER 2 - Solutions 2.1 Identifying appropriate solutions . page 21 Solutions chart - which solutions work? .........page 22 2.2 Mining and concentration ....................page 24 Gold liberation.............................page 24 The importance of grain size..................page 26 2.3 Improving concentration .....................page 28 Sluices ..................................page 30 Centrifuges . page 32 Spiral concentrators ........................page 34 Vortex ...................................page 35 Shaking tables . page 36 Flotation .................................page 37 Magnets .................................page 38 Reducing mercury use in artisanal and small-scale gold mining 4 2.4 Processing and refining. ...........................page 40 Avoiding open air burning of amalgam ...........page 40 2.5 Improving processing and refining. .. .. .. page 42 Retorts.........................................page 42 Fume hoods .. ... ... ... ... ... ... ... ... ... ... ... page 44 Mercury activation . .. .. .. .. .. .. .. .. .. .. page 46 2.6 Eliminating mercury use: zero-mercury processes. page 48 Gravity only . .. .. .. .. .. .. .. .. .. .. .. .. page 48 Direct smelting . .. .. .. .. .. .. .. .. .. .. .. page 50 Chemical leaching as an alternative to mercury. .. page 54 Model of a mercury-free processing plant .. ... ... page 56 2.7 Related topics .....................................page 60 Gold deposit type, exploration and planning . .. .. page 60 Purifying gold - the quartering method .. ... ... ... page 61 Mercury use before cyanidation .. ... ... ... ... ... page 64 Waste management and contaminated sites .. ... page 66 Annex 1. Summary of the ASGM sector .................page 68 Annex 2. Relative costs of technical interventions........page 69 Annex 3. UNIDO Technical Guidelines on mercury . .. page 70 Pieces of ‘sponge gold’ in this photograph are the result of mercury amalgamation. Each piece of sponge gold represents a day of work for a group of miners. The large ball in the foreground, is 8 grams - worth 385 USD, at a price of 1500 USD/ounce. Reducing mercury use in artisanal and small-scale gold mining 5 Miners attending a training session in Mozambique Artisanal and small-scale gold mining (ASGM) is an important development opportunity which can contribute directly to poverty alleviation and regional development. Although social and environmental problems are common in this sector, there is also an opportunity to transform mineral wealth into lasting local development. Reducing6 mercury use in artisanal and small-scale gold mining 6 Perspective 1. Gold can represent an excellent method of transferring wealth to rural communities: small-scale producers often get 70% or more of international prices, even in remote areas. This is much higher than other products such as coffee, bananas, etc. 2. Artisanal and small-scale gold mining (ASGM) needs to be brought into the formal economy to maximize benefits and enable improvements 3. In order to comply with modern environmental standards, reducing mercury use is a key step in realizing ASGM development opportunities Who can use this document? Policy makers, miners and civil society can use this document to learn about technologies and approaches for reducing and eliminating mercury use in artisanal and small-scale gold mining (ASGM). Governments: • A simple educational and planning tool for technical aspects of intervention programs and policy considerations • A decision tool to understand best practice options • An explanation of the technical fundamentals that underpin and encourage formalization of the ASGM sector Miners: • A graphic introduction of best practices • A guide on how local conditions influence possible improvements in mining practices • An explanation of barriers to be overcome to improve practices and reduce mercury use Civil society: • An educational tool to better understand ASGM • An explanation of barriers that mining communities face when trying to improve mining practices and reduce mercury use Reducing7 mercury use in artisanal and small-scale gold mining 7 Why worry about mercury? Mercury is a powerful neurotoxin that is harmful to people, but especially to developing fetuses, and young children. Once emitted, mercury can travel great distances through the atmosphere, causing global contamination of ecosystems, fish, birds, mammals, and the human food chain. Worldwide, consumption of mercury contaminated seafood puts billions of people at risk of mercury poisoning, which affects brain and nervous system development and function. Local exposures in mining communities that use mercury can be even more acute. Reducing8 mercury use in artisanal and small-scale gold mining 8 Worldwide mercury consumption and emissions1 Electrical and Other (paints, cultural, electronic devices pharmaceutical) 7% 1% Mercury Demand Lighting (Annual Consumption) 4% Measuring and control devices ASGM Total = 4,167 tonnes 7% 24% ASGM is the single largest Dental Use demand for mercury in the 8% world. An estimated 1400 tonnes of mercury were used by Vinyl Chloride Batteries Monomer ASGM miners globally in 2011 13% 21% (www.mercurywatch.org). Chlorine production 15% *Subject to change Pig iron and steel, sec. steel, 3% Other waste, 4% Chlor alkali industry, 2% Mercury emissions to Dental amalgam (cremation)**, 1% atmosphere ASGM, 17% Other, 1% Mercury Total = 1,921 tonnes production, 0.5% Coal combustion in ASGM is the largest source Residential power plants and of mercury pollution to air and heating/other industrial boilers, combustion, 20% water combined. It is second 26% only to coal combustion as a source of worldwide mercury emission to the atmosphere Cement production, (illustrated in pie graph, left). 10% Non-ferrous metals (Cu, Zn, Pb), 7% Waste incineration, 2% Large scale gold production, 6% *Subject to change [1] United Nation Environment Programme, Summary of Supply, Trade and demand information on mercury. Reducing9 mercury use in artisanal and small-scale gold mining 9 How is mercury used to capture gold? When mercury is brought into contact with gold particles in sediments or crushed ore, it forms “amalgam” - a soft mixture of roughly 50% mercury and 50% gold. To recover gold from the amalgam, it is heated to evaporate the mercury, leaving the gold behind. Mercury is released into air, water, and soil in several of the steps of this process. 1. Rocks or sediment containing gold 2. If necessary, the ore is crushed (“ore”) are mined. to liberate gold particles. 4. Mercury is added to extract the 5. Amalgam is collected and heated, gold by forming an amalgam evaporating the mercury, and leaving (mixture of mercury + gold). a porous “sponge gold” product. Reducing10 mercury use in artisanal and small-scale gold mining 10 Note: Unlike many pollutants, Why is mercury used? mercury is an element- it cannot be broken down in the environment. The • Quick and easy element symbol for mercury is Hg. The • Independent - it can be used by one diamond symbol at right, is used here person independently
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